Study on Arsenic Removal Efficiency and Mechanism of Titanium Modified Manganese Ore

2011 ◽  
Vol 356-360 ◽  
pp. 1061-1065
Author(s):  
Yong Bing Huang ◽  
Xiu Ying Liu ◽  
Li Li Wang ◽  
Xiao Juan Li ◽  
Shu Xin Tu

Natural manganese ore is a kind of arsenic removal mineral. It is low-cost and widely available. In order to enhance its removal efficiency and adsorption quantity of arsenic, this paper adopted TiCl4 to modify natural manganese ore and optimized the conditions of modification. The results showed that the best modification condition was: TiCl4 at a concentration of 10 mg•L-1, dipping time of 18h, pH 3.05, reaction time of 60 min; under these conditions, the removal rates of As (Ⅲ) and As (Ⅴ) respectively reached 94.87% and 99.31%, much higher compared with natural manganese ore (82.95% and 77.93%). The saturated adsorption quantity of As (Ⅲ) and As (Ⅴ) reached 3.48 mg•g-1 and 3.27 mg•g-1, each increasing 1.25 mg•g-1 and 1.21 mg•g-1. The adsorption of As (Ⅲ) by modified manganese ore fits the Freundlich adsorption isotherm, while As (Ⅴ) fits the Langmuir adsorption isotherm best.

2014 ◽  
Vol 511-512 ◽  
pp. 55-58
Author(s):  
Zhe Qin ◽  
Qian Wang ◽  
Zheng Liu

This paper regarded the sediments of Lake Baiyangdian as the object of study, researched and analyzed ammonia nitrogen adsorption characteristics of sediment samples. The results showed that: the sediments adsorption to ammonia nitrogen reached a state of equilibrium after 2.5h, The ammonia nitrogen adsorption rate was maximum in 0~10min. Sediment adsorption of ammonia nitrogen was higher as ammonia nitrogen liquid balance concentration increased. The adsorption isotherm curve of ammonia nitreogen can be fitted well by the Langmuir adsorption isotherm model. The total maximum adsorption quantity of ammonia nitrogen by the sediments of Lake Baiyangdian is between 54.12mg/kg to 240.12mg/kg.


2013 ◽  
Vol 726-731 ◽  
pp. 1659-1663
Author(s):  
Ning Xin Chen ◽  
Yong Bing Huang ◽  
Jing Dong

Using manganese ore coated with small stones to adsorb arsenic from the contaminated water samples of Yangzonghai Lake, and several factors that may have impacts on the arsenic removal efficiency are analyzed. The result shows that the new adsorbent material has a great effect on arsenic removal. Temperature's effect on arsenic removal efficiency is not obvious. The arsenic removal efficiency increased dramatically in accordance with residence time within 0-660s, and then stabilized. The adsorption process is better when conducted in acidic conditions, the maximum adsorption rate reached 83.0% with the pH of 3.0 and it reached the minimum value of 14.7% when pH is 10. Fe3+ and Ca2+ can slightly promote manganese ore's adsorption of arsenic, and with anions CO32-, SiO32- , efficiency was slightly reduced. When fitting the kinetics data of arsenic removal by coated manganese ore, the adsorption process is correspondent with first-order reaction kinetics model. The adsorption isotherm is more close to the Freundlich isotherm model.


2012 ◽  
Vol 209-211 ◽  
pp. 2058-2062
Author(s):  
Yong Bing Huang ◽  
Jing Dong ◽  
Xian Juan Li ◽  
Li Li Wang ◽  
Ye Li ◽  
...  

Ferrum manganese composite materials (1-3μm) had been successfully synthesized by low-cost ferruginous manganese ore in wet granulation to treat the arsenic wastewater effectively. The experiment showed when the cement content was 10%, the amount of saw dust was 5% and roasting temperature was 250°C, the composite materials was able to meet the demand of the particles strength and the removal rates of As(Ⅲ) and As(Ⅴ) were up to 85.25% and 80.13% respectively. The analysis for the materials of adsorption effect factors indicated as pH value increased, the removal rate reduced. The temperature was in an opposite way. Within 0-40min, the adsorption of arsenic became better and better. After 60min, the process basically reached the adsorption equilibrium. In addition, the removal rate also reduced following with the increasing dosing quantity of SO42- and HPO42-. Especially the HPO42- influenced it heavily. Therefore, it was important to control the content of HPO42- for the arsenic removal.


Irriga ◽  
2018 ◽  
Vol 1 (1) ◽  
pp. 155-170
Author(s):  
Mara Lúcia Cruz de Souza ◽  
José Antonio Rodrigues de Souza ◽  
DÉBORA ASTONI MOREIRA ◽  
JOÃO DE JESUS GUIMARÃES ◽  
ELLEN LEMES SILVA ◽  
...  

UTILIZAÇÃO DE BIOSSORVENTE NO TRATAMENTO DE ÁGUAS RESIDUÁRIAS RICAS EM COBRE (II) E SUA REUTILIZAÇÃO NA PRODUÇÃO DE ALFACE     MARA LÚCIA CRUZ DE SOUZA1; JOSÉ ANTONIO RODRIGUES DE SOUZA 2; DÉBORA ASTONI MOREIRA3; JOÃO DE JESUS GUIMARÃES 4; ELLEN LEMES SILVA 5 E JOÃO VICTOR COSTA6   Departamento de Engenharia Rural, Faculdade de Ciências Agronômicas – FCA – Unesp, Câmpus Botucatu, Avenida Universitária, 3780, CEP 18610-034, Altos do Paraíso, Botucatu/SP, Brasil, [email protected] Departamento de Engenharia Agrícola, Instituto Federal de Educação Ciência e Tecnologia Goiano-Campus Urutaí, Rodovia Geraldo Silva Nascimento Km 2,5, Zona Rural, Urutaí-GO, Brasil, [email protected] Departamento de Engenharia Agrícola, Instituto Federal de Educação Ciência e Tecnologia Goiano-Campus Urutaí, Rodovia Geraldo Silva Nascimento Km 2,5, Zona Rural, Urutaí-GO, Brasil, [email protected] Departamento de Engenharia Rural, Faculdade de Ciências Agronômicas – FCA – Unesp, Câmpus Botucatu, Avenida Universitária, 3780, CEP 18610-034, Altos do Paraíso, Botucatu/SP, Brasil, [email protected] Departamento de Recursos Naturais do Cerrado, Instituto Federal de Educação Ciência e Tecnologia Goiano-Campus Urutaí, Rodovia Geraldo Silva Nascimento Km 2,5, Zona Rural, Urutaí-GO, Brasil, [email protected] Instituto Federal de Educação Ciência e Tecnologia Goiano-Campus Urutaí, Rodovia Geraldo Silva Nascimento Km2.5, Zona Rural, Urutaí-GO, Brasil, [email protected]     1 RESUMO   Neste trabalho objetivou-se, estudar o tratamento de águas residuárias ricas em cobre por meio de biossorção, bem como o posterior reuso deste biossorvente na produção de alface. Para isso, avaliou-se a capacidade de remoção do cobre (II) pela casca de ovo moída por meio da isoterma de adsorção de Langmuir. Posteriormente, para estudar os efeitos do reuso deste adsorvente, diferentes doses foram adicionadas a vasos cultivados com alface, avaliando-se os efeitos no solo e na planta. Os resultados permitiram concluir que a casca de ovo moída apresentou elevada capacidade de remoção do cobre (25,4291 mg g-1), não havendo contaminação do solo e as plantas de alface apresentaram-se aptas para o consumo. Assim, a bioadssorção e o posterior reuso do adsorvente na produção de alface mostrou-se uma técnica ambientalmente adequada e de baixo custo. Palavras-chave: reuso, bioadssorvente, metal pesado.     SOUZA, M. L. C.1; SOUZA, J. A. R.2; MOREIRA, D. A.3; GUIMARÃES, J. J.4; SILVA, E. L.5; COSTA, J. V.6 USE OF BIOSORBENTS IN THE TREATMENT OF WASTEWATER RICH IN COPPER (II) AND THEIR REUSE ON LETTUCE PRODUCTION         2 ABSTRACT   The present work aimed at studying the treatment of wastewater rich in copper by biosorption, and the subsequent reuse of this biosorbent in the production of lettuce. For this, the capacity of copper (II) removal by the egg shell ground by means of the Langmuir adsorption isotherm was evaluated. Subsequently, the effects of reuse of this adsorbent was studied, and different concentrations were added to pots grown with lettuce, evaluating the effects on soil and plant. The results showed that the egg shell ground presented high copper removal capacity (25.4291 mg g-1), with no contamination of the soil and the lettuce plants were suitable for consumption. Thus, biosorption and subsequent reuse of the adsorbent in the production of lettuce proved to be an environmentally adequate and low-cost technique.   Keywords: reuse, biosorbent, heavy metal.


2002 ◽  
Vol 2 (2) ◽  
pp. 281-288 ◽  
Author(s):  
M.M.T. Khan ◽  
K. Yamamoto ◽  
M.F. Ahmed

A variety of treatment processes have been used for arsenic removal from water. In a laboratory study using natural (tubewell) water, ferric chloride salt and alum were used, which are the most studied and widely used flocculents in water treatment due to their low price, comfortable availability and low risk usability. The solubility of arsenate(III) is much more than arsenite(V). Arsenate(III) was converted into arsenite(V) by proper oxidation using bleaching powder as an oxidizing agent before coagulation. The concentrations of ferric chloride salt and alum dose were varied from 10 mg/l to 200 mg/l, and pH was varied from 4 to 9. After intensive investigation, it was found that at pH 7 and for 100 mg/l to 125 mg/l dose of alum, the removal efficiency of arsenic and iron were around 82 to 86% and 92 to 95% respectively. Again, the optimum removal of arsenic and iron were around 90 to 93% and 97 to 100% respectively at pH 7 for 200 mg/l of ferric chloride salt. This research was carried out not only to observe the removal efficiency of arsenic, but also iron. Because most of the tubewells in Bangladesh, sometimes, contain higher amount of iron.


2011 ◽  
Vol 71-78 ◽  
pp. 2753-2758 ◽  
Author(s):  
Yong Bing Huang ◽  
Li Li Wang ◽  
Shu Xin Tu ◽  
Xiu Ying Liu ◽  
Xiao Juan Li ◽  
...  

This paper dealt with the influence of various factors on As(Ⅲ) and As(Ⅴ) removal using ferruginous manganese ore, including environmental factors (temperature, time, light, pH) and coexisting ions(HCO3-,CO32-,Cl-,HPO42-,SiO32-,SO42-,Mg2+,Ca2+,Fe3+). The comprehensive influence of various factors was also studied in orthogonal experiment. The results showed that the removal efficiency of As(Ⅲ) was up to 90.26%, while As(Ⅴ) was only 79.88%, under the conditions of that manganese ore dosage was 0.1000g per 50ml polluted water, reaction time was 1h, pH was 3.05, the concentration of arsenic was 204.45ug/l. Lower pH could achieve higher removal efficiency. Illumination was little beneficial to the removal efficiency. SiO32-, HPO42-, CO32- and HCO3- could reduce the efficiency, due to competitive adsorption and electrostatic repulsion. The results of orthogonal experiment indicated that SiO32- and HPO42- were the greatest competitors with arsenic for adsorptive sites on the manganese ore, while temperature and time had no significant effect on arsenic removal.


2021 ◽  
Vol 1 ◽  
pp. 80-87
Author(s):  
Neni Damajanti ◽  
Anwar Ma’ruf ◽  
Hanafi Khafid Nugraha

Zeolite as an adsorbent has been widely used. Zeolite activation was carried out to increase the absorption. This study aimed to determine the characteristics of the active zeolite and apply it as an adsorbent. The activation process was carried out by adding acid and calcining at 4500C for 6 hours. Remazol Yellow FG is a dye that is widely used in the textile industry. In this study, the adsorption process was carried out on the Remazol Yellow FG solution, then analyzed the effect of changes in pH (5, 6, 7, 8, 9), contact time (30, 60, 90, 120, 150 minutes) and the concentration of Remazol Yellow FG solution ( 50, 100, 150, 200, 250 ppm) on the adsorption of Remazol Yellow FG dye. From the analysis of the sample solution of Remazol Yellow, the values of Ce and qe can be calculated. These values were then used to calculate KL and KF in the Langmuir adsorption isotherm and Freundlich adsorption isotherm models. From the experimental results, it could be seen that as the contact time increased, the adsorption capacity would be greater. However, when the zeolite was already in the saturated phase, the adsorption capacity would tend to decrease. In the Langmuir adsorption isotherm, the KL value was 0.0274 L/mg and in the Freundlich adsorption isotherm model, the KF value was 29.25 L/mg. Remazol Yellow FG adsorption tended to follow the Langmuir adsorption isotherm model with an R2 value of 0.998.


2012 ◽  
Vol 599 ◽  
pp. 354-357
Author(s):  
Hui Xia Lan ◽  
Xiao Feng Liu ◽  
Rui Chen ◽  
Heng Zhang

the adsorption of PCP using aerobic granules was studied. The static adsorption experiments were carried out and the Freundlich and Langmuir adsorption isotherms were applied to describe the biosorption processes and the isotherm constants were evaluated. The Freundlich and Langmuir isothermy adsorption equations obtained from the static experients were q=2.04ce0.82 and q=3.47ce /(1+0.56 ce), respectively. Both the adsorption isotherms described the static adsorption behavior of PCP well. Then the Freundlich adsorption isotherm was used to estimate the adsorption of PCP by aerobic granules in the dynamic state. The results showed that the adsorption mainly occurred in the initial periods during the operation of the reactor.


2019 ◽  
Vol 12 (4) ◽  
pp. 1-8
Author(s):  
Nidaa Adil Jasim ◽  
Tamara Kawther Hussein

Removal of Cd(II) from  aqueous solution through adsorption using flax seeds was studied. Adsorption parameters such as pH, adsorbent particle size, adsorbent dosages, and initial concentrations of metal ions were studied. All experiments were conducted at room temperature. Langmuir and Freundlich adsorption isotherm models were applied to describe the quantitative uptake of Cd(II) ions by adsorbent. The results show that the maximum adsorption removal reach to 77 %   for Cd (II) onto flax seeds, at optimum operating conditions: pH of 5, particle size of 75µm, adsorbent dosage of 2 g/100 ml and metal concentration of  5 mg/L . The equilibrium adsorption data for Cd(II) were better fitted to  Freundlich adsorption isotherm model than Langmuir. The study concludes that the use of flax seeds as an economic and locally adsorbent for removing Cd(II) from polluted solution is effective. Thus offering a low cost material show potential use it to remove heavy metals.


2013 ◽  
Vol 647 ◽  
pp. 753-757 ◽  
Author(s):  
Grace K. Luk

Chemical adsorption of a clay-zeolite pellet medium is being investigated for the removal of total phosphorus from domestic wastewater. The effect of pellet composition, influent concentration, and contact time on the overall removal efficiency is being studied in a five-layer bench-scale model. Results showed that an equilibrium removal of 72% is achieved after a 3 hour contact time, supporting the Freundlich adsorption isotherm model based on the linearization of solute adsorption to equilibrium solvent concentration.


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