Adsorption of Phosphate in Aqueous Solution with Steel Slag

2014 ◽  
Vol 522-524 ◽  
pp. 401-404 ◽  
Author(s):  
Jia Xi Tang ◽  
Li Na Sun ◽  
Yu Pan Yun ◽  
Miao Miao He ◽  
Mei Hua Lian ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Steel Slag ◽  
Ammonia Nitrogen ◽  
Isothermal Adsorption ◽  
Langmuir Adsorption ◽  
Adsorption Equation ◽  
Strong Adsorption ◽  
Adsorption Intensity ◽  
Adsorption Quantity

The steel slag was used as adsorbent for the adsorption of Phosphate. the isothermal adsorption test studies adsorption of the steel slag on phosphorus and ammonia nitrogen. The results showed that that the steel slag have very strong adsorption capacity on phosphorus. Langmuir adsorption equation can better describe adsorption of steel slag on phosphorus, the max adsorption quantity of steel slag on phosphorus is 9495.916 mg·kg-1, adsorption intensity is 0.0132.

Adsorption of Cu(II) from Aqueous Solution by Peanut Shell

2011 ◽  
Vol 347-353 ◽  
pp. 1852-1855 ◽  
Author(s):  
Zheng Jun Gong ◽  
Cong Cong Tang ◽  
Cai Yun Sun ◽  
Lu Tang ◽  
Jun Chen
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Adsorption Isotherms ◽  
Batch Adsorption ◽  
Present System ◽  
Peanut Shell ◽  
Optimum Conditions ◽  
Langmuir Adsorption ◽  
Adsorption Data ◽  
Adsorption Intensity

A natural peanut shell was used as adsorbent for removal of Cu(Ⅱ) from aqueous solution. Optimum conditions for the elimination of Cu(Ⅱ) from aqueous solution were established by means of a batch adsorption technique. The applicability of the Langmuir and Freundlich adsorption isotherms for the present system was tested. The Langmuir adsorption capacity Qmax (mg/g) is 39.68 and the equilibrium constant b is 0.00776. The Freundlich adsorption capacity k is 0.978 and adsorption intensity n is 1.65. The goodness of fitness was obtained with the Langmuir and Freundlich adsorption isotherms from the equilibrium adsorption data.

Experimental Study of Adsorption of Ammonia Nitrogen from Wastewater onto the Bagasse Adsorbent

2014 ◽  
Vol 529 ◽  
pp. 22-25 ◽  
Author(s):  
Li Wei Xie ◽  
Ze Long Xu ◽  
Yan Hua Huang ◽  
Shuang Cao ◽  
Zong Qiang Zhu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Experimental Study ◽  
Adsorption Capacity ◽  
Ammonia Nitrogen ◽  
Alkaline Condition ◽  
Maximum Adsorption Capacity ◽  
Initial Concentration ◽  
Adsorption Capacities ◽  
Neutrality Condition ◽  
Adsorbent Dose

Adsorption of ammonia nitrogen from aqueous solution onto the bagasse adsorbent has been investigated to evaluate the effects of Adsorbent dose, initial NH4+-N concentration, and pH on the removal systematically. With increasing initial concentration, the amount of ammonia nitrogen sorbed onto the adsorbent increased until it gradually decreased due to the initial concentration exceed 50 mg·L-1, and the maximum adsorption capacity was observed for the sample to be 1.31 mg·g-1 at the initial concentration of 30 mg·L-1, and the corresponding removal rates decreased from 94.01 to 3.89%, with increase in initial concentration from 5 to 100 mg·L-1. Adsorption capacities decreased from 6.04 to 0.49 mg·g-1 with increasing adsorbent dose from 0.1 to 1.5g. What’s more, under alkaline condition, the removal efficiency of ammonia nitrogen from aqueous solution onto the samples were superior to that under acidity and neutrality condition.

Adsorption Characteristic Research of Sediments of Lake Baiyangdian

2014 ◽  
Vol 511-512 ◽  
pp. 55-58
Author(s):  
Zhe Qin ◽  
Qian Wang ◽  
Zheng Liu
Keyword(s):  
Adsorption Isotherm ◽  
Nitrogen Adsorption ◽  
Ammonia Nitrogen ◽  
Langmuir Adsorption Isotherm ◽  
Adsorption Characteristic ◽  
Langmuir Adsorption ◽  
Lake Baiyangdian ◽  
Object Of Study ◽  
Total Maximum ◽  
Adsorption Quantity

This paper regarded the sediments of Lake Baiyangdian as the object of study, researched and analyzed ammonia nitrogen adsorption characteristics of sediment samples. The results showed that: the sediments adsorption to ammonia nitrogen reached a state of equilibrium after 2.5h, The ammonia nitrogen adsorption rate was maximum in 0~10min. Sediment adsorption of ammonia nitrogen was higher as ammonia nitrogen liquid balance concentration increased. The adsorption isotherm curve of ammonia nitreogen can be fitted well by the Langmuir adsorption isotherm model. The total maximum adsorption quantity of ammonia nitrogen by the sediments of Lake Baiyangdian is between 54.12mg/kg to 240.12mg/kg.

Carbonized medlar-core particles as a new biosorbent for removal of Cu2+ from aqueous solution and study of its surface morphology

2016 ◽  
Vol 74 (1) ◽  
pp. 236-245 ◽  
Author(s):  
Narges Samadani Langeroodi ◽  
Elaheh Safaei
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
High Adsorption ◽  
Langmuir Adsorption ◽  
Adsorption Isotherm Models ◽  
Freundlich Adsorption Isotherm ◽  
High Adsorption Capacity ◽  
Core Particles

The objective of this study was to investigate the use of carbonized medlar-core particles as a new biosorbent to remove Cu2+ from aqueous solution. Fourier transform infrared spectroscopy and scanning electron microscopy were used to characterize the biosorbent. This paper reports the effects of adsorbent dose, pH, temperature and concentration of adsorbate. Batch isotherm studies were also performed to understand the ability of the adsorbent. The adsorption behavior of the Cu2+ was studied using Langmuir and Freundlich adsorption isotherm models. The maximum adsorption capacity determined from the Langmuir adsorption equation has been found as 43.478 mg.g−1 at 298.15 K. The adsorption of Cu2+ by medlar core in carbonized form was spontaneous and endothermic. It was also found that the biosorption of Cu2+ followed second-order kinetics. Carbonized medlar-core particles showed great potential in aqueous solution due to the high adsorption capacity.

Synthesis of a Fe/Ca-based phosphate material and its application for adsorption of uranium ions from aqueous solution

2021 ◽  
pp. geochem2021-052
Author(s):  
Haiyan Liu ◽  
Weimin Zhang ◽  
Jingyi Mo ◽  
Zhen Wang ◽  
Jiahong Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Sol Gel ◽  
Steel Slag ◽  
Single Layer ◽  
Zero Valent Iron ◽  
Separation Coefficient ◽  
Ion Adsorption ◽  
Ion Removal ◽  
Nano Zero Valent Iron

Uranium (U) ion contamination in aquatic systems has received considerable attention worldwide. In this paper, an adsorption material was synthesized with Fe/Ca-based phosphate (CFB-PM) by a sol-gel method. The effect of pH, reaction time and initial concentration of U ions on its capacity of removing U ions from aqueous solution was investigated by static batch experiments. Comparative studies of U ion removal by CFB-PM with four sorbents, namely: nano zero-valent iron (nZVI), hydroxyapatite (HAP), hydroxyapatite-loaded nano zero-valent iron (HAP@nZVI) and high basicity steel slag loaded hydroxyapatite (HBSS@HAP), were performed. Results showed that U ion adsorption capacity of CFB-PM was better than that of nZVI, HAP, HAP@nZVI and HBSS@HAP. The adsorption capacity showed a decreasing order as: CFB-PM (643.34 mg/g) > HAP (549.86 mg/g) > HBSS@HAP (321.82 mg/g) > HAP@nZVI (153.62 mg/g) > nZVI (102.65 mg/g). SEM-EDS examination suggested that the adsorbed U ions were mainly in the form of spheres, sheets or petals on the surfaces of CFB-PM. XRD detection revealed several U-bearing mineral phases (i.e. Ca(UO2)2(PO4)2·3H2O, HPUO6·4H2O and (UO2)3PO4·4H2O). The U ion adsorption behaviors were further explored by FTIR spectroscopy. The uranium ion adsorption process of CFB-PM could be well described by quasi-second-order adsorption kinetics model and the Langmuir adsorption isotherm model. The separation coefficient (RL) was close to zero, indicating that U ion adsorption was dominated by single-layer chemisorption. The findings reported in this study have implications for applying the synthesized material for remediation of U ion-contaminated groundwater.

Preparation of a Novel Cation Exchange Resin PSSS-g-CD301 and its Adsorption Properties towards Metal Ion

2014 ◽  
Vol 1053 ◽  
pp. 216-223 ◽  
Author(s):  
Wei Guang Ping ◽  
Tuo Ping Hu ◽  
Jian Feng Gao ◽  
Xi Chen ◽  
Wen Xia Zhou
Keyword(s):  
Adsorption Capacity ◽  
Metal Ion ◽  
Exchange Resin ◽  
Cation Exchange Resin ◽  
Gravimetric Method ◽  
Amino Groups ◽  
Adsorption Ability ◽  
Isothermal Adsorption ◽  
Sodium Styrene Sulfonate ◽  
Strong Adsorption

Resin D301 was surface-carbonized to obtain the surface charring materials (CD301). Using redox initiating system constituted by the amino groups of CD301 particles and persulfate in the solution, the poly (sodium styrene sulfonate) (PSSS) was grafted onto the surface of CD301, obtaining the grafted material PSSS-g-CD301, and the degree of grafting can reach 17.7% under suitable conditions. PSSS-g-CD301 was characterized by infrared spectrum (FTIR), and the degree of grafting was measured by gravimetric method. The adsorption character of PSSS-g-CD301 towards Al3+, Fe3+ and Cu2+ were mainly examined and investigated. PSSS-g-CD301 possesses strong adsorption ability towards Al3+, Fe3+and Cu2+. The adsorption capacity can get up to 13.285mg·g-1, 14.864mg·g-1, and 15.10mg·g-1, respectively. The data of isothermal adsorption matched well with Langmuir equation. The adsorption capacity increased with the increase of temperature and the value of pH. The adsorption capacity of PSSS-g-CD301 towards Fe3+ changed little after use them six times.

scholarly journals Adsorption of ammonia nitrogen by jackfruit (Artocarpus heterophyllus) seeds: Isotherms and kinetic modeling studies

2017 ◽  
Vol 13 (4) ◽  
pp. 778-783
Author(s):  
Azreen Ibrahim ◽  
Lija Yusof ◽  
Abu Zahrim Yaser
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Kinetic Modeling ◽  
Ph Value ◽  
Aquatic Organisms ◽  
Ammonia Nitrogen ◽  
Artocarpus Heterophyllus ◽  
Initial Ph ◽  
Pseudo Second Order ◽  
Modeling Of Adsorption

Ammonia nitrogen (NH3 - N) is one of the common and toxic species of nitrogen and excess of it in waterway causes eutrophication, decreased in dissolved oxygen and toxic to aquatic organisms. This study aims to investigate the isotherm and kinetic modeling of adsorption of ammonia nitrogen from aqueous solution by using jackfruit (Artocarpus heterophyllus) seed. Batch equilibrium experiments were carried out at 60 minute of contact time with initial pH value of 7. The adsorption isotherm data fitted well with Langmuir model with correlation (R2) of 0.9809 and maximum monolayer adsorption capacitiy (Qe) of 3.94 mg/g. Meanwhile, the adsorption of NH3 - N follows pseudo second order with correlation (R2) values ranges from 0.62 to 0.96 for various concentrations. Besides, the adsorption capacity obtained from experiment also has the smallest difference with calculated adsorption capacity. This suggest that the adsorption is mainly governed by chemical process involving cations sharing or exchange between the adsorbent and NH3 - N in the solution. In conclusion, jackfruit seed can be used as adsorbent materials for ammonia nitrogen removal from aqueous solution. 

Adsorption and Migration Characteristics of Fluorine in Ash-Sluicing Water in Soils

2021 ◽  
Vol 13 (4) ◽  
pp. 705-717
Author(s):  
Jun Yan ◽  
Yingqi Wei ◽  
Yanfeng Wen ◽  
Hong Cai ◽  
Jianzhang Xiao ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Sandy Soil ◽  
Thermal Power ◽  
Fluorine Content ◽  
Control Factor ◽  
Maximum Adsorption Capacity ◽  
Red Clay ◽  
Isothermal Adsorption ◽  
Silty Soil ◽  
Adsorption Equation

The excessive fluorine content in ash-sluicing water has become one of the main environmental pollution problems in the thermal power generation industry. This study selected 5 representative soil types and used fluoride ions (F-) as the pollution control factor. The experimental results showed that the isotherms of the F- solutions prepared by deionized water (adsorbed by Jianbi clay and Fengrun sandy soil) and ash-sluicing water all conformed to the Langmuir isothermal adsorption equation. In terms of the F- solution prepared with ash-sluicing water, the adsorption isotherm of Tianshengqiao red clay conformed to the Langmuir isothermal adsorption equation; the adsorption isotherms of Beijing silty soil and Fen River loess conformed to the Henry isothermal adsorption equation. In terms of the maximum adsorption capacity, Tianshengqiao red clay > Jianbi clay > Beijing silty soil ? Fen River loess > Fengrun sandy soil. Through the experiments, we also found that the adsorption capacity decreased with increasing pH, and the pH buffering effects of the 5 soils, from high to low, were Tianshengqiao red clay > Jianbi clay > Beijing silty soil > Fen River loess > Fengrun sandy soil.

Utilization of Waste of Enzymes Biomass as Biosorbent for the Removal of Dyes from Aqueous Solution in Batch and Fluidized Bed Column

2020 ◽  
Vol 71 (1) ◽  
pp. 1-12
Author(s):  
Salman H. Abbas ◽  
Younis M. Younis ◽  
Mohammed K. Hussain ◽  
Firas Hashim Kamar ◽  
Gheorghe Nechifor ◽  
...  
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Particle Size ◽  
Adsorption Capacity ◽  
Fluidized Bed ◽  
Flow Rate ◽  
Fungal Biomass ◽  
Solution Flow Rate ◽  
Maximum Adsorption Capacity ◽  
Solution Flow

The biosorption performance of both batch and liquid-solid fluidized bed operations of dead fungal biomass type (Agaricusbisporus ) for removal of methylene blue from aqueous solution was investigated. In batch system, the adsorption capacity and removal efficiency of dead fungal biomass were evaluated. In fluidized bed system, the experiments were conducted to study the effects of important parameters such as particle size (701-1400�m), initial dye concentration(10-100 mg/L), bed depth (5-15 cm) and solution flow rate (5-20 ml/min) on breakthrough curves. In batch method, the experimental data was modeled using several models (Langmuir,Freundlich, Temkin and Dubinin-Radushkviechmodels) to study equilibrium isotherms, the experimental data followed Langmuir model and the results showed that the maximum adsorption capacity obtained was (28.90, 24.15, 21.23 mg/g) at mean particle size (0.786, 0.935, 1.280 mm) respectively. In Fluidized-bed method, the results show that the total ion uptake and the overall capacity will be decreased with increasing flow rate and increased with increasing initial concentrations, bed depth and decreasing particle size.

scholarly journals Study on the adsorption selection of CH$$_4$$ on CuO (110) versus (111) surfaces: a density functional theory study

2021 ◽  
Vol 3 (4) ◽  
Author(s):  
Long Lin ◽  
Linwei Yao ◽  
Shaofei Li ◽  
Zhengguang Shi ◽  
Kun Xie ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Adsorption Capacity ◽  
Active Sites ◽  
Density Functional ◽  
Oxygen Vacancies ◽  
Density Functional Theory Calculations ◽  
Density Functional Theory Study ◽  
Functional Theory ◽  
Strong Adsorption ◽  
Selection Of

AbstractFinding the active sites of suitable metal oxides is a key prerequisite for detecting CH$$_4$$ 4 . The purpose of the paper is to investigate the adsorption of CH$$_4$$ 4 on intrinsic and oxygen-vacancies CuO (111) and (110) surfaces using density functional theory calculations. The results show that CH$$_4$$ 4 has a strong adsorption energy of −0.370 to 0.391 eV at all site on the CuO (110) surface. The adsorption capacity of CH$$_4$$ 4 on CuO (111) surface is weak, ranging from −0.156 to −0.325 eV. In the surface containing oxygen vacancies, the adsorption capacity of CuO surface to CH$$_4$$ 4 is significantly stronger than that of intrinsic CuO surface. The results indicate that CuO (110) has strong adsorption and charge transfer capacity for CH$$_4$$ 4 , which may provide experimental guidance.

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