Determination of Fluorine in the Atmosphere Surrounded the Yellow Phosphorous Enterprise Using Ion Chromatography

2014 ◽  
Vol 507 ◽  
pp. 773-776
Author(s):  
Xin Yuan ◽  
Sen Lin Tian ◽  
Ming Jiang ◽  
Rong Rong Miao ◽  
Qian Wang ◽  
...  
Keyword(s):  
Ion Chromatography ◽  
Linear Response ◽  
Standard Addition ◽  
Peak Height ◽  
Yellow Phosphorus ◽  
Relative Standard ◽  
Sensitivity And Selectivity ◽  
R Value ◽  
Calm Wind

Ion chromatography (IC) method was applied to detection of fluorine in the atmosphere calm wind conditions at the area around the yellow phosphorus enterprise. The results indicated that the recovery of standard addition of Fluroide is 96.7%~100.6%. It gives a linear response of chromatographic peak height with respect to the fluoride in the range of 1~25 μg/mL, and the coefficient correlations R value is 0.9994. The concentration of Fluorine in the surrounding of yellow phosphorus enterprise ranging from 100~1500 m varies from 0.641~0.070 mg/m3. The relative standard deviation (RSD) of this method is between 2.10%~0.50%. This method is sensitivity and selectivity, low disturbance, and it is considered as a promising method for the detection of Fluorine surrounded yellow phosphorus enterprise.

scholarly journals Determination of Oxalate and Some Inorganic Anions in Green and Black Tea

2013 ◽  
Vol 67 (4-5) ◽  
pp. 429-432 ◽  
Author(s):  
Elena Yusenko ◽  
Evgeniya Polyntseva ◽  
Anna Lyzhova ◽  
Olga Kalyakina
Keyword(s):  
Oxalic Acid ◽  
Green Tea ◽  
Ion Chromatography ◽  
Black Tea ◽  
Inorganic Anions ◽  
Sample Treatment ◽  
Oxalate Concentration ◽  
Relative Standard ◽  
Oxalate Ions

Abstract Oxalate concentration differs in various daily consumed food products. The role of oxalic acid in the human body is very significant, as its compounds are responsible for the stability of biological membranes. However, insoluble calcium and magnesium oxalates can be accumulated in the body in the form of kidney stones. Oxalate concentration has been measured by high performance liquid, gas after derivatization and ion chromatography (IC). The most effective method for the simultaneous determination of oxalate and inorganic anions is ion chromatography with conductometric detection. Here, we report the results of the measurement of oxalic acid in bleak and green tea samples. Separation was performed by IC on an anion-exchange column Shodex IC SI-90 with surface-layer sorbent and conductimetric detection. The main analytical features of the method were: limit of detection of oxalic acid 0.03 mg/l, linear range 0.1-20 mg/l, correlation 0.9998, relative standard deviation 1%. The method did not need specific sample treatment and was successfully applied to the analysis of black and green tea samples. Oxalic acid was determined in the ranges 16.7-84 mg/l for green tea and 63-116 mg/l for black tea. Green tea contained lower oxalate ions concentration than black tea. The IC method has a lower detection limit for oxalate ions than HPLS and GC, ten and two times less, respectively

Analysis of Synthetic Antioxidant in Food by Capillary Electrophoresis

2011 ◽  
Vol 361-363 ◽  
pp. 1855-1858 ◽  
Author(s):  
Qian Xiang ◽  
Ying Gao
Keyword(s):  
Capillary Electrophoresis ◽  
Amperometric Detection ◽  
Peak Height ◽  
Butylated Hydroxyanisole ◽  
Applied Potential ◽  
Synthetic Antioxidant ◽  
Separation Potential ◽  
Relative Standard ◽  
Capillary Electrophoretic

A capillary electrophoretic assay for determining synthetic antioxidant butylated hydroxyanisole in food has been developed. The extraction with 70% (v/v) methanol quantitatively extracted synthetic antioxidant. The separation was carried out by CZE using phosphate at a separation potential of 18 kV. Amperometric detection was achieved with an applied potential of 0.60 V. A linear relationship between the peak height and the concentration of the analyte was found in the range 1.8-180 µg/mL for BHA, with correlation coefficient of 0.994. The relative standard deviations of migration time and peak height were 0.19 and 5.3 %, respectively. The method developed was successfully applied for the determination of synthetic antioxidant butylated hydroxyanisole in food. Recovery of butylated hydroxyanisole was 93%.

Liquid Chromatographic Determination of Quinine, Hydroquinine, Saccharin, and Sodium Benzoate in Quinine Beverages

1985 ◽  
Vol 68 (4) ◽  
pp. 782-784
Author(s):  
Leonard P Valenti
Keyword(s):  
Sodium Benzoate ◽  
Direct Injection ◽  
Chromatographic Determination ◽  
Peak Height ◽  
Relative Standard ◽  
Sodium Saccharin ◽  
Liquid Chromatographic Determination ◽  
Liquid Chromatographic ◽  
The Relationship

Abstract A liquid chromatographic (LC) method is described for the determination of quinine, hydroquinine, sodium saccharin, and sodium benzoate in soft drinks. The method involves simple sample preparation, direct injection onto an octadecylsilane column, and elution with a methanol-acetonitrile-water-acetic acid (20 + 10 + 70 + 1) mobile phase. Eluted constituents are measured spectrophotometrically at 254 nm. The relationship between peak height and concentration was linear between 20 and 120 μg/mL for quinine. A relative standard deviation of 0.82% was obtained for commercial samples spiked with quinine, and the average recovery was 100.3%. The proposed procedure is accurate and rapid and can also detect hydroquinine (a natural contaminant of quinine), sodium saccharin, and sodium benzoate. Linear responses ranged from 0.45 to 20 (xg/mL for hydroquinine, from 54.8 to 219 μg/mL for sodium saccharin, and from 10.1 to 145.1 (ig/mL for sodium benzoate. The reproducibility of the LC method was evaluated with standard solutions of hydroquinine, sodium saccharin, and sodium benzoate, which produced relative standard deviations of 0.42, 0.46, and 1.13%, respectively. The average recoveries for sodium saccharin and sodium benzoate from spiked samples were 99.4 and 100.2%, respectively.

scholarly journals Determination of Platinum in Wine by Graphite Furnace Atomic Absorption Spectrometry

1997 ◽  
Vol 80 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Carmen Cabrera-Vique ◽  
Pierra-Louis Teissedre ◽  
Marie-Thérèse Cabanis ◽  
Jean-Claude Cabanis
Keyword(s):  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Graphite Furnace ◽  
Standard Addition ◽  
Absorption Spectrometry ◽  
Acid Digestion ◽  
White Wines ◽  
Relative Standard ◽  
Graphite Furnace Atomic Absorption

Abstract A method based on graphite furnace atomic absorption spectrometry (GFAAS) was developed for determining platinum in wine. Wine samples were prepared by microwave acid digestion or dry mineralization. The method of standard addition was used for Pt determination in untreated wine samples and mineralized samples. Analyte modifiers and furnace conditions were optimized. Effects of cations (Mg2+, Ca2+, K+, Na+, and NH|) and anions (PO43, SO42) were tested separately and in combination. Analytical characteristics of the method were optimized for analyte recovery and signal enhancement. Recoveries ranged from 92.5 to 102%, and precision reproducibility relative standard deviation varied from 7.5 to 10%. Red, rosé, and white wines from France were analyzed. Platinum levels found in most wines were very low (<10 μg/L).

scholarly journals Derivatization Ion Chromatography for the Determination of Monoethanolamine in Presence of Hydrazine in PHWR Steam-Water Circuits

2011 ◽  
Vol 2011 ◽  
pp. 1-5
Author(s):  
Ayushi D. ◽  
Arijit Sengupta ◽  
Sangita D. Kumar ◽  
A. G. Kumbhar ◽  
G. Venkateswaran
Keyword(s):  
Ion Chromatography ◽  
Mobile Phase ◽  
Limit Of Detection ◽  
Accurate Method ◽  
Feed Water ◽  
Relative Standard ◽  
Conductometric Detection ◽  
Mode A ◽  
Eluent Acetone

A simple, rapid and accurate method for the determination of monoethanolamine (MEA) in PHWR steam-water circuits has been developed. MEA is added in the feed water to provide protection against corrosion while hydrazine is added to scavenge dissolved oxygen. The quantitative determination of MEA in presence of hydrazine was accomplished using derivatization ion chromatography with conductometric detection in nonsuppressed mode. A Metrosep cation 1-2 analytical column and a Metrosep cartridge were used for cation separation. A mixture of 4 mM tartaric acid, 20% acetone and 0.05 mM HNO3was used as eluent. Acetone in the mobile phase leads to the formation of different derivatives with MEA and hydrazine. The interferences due Na+and NH4 +were eliminated by adopting a simple pretreatment procedure employing OnGuard-H cartridge. The limit of detection limit of MEA was 0.1 μg mL−1and the relative standard deviation was 2% for the overall method. The recovery of MEA added was in the range 95%–102%. The method was applied to the determination of MEA in steam generator water samples.

scholarly journals Determination of cyanide in bamboo shoots by microdiffusion combined with ion chromatography–pulsed amperometric detection

2018 ◽  
Vol 5 (4) ◽  
pp. 172128 ◽  
Author(s):  
Ming Ding ◽  
Kailiang Wang
Keyword(s):  
Ion Chromatography ◽  
Limit Of Detection ◽  
Correlation Coefficients ◽  
Amperometric Detection ◽  
High Sensitivity ◽  
Practical Method ◽  
Pulsed Amperometric Detection ◽  
Bamboo Shoots ◽  
Relative Standard

A practical method for the determination of cyanide in bamboo shoots has been developed using microdiffusion preparation integrated with ion chromatography–pulsed amperometric detection (IC-PAD). Cyanide was released from bamboo shoots after Conway cell microdiffusion, and then analysed by IC-PAD. In comparison with the previously reported methods, derivatization and ion-pairing agent addition were not required in this proposed microdiffusion combined with IC-PAD method. The microdiffusion parameters were optimized including hydrolysis systems, temperature, time, and so on. Under the optimum conditions, the linear range of the calibration curve for cyanide was 0.2–200.0 µg kg −1 with satisfactory correlation coefficients of 0.9996 and the limit of detection was 0.2 µg kg −1 ( S/N  = 3). The spiked recovery range was from 92.8 to 98.6%. The intra-day and inter-day relative standard deviations of cyanide were 2.7–14.9% and 3.0–18.3%, respectively. This method was proved to be convenient in operation with high sensitivity, precision and accuracy, and was successfully applied in the determination of cyanide in bamboo shoot samples.

scholarly journals Voltammetric Determination of Phenylalanine Using Chemically Modified Screen-Printed Based Sensors

Chemosensors ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 113
Author(s):  
Ancuta Dinu ◽  
Constantin Apetrei
Keyword(s):  
Prussian Blue ◽  
Direct Determination ◽  
Standard Addition ◽  
Pharmaceutical Products ◽  
Electrochemical Process ◽  
Pharmaceutical Samples ◽  
Analytical Recovery ◽  
Relative Standard ◽  
Screen Printed

This paper describes the sensitive properties of screen-printed carbon electrodes (SPCE) modified by using three different electroactive chemical compounds: Meldola’s Blue, Cobalt Phthalocyanine and Prussian Blue, respectively. It was demonstrated that the Prussian Blue (PB) modified SPCE presented electrochemical signals with the highest performances in terms of electrochemical process kinetics and sensitivity in all the solutions analyzed. PB-SPCE was demonstrated to detect Phe through the influence it exerts on the redox processes of PB. The PB-SPCE calibration have shown a linearity range of 0.33–14.5 µM, a detection limit (LOD) of 1.23 × 10−8 M and the standard deviation relative to 3%. The PB-SPCE sensor was used to determine Phe by means of calibration and standard addition techniques on pure samples, on simple pharmaceutical samples or on multicomponent pharmaceutical samples. Direct determination of the concentration of 4 × 10−6–5 × 10−5 M Phe in KCl solution showed that the analytical recovery falls in the range of 99.75–100.28%, and relative standard deviations in the range of 2.28–3.02%. The sensors were successfully applied to determine the Phe in pharmaceuticals. The validation of the method was performed by using the FTIR, and by comparing the results obtained by PB-SPCE in the analysis of three pharmaceutical products of different concentrations with those indicated by the producer.

The Removal of Interference from Microwave Digestion Solution of Industrial Wastewater on the Determination of Arsenic

2014 ◽  
Vol 587-589 ◽  
pp. 625-628
Author(s):  
Ming Ming Yang ◽  
Hong Wei An
Keyword(s):  
Detection Limit ◽  
Microwave Digestion ◽  
Hydride Generation ◽  
Standard Addition ◽  
Absorption Spectrometry ◽  
Quantitative Detection ◽  
Nitrite Ion ◽  
Digestion Solution ◽  
Relative Standard

In existing literature ,there is no unified time for the evaporating excessive acid to microwave digestion solution of different samples. a new method was developed .The interference from nitrite ion and volatile nitrogen oxides which were generated during digestion were quickly removed by the adding urea and heating with boiling water. The interference from nitrate was studied. Optimized conditions of determination of arsenic with hydride generation atomic absorption spectrometry. The detection limit was 0.3μg·L-1 and minimum quantitative detection limit was 1.0μg·L-1, the relative standard deviation of standard addition method in sample was 1.1% and recovery from 98 % to 102%.

4-Amino-Benzo[F]Isoindole-1,3-Dione Derivatives As Turn-On Fluorescent Indicators For Water Determination In Acetonitrile

2018 ◽  
pp. 183-191
Author(s):  
R. Linnik ◽  
I. Levkov ◽  
A. Chemnyi ◽  
O. Radchenko ◽  
Z. Voitenko ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Linear Response ◽  
Emission Peak ◽  
Water Determination ◽  
Fluorescent Indicators ◽  
Turn On ◽  
Peak Intensity ◽  
Relative Standard ◽  
Acetonitrile Solutions

4-Amino-9-(2,5-dioxo-pyrrolidin-1-phenyl-3-yl)-1-phenyl-benzo[f]isoindole-1,3-dione (1) and 4-amino-9-(2,5- dioxo-1-(4-methylphenyl)-pyrrolidin-3-yl)-1-(4-methylphenyl)-benzo[f]isoindole-1,3-dione (2) were studied as fluorescent indicators for water determination in acetonitrile. The intensity of fluorescence of these compounds in acetonitrile solutions increases in presence of water along with red shift of the emission peak. Intensity-based and wavelength-based procedures of water determination in acetonitrile are suggested with detection limit of 0.2 % (v/v) H2O in both cases. The linear response covers a concentration range of 0.2–20 % (v/v). The relative standard deviation at 1 % (v/v) water content is 0.20. The interferences of acetic acid, ammonia and metal ions have been studied. Ammonia and acetic acid don’t interfere with the determination of water by wavelength-based fluorescence technique. In intensity-based mode the determination of water is possible at concentration of these impurities up to 0.25 and 0.02 mol·L -1, respectively. Cu(II) ions have almost no effect on fluorescence of indicators up to 1·10 -5 mol·L -1 ; Zn (II) ions enhance fluorescence of 1 at concentration ≥ 5·10-6 mol·L-1 . The 4-amino-benzo[f]- isoindole-1,3-dione-based fluorescent indicators are pH-insensitive.

Determination of Ten Trace Element in River Deposit by ICP-OES

2013 ◽  
Vol 807-809 ◽  
pp. 196-199
Author(s):  
Ting Ting Liu ◽  
Hong Yuan Shen
Keyword(s):  
Trace Element ◽  
Standard Addition ◽  
Measured Data ◽  
Good Precision ◽  
Icp Oes ◽  
Digestion Method ◽  
Wet Digestion ◽  
Relative Standard ◽  
Precision And Accuracy

Wet digestion method had been used in river deposit of BZ profile. At the same time, Mn, Cu, Ba, Ni, Pb, Zn, Rb, V, Sr and Zr in river deposit were determined by ICP-OES. The results show that the relative standard deviations are all below 0.39%, while the recovery of standard addition is 94.3%~117.1%. The method is proved to have good precision and accuracy, and to be simple and rapid. And the measured data provide basis for paleoflood study in this area.

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