Preparation and Properties of Ageing Resistant Asphalt Binder with Various Anti-Ageing Additives

2011 ◽  
Vol 71-78 ◽  
pp. 1062-1067 ◽  
Author(s):  
Zhen Gang Feng ◽  
Jian Ying Yu ◽  
Heng Long Zhang ◽  
Dong Liang Kuang
Keyword(s):  
Synergistic Effect ◽  
Softening Point ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Uv Absorber ◽  
Modified Asphalt Binder ◽  
Uv Absorbers ◽  
Compound Modification ◽  
Oxidative Ageing

The modified asphalt binders with various anti-ageing additives, including ultraviolet (UV) absorber, antioxidant and combination of them, were prepared, and the effects of UV absorber contents, antioxidant contents and combination of UV absorber and antioxidant on physical properties and ageing characteristics of the asphalt binder were investigated. Results show that the ductility of asphalt binder increases whereas the softening point and viscosity decrease with addition of anti-ageing additives. UV absorbers and antioxidants exhibit different influences on the ageing properties of asphalt binder. The thermal- and photo-oxidative ageing performance of asphalt binder can be simultaneously improved by the compound modification with UV absorber and antioxidant. The combination of UV326 and antioxidant 1010 shows synergistic effect in preventing the asphalt binder from thermal- and photo-oxidative ageing, which contributes to excellent ageing resistance of modified asphalt binder.

CHARACTERIZATION OF THE PERFORMANCE OF ALUMINUM OXIDE NANOPARTICLES MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (4) ◽  
Author(s):  
Shaban Imael Albrka Ali ◽  
Amiruddin Ismail ◽  
Nur Izzi Md. Yusoff ◽  
Norhidayah Abdul Hassan ◽  
Ahmad Nazrul Hakimi Ibrahim
Keyword(s):  
Aluminum Oxide ◽  
Softening Point ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Aluminum Oxide Nanoparticles ◽  
Asphalt Cement ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Rotational Viscosity

This study investigates the physical and rheological properties of asphalt binders modified by nano aluminum oxide (AL2O3). Several conventional tests were conducted, including penetration, softening point and ductility, rotational viscosity and dynamic shear rheometer (DSR). Based on the results of the tests, it was found that the hardness of modified asphalt binders increased with the addition of nano AL2O3 up to 5%. As a result of the increased hardness, the softening point of modified asphalt improved compared with base asphalt binders. The rheological property of modified binders was enhanced at low and high temperatures. The results of a DSR test revealed that the G* were improved, whereas the δ decreased slightly. The addition of a different percentage of AL2O3 to base binder had a remarkable influence on resistance to permanent deformation (high temperature rutting and low temperature fatigue). Results recognize 5 wt.% as the optimum content of the modifier. Therefore, nano AL2O3 can be considered as a proper alternative additive to modify the properties of asphalt cement.

scholarly journals Evaluating the Rheological, Chemical and Morphological Properties of SBS Modified Asphalt-Binder under Multiple Aging and Rejuvenation Cycles

2021 ◽  
Vol 11 (19) ◽  
pp. 9242
Author(s):  
Xiaobing Chen ◽  
Yunfeng Ning ◽  
Yongming Gu ◽  
Ronglong Zhao ◽  
Jinhu Tong ◽  
...  
Keyword(s):  
Asphalt Binder ◽  
Morphological Properties ◽  
Asphalt Binders ◽  
Laboratory Simulation ◽  
Fatigue Properties ◽  
Type I ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Microscopic Morphology ◽  
Sbs Modified Asphalt

To investigate the influence of multiple cycles of aging and rejuvenation on the rheological, chemical, and morphological properties of styrene–butadiene–styrene (SBS)-modified asphalt-binders, the asphalt-binders were aged using two laboratory simulation methods, namely a rolling thin film oven (RTFO) test for short-term aging and pressure aging vessel (PAV) for long-term aging. The asphalt-binders were then rejuvenated with three types of rejuvenators (Type I, II, and III) with different dosages (i.e., 6%, 10%, and 14% for the first, second, and third rejuvenation, respectively). A dynamic shear rheometer (DSR) was then used to analyze the effect of rejuvenators on the rheological properties of all the asphalt-binders. The changes in the functional groups and microscopic morphology in the process of multiple aging and rejuvenation cycles were studied using Fourier transform infrared (FTIR) and atomic force microscopy (AFM). The results indicated that the three rejuvenators could soften the stiffness and restore the microstructures of the aged asphalt-binders in the process of repeated aging and rejuvenation from DSR and AFM testing. Considering the rutting and fatigue properties, the Type I rejuvenator exhibited the potential to achieve the desired rejuvenation effects under multiple rejuvenation cycles. During the multiple aging and rejuvenation cycles, the aging resistance of SBSMA decreased gradually from the FTIR results. This inherently limited the number of repeated rejuvenation cycles. This research is conducive to promoting the application of repeated penetrating rejuvenation.

scholarly journals Evaluation of Selected Performance Properties of Nanoclay-Modified Asphalt Binders

2019 ◽  
Vol 271 ◽  
pp. 03006
Author(s):  
Mohammad N. Hassan ◽  
M M Tariq Morshed ◽  
Zahid Hossain
Keyword(s):  
Colloidal Stability ◽  
Asphalt Binder ◽  
Weather Conditions ◽  
Good Alternative ◽  
Asphalt Binders ◽  
Chemical Compositions ◽  
Modified Asphalt ◽  
Adverse Weather ◽  
Modified Asphalt Binder ◽  
Improved Performance

Asphalt binders are often modified with additives such as acid, polymer, or a combination of multiple additives to achieve improved performance to sustain heavy loads and adverse weather conditions. According to some previous researches, nanoclay can be a good alternative of currently practiced Styrene-Butadiene-Styrene (SBS) modification, and the former is expected to reduce the overall cost of the asphalt binder. Three types of nanoclay (Cloisite 10A, 11B, and 15A) were blended with asphalt binders prepared from two different sources (Arabian Crude and Canadian Crude). A blending protocol has been developed to blend nanoclay with the base binders. Mechanical properties including viscosity, rutting parameter have undergone significant changes after the nanoclay modification. It was also observed that nanoclay modified binders offer different moisture susceptibility while bonding with different aggregates; the nanoclay modified asphalt binder exhibits better bonding with gravel than sandstone. Mechanistic properties such as viscosity and rutting parameter are found to be highly correlated with the chemical compositions. Binders from the Canadian crude showed more colloidal stability than binders from the Arabian crude after nanoclay modification.

RHEOLOGICAL BEHAVIOUR OF COCONUT SHELL POWDER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-3) ◽  
Author(s):  
Rosnawati Buhari ◽  
Nur Fareesya Zabidi ◽  
Mohd Ezree Abdullah ◽  
Siti Khatijah Abu Bakar ◽  
Nurul Hidayah Mohd Kamarudin
Keyword(s):  
Rheological Properties ◽  
Softening Point ◽  
Asphalt Binder ◽  
Rheological Behaviour ◽  
Coconut Shell ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Modified Binder ◽  
Coconut Shell Powder ◽  
Shell Powder

The objectives of this study were to determine the blending parameters of coconut shell powder (CSP) modified asphalt binder and to evaluate the rheological properties of CSP modified asphalt binder. CSP of 2%, 4%, 6%, 8% and 10% by weight of asphalt have been incorporated into an unaged 80/100 asphalt mix in order to improve its performance. The influence of the additives on the physical and rheological properties was evaluated with penetration test, softening point, storage stability, dynamic shear rheometer test (DSR), and Field Emission Scanning Electron Microscope (FESEM). The aging of asphalt binders was simulated in a laboratory by using Rotational Thin Film Oven (RTFO). The results showed that the addition of CSP into virgin binder was decreasing the penetration value and increasing the softening point temperature compared to the original binder. On the rheological effect, for unaged modified binder, higher CSP resulted higher G*/sin δ especially at lower temperature compared to the unaged control binder. Besides, for the aged modified binder, stiffness was lower than the control aged binder for all temperature.

scholarly journals Cellulose Microfibril and Micronized Rubber Modified Asphalt Binder

Fibers ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 25
Author(s):  
Ang Li ◽  
Abdu A. Danladi ◽  
Rahul Vallabh ◽  
Mohammed K. Yakubu ◽  
Umar Ishiaku ◽  
...  
Keyword(s):  
Linear Regression Analysis ◽  
Asphalt Binder ◽  
Cost Effective ◽  
Cellulose Microfibrils ◽  
Asphalt Binders ◽  
Asphalt Emulsion ◽  
Clear Trend ◽  
Modified Asphalt ◽  
Weight Content ◽  
Modified Asphalt Binder

Cellulose microfibrils (CMFs) and micronized rubber powder (MRP) can be derived from low or negative-cost agricultural/industrial waste streams and offer environment-friendly and cost-effective pathways to develop engineering products. This study investigated the efficacy of adding these micromodifiers on the performance characteristics of asphalt binders. In this work, samples were produced using a mixture of slow-setting anionic asphalt emulsion with various combinations of MRP (at 0, 2 and 10 wt %) and four types of CMFs (hydrophobic and hydrophilic with crystalline ratios of 86% and 95%) at 0, 2 and 5 wt %. The performance of modified asphalt samples was assessed by penetration depth (PD), softening point (SP), and penetration index (PI). Linear regression analysis showed that adding CMFs and/or MRP reduced PD and increased SP values. The type of CMFs significantly affected the performance, which becomes more distinct with the increased weight content of CMFs. While hydrophilic CMFs caused increases in SP and PI values, no clear trend was seen to determine the effect of CMF crystallinity. It was also discovered that the combined addition of CMF and MRP achieved similar PI values at lower total weight content compared to using MRP alone.

Highly Modified Asphalt Binder for Asphalt Crack Relief Mix

2017 ◽  
Vol 2630 (1) ◽  
pp. 110-117 ◽  
Author(s):  
Matheus S. Gaspar ◽  
Kamilla L. Vasconcelos ◽  
Amanda H. M. da Silva ◽  
Liedi L. B. Bernucci
Keyword(s):  
Hot Mix Asphalt ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Bending Test ◽  
Asphalt Binders ◽  
Reflective Cracking ◽  
Modified Asphalt ◽  
Asphalt Overlay ◽  
Modified Asphalt Binder ◽  
Styrene Butadiene

Reflective cracking is a common issue with respect to rehabilitated asphalt pavements, especially when the rehabilitation is done by applying a hot-mix asphalt overlay on the existing damaged pavement. Several approaches can be adopted to delay reflective cracking. They include an increase of the overlay thickness and the use of a stress relief asphalt mixture (SRAM), which is a fine-graded, flexible, and thin asphalt interlayer. Because the efficiency of a SRAM is highly related to the properties of the asphalt binder used in the mixture, it is of interest to use a highly modified asphalt (HiMA) binder. This paper describes a field test comprising three sections at BR-116 (a heavily trafficked highway in Brazil). One of the rehabilitation strategies used for a cracked asphalt pavement was a 2.5-cm SRAM (produced with a HiMA binder) and 5-cm styrene–butadiene–styrene (SBS) hot-mix asphalt (HMA). The other two strategies were to apply SBS HMA overlays of different thicknesses (7.5 cm and 10.5 cm). The aim was to evaluate and compare the capability of these solutions to control reflective cracking. Rheological properties and multiple stress creep and recovery tests were performed on the asphalt binders, and the semicircular bending test was performed on the asphalt mixtures. The surface conditions were monitored, and the results for each section were compared. After a 29-month period, the section that received the interlayer had the lowest cracked area and showed better resistance than the overlays did to reflective cracking and better maintenance of the original thickness of the pavement.

Nonlinear Viscoelastic Response of Crumb Rubber Modified Asphalt Binder Under Large Strains

2020 ◽  
Vol 2674 (3) ◽  
pp. 139-149
Author(s):  
Saqib Gulzar ◽  
B. Shane Underwood
Keyword(s):  
Asphalt Binder ◽  
Crumb Rubber ◽  
Oscillatory Shear ◽  
Asphalt Binders ◽  
Large Strains ◽  
Viscoelastic Response ◽  
Modified Asphalt ◽  
Nonlinear Viscoelastic ◽  
Modified Asphalt Binder ◽  
Polymer Modified Asphalt

Agencies have been increasing their use of polymer modified asphalt binders in recent years to address performance issues and lengthen the useful life of their pavements. When deployed these materials likely experience strain levels exceeding their linear viscoelastic (LVE) limits. The same situation exists in non-polymer modified asphalt binders as well, but the effect may be more pronounced in polymer modified systems because of their bi-phasic nature. In this study, terminally blended crumb rubber (CR-TB) modified asphalt is studied to understand and quantify the nonlinear viscoelastic response under large strains. The CR-TB binders are extensively used in pavements subjected to high vehicular loads and extreme climatic conditions; thereby, their response under large strains becomes more critical. The current standard characterization techniques are based on LVE response using small amplitude oscillatory shear rheology only and do not consider the behavior of binders under large strains. In this study, large amplitude oscillatory shear (LAOS) rheology is used as a framework to more thoroughly investigate the complete response of the CR-TB modified asphalt binder under large strains at 30°C, 40°C, 50°C, and 60°C and at the frequencies of 0.5, 1, and 5 Hz. The LAOS response is analyzed using Fourier-transform rheology and the orthogonal stress decomposition method involving Chebyshev polynomial representation. It is found that nonlinearity manifests greatly in this study material as strain levels increase and frequencies decrease. The relative nonlinearity increases with increasing strain amplitude and is more significant towards lower end of the tested temperature range. The CR-TB binder shows strain-stiffening/softening and shear-thinning/thickening behavior depending upon a specific temperature, strain level, and frequency.

EFFECT OF VISCOELASTIC BEHAVIOR OF CELLULOSE OIL PALM FIBER (COPF) MODIFIED 60-70 ASPHALT BINDER FOR DETERIORATION FOR ROADS AND HIGHWAYS

2015 ◽  
Vol 75 (11) ◽  
Author(s):  
Md. Maniruzzaman A. Aziz ◽  
Ahmed Wsoo Hamad ◽  
Abdulmalik Musa Maleka ◽  
Fauzan Mohd Jakarni
Keyword(s):  
Shear Modulus ◽  
Oil Palm ◽  
Softening Point ◽  
Asphalt Binder ◽  
Viscoelastic Behavior ◽  
Complex Shear Modulus ◽  
Palm Fiber ◽  
Modified Asphalt ◽  
Complex Shear ◽  
Modified Asphalt Binder

This paper dealt with the viscoelastic behavior of Cellulose Oil Palm Fiber (COPF) modified 60-70 penetration grade asphalt binder for the deterioration of roads. The main objective of this study was to investigate the effect of various COPF contents on the physical and the rheological properties of penetration grade 60-70 asphalt binder. Laboratory tests performed comprised of viscosity, penetration, softening point, short & long term ageing, as well as complex shear modulus (G*).  The COPF was blended in 0.2, 0.4, 0.6, 0.8, and 1.0% by weight of asphalt binder, including 0% as control. The COPF modified asphalt binder showed an increasing viscosity and softening point with the increase of COPF content, whereas the penetration decreased as the COPF was increased for the binder. The complex shear modulus (G*), rutting factor (G*/sin δ), and fatigue factor (G*sin δ) showed significant improvement for the modified samples compared to the unmodified samples. The results indicated that the COPF modified asphalt binder had high potential to resist permanent (rutting) deformation and fatigue cracking than the unmodified sample. 

PHYSICAL PROPERTIES AND STORAGE STABILITY OF GEOPOLYMER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-2) ◽  
Author(s):  
Ahmad Nazrul Hakimi Ibrahim ◽  
Nur Izzi Md. Yusoff ◽  
Norliza Mohd Akhir ◽  
Muhamad Nazri Borhan
Keyword(s):  
Physical Properties ◽  
Storage Stability ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Potential Alternative ◽  
Modified Binder ◽  
And Storage

This study was conducted to investigate the physical properties and storage stability of the 80/100 penetration grade asphalt modified with geopolymer. In this research, fly ash and alkali activators, namely sodium silicate (Na2SiO3) and sodium hydroxide (NaOH), were used as geopolymer components. The penetration, Ring and Ball softening point, ductility, and viscosity tests were conducted to determine the physical properties of geopolymer modified asphalt (GMA). Five samples of asphalt binders with varying percentages of geopolymer, namely 0, 3, 5, 7 and 9%, by weight of asphalt binder were studied. Results show that geopolymer has good compatibility with asphalt binder. The addition of geopolymer into asphalt binder resulted in improved permanent deformation resistance of the modified binder compared to that of the conventional asphalt. In conclusion, geopolymer could be considered as a potential alternative in the modification of the properties of asphalt binder.

Experimental Study on Polyphosphoric Acid (PPA) Modified Asphalt Binders

2010 ◽  
Vol 152-153 ◽  
pp. 288-294 ◽  
Author(s):  
Wei Dong Cao ◽  
Shu Tang Liu ◽  
Hong Lu Mao
Keyword(s):  
Low Temperature ◽  
Softening Point ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Point Test ◽  
Low Temperature Performance ◽  
Four Levels ◽  
Temperature Susceptibility

Polyphosphric acid (PPA) modified asphalt binders were produced in the laboratory using one base asphalt and four levels of PPA contents (0.6%, 1.0%, 1.5% and 2.0% by weight of base asphalt). Penetration test, softening point test, rotation viscosity test, creep test with bending beam rheometer (BBR) and four components test were carried out to study the performance of PPA modified asphalt binders and possible modification mechanism. The results indicate that the high-temperature performance of PPA modified asphalt binders are obviously improved and temperature susceptibility are decreased, but the low-temperature performance slightly decline compared with base asphalt. The PPA content has a very significant effect on softening point whereas it has no significant influence on low-temperature performance according to variance analysis (ANOVA). Finally, four components test reveals that the primary modification mechanism of PPA is the change of chemical composition of asphalt binder.

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