Removal of Heavy Metal Ions from Water Using Nano-Barium Strontium Titanate Immobilized on the Silica Gel G as an Adsorbent

2011 ◽  
Vol 71-78 ◽  
pp. 3500-3503 ◽  
Author(s):  
Dong Zhang

A new method based on the sorption of the nano-barium strontium titanate immobilized on the silica gel G(GBST) to heavy metal ions, included Mn(Ⅱ), Cu2+, Ni2+,Co2+and Ag+, in waste water. The effects of process parameters such as pH, contact time, regeneration conditions and the effects of common coexisting ions on the ions uptake were investigated. The results showed that the manganese, copper, nickel, cobalt and silver ions studied could be quantitatively retained at a pH value range of 7~9. The adsorption capacities of GBST for manganese, copper, nickel, cobalt and silver ions were found to be 8.2 mg/g, 18.3 mg/g, 4.2 mg/g, 2.2 mg/g and 3.1 mg/g, respectively. The heavy metal ions adsorbed on the sorbent could be eluated completely with diluted HNO3solutions. The GBST can be used as an effective adsorbent for the treatment of wastewaters contaminated with manganese, copper, nickel, cobalt and silver ions.

2012 ◽  
Vol 433-440 ◽  
pp. 689-692
Author(s):  
Dong Zhang

The micro-column packed with porous nano-barium- strontium titanate microspheres, joining with injector, a new manual-controlled injection porous nano-barium- strontium titanate microspheres enricher (PBSTME) was prepared. The enrichment capability of the PBSTME for the heavy metal ions, such as zinc, nickel, copper, manganese, cobalt and silver was investigated. The results showed that all the heavy metals studied could be quantitatively retained by the PBSTME in the pH range of 5–8, and then eluted completely with 2 mol•L-1 HNO3. The detection limits of this method for zinc, nickel, copper, manganese, cobalt and silver ions were 0.028 μg•L-1, 0.2μg•L-1, 0.031 μg•L-1, 0.022 μg•L-1, 0.057μg•L-1 and 0.039 μg•L-1 with an enrichment factor of 50, respectively. A new method has been developed for the determination of trace heavy metal ions based on pre-concentration with a PBSTME prior to their determination by flame atomic absorption spectrometry. The method has been applied to the simultaneous determination of trace amounts of zinc, nickel, copper, manganese, cobalt and silver ions in water sample with satisfactory results.


Author(s):  
Kiflom Gebremedhn Kelele ◽  
Aschalew Tadesse ◽  
Tegene Desalegn ◽  
Suresh Ghotekar ◽  
Ruthramurthy Balachandran ◽  
...  

Abstract The ferroelectric barium strontium titanate (Ba1-xSrxTiO3) is a homogeneous solid solution prepared from the mixture of barium titanate (BaTiO3), strontium titanate (SrTiO3) and titanium (IV) isopropoxide. Barium strontium titanate (BST) nanomaterials with improved permittivity and dielectric properties due to their nano-properties have attracted great interest for extensive and versatile applications as super capacitors, dielectrics, ceramics and catalysts. Introduction of metal ion dopants into the parent system of BST significantly alters its structural, morphological, electrical, optical and dielectric characteristics. This review is aimed at addressing synthesis, characterization methods, photocatalytic and electrical applications of metal ions doped BST nanomaterials. The effect of doping BST, through metal ions, on its properties and application with most probable reasons have been thoroughly discussed.


to achieve - study the sorption of silver, copper, nickel ions, the method of changing the volume of solutions of a constant concentration of metal ions is used. The amount of zeolite and constant concentrated solution is taken in such an amount that the molar (molecular) parts of the exchanged ions are in a wider range. Some concentrated solutions are taken in flasks in an amount of 20 40 60 80 120 ml and 0.5 g of zeolite are added to them, mixed and a sample is taken periodically for analysis. After 2-2.5 hours, equilibrium occurs. By measuring the density of equilibrium, the amount of sorption of ions is determined.


The Analyst ◽  
2014 ◽  
Vol 139 (12) ◽  
pp. 2998-3001 ◽  
Author(s):  
Juan Tang ◽  
Minghua Lu ◽  
Dianping Tang

A target-initiated proximity ligation assay protocol with DNAzyme formation was for the first time designed for ultrasensitive impedimetric monitoring of heavy metal ions (silver ions were used in this case) by coupling with an enzymatic biocatalytic precipitation technique.


2019 ◽  
Vol 20 (11) ◽  
pp. 146-151
Author(s):  
Anastasiia Koliehova ◽  
Hanna Trokhymenko ◽  
Svitlana Melnychuk ◽  
Mykola Gomelya

2011 ◽  
Vol 194-196 ◽  
pp. 751-754
Author(s):  
Dong Zhang ◽  
Yan Cheng

A new adsorption agent, nanosized strontium titanate immobilized on the silica gel G (GSTO) was prepared, and it was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The ability of the new adsorption to remove heavy metal Pb, Cd, Zn, Cu, Ni and Mn from water samples was assessed. The research results displayed that adsorbent has the highest adsorption capacity for Pb, Cd, Zn, Cu, Ni and Mn in ions mixture system. Optimal experimental conditions including pH and contact time have been established. Desorption studies were carried out successfully with diluted HNO3 solutions. Thus, nano-strontium titanate immobilized on the silica gel G is favorable and useful for the removal of these heavy metal ions, and the high adsorption capacity makes it a good promising candidate material for Pb, Cd, Zn, Cu, Ni and Mn removal.


Sign in / Sign up

Export Citation Format

Share Document