Mechanical Properties and Thermal Behavior of TPS/PBS Blends with Maleated PBS as a Compatibilizer

2015 ◽  
Vol 1119 ◽  
pp. 306-309 ◽  
Author(s):  
Qun Jie Yin ◽  
Fang Ping Chen ◽  
He Zhang ◽  
Chang Sheng Liu
Keyword(s):  
Mechanical Properties ◽  
Thermal Behavior ◽  
Polymer Blend ◽  
Biodegradable Polymer ◽  
Thermoplastic Starch ◽  
Extrusion Process ◽  
Butylene Succinate ◽  
Elongation At Break

Thermoplastic starch/poly (butylene succinate),an entirely biodegradable polymer blend was prepared using a two-step extrusion process. The mechanical properties and thermal behavior of TPS/PBS blends were investigated. The results demonstrated that the strength and elongation at break of TPS/PBS blends were greatly improved with the addition of rPBS in PBS blends due to its contribution in the improvement of interfacial compatibilizing and miscibility.

scholarly journals Sericin cocoon bio-compatibilizer for reactive blending of thermoplastic cassava starch

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Thanongsak Chaiyaso ◽  
Pornchai Rachtanapun ◽  
Nanthicha Thajai ◽  
Krittameth Kiattipornpithak ◽  
Pensak Jantrawut ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Crystal Size ◽  
Thermoplastic Starch ◽  
Cassava Starch ◽  
Chain Extension ◽  
Amino Groups ◽  
Reactive Blending ◽  
Elongation At Break ◽  
Small Crystal Size

AbstractCassava starch was blended with glycerol to prepare thermoplastic starch (TPS). Thermoplastic starch was premixed with sericin (TPSS) by solution mixing and then melt-blended with polyethylene grafted maleic anhydride (PEMAH). The effect of sericin on the mechanical properties, morphology, thermal properties, rheology, and reaction mechanism was investigated. The tensile strength and elongation at break of the TPSS10/PEMAH blend were improved to 12.2 MPa and 100.4%, respectively. The TPS/PEMAH morphology presented polyethylene grafted maleic anhydride particles (2 μm) dispersed in the thermoplastic starch matrix, which decreased in size to approximately 200 nm when 5% sericin was used. The melting temperature of polyethylene grafted maleic anhydride (121 °C) decreased to 111 °C because of the small crystal size of the polyethylene grafted maleic anhydride phase. The viscosity of TPS/PEMAH increased with increasing sericin content because of the chain extension. Fourier-transform infrared spectroscopy confirmed the reaction between the amino groups of sericin and the maleic anhydride groups of polyethylene grafted maleic anhydride. This reaction reduced the interfacial tension between thermoplastic starch and polyethylene grafted maleic anhydride, which improved the compatibility, mechanical properties, and morphology of the blend.

scholarly journals Monitoring the degradation of partly decomposable plastic foils

2014 ◽  
Vol 6 (1) ◽  
pp. 39-44
Author(s):  
Gabriella Rétháti ◽  
Krisztina Pogácsás ◽  
Tamás Heffner ◽  
Barbara Simon ◽  
Imre Czinkota ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Molecular Mass ◽  
Structural Changes ◽  
Thermoplastic Starch ◽  
Medium Density ◽  
Insulating Layer ◽  
Elongation At Break ◽  
One Year ◽  
The One

Abstract We have monitored the behaviour of different polyethylene foils including virgin medium density polyethylene (MDPE), MDPE containing pro-oxydative additives (238, 242) and MDPE with pro-oxydative additives and thermoplastic starch (297) in the soil for a period of one year. A foil based on a blend of polyester and polylactic acid (BASF Ecovio) served as degradable control. The experiment was carried out by weekly measurements of conductivity and capacity of the soil, since the setup was analogous to a condenser, of which the insulating layer was the foil itself. The twelve replications allowed monthly sampling; the specimen taken out from the soil each month were tested visually for thickness, mechanical properties, morphological and structural changes, and molecular mass. Based on the obtained capacity values, we found that among the polyethylene foils, the one that contained thermoplastic starch extenuated the most. This foil had the greatest decrease in tensile strength and elongation at break due to the presence of thermoplastic starch. The starch can completely degrade in the soil; thus, the foil had cracks and pores. The polyethylene foils that contained pro-oxydant additives showed smaller external change compared to the virgin foil, since there was no available UV radiation and oxygen for their degradation. The smallest change occurred in the virgin polyethylene foil. Among the five examined samples, the commercially available BASF foil showed the largest extenuation and external change, and it deteriorated the most in the soil.

scholarly journals Bio-Based Thermoplastic Starch Composites Reinforced by Dialdehyde Lignocellulose

Molecules ◽  
2020 ◽  
Vol 25 (14) ◽  
pp. 3236
Author(s):  
Peng Yin ◽  
Wen Zhou ◽  
Xin Zhang ◽  
Bin Guo ◽  
Panxin Li
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Water Resistance ◽  
Thermoplastic Starch ◽  
Contact Angles ◽  
Sem Images ◽  
Elongation At Break ◽  
Injection Process ◽  
Oxidation Damage

In order to improve the mechanical properties and water resistance of thermoplastic starch (TPS), a novel reinforcement of dialdehyde lignocellulose (DLC) was prepared via the oxidation of lignocellulose (LC) using sodium periodate. Then, the DLC-reinforced TPS composites were prepared by an extrusion and injection process using glycerol as a plasticizer. The DLC and LC were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the effects of DLC content on the properties of the DLC/TPS composites were investigated via the evaluation of SEM images, mechanical properties, thermal stability, and contact angles. XRD showed that the crystallinity of the DLC decreased due to oxidation damage to the LC. SEM showed good dispersion of the DLC in the continuous TPS phase at low amounts of DLC, which related to good mechanical properties. The tensile strength of the DLC/TPS composite reached a maximum at a DLC content of 3 wt.%, while the elongation at break of the DLC/TPS composites increased with increasing DLC content. The DLC/TPS composites had better thermal stability than the neat TPS. As the DLC content increased, the water resistance first increased, then decreased. The highest tensile strength and elongation at break reached 5.26 MPa and 111.25%, respectively, and the highest contact angle was about 90.7°.

Effect of Co60γ Ray Irradiation on Thermoplastic Corn Starch Plastic

2013 ◽  
Vol 772 ◽  
pp. 34-37
Author(s):  
Hao Tang ◽  
Hai Tian Jiang ◽  
Bin Guo ◽  
Pan Xin Li
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Corn Starch ◽  
Irradiation Time ◽  
Thermoplastic Starch ◽  
Endothermic Peak ◽  
Macromolecular Structure ◽  
Thermal And Mechanical Properties ◽  
Elongation At Break ◽  
Γ Ray

Corn starch was irradiated by 60Coγ ray, and then the thermoplastic starch plastic (TPS) was prepared by adding glycerol. Microstructure, thermal and mechanical properties of the corn starch and starch plastic were studied in details by FTIR, DSC and SEM. Results showed that the starch macromolecular structure was damaged by irradiation, and with increased irradiation time, the temperature of melt endothermic peak and tensile strength decreased, elongation at break increases for starch plastic, the thermoplastic property of starch was enhanced obviously.

scholarly journals Sericin cocoon bio-compatibilizer for reactive blending of thermoplastic cassava starch

2021 ◽  
Author(s):  
Thanongsak Chaiyaso ◽  
Pornchai Rachtanapun ◽  
Nanthicha Thajai ◽  
Krittameth kiattipronpithak ◽  
Pensak Jantrawut ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Crystal Size ◽  
Thermoplastic Starch ◽  
Cassava Starch ◽  
Chain Extension ◽  
Amino Groups ◽  
Reactive Blending ◽  
Elongation At Break ◽  
Small Crystal Size

Abstract Cassava starch was blended with glycerol to prepare thermoplastic starch (TPS). TPS was premixed with sericin (TPSS) by solution mixing and then melt-blended with polyethylene grafted maleic anhydride (PEMAH). The effect of sericin on the mechanical properties, morphology, thermal properties, rheology, and reaction mechanism was investigated. The tensile strength and elongation at break of the TPSS10/PEMAH blend were improved to 12.2 MPa and 100.4%, respectively. The TPS/PEMAH morphology presented PEMAH particles (2 µm) dispersed in the TPS matrix, which decreased in size to approximately 200 nm when 5% sericin was used. The melting temperature of PEMAH (121°C) decreased to 111°C because of the small crystal size of the PEMAH phase. The viscosity of TPS/PEMAH increased with increasing sericin content because of the chain extension. Fourier-transform infrared spectroscopy (FTIR) confirmed the reaction between the amino groups of sericin and the maleic anhydride groups of PEMAH. This reaction reduced the interfacial tension between TPS and PEMAH, which improved the compatibility, mechanical properties, and morphology of the blend.

scholarly journals Mechanical Properties of Thermoplastic Starch Biocomposite Films with Hybrid Fillers

2021 ◽  
Vol 2080 (1) ◽  
pp. 012011
Author(s):  
Di Sheng Lai ◽  
Sinar Arzuria Adnan ◽  
Azlin Fazlina Osman ◽  
Ismail Ibrahim ◽  
Hazrul Haq
Keyword(s):  
Mechanical Properties ◽  
Food Packaging ◽  
Corn Starch ◽  
Composite Films ◽  
Thermoplastic Starch ◽  
Elongation At Break ◽  
Biocomposite Films ◽  
Hybrid Fillers ◽  
The Matrix ◽  
Dry Food

Abstract Thermoplastic starch (TPS) was studied extensively to replace conventional plastic in packaging application. In this study, granule corn starch was first plasticized with water and glycerol to form TPS films and two different fillers were incorporated with TPS to form hybrid biocomposite films (TPSB). Two different fillers: Microcrystalline cellulose (MC) and Nano bentonite (NB) fixed at 1: 4 ratios in various loading (1wt%-6wt%) were incorporated in TPS to study effect of hybrid fillers on the mechanical properties of TPSB films. The effect of different loading of MC/NB on TPSB films was investigated through the structural, morphological and mechanical testing. Fourier Transform Infrared Spectroscopy (FTIR) shows TPS matrix and hybrid fillers are highly compatible due to hydroxyl bonding and verified through the shifting of spectra band. Scanning Electron Microscope (SEM) showed even distribution of fillers in the matrix of TPS. The TPSB films exhibited significant improvement 40% in elongation at break compared to pure TPS films. In this study, 5wt% is best loading of the hybrid fillers to incorporated in TPSB films as it achieved the highest value of tensile strength (8.52MPa), Young’s Modulus (42.0 MPa) and elongation at break (116.3%). Generally, previous studies showed flexibility of TPS composite films reduced with incorporating filler, however in this study, the flexibility TPSB show significant improvement compared to previous studies and exhibit promising potential in dry food packaging application.

scholarly journals The electrical and mechanical properties of Cadmium chloride reinforced PVA:PVP blend films

2020 ◽  
Vol 12 ◽  
pp. 120006
Author(s):  
Rana S. Mahmood ◽  
Sabah A. Salman ◽  
Nabeel Ali Bakr
Keyword(s):  
Mechanical Properties ◽  
Electrical Conductivity ◽  
Polymer Blend ◽  
Weight Ratio ◽  
Experimental Results ◽  
Casting Method ◽  
Ac Electrical Conductivity ◽  
Elongation At Break ◽  
Blend Films ◽  
Reinforced Polymer

In this study, pure polymer blend (PVA:PVP) film and salt (CdCl2·H2O) reinforced polymer blend films were prepared at different weight ratios (10 wt%, 20 wt%, 40 wt%) using the casting method. The effect of the salt weight ratio on the dielectric properties of the polymer blend films reinforced by CdCl2·H2O salt were investigated, and the experimental results showed that the dielectric constant and the dielectric loss factor decreased as the frequency increased for all polymer blend films. Moreover, the above-mentioned properties increased with increasing salt weight ratios at the same frequency. The experimental results also showed an increase in AC electrical conductivity with increasing frequency, for all polymer blend films, and the AC electrical conductivity also increased with an increase in the weight ratio of the salt at the same frequency. The effect of the salt weight ratio on the mechanical properties of the salt-reinforced PVA:PVP polymer blend films was also studied. The experimental results obtained from the tensile test of the salt-reinforced polymer blend films show significant change in the values of tensile strength, elongation at break, and Young’s modulus with increasing salt weight ratios; the hardness value first increases then decreases with increasing salt weight ratios, and the fracture energy value increases with increasing salt weight ratios, thus they could be good candidates for hard adhesives with low flexibility.

A Review on Mechanical Properties of Natural Fibre Reinforced PLA Composites

2021 ◽  
Vol 15 ◽  
Author(s):  
Agnivesh Kumar Sinha ◽  
Kasi Raja Rao ◽  
Vinay Kumar Soni ◽  
Rituraj Chandrakar ◽  
Hemant Kumar Sharma ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymer Composites ◽  
Biodegradable Polymer ◽  
Weight Ratio ◽  
Natural Fibre ◽  
Polymer Matrices ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Reinforced Polymer ◽  
Fibre Reinforced Polymer

Presently, scientists and researchers are in an endless quest to develop green, recyclable, and eco-friendly materials. Natural fibre reinforced polymer composites became popular among materialists due to their lightweight, high strength-to-weight ratio, and biodegradability. However, all-natural fibre reinforced polymer composites are not biodegradable. Polymer matrices like poly-lactic acid (PLA) and poly-butylene succinate (PBS) are biodegradable, whereas epoxy, polypropylene, and polystyrene are non-biodegradable polymer matrices. Besides biodegradability, PLA has been known for its excellent physical and mechanical properties. This review emphasises the mechanical properties (tensile, flexural, and impact strengths) of natural fibrereinforced PLA composites. Factors affecting the mechanical properties of PLA composites are also discussed. It also unveils research gaps from the previous literature, which shows that limited studies are reported based on modeling and prediction of mechanical properties of hybrid PLA composites reinforcing natural fibres like abaca, aloe vera, and bamboo fibres.

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