POSS-NH2/Cyanate Ester Resin Organic-Inorganic Hybrids: Curing Reaction and Dielectric Properties

2011 ◽  
Vol 266 ◽  
pp. 147-150 ◽  
Author(s):  
Zeng Ping Zhang ◽  
Shuan Fa Chen ◽  
Jian Zhong Pei
Keyword(s):  
Dielectric Properties ◽  
Catalytic Effect ◽  
Curing Kinetics ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Curing Reaction ◽  
Ft Ir ◽  
Higher Temperature ◽  
Lower Temperature ◽  
Different Content

A functional POSS monomer (POSS-NH2) was employed to modify cyanate ester (CE) resin. A series of POSS-NH2/CE hybrids containing different content of POSS have been prepared by melt casting and then curing. The curing kinetics and reaction mechanisms of the resin systems were studied by using FT-IR. Dielectric properties of the hybrids were also investigated. FT-IR results show that both temperature and POSS content may influence the curing reaction of CE. POSS-NH2 mainly displays the catalytic effect at higher temperature (220oC). The circumstance is more complex at lower temperature(190oC). CE1 containing 1 wt% of POSS has the best dielectric properties.

The Effect of POSS-NH2 on the Curing Reaction of Cyanate Ester Resin

2011 ◽  
Vol 217-218 ◽  
pp. 274-279 ◽  
Author(s):  
Zeng Ping Zhang ◽  
Jian Zhong Pei ◽  
Shuan Fa Chen ◽  
Hong Zhao Du ◽  
Yong Wen
Keyword(s):  
Reaction Mechanisms ◽  
Catalytic Effect ◽  
Curing Kinetics ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Curing Reaction ◽  
Ft Ir ◽  
Higher Temperature ◽  
Lower Temperature ◽  
Different Content

A functional POSS monomer (POSS-NH2) was employed to modify cyanate ester (CE) resin. A series of POSS-NH2/CE hybrids containing different content of POSS have been prepared by melt casting and then curing. The curing kinetics and reaction mechanisms of the resin systems were studied by using FT-IR. The experimental results show that both temperature and POSS content may influence the curing reaction of CE. POSS-NH2 mainly displays the catalytic effect at higher temperature (220oC). While the circumstance is more complex at lower temperature (190oC).

Preparation and Dielectric Properties of POSS-NH2/Cyanate Ester Resin Organic-Inorganic Hybrids

2011 ◽  
Vol 216 ◽  
pp. 635-639 ◽  
Author(s):  
Zeng Ping Zhang ◽  
Jian Zhong Pei ◽  
Shuan Fa Chen ◽  
Hong Zhao Du ◽  
Yong Wen
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Curing Reaction ◽  
Ft Ir ◽  
Different Content

In order to improve the dielectric and overal properties of cyanate ester (CE) resin, a functional POSS monomer(octa(aminopropyl)silsesquioxane, POSS-NH2), was employed to modify CE. A series of POSS-NH2/CE hybrids (CE, CE1, CE2, CE3 and CE4) containing different content of POSS have been prepared by melt casting and then curing. The curing reaction of the resin systems were monitored by FT-IR. Dielectric properties of the hybrids were investigated in detail. FT-IR results showed the almost disappearance of the –OCN for all resin systems, suggesting the complete curing of CE using the experimental curing technique. Dielectric investigation indicates that CE1 which contains 1 wt% of POSS has the best dielectric properties with not only lowest dielectric constant but also lowest dielectric loss.

Preparation and Properties of Silicon-Containing Arylacetylene Resins with Octa(maleimidophenyl)silsesquioxane

2012 ◽  
Vol 557-559 ◽  
pp. 1152-1156
Author(s):  
Yan Zhou ◽  
Fu Wei Huang ◽  
Fa Rong Huang ◽  
Lei Du
Keyword(s):  
Thermal Stability ◽  
Dielectric Constant ◽  
Dielectric Properties ◽  
Thermal Polymerization ◽  
Curing Process ◽  
Thermal Stabilities ◽  
Curing Reaction ◽  
Air Atmosphere ◽  
Ft Ir ◽  
Dsc Analyses

Modified silicon-containing arylacetylene resins (DMSEPE-OMPS) were prepared from poly(dimethylsilyleneethynylenephenyleneethynylene) (DMSEPE) and Octa(maleimidophenyl)- silsesquioxane (OMPS). The curing reaction of DMSEPE-OMPS resin was studied by FT-IR and DSC techniques. Thermal stability and dielectric properties of cured DMSEPE-OMPS resins were determined. FT-IR and DSC analyses indicate that thermal polymerization of DMSEPE-OMPS resin occurs in the curing process. Thermal stabilities of cured DMSEPE-OMPS resins under N2 and air atmosphere decrease gradually with the increment of OMPS components. The incorporation of OMPS can obviously reduce dielectric constant of DMSEPE-OMPS resins.

scholarly journals Synthesis of Fe3O4 and Fe2O3 nanoparticles using hybrid electrochemical-thermal method

2020 ◽  
Vol 55 (3) ◽  
pp. 221-228
Author(s):  
HA Simol ◽  
R Sultana ◽  
M Y A Mollah ◽  
MS Miran
Keyword(s):  
Iron Oxide ◽  
Total Pore Volume ◽  
Thermal Method ◽  
Prepared Compound ◽  
Xrd Pattern ◽  
Spectral Techniques ◽  
Different Temperatures ◽  
Ft Ir ◽  
Higher Temperature ◽  
Lower Temperature

Nanocrystalline Fe3O4 and Fe2O3 particles were successfully synthesized by an innovative hybrid electrochemical-thermal method. The as-prepared compound was calcined for an hour from 100 to 600oC temperatures. The crystallinity, morphology and chemical state of the synthesized powders were characterized by XRD, TG-DTA, SEM/EDS, FT-IR, and UV–Vis spectral techniques after calcinations. The Brunauer–Emmett–Teller (BET) plots confirmed that iron oxide nanoparticles (NPs) calcined at 400oC has a surface area of 18.28 m2 g-1 with a total pore volume of 0.2064 cc g-1. From XRD pattern it is revealed that the precursor calcined at lower temperature (100-400oC) correspond to Fe3O4,while the ones calcined at higher temperature follow Fe2O3 pattern. The morphology of iron oxide NPs calcined at different temperatures were studied with scanning electron microscope (SEM) and exhibits spherical shaped geometries with average diameters of 80-150nm. Bangladesh J. Sci. Ind. Res.55(3), 221-228, 2020

An in situ (K0.5Na0.5)NbO3-doped barium titanate foam framework and its cyanate ester resin composites with temperature-stable dielectric properties and low dielectric loss

2019 ◽  
Vol 3 (4) ◽  
pp. 726-736 ◽  
Author(s):  
Longhui Zheng ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
Barium Titanate ◽  
Cyanate Ester ◽  
Resin Composites ◽  
Cyanate Ester Resin ◽  
Low Dielectric ◽  
Doped Barium Titanate

High-k composites with temperature-stable dielectric properties and low dielectric loss obtained through building a network with in situ-doped barium titanate foam.

Preparation of hybrid cyanate ester resin in the presence of polysilazane and its properties

2020 ◽  
pp. 095400832095161
Author(s):  
Xiaomeng Huo ◽  
Kangkang Guo ◽  
Fan Wang ◽  
Yaping Zhu ◽  
Huimin Qi
Keyword(s):  
Ir Spectroscopy ◽  
Flexural Modulus ◽  
Cyanate Ester ◽  
Curing Temperature ◽  
Polymerization Reaction ◽  
Polymerization Temperature ◽  
Cyanate Ester Resin ◽  
Short Period ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

A hybrid cyanate ester resin containing polysilazane was prepared via the prepolymerization of bisphenol-A dicyanate ester monomer (BADCy) in the presence of polysilazane (PSZ) under low temperature conditions in a short period of time. Fourier transform-infrared (FT-IR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy reveal that the polymerization reaction of BADCy can be carried out in the presence of PSZ to obtain a hybrid resin below 100°C and polymethylsilazane (PHS) exhibits an improved prepolymerization effect when compared to polydimethylsilazane (PMS). FT-IR spectroscopy and gel permeation chromatography (GPC) showed that the prepolymerization degree of the PHS/BADCy resin increased upon increasing PHS mass fraction from 0 to 12 wt%, polymerization temperature from 60 to 100°C and polymerization time from 0 to 4 h. The PHS/BADCy hybrid resins samples were prepared and their process properties were investigated by rheometry and Differential scanning calorimetry (DSC). The results indicated that their viscosity was <10 Pa.s in the temperature range of 60–130°C, and the initial curing temperature and curing exothermic enthalpy were 121.9°C and 358.9 J/g, respectively. Furthermore, the cured PHS/BADCy resin possesses excellent thermal and mechanical properties, the 5% weight loss temperature (Td5) and glass transition temperature (Tg) were 424–441°C and 273–282°C, respectively. The cured PHS/BADCy resin with 4 wt% PHS showed the highest flexural strength of 146 MPa and flexural modulus of 4.1 GPa.

Investigation on the Effect of Mn on the Dielectric Properties of Ba0.4Sr0.6TiO3/MgAl2O4/MgO Composite Ceramics

2009 ◽  
Vol 421-422 ◽  
pp. 65-68
Author(s):  
Jing Ji Zhang ◽  
Ji Wei Zhai ◽  
Ming Wei Zhang ◽  
Xi Yao
Keyword(s):  
Dielectric Properties ◽  
Solid State ◽  
Solid State Reactions ◽  
Composite Ceramics ◽  
Higher Temperature ◽  
Lower Temperature ◽  
Three Phases

xMnCO3–(1–x)[70wt% (10wt% MgO–90wt% Ba0.4Sr0.6TiO3)–30wt% MgAl2O4] (where x=0.0, 0.5, 1.0, 2.0, 5.0 and 10.0wt%) composite ceramics have been prepared through the solid-state reactions. Three phases, corresponding to the Ba0.4Sr0.6TiO3(BST), MgAl2O4(MA) and MgO phases, are clearly visible in the composite ceramics. The permittivity peak is initially enhanced and shifted toward a higher temperature and then suppressed, shifted toward a lower temperature. Meanwhile, the tunability (calculated by [ε(E0)−ε(E)]/ε(E0)) is also initially improved and then decreased by doping MnCO3.

Significantly improving mechanical, thermal and dielectric properties of cyanate ester resin through building a new crosslinked network with unique polysiloxane@polyimide core–shell microsphere

RSC Advances ◽  
2016 ◽  
Vol 6 (47) ◽  
pp. 40962-40969 ◽  
Author(s):  
Xinyi Dong ◽  
Zhijuan Zhang ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Dielectric Properties ◽  
Cyanate Ester ◽  
Core Shell ◽  
Cyanate Ester Resin

Tough, rigid and thermally resistant resins with outstanding dielectric properties were developed based on polysiloxane@polyimide core–shell microspheres and cyanate ester.

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