Recyclability and Performance Stability of Corrosion Inhibition Improved Amine-Free Water-Soluble Cutting Coolant

2016 ◽  
Vol 1136 ◽  
pp. 104-109 ◽  
Author(s):  
Kenji Yamaguchi ◽  
Tsuyoshi Fujita ◽  
Yasuo Kondo ◽  
Satoshi Sakamoto ◽  
Subaru Tsukano ◽  
...  
Keyword(s):  
Corrosion Inhibition ◽  
Waste Treatment ◽  
Free Water ◽  
Water Soluble ◽  
Environmental Load ◽  
Machining Processes ◽  
Recycling System ◽  
Treatment Processes ◽  
And Performance ◽  
Inhibition Performance

The concern for environmental problems has been increasing rapidly in recent years. Water-soluble coolants are widely used in machining processes. To reduce management costs and the environmental load of water-soluble coolants, the authors studied a recycling system for water-soluble coolants. With this recycling system, water is extracted from a waste coolant by chemical or biochemical treatment; the recovered water is re-utilized as a diluent for a new coolant. Coolant recyclability depends on the coolant type. Most water-soluble coolants contain alkanolamines for corrosion inhibition and maintenance of putrefaction prevention. However, alkanolamines are difficult to eliminate from water-soluble coolants by chemical and physical waste treatment processes. Some amine-free, water-soluble coolants have been developed and are commercially available. The reduction of environmental load in the treatment of waste coolants is anticipated for amine-free coolants. We applied the recycling process to a commercially available amine-free, water-soluble coolant. The amine-free coolant showed good recyclability and lubricating performance. However, the corrosion inhibition performance of the coolant was inadequate for use in general machining. Recently, our cooperative company developed a prototype amine-free, water-soluble coolant with improved corrosion inhibition. In this study, we experimentally examined the recyclability and performance stability of this newly developed coolant. The experimental results showed that the new amine-free coolant has good corrosion inhibition equivalent to conventional amine-containing coolants. In addition, the recyclability, stability, and cooling and lubricating performance of the coolant are equal to conventional amine-free coolants. The amine-free, water-soluble coolant with improved corrosion inhibition has the advantage that it can be used in the recycling system for water-soluble coolants.

Property and Recyclability Change of Corrosion-Inhibition-Improved Amine-Free Water-Soluble Cutting Fluid with Repeated Recycling

2017 ◽  
Vol 749 ◽  
pp. 65-69
Author(s):  
Kenji Yamaguchi ◽  
Kazuo Ogawa ◽  
Tsuyoshi Fujita ◽  
Yasuo Kondo ◽  
Satoshi Sakamoto ◽  
...  
Keyword(s):  
Corrosion Inhibition ◽  
Metal Cutting ◽  
Free Water ◽  
Water Soluble ◽  
Cutting Fluid ◽  
Water Recovery ◽  
Recycled Water ◽  
Recycling System ◽  
Inhibition Performance ◽  
Cooling And Lubrication

Cutting fluid is commonly used during metal cutting process for cooling and lubrication. Fluid types are generally classified into mineral or fatty oils and water miscible oils. In Japan, the former is called water-insoluble coolants, and the latter is called water-soluble coolants. Water-insoluble coolants are specified as dangerous material by the Japanese law due to its flammability. Therefore, the water-insoluble coolants are not appropriate for unmanned operation of machine tools. Therefore, the usage rate of water-soluble coolants is increasing. Water soluble coolants are diluted with a water by several ten times. The waste management of the water-soluble coolant become important for environment-conscious green manufacturing. We have been developing a recycling system for water-soluble coolants. In the recycle system, water is extracted from the waste coolant and the water is then reutilized as a diluent of a new coolant. We have developed various types of chemical or bio-chemical water recovery methods for recycling systems. We found a commercially available amine-free water-soluble coolant is suitable for the recycling system. The processing time, processing cost, and the biochemical and chemical oxygen demand of the extracted water are improved by the amine-free water soluble coolant compared with a conventional amine-containing coolant. However, its corrosion inhibition performance was poor in general machining applications. Our cooperative company developed a prototype of a corrosion-inhibition-improved amine-free water-soluble cutting coolant. The prototype coolant showed a good stability and cooling and lubricating performances, and its recyclability was as good as that of conventional amine-free coolants. In this study, we focused on repeated recycling of the prototype coolant. We repeatedly applied the water recycling process to the recycled coolant. The recyclability of the prototype coolant was not affected by repeated recycling; however, process residues increased with the number of recycles, and a deterioration was noticed in the corrosion-inhibition performance of the coolant diluted with recycled water.

Performance Stability of Recycle Amine-Free Water-Soluble Coolant in Long Term Operation

2014 ◽  
Vol 625 ◽  
pp. 530-535
Author(s):  
Kenji Yamaguchi ◽  
Yasuo Kondo ◽  
Satoshi Sakamoto ◽  
Mitsugu Yamaguchi ◽  
Ryoichi Nakazawa
Keyword(s):  
Environmental Effect ◽  
Free Water ◽  
Water Soluble ◽  
Water Recovery ◽  
Machining Processes ◽  
Cooling Performance ◽  
Recycling System ◽  
Term Operation ◽  
The Stability

Recently, the concern for the environment has been increasing rapidly. In machining processes, the treatment of water-soluble coolants waste has caused environmental problems. Water-soluble coolants contain surfactants, preservatives, and corrosion inhibitors for maintaining the stability and performance of the coolants. To reduce the management cost and environmental effect of water-soluble coolants, the authors have been studying a recycling system for water-soluble coolants. In the recycling system, oil-free recycle water is isolated from the coolant waste and reused as a diluent of the new coolant. The authors have been developing different types of water recovery methods for the recycling system, and the recovered water from the coolant waste has potential as a diluent for a new coolant. In this report, we focused on the amine (alkanolamine) -free water-soluble coolant. Some amine-free water-soluble coolants have been developed and are commercially available. A reduction in the environmental effect in the waste treatment of coolants is expected with amine-free coolants. We have demonstrated that the amine-free water-soluble coolant has equal or better cooling and lubricating performance compared with the conventional amine-containing coolant. In addition, the amine-free coolant shows good recyclability for the recycling system. The processing time of the recycling treatment of the amine-free coolant has been decreased by half with our recycling process compared with the conventional amine-containing coolant. In this report, we examined the stability, cooling performance and lubricating performance of the recycle amine-free water-soluble coolant in long term operation. The recycle amine-free water-soluble coolant is operated in a 3-axis machining center for several months. We observed concentration, pH, corrosion inhibition performance, cooling performance, and lubricating performance of the coolant. The results from these experiments show the amine-free water-soluble coolant has the advantage to use in the recycling system for water-soluble coolant.

scholarly journals Water-Soluble and Biodegradable Pectin-Grafted Polyacrylamide and Pectin-Grafted Polyacrylic Acid: Electrochemical Investigation of Corrosion-Inhibition Behaviour on Mild Steel in 3.5% NaCl Media

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
R. Geethanjali ◽  
A. Ali Fathima Sabirneeza ◽  
S. Subhashini
Keyword(s):  
Electron Microscopy ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Polyacrylic Acid ◽  
Water Soluble ◽  
Electrochemical Investigation ◽  
Grafted Polymers ◽  
Tafel Polarization ◽  
Inhibition Performance ◽  
Scanning Electron

Pectin-g-polyacrylamide (denoted as Pec-g-PAAm) and pectin-g-polyacrylic acid (denoted as Pec-g-PAA) were synthesized using pectin, acrylamide, and acrylic acid as starting materials. The grafted polymers were characterized using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analyser (TGA), and scanning electron microscopy (SEM). The corrosion inhibition behaviour of the grafted polymers on mild steel in 3.5% NaCl was evaluated electrochemically through Tafel polarization and impedance studies. The corrosion inhibition performance of both the polymers was found to be around 85%.

The Preparation and Performance of a Multifunctional Corrosion Inhibitor in Seawater

2013 ◽  
Vol 773 ◽  
pp. 704-708
Author(s):  
Xin Wang ◽  
Zhen Fa Liu ◽  
Zhan Liu ◽  
Yun Juan Wu ◽  
Li Hui Zhang
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Zinc Sulfate ◽  
Inhibition Rate ◽  
Sodium Gluconate ◽  
Polyaspartic Acid ◽  
Corrosion Tests ◽  
And Performance ◽  
Inhibition Performance

A multifunctional corrosion inhibitor was prepared from polyaspartic acid (PASP), sodium gluconate,zinc sulfate,hydroxyphosphonoacetic acid (HPAA) and benzotriazole (BTA). The performance of corrosion inhibition was evaluated by rotary hanging-piece corrosion tests and steady polarization. The result showed that the corrosion inhibitor was an anodic inhibitor and had good corrosion inhibition performance both on A3 carbon steel and H62 copper in seawater. The corrosion inhibition rate of A3 carbon steel was 93.15% and the corrosion inhibition rate of H62 copper was 93.55% when the concentration of corrosion inhibitor was 150 mgL-1in seawater at 40°C.

Preparation and Performance of Enviromentally Friendly Chemical Cleaner

2012 ◽  
Vol 557-559 ◽  
pp. 1552-1555
Author(s):  
Zhen Fa Liu ◽  
Li Hui Zhang ◽  
Mei Fang Yan ◽  
Rui He
Keyword(s):  
Stainless Steel ◽  
Citric Acid ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Sulfamic Acid ◽  
Corrosion Testing ◽  
Inhibition Mechanism ◽  
Biodegradation Rate ◽  
And Performance ◽  
Inhibition Performance

A enviromentally friendly solid chemical cleaner is made from citric acid,sulfamic acid,polyasparticacid,sulfourea and accessory ingredient.The performances of corrosion inhibition and biodegradability of cleaner are studied by the static hanging piece and shaking-bottle incubating test.The corrosion inhibition mechanism of cleaner is studied by potent iodynamic polarization and the corrosion testing piece is observed by means of SEM.The results show that the cleaner has good corrosion inhibition performance on carbon steel,stainless steel,copper and aluminum.The biodegradation rate is above 94% after 28 days.

scholarly journals The “ReWaste4.0” Project—A Review

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 764
Author(s):  
Renato Sarc
Keyword(s):  
Circular Economy ◽  
Industry 4.0 ◽  
Waste Treatment ◽  
Digital Communication ◽  
Review Article ◽  
Plant Performance ◽  
Energy Materials ◽  
Treatment Processes ◽  
Mixed Waste ◽  
Further Development

ReWaste4.0 is an innovative and cooperative K-Project in the period 2017–2021. Through ReWaste4.0 the transformation of the non-hazardous mixed municipal and commercial waste treatment industry towards a circular economy has started by investigating and applying the new approaches of the Industry 4.0. Vision of the ReWaste4.0 is, among others, the development of treatment plants for non-hazardous waste into a “Smart Waste Factory” in which a digital communication and interconnection between material quality and machine as well as plant performance is reached. After four years of research and development, various results have been gained and the present review article summarizes, links and discuss the outputs (especially from peer-reviewed papers) of seven sub-projects, in total, within the K-project and discusses the main findings and their relevance and importance for further development of the waste treatment sector. Results are allocated into three areas, namely: contaminants in mixed waste and technical possibilities for their reduction as well as removal; secondary raw and energy materials in mixed waste and digitalization in waste characterization and treatment processes for mixed waste. The research conducted in ReWaste4.0 will be continued in ReWaste F for further development towards a particle-, sensor- and data-based circular economy in the period 2021–2025.

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