Polymerization of Methyl Methacrylate with a Novel Titanium Complex
2011 ◽
Vol 179-180
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pp. 1203-1207
Keyword(s):
Novel titanium complex [2-O-(5- NO2)C6H3CH=N[(C6H4) –2-O ]]2TiCl2 (1) has been prepared by treatment of the ligand complex 1a with TiCl4•2THF in dichloromethane solution. The complex 1a and 1 were characterized by 1H-NMR . Activated by MAO, Complex 1 displayed very high activity for methyl methacrylate polymerization and the viscosity-average molecular weight of PMMA is more than 35×104 at 60°C.The molecular-weight distribution of PMMA measured by gel permeation chromatography (GPC) is narrow.
2011 ◽
Vol 179-180
◽
pp. 1091-1095
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2020 ◽
Vol 34
(10)
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pp. 12535-12544
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1984 ◽
pp. 227-240
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2011 ◽
Vol 138-139
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pp. 1072-1077
2010 ◽
Vol 129-131
◽
pp. 872-876
2011 ◽
Vol 230-232
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pp. 1005-1009