Corrosion Behavior of Die-Cast and Thixocast AXJ530 Magnesium Alloy in Chloride Medium

2006 ◽  
Vol 15-17 ◽  
pp. 449-454 ◽  
Author(s):  
Sofiene Amira ◽  
M. Shehata ◽  
Dominique Dubé ◽  
R. Tremblay ◽  
Edward Ghali
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Corrosion Behavior ◽  
Electrochemical Noise ◽  
Noise Analysis ◽  
Nacl Solution ◽  
Chloride Medium ◽  
Die Cast ◽  
Immersion Technique ◽  
Superior Corrosion Resistance

The corrosion behavior of AXJ530 magnesium alloy in 3.5% NaCl solution at 25°C and pH 7.25 has been studied. Die-cast and thixocast specimens were tested using constant immersion technique, potentiodynamic polarization measurements and electrochemical noise analysis. The microstructure of cast specimens and their surface aspect after corrosion tests were analysed and compared. The results show that thixocast specimens have the best corrosion resistance. Their superior corrosion resistance can be attributed mainly to the presence of large pre-existing α-Mg grains.

The Influence of Sn Addition on the Corrosion Behavior of Mg-5Al-1Zn Alloy

2009 ◽  
Vol 620-622 ◽  
pp. 153-156 ◽  
Author(s):  
Kyung Chul Park ◽  
Byung Ho Kim ◽  
Jong Jin Jeon ◽  
Yong Ho Park ◽  
Ik Min Park
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Volume Fraction ◽  
Secondary Phases ◽  
Nacl Solution ◽  
High Hydrogen ◽  
Hydrogen Overvoltage ◽  
Mg2sn Phase ◽  
Superior Corrosion Resistance

In the present work, the effect of Sn addition on the corrosion behavior of Mg–5Al–1Zn alloys was investigated. Microstructure, potentiodynamic polarization and immersion tests were carried out in 3.5% NaCl solution of pH 7.2 to estimate the corrosion behavior of AZ51 alloys with and without Sn addition. Mg17Al12 and Mg2Sn phases were mainly precipitated in inter-dendrite structures. With increasing the Sn content, the volume fraction of the Mg2Sn phase was increased and coarsening tendency was observed. The corrosion resistance was increased by Sn addition. Especially, the AZ51-5wt.%Sn alloy characterized the superior corrosion resistance among the four alloys. The Sn is known for a high hydrogen overvoltage and the secondary phases effectively formed the network structure, resulting in a drastically decreasing corrosion rate of AZ51 alloy.

Corrosion Behavior of Die-Cast and Thixocast AXJ530 Magnesium Alloy in Chloride Medium

2006 ◽  
pp. 449-454
Author(s):  
Sofiene Amira ◽  
M. Shehata ◽  
Dominique Dubé ◽  
R. Tremblay ◽  
Edward Ghali
Keyword(s):  
Magnesium Alloy ◽  
Corrosion Behavior ◽  
Chloride Medium ◽  
Die Cast

scholarly journals Corrosion Behavior of Chemical Oxidation Film of Magnesium Alloy in NaCl Solution

2021 ◽  
Vol 719 (2) ◽  
pp. 022092
Author(s):  
De Cheng ◽  
Chen Wen ◽  
Jingying Bai ◽  
Yeshen Qin ◽  
Baocheng Jiao
Keyword(s):  
Magnesium Alloy ◽  
Corrosion Behavior ◽  
Chemical Oxidation ◽  
Nacl Solution

scholarly journals Effect of Fluid Flow on the Corrosion Performance of as-Cast and Heat-Treated Nickel Aluminum Bronze Alloy (UNS C95800) in Saline Solution

2021 ◽  
Vol 2 (1) ◽  
pp. 61-77
Author(s):  
Hamid Reza Jafari ◽  
Ali Davoodi ◽  
Saman Hosseinpour
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Flow Rate ◽  
Solution Temperature ◽  
Aluminum Bronze ◽  
Nickel Aluminum ◽  
Nacl Solution ◽  
Flow Conditions ◽  
Heat Treated ◽  
Nickel Aluminum Bronze

In this work, the corrosion behavior and surface reactivity of as-cast and heat-treated nickel aluminum bronze casting alloy (UNS C95800) in 3.5 wt% NaCl solution is investigated under stagnant and flow conditions. Increasing flow rate conditions are simulated using a rotating disk electrode from 0 to 9000 revolutions per minute (rpm). Optical micrographs confirm the decrease in the phase fraction of corrosion-sensitive β phase in the microstructure of C95800 after annealing, which, in turn, enhances the corrosion resistance of the alloy. Electrochemical studies including open circuit potentiometry, potentiodynamic polarization, and electrochemical impedance spectroscopy are performed to assess the effect of flow rate and heat treatment on the corrosion of samples at 25 and 40 °C in 3.5 wt% NaCl solution. For both as-cast and heat-treated samples, increasing the flow rate (i.e., electrode rotating rate) linearly reduces the corrosion resistance, indicating that the metal dissolution rate is significantly affected by hydrodynamic flow. Increasing the solution temperature negatively impacts the corrosion behavior of the as-cast and heat-treated samples at all flow conditions.

Improving Corrosion Resistance of Hot Extruded Mg-Sn-Al-Ce Magnesium Alloy by Rapid Solidification

2017 ◽  
Vol 904 ◽  
pp. 80-84 ◽  
Author(s):  
Peng Cheng ◽  
Yun Gui Chen ◽  
Wu Cheng Ding
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Rapid Solidification ◽  
Corrosion Behavior ◽  
Corrosion Products ◽  
Uniform Particles

The corrosion behavior and microstructure of hot extruded Mg-5 wt.%Sn-4 wt.%Al-2 wt.%Ce alloy by rapid solidification ribbon (RS-EX TAE542) are investigated. The results shows that corrosion resistance of RS-EX alloy is remarkably improved, compared with that of hot extruded TAE542 alloy by homogenized ingot (HI-EX TAE542). Relatively compact corrosion products and bedded corrosion surface of RS-EX alloy is connected with the fine grains and uniform particles caused by rapid solidification, and they can suppress the corrosion reactions.

scholarly journals Assessment of nickel titanium and beta titanium corrosion resistance behavior in fluoride and chloride environments

2013 ◽  
Vol 83 (5) ◽  
pp. 864-869 ◽  
Author(s):  
Elisa J. Kassab ◽  
José Ponciano Gomes
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Fluoride Concentration ◽  
Nickel Titanium ◽  
Localized Corrosion ◽  
General Corrosion ◽  
Nacl Solution ◽  
Galvanic Coupling ◽  
Beta Titanium

ABSTRACT Objective: To assess the influence of fluoride concentration on the corrosion behavior of nickel titanium (NiTi) superelastic wire and to compare the corrosion resistance of NiTi with that of beta titanium alloy in physiological solution with and without addition of fluoride. Materials and Methods: NiTi corrosion resistance was investigated through electrochemical impedance spectroscopy and anodic polarization in sodium chloride (NaCl 0.15 M) with and without addition of 0.02 M sodium fluoride (NaF), and the results were compared with those associated with beta titanium. The influence of fluoride concentration on NiTi corrosion behavior was assessed in NaCl (0.15 M) with and without 0.02, 0.04, 0.05, 0.07, and 0.12 M NaF solution. Galvanic corrosion between NiTi and beta titanium were investigated. All samples were characterized by scanning electron microscopy. Results: Polarization resistance decreased when NaF concentration was increased, and, depending on NaF concentration, NiTi can suffer localized or generalized corrosion. In NaCl solution with 0.02 M NaF, NiTi suffer localized corrosion, while beta titanium alloys remained passive. Current values near zero were observed by galvanic coupling of NiTi and beta titanium. Conclusions: There is a decrease in NiTi corrosion resistance in the presence of fluoride. The corrosion behavior of NiTi alloy depends on fluoride concentration. When 0.02 and 0.04 M of NaF were added to the NaCl solution, NiTi presented localized corrosion. When NaF concentration increased to 0.05, 0.07, and 0.12 M, the alloy presented general corrosion. NiTi corrosion resistance behavior is lower than that of beta titanium. Galvanic coupling of these alloys does not increase corrosion rates.

Improved Corrosion Resistance and Increased Hardness of Copper Substrates from Cu-Ni/Ni-P Composite Coatings

MRS Advances ◽  
2020 ◽  
Vol 5 (40-41) ◽  
pp. 2129-2137 ◽  
Author(s):  
Wenwen Dou ◽  
Wen Li ◽  
Yuchen Cai ◽  
Mengyao Dong ◽  
Xiaojing Wang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Copper Substrate ◽  
Electrolytic Deposition ◽  
Deposition Method ◽  
Nacl Solution ◽  
Current Densities ◽  
Superior Corrosion Resistance ◽  
Deposition Conditions

ABSTRACTTo improve the corrosion resistance and to increase the hardness of copper substrate in marine environment, the Cu-Ni/Ni-P composite coatings were prepared on the copper substrate using the galvanostatic electrolytic deposition method. The deposition current densities were explored to find the optimized deposition conditions for forming the composite coatings. Corrosion resistance properties were analyzed using the polarization curves and electrochemical impedance spectroscopy (EIS). Considering the corrosion resistance and hardness, the −20 mA/cm2 was selected to deposit Cu-Ni coatings on copper substrate and the −30 mA/cm2 was selected to deposit Ni-P coating on the Cu-Ni layer. The Cu-Ni/Ni-P composite coatings not only exhibited superior corrosion resistance compared to single Cu-Ni coating in 3.5 wt.% NaCl solution, but also showed much better mechanical properties than single Cu-Ni coating.

scholarly journals Comparison of Corrosion Resistance in Physiological Saline Solution of Two Austenitic Stainless Steels – 316LV and REX734

2017 ◽  
Vol 11 (2) ◽  
pp. 91-95 ◽  
Author(s):  
Eliza Romańczuk ◽  
Zbigniew Oksiuta
Keyword(s):  
Corrosion Resistance ◽  
Stainless Steels ◽  
Saline Solution ◽  
Austenitic Stainless Steels ◽  
Physiological Saline ◽  
Nacl Solution ◽  
Corrosion Properties ◽  
Physiological Saline Solution ◽  
Superior Corrosion Resistance ◽  
Lower Nickel

AbstractIn this work two austenitic stainless steels, REX734 and 316LV were tested in terms of their microstructure and corrosion properties. The REX734 is a newer generation stainless steel, with modified chemical composition, in comparison to the 316LV grade. Potentiodynamic study of corrosion resistance was conducted in physiological saline solution (0.9% NaCl solution). In spite of the similarities of microstructure, grain size and phase structure in both materials, the corrosion tests revealed that the REX734, with lower nickel and higher nitrogen content, had better corrosion resistance than 316LV. Repassivation potential in the REX734 was almost six times higher than for the 316LV steel. Superior corrosion resistance of the REX734 steel was also confirmed by surface observations of both materials, since bigger and more densely distributed pits were detected in 316LV alloy.

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