Effect of Nano Calcium Carbonate and Montmorillonite on Properties of Styrene–Butadiene–Styrene Copolymer Modified Asphalt

2011 ◽  
Vol 99-100 ◽  
pp. 1035-1038 ◽  
Author(s):  
Nian Feng Han ◽  
De Jie Zhou ◽  
Xin De Tang

Composite modified asphalts with nano calcium carbonate (nano CaCO3)/ SBS and nano montmorillonite (nano MMT)/SBS were prepared respectively by melt blending. Rolling thin film oven test (RTFOT) was carried out to study the aging properties. The results demonstrate that CaCO3/SBS and MMT/SBS homogeneously disperse in the base asphalt, which lead to an improvement in terms of toughness, strength, and thermal stability. Effects of the nano CaCO3 and nano MMT on the properties of SBS modified asphalt appear as a decreasing penetration, an increasing softening point, and a decreasing ductility. The anti-aging property of the nano MMT/SBS modified asphalt was better than that of the CaCO3/SBS modified asphalt and SBS modified asphalt.

2014 ◽  
Vol 919-921 ◽  
pp. 1169-1172
Author(s):  
De Jie Zhou ◽  
Nian Feng Han

Composite modified asphalts with micron fly ash/SBS and nanocalcium carbonate (nanoCaCO3)/ SBS were prepared respectively by melt blending. The ageing properties and physical properties of micron fly ash/SBS and CaCO3/SBS modified bitumen were investigated. The results demonstrate that micron fly ash/SBS modified bitumen exhibited an increasing softening point, a decreasing penetration and a decreasing ductility. Compared with that of SBS modified bitumen, the anti-aging property of the micron fly ash/SBS modified bitumen becomes worse. Effects of the nanoCaCO3 on the properties of SBS modified asphalt appear as a decreasing penetration, an increasing softening point, and a decreasing ductility. The anti-aging property of the CaCO3/SBS modified asphalt was better than that of the SBS modified asphalt.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.


2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Haitao Zhang ◽  
Ying Wang ◽  
Zuoqiang Liu ◽  
Quansheng Sun

Although the aging asphalt and its regeneration were researched by many researchers, the poor low-temperature performance of regenerating asphalt has still not been solved yet. In this project, the composite technology of regeneration and modification will be used to solve the problem mentioned above. Through the investigation and analysis on the composite mechanism of regeneration and modification for aging asphalt, the objective of the project attempts to explore a method for the synchronized recovery of high- and low-temperature performance of aging asphalt. The research results show that the single regenerating technology cannot fully recover the low-temperature performance of aging asphalt, and the composite technology of regeneration and modification can make the performance of aging asphalt recovery well. The indexes of aging asphalt after composite regeneration and modification have been recovered, which are better than the indexes of 90# asphalt (25°C penetration is 80–100/0.1 mm) and close with the indexes of styrene-butadiene-styrene (SBS) modified asphalt. The project has demonstrated that the composite technology of regeneration and modification can make the high- and low-temperature performance of aging asphalt recovery well. The research results can obtain better economic and social benefits.


2013 ◽  
Vol 753-755 ◽  
pp. 715-718
Author(s):  
Xiu Hua Yang

SBS is a styrene - butadiene - styrene block copolymer, the addition of SBS of high and low temperature performance and road can be very good to improve the performance of asphalt. This paper studied the performance of the modified asphalt on the content of modifier.


2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Xing-jun Zhang ◽  
Hui-xia Feng ◽  
Xiao-min Li ◽  
Xiao-yu Ren ◽  
Zhen-feng Lv ◽  
...  

Styrene-butadiene-styrene- (SBS-) modified asphalts were prepared by mixing different base asphalts, SBS modifier, extracting oil, and stabilizing agents. The contact angles between SBS-modified asphalt and distilled water, glycerol, and formamide were detected by the sessile drop method. Based on the surface energy theory, the surface free energy and cohesive power of SBS-modified asphalt were calculated. The influence of the raw materials composition, such as the virgin asphalt and SBS modifier types as well as the extracting oil and stabilizing agent contents, on the cohesive characteristics of SBS-modified asphalt was discussed. The results showed that virgin asphalt was compatible with SBS modifiers to improve cohesiveness. The cohesive power of branched SBS-modified asphalt was larger than that of linear SBS-modified asphalt. The cohesion of SBS-modified asphalt was improved as the SBS modifier and stabilizer contents increased but was reduced for excessive extraction oil contents. The cohesive characteristics of the SBS-modified asphalt were improved by the formation of stable three-dimensional network structures by cross-linking, winding, and grafting among different raw materials.


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