Effect of Amino Acids on the Corrosion of Steel in Sulfuric Acid Solutions

2011 ◽  
Vol 239-242 ◽  
pp. 3142-3145
Author(s):  
Xin Hua Liu ◽  
Qing Hui Wang ◽  
Yu Lan Rui
Keyword(s):  
Amino Acids ◽  
Weight Loss ◽  
Sulfuric Acid ◽  
Phase Angle ◽  
Potentiodynamic Polarization ◽  
Corrosion Behaviour ◽  
Ac Impedance ◽  
Weight Loss Method ◽  
Loss Method ◽  
Sulfuric Acid Solutions

The influence of amino acids on the corrosion behaviour of steel in H2SO4solutions was studied by potentiodynamic polarization, AC impedance and weight-loss. The Potentiodynamic polarization curve results show that compound amino acids are mixed-type inhibitors which inhibit the reactions of anode and cathode; AC impedance results show that the ternary complex inhibitors have a good synergistic effect and high corrosion rate which can be proved by Resistance (Rt), double-layer capacitance (Cdl), Resistance modulus(︱Z︱), and phase angle from the Nyquist chart, Bode chart and phase angle chart. The weight-loss method show that the corrosion efficiency of composite amino acids are over 90% in 0-16 hours, 30-50°Cand 0.4-2.0mol / L sulfuric acid.

Corrosion Behaviour of Aluminium Alloy in Palm Oil Methyl Ester (B100)

2012 ◽  
Vol 58 (2) ◽  
Author(s):  
W. B. Wan Nik ◽  
S. Syahrullail ◽  
R. Rosliza ◽  
M. M. Rahman ◽  
M. F. R. Zulkifli
Keyword(s):  
Weight Loss ◽  
Methyl Ester ◽  
Corrosion Rate ◽  
Aluminium Alloy ◽  
Palm Oil ◽  
Corrosion Behaviour ◽  
Corrosion Current ◽  
Electrochemical Test ◽  
Weight Loss Method ◽  
Loss Method

The aim of this study is to determine the corrosion effect of palm oil methyl ester (POME) on aluminium alloy 5083 (AA5083). The static immersion test was carried out at 60°C for 68 days according to ASTM G–31–72. The corrosion analysis was done by using weight loss method and electrochemical test. The result from weight loss method shows the decreasing in weight loss of AA5083 which signifies the ability of POME to reduce corrosion rate. The electrochemical test shows the decreasing in polarization resistance,Rp, while the corrosion current densities, Icorr, increase. The corrosion rate reduces from 2.250mpy to 0.1946mpy. The low concentration of fatty acid C18:2 and high anti oxidant element contributes to the reduction of corrosion rate of AA5083 in POME.

scholarly journals Glycerin-Grafted Starch as Corrosion Inhibitor of C-Mn Steel in 1 M HCl solution

2019 ◽  
Vol 9 (21) ◽  
pp. 4684 ◽  
Author(s):  
Sihem Lahrour ◽  
Abderrahim Benmoussat ◽  
Brahim Bouras ◽  
Asma Mansri ◽  
Lahcene Tannouga ◽  
...  
Keyword(s):  
Weight Loss ◽  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
General Corrosion ◽  
Structural Applications ◽  
Weight Loss Method ◽  
Loss Method ◽  
Mn Steel

C-Mn steels, commonly employed in structural applications, are often exposed to near-neutral aerated environments and hence subjected to general corrosion. In broader contexts, for example during pickling, acidizing treatments, or acid-releasing processes, where steel comes in contact with more aggressive solutions, the use of corrosion inhibitors is a supplementary strategy to cathodic protection and/or coating. This work focuses on the C-Mn steel corrosion protection in the presence of HCl, either as process fluid or by product. In order to avoid the toxicological issues related to conventional synthetic products, a bio-copolymer containing glycerin-grafted starch, synthesized by modification of maize starch, was studied as a “green” corrosion inhibitor by the weight loss method and electrochemical techniques (open circuit potential, potentiodynamic polarization and electrochemical impedance spectroscopy). Corrosion-related parameters, such as inhibitor concentration and temperature, were varied and optimized to characterize the corrosion process. Results showed that inhibition efficiency increases with increasing bio-copolymer concentration, reaching a maximum of 94%at the concentration of 300 mg L−1. The kinetic and thermodynamic parameters were determined and discussed. The obtained values of corrosion potential and corrosion current density, Ecorr and icorr, obtained by potentiodynamic polarization, are in agreement with the weight loss method. The corrosion current densities decrease when the concentration of the inhibitor increases.

scholarly journals Effect of N-(6-aminobenzo[d]thiazol-2-yl)benzamide and 2,6-diamino-benzothiazole as Corrosion Inhibitor in acid medium

2016 ◽  
Vol 12 (12) ◽  
pp. 4593-4613
Author(s):  
Rekha. S ◽  
Kannan. K ◽  
Gnanavel. S
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Acid Medium ◽  
Potentiodynamic Polarization ◽  
Inhibition Efficiency ◽  
Free Energy Of Adsorption ◽  
Weight Loss Method ◽  
Ft Ir ◽  
Loss Method

2-amino-6-nitrobenzothiazole(ANBT) was used as an inhibitor for the corrosion of mild steel in acid medium since the inhibition efficiency was low for that compound, 2,6-diaminobenzothiazole (DABT) and N-(6-aminobenzo [d] thiazol-2-y1) benzamide(ABTB) was synthesized,  and characterized by FT-IR, H1NMR, and C13NMR.The synthesized compound was tested as a corrosion inhibitor for mild steel in 1N HCl solution using weight loss, Potentiodynamic polarization, and AC impedance techniques. The inhibition efficiency was studied at the different time, temperature and acid concentration by weight loss method. The values of activation energy and free energy of adsorption of these compounds were also calculated, which reveals that the inhibitor was adsorbed on the mild steel by physisorption mechanism. Adsorption obeys Langmuir and Temkin adsorption isotherms. The results obtained by weight loss method revealed that the compound performed as a better inhibitor for mild steel in 1N HCl. Potentiodynamic polarization studies showed that the inhibitor acts as a mixed type inhibitor.AC impedance studies revealed that the corrosion process was controlled by charge transfer process. Surface analysis was studied using SEM and FT-IR.

scholarly journals Inhibition of corrosion of SS 18/8 alloy is sea water by Thiourea-Zn2+ system

2021 ◽  
Vol 62 (3) ◽  
pp. 191-203
Author(s):  
Josephath Praveena ◽  
Somasundaram Gowri ◽  
Gunasekaran Nethravathi ◽  
Vincent Varsha ◽  
Arockiasamy Vieyana ◽  
...  
Keyword(s):  
Weight Loss ◽  
Corrosion Resistance ◽  
Metal Surface ◽  
Sea Water ◽  
Ac Impedance ◽  
Protective Film ◽  
Impedance Spectra ◽  
Weight Loss Method ◽  
Loss Method ◽  
Ac Impedance Spectra

The corrosion resistance of SS 18/8 in natural sea water, in presence of an inhibitor named Thiourea-Zn2+ has been evaluated. Weight loss method, polarization study and AC impedance spectra have been employed to evaluate the corrosion resistance of SS 18/8 alloy in natural sea water, in presence of an inhibitor named Thiourea-Zn2+ system. Weight loss method reveals that Thiourea-Zn2+ system offers a maximum corrosion inhibition efficiency of 95% in controlling corrosion of SS 18/8 alloy in natural sea water. Synergism parameters are found to be greater than 1, confirming the synergistic effect existing between Thiourea-Zn2+. Adsorption of inhibitor molecules on the metal surface obey Langmuir adsorption isotherm. Polarisation study reveals that the inhibitors named Thiourea-Zn2+ system functions as mixed type of inhibitor. AC impedance spectra confirm the formation of a protective film on the metal surface. This formulation of Thiourea-Zn2+ may be used in cooling water systems where SS 18/8 alloy pipelines are used to carry sea water which is used as coolant. Also, Thiourea-Zn2+ coating can be given on SS 18/8 alloy to protect it from corrosion by sea water when SS 18/8 alloy is used as hull plates in ship industry.

scholarly journals ANALYSIS OF CORROSION RATE OF ASTM A 387 GRADE 12 AND A 283 GRADE FOR SULFURIC ACID TANK MATERIAL

2020 ◽  
Vol 1 (2) ◽  
pp. 50-57
Author(s):  
Meryanalinda Meryanalinda ◽  
Dedy Rachman Ardian ◽  
Mochammad Shocib ◽  
Ahmad Yasin
Keyword(s):  
Weight Loss ◽  
Sulfuric Acid ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Remaining Life ◽  
Metal Quality ◽  
Weight Loss Method ◽  
Loss Method ◽  
Preventive Methods

Corrosion is a process of degradation metal quality which is very detrimental in the industry. Especially in an industries related to utilization of acidic liquids such assulfuric acid, hydrochloric acid, etc. If corrosion rate of carbon steel can be estimated, the prediction of remaining life of carbon steel, and the preventive methods of corrosionwould be more appropriate. This will reduce technical, economic and aesthetic losses. The aims of this study was to determine corrosion rate of carbon steel in sulfuric acid. This study used ASTM A 387 Grade 12 and ASTM A 283 Grade A carbon steel type fortank material, where one material is represented by 5 specimen. The corrosion rate of Specimens were measured by the weight loss method for 31 days. The 5 specimens were divided into 3 regions where specimens no.1 and 2 were immersed in  sulfuric acid , specimens no.3 were in the middle area or zone level (partially immersed), and specimens no.4 and 5 were not immersed in sulfuric acid. The highst corrosion rate occured on specimen No.3 with maximum corrosion rate was 0,097 mm/y for ASTM A 387 Gr 12 and 0,096 mm/y untuk material ASTM A 283 Gr A. The results of corrosion rate on ASTM A 387 Grade 12 material are lower than corrosion rate of ASTM A 283 Grade A material. This is caused by presence of Mo and Cr alloy elements in ASTM A 387 Grade 12.

Study on Anti-Corrosion Behaviour of 304 Stainless Steel in Circulating Cooling Water

2012 ◽  
Vol 511 ◽  
pp. 74-77
Author(s):  
Yu Chun Li ◽  
Ya Jiang ◽  
Heng Zheng ◽  
Kang Juan ◽  
Xiao Wei Liu
Keyword(s):  
Weight Loss ◽  
Stainless Steel ◽  
Concentration Ratio ◽  
Corrosion Behaviour ◽  
Cooling Water ◽  
304 Stainless Steel ◽  
Circulating Cooling Water ◽  
Weight Loss Method ◽  
Ratio Condition ◽  
Loss Method

Abstract: The corrosion behaviour of 304SS in cooling water was studied through weight-loss method and electrochemistry measurements in different concentration ratio condition. The results obtained from this study showed that 304SS material was anti-corrosive with inhibitor when concentration ratio of circulating cooling water was 3 ~ 10, especially in CR 10 condition, and the advised CR running range was 3~10.

A Note on Groove Depth Changes Without Wear

1980 ◽  
Vol 8 (1) ◽  
pp. 10-12
Author(s):  
F. C. Brenner
Keyword(s):  
Weight Loss ◽  
Wear Test ◽  
Groove Depth ◽  
High Rate ◽  
Weight Changes ◽  
Wear Rates ◽  
Weight Loss Method ◽  
Loss Method ◽  
And Storage ◽  
Low Rate

Abstract Tread wear rates during first wear measured by groove depth and weight changes do not always agree. Sometimes, the groove depth method shows a high rate and the weight loss method a low rate. Reported here are experiments designed to determine if grooves show depth changes without wear. Four tires were measured before mounting on a wheel, after mounting and inflation, and after inflation and storage. The mounted and inflated tires showed shallower shoulder grooves and deeper center grooves than the unmounted tires. In a second experiment, tires were measured immediately after a tread wear test and then stored mounted for two weeks before remeasuring. Each groove became deeper, and there was no change in the crown radius of any tire.

scholarly journals Synergistic and Antagonistic Effects of Sodium Molybdate-Zn2+System

2012 ◽  
Vol 9 (4) ◽  
pp. 1746-1752 ◽  
Author(s):  
J. Wilson Sahayaraj ◽  
A. John Amalraj ◽  
Susai Rajendran ◽  
N. Vijaya
Keyword(s):  
Aqueous Solution ◽  
Weight Loss ◽  
Inhibition Efficiency ◽  
Sodium Molybdate ◽  
Antagonistic Effect ◽  
Protective Film ◽  
Antagonistic Effects ◽  
Polarization Study ◽  
Weight Loss Method ◽  
Loss Method

The inhibition efficiency (IE) of sodium molybdate (SM) in controlling corrosion of carbon steel in an aqueous solution containing 120 ppm of Cl-, in the absence and presence of Zn2+has been evaluated by weight-loss method. A synergistic effect exists between SM and Zn2+when the concentration of Zn2+is 25 ppm and above. Inhibition efficiencies obtained are greater than 85%. Antagonistic effect exists between SM and Zn2+when the concentration of Zn2+is 10 ppm and below. The SM-Zn2+system shows excellent IE up to third day. Above third day IE decreases. Acceleration of corrosion takes place. Excellent IE is shown at pH 5,7 and 12. At pH 9, IE decreases since Zn2+is precipitated as Zn(OH)2in the bulk of the solution. Polarization study reveals that SM-Zn2+system functions as a mixed inhibitor. FTIR spectra reveal that the protective film consists of Fe2+-SM complex and Zn(OH)2.

Experimental Research on Erosion of P110 Tubing during Perforating

2014 ◽  
Vol 1073-1076 ◽  
pp. 2244-2247
Author(s):  
Hu Sun ◽  
Zhi Jun Ning ◽  
Zu Wen Wang ◽  
Zhen Li ◽  
Zhi Guo Wang
Keyword(s):  
Weight Loss ◽  
Erosion Rate ◽  
Large Scale ◽  
Guar Gum ◽  
Electrochemical Corrosion ◽  
Low Velocity ◽  
Gas Field ◽  
Weight Loss Method ◽  
Loss Method ◽  
Gas Fields

Erosion is a main failure of tubings and downhole tools in Changqing gas field. It is necessary to evaluate the erosion rate for the safety of tubing and strings. In this paper, the erosion of P110 steel, in the 0.2%wt guar gum fracturing fluid which contains sands, is investigated by weight loss method in the self-made jet experiment device. It is indicated that the erosion rate increases with the increment of slurry velocity exponentially. When the slurry velocity is in low velocity area, the electrochemical corrosion of dissolved oxygen dominates in erosion mechanism; when slurry velocity increases into middle velocity area, the weight loss is controlled by the synergism of corrosion-erosion; and when the slurry velocity increases into high velocity area, the weight loss rate is dominantly depended on erosion of particles. The results can provide guidelines for large-scale fracturing work of Changqing gas fields.

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