High-Temperature Thermoelectric Properties of Cu-Substituted Bi2Sr2Co2OY Oxides

2011 ◽  
Vol 228-229 ◽  
pp. 656-660
Author(s):  
Li Min Zhao ◽  
Wei Fen Jiang ◽  
Hao Shan Hao
Keyword(s):  
Grain Size ◽  
High Temperature ◽  
Solid State ◽  
Thermoelectric Properties ◽  
Solid State Reaction Method ◽  
Simultaneous Increase ◽  
Reaction Method ◽  
Seebeck Coefficients ◽  
Cu Substitution ◽  
Free Sample

Bi2Sr2Co2-xCuxOy (x=0.0, 0.2, 0.4) samples were prepared by solid-state reaction method and the effect of Cu substitution on the high-temperature thermoelectric properties was investigated. The presence of Cu element improved the grain size and the thermoelectric properties increased owing to the simultaneous increase of conductivity and Seebeck coefficients. The optimal thermoelectric performance was obtained in x=0.2 sample and the power factor was two times as large as that in Cu-free sample at 923K.

Thermoelectric Properties of Cu-Substituted Bi2Ca2Co2Oy Misfit Oxides

2011 ◽  
Vol 284-286 ◽  
pp. 2263-2267 ◽  
Author(s):  
Hao Shan Hao ◽  
Qing Lin He ◽  
Li Min Zhao
Keyword(s):  
Electrical Conductivity ◽  
Grain Size ◽  
High Temperature ◽  
Solid State ◽  
Thermoelectric Properties ◽  
Solid State Reaction Method ◽  
Reaction Method ◽  
Seebeck Coefficients ◽  
Cu Substitution ◽  
Performance System

Co2-xCuxOy (x=0.0, 0.2, 0.4) Samples were prepared by solid-state reaction method and the effect of Cu substitution on the thermoelectric properties was investigated. The presence of Cu element improved the grain size and electrical conductivity, but Seebeck coefficients were reduced by Cu substitution. It was found Cu substitution is an effective way to improve the thermoelectric performance system at high temperature.

High-Temperature Thermoelectric Properties of Pb- and La-Substituted Bi2Sr2Co2Oy Misfit Compounds

2010 ◽  
Vol 105-106 ◽  
pp. 336-338 ◽  
Author(s):  
Hao Shan Hao ◽  
Jin Qin Ye ◽  
Yong Tao Liu ◽  
Xing Hu
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Thermoelectric Properties ◽  
Power Factor ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Thermoelectric Performance ◽  
Simultaneous Increase ◽  
Reaction Method ◽  
Seebeck Coefficients

Pb- and La-substituted (Bi,Pb)2(Sr,La)2Co2Oy samples were prepared by solid-state reaction method and the effect of element substitution on the high-temperature thermoelectric properties was investigated. It was found that the presence of Pb and La elements improved the thermoelectric properties of the Bi2Sr2Co2Oy system owing to the simultaneous increase of conductivity and Seebeck coefficients. The optimal thermoelectric performance was obtained in Pb and La co-substituted samples and the power factor could reach 2.1×10-4Wm-1K-2 at 1000K.

Influence of R3+ ion sizes on the thermoelectric properties of RBaCo4O7+δ ceramics

2015 ◽  
Vol 29 (26) ◽  
pp. 1550154 ◽  
Author(s):  
F. Gao ◽  
Q. L. He ◽  
F. Wu ◽  
D. L. Yang ◽  
X. Hu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Electrical Resistivity ◽  
Solid State ◽  
Thermoelectric Properties ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Oxygen Adsorption ◽  
Reaction Method ◽  
Transition Phenomenon ◽  
Seebeck Coefficients

The influence of [Formula: see text] ion sizes on the electrical resistivity, Seebeck coefficients, thermal conductivity and [Formula: see text] values of [Formula: see text] prepared by the solid-state reaction method was investigated from 373 K to 973 K. The electrical resistivity decreases with decreasing [Formula: see text] ion sizes. Both the electrical resistivity and the Seebeck coefficients have a transition at about 630 K. Especially, the transition phenomenon disappears gradually with decreasing [Formula: see text] ion sizes, and is attributed to the oxygen adsorption of [Formula: see text]. The [Formula: see text] values increase with rising temperature or decreasing [Formula: see text] ion sizes. The [Formula: see text] with the smallest [Formula: see text] size has the maximum [Formula: see text] value that reaches 0.1 at 973 K.

Thermoelectric Characteristics of Pb- and La-Doped Bi2Ba2Co2OY Ceramics

2011 ◽  
Vol 228-229 ◽  
pp. 804-808 ◽  
Author(s):  
Hao Shan Hao ◽  
Hai Peng Yu ◽  
Li Min Zhao
Keyword(s):  
Electrical Conductivity ◽  
High Temperature ◽  
Solid State ◽  
Solid State Reaction Method ◽  
Reaction Method ◽  
Co Doping ◽  
Seebeck Coefficients ◽  
Element Doping ◽  
Pb Doping ◽  
La Doped

Pb- and La-doped (Bi,Pb)2(Ba,La)2Co2Oy ceramics were prepared by solid-state reaction method and the effect of element doping on the thermoelectric characteristics was investigated. Pb and La doping increased the electrical conductivity and transformed the conduction from a metal-like behavior to a semiconducting one. Different from the undoped samples, the values of Seebeck coefficients decreased with the increase of the temperature in the Pb- and La-doped samples. Pb doping in Bi2Ba2Co2Oy system improved the thermoelectric characteristics at high temperature and Pb/La co-doping improved thermoelectric characteristics at low temperature.

A high temperature stable piezoelectric strain of KNN-based ceramics

2018 ◽  
Vol 6 (41) ◽  
pp. 19967-19973 ◽  
Author(s):  
Zhenyong Cen ◽  
Yu Huan ◽  
Wei Feng ◽  
Yan Yu ◽  
Peiyao Zhao ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid State Reaction ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Piezoelectric Strain

Lead-free (1 − x)(0.96K0.46Na0.54Nb0.98Ta0.02O3–0.04Bi0.5(Na0.82K0.18)0.5ZrO3)–xCaZrO3 ((1 − x)(0.96KNNT–0.04BNKZ)–xCZ) piezoelectric ceramics were prepared by the conventional solid-state reaction method.

Superconducting Compound Hg0.8Sb0.2Ba2Ca2Cu3O8+δ Compared with Hg0.8Sb0.2Ba2Ca1Cu2O6+δ to Evaluate Transition Temperature

2020 ◽  
Vol 18 (11) ◽  
pp. 14-18
Author(s):  
Abbas K. Saadon ◽  
Kareem A. Jasim ◽  
Auday H. Shaban
Keyword(s):  
High Temperature ◽  
Transition Temperature ◽  
Solid State ◽  
Solid State Reaction ◽  
Hot Spot ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Reaction Method ◽  
X Ray ◽  
Superconducting Compound

The high temperature superconductor’s compounds are one of the hot spot field of science, due to their applications in industries. Hg0.8Sb0.2Ba2Ca2Cu3O8+δ and Hg0.8Sb0.2Ba2Ca1Cu2O6+δ, were manufactured using a doable-step of solid state reaction method. The samples were sintered at 800 ° C. The transition temperatures Tc are found from electrically resistively by using four probe techniques. The resistivity become zero when the transition temperature Tc(offset) have 131 and 119 K, and the onset temperature Tc(onset) have 139 K for Hg0.8Sb0.2Ba2Ca2Cu3O8+δ and 132 K for Hg0.8Sb0.2Ba2Ca1Cu2O6+δ. Analysis of X-ray diffraction showed a tetragonal structure with lattice parameters changes for all samples.

scholarly journals The investigation of electrical properties and microstructure of ZnO-doped Ba0.9Sr0.1TiO3 ceramics

2017 ◽  
Vol 07 (01) ◽  
pp. 1750007 ◽  
Author(s):  
Gang Liu ◽  
Wentao Jiang ◽  
Jingyong Jiao ◽  
Li Liu ◽  
Ziyang Wang ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Grain Size ◽  
Dielectric Properties ◽  
Solid State ◽  
Breakdown Strength ◽  
Electrical Breakdown ◽  
Xrd Analysis ◽  
Solid State Reaction Method ◽  
Reaction Method ◽  
Electrical Breakdown Strength

Ba[Formula: see text]Sr[Formula: see text]TiO3 ceramics with or without ZnO have been prepared by traditional solid state reaction method. The XRD analysis showed that the doped Zn[Formula: see text] ions diffused into the BST crystal lattice, resulting in the variation of dielectric properties. Especially the dielectric constant at Curie point decreased with doping ZnO content when it is lower than 0.5[Formula: see text]mol%. Due to the promotion of sintering, doping ZnO can enhance the density of ceramics but increase grain size. However, ZnO is a kind of semiconductor and can lead to the decrease in electrical breakdown strength value.

The long persistent luminescence properties of phosphors: Li2ZnGeO4 and Li2ZnGeO4:Mn2+

RSC Advances ◽  
2014 ◽  
Vol 4 (22) ◽  
pp. 11360-11366 ◽  
Author(s):  
Yahong Jin ◽  
Yihua Hu ◽  
He Duan ◽  
Li Chen ◽  
Xiaojuan Wang
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Luminescence Properties ◽  
Persistent Luminescence ◽  
Reaction Method

The blue emitting long persistent phosphor (LPP) Li2ZnGeO4 and green emitting LPP Li2ZnGeO4:Mn2+ were newly prepared by a high temperature solid-state reaction method.

TEXTURED STRUCTURE AND ANISOTROPIC THERMOELECTRIC PROPERTIES OF Ca2.7Bi0.3Co4O9 OXIDE PREPARED BY CONVENTIONAL SOLID-STATE REACTION

2009 ◽  
Vol 23 (01) ◽  
pp. 87-95 ◽  
Author(s):  
HAOSHAN HAO ◽  
QINGLIN HE ◽  
CHANGQING CHEN ◽  
HONGWEI SUN ◽  
XING HU
Keyword(s):  
Electrical Conductivity ◽  
Grain Size ◽  
Solid State ◽  
Seebeck Coefficient ◽  
Power Factor ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Bi Doping

Ca 3-x Bi x Co 4 O 9(x = 0.0, 0.3) samples have been prepared at 1223 K by conventional solid-state reaction method. XRD and SEM investigations reveal that c-axis-oriented structure could be formed in Ca 2.7 Bi 0.3 Co 4 O 9 samples, whereas grains in Ca 3 Co 4 O 9 samples distribute randomly. Moreover, Bi doping increases the grain size and relative density of Ca 2.7 Bi 0.3 Co 4 O 9. The electrical conductivity along the ab plane for Ca 2.7 Bi 0.3 Co 4 O 9 is about four times as large as that along the c-axis, but the Seebeck coefficient is almost isotropic, which leads to a remarkable rise of the power factor in ab plane for Ca 2.7 Bi 0.3 Co 4 O 9 compared with untextured Ca 3 Co 4 O 9. The textured structure in Ca 2.7 Bi 0.3 Co 4 O 9 sample should be attributed to the effect of Bi doping.

Photoluminescence properties of single-component white-emitting Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors for UV LEDs

2015 ◽  
Vol 3 (27) ◽  
pp. 7096-7104 ◽  
Author(s):  
Kai Li ◽  
Mengmeng Shang ◽  
Yang Zhang ◽  
Jian Fan ◽  
Hongzhou Lian ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
White Light ◽  
Solid State Reaction Method ◽  
Photoluminescence Properties ◽  
Light Emitting ◽  
Reaction Method ◽  
White Light Emitting Diodes ◽  
Uv Leds ◽  
Uv Excitation

A series of Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors synthesizedviathe high-temperature solid-state reaction method can emit intense tunable color from purple-blue to red including white under UV excitation, which shows their potential application in UV-pumped white-light-emitting diodes.

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