Optical Properties of Near-Infrared Cyanine Dye Molecules Adsorbed on Silver Nanoparticles

2012 ◽  
Vol 457-458 ◽  
pp. 1250-1253
Author(s):  
Tao Meng ◽  
Chun Mei Zhang ◽  
Mi Dan Li ◽  
Chun Liu ◽  
Shan Shan Meng

The optical property of near-infrared cyanine dye adsorbed on silver nanopaticals has been studied by means of UV-Vis spectrophotometer. The adsorption of near-IR cyanine dye on silver nanopaticles was highly dependent on the concentration of silver nanoparticles. As a result, in the UV-Vis spectra, it was shown that the “red-shift”, as silver nanoparticles size, increased and the “blue-shift”, as concentration of silver nanoparticle increased as well. The adsorbed spectral peaks of near-infrared cyanine dye disappeared as concentration of silver nanoparticles increased.

2012 ◽  
Vol 457-458 ◽  
pp. 1250-1253
Author(s):  
Tao Meng ◽  
Chun Mei Zhang ◽  
Mi Dan Li ◽  
Chun Liu ◽  
Shan Shan Meng

2012 ◽  
Vol 488-489 ◽  
pp. 103-108 ◽  
Author(s):  
Manisha Tyagi ◽  
Monika Tomar ◽  
Vinay Gupta

The influence of substrate temperature on the UV-Visible-near-IR optical properties, namely the band gap, the Urbach energy and the refractive index of NiO thin films deposited by RF sputtering has been investigated. The optical band gap of thin films showed the blue-shift in the transmission spectra with increase in the substrate temperature which is related to variation in carrier concentration of the deposited films. Urbach energy (EU) values indicate that the films deposited at 400 oC substrate temperature show least structural disorder. The refractive index of the films is found to decrease continuously with increase in the substrate temperature at all photon energies in the visible and near-IR region, and is attributed to the decreasing packing density of the films. Introduction


2021 ◽  
Author(s):  
Luca Tomarchio ◽  
Salvatore Macis ◽  
Lorenzo Mosesso ◽  
Loi T. Nguyen ◽  
Antonio Grilli ◽  
...  

Abstract We report on the optical properties from terahertz (THz) to Near-Infrared (NIR) of the layered magnetic compound CrI3 at various temperatures, both in the para- magnetic and ferromagnetic phase. In the NIR spectral range, we have observed an insulating electronic gap around 1.1 eV which strongly hardens with decreasing temperature. The blue shift observed represents a record in insulating materials and it is a fingerprint of a strong electron-phonon interaction. Moreover, a further gap hardening is observed below the Curie temperature, indicating the establishment of an effective interaction between electrons and magnetic degrees of freedom in the ferromagnetic phase. This interaction is confirmed by the disappearance of some phonon modes in the same phase as expected from a spin-lattice interaction theory. Therefore, the optical properties of CrI3 reveal a complex interaction among electronic, phononic and magnetic degrees of freedom, opening many possibilities for its use in 2-Dimensional heterostructures.


2014 ◽  
Vol 28 ◽  
pp. 91-99 ◽  
Author(s):  
Mou Pal ◽  
A. Martinez Ayala ◽  
N.R. Mathews ◽  
X. Mathew

SnS nanocrystals of sub-10 nm in size were synthesized by a room temperature, non-aqueous chemical route in the presence of different amounts of triethanolamine (TEA) used as a complexing agent. The crystallinity, size, morphology, chemical composition and optical properties of the as-prepared SnS nanoparticles were investigated by powder X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Energy-dispersive X-ray spectroscopy (EDS), micro Raman and optical absorption spectroscopy. The XRD analysis and HRTEM investigation of SnS nanoparticles confirmed the presence of crystalline orthorhombic SnS phase. Upon increasing the amount of TEA, the crystallite size of the samples decreased gradually showing evidence of quantum confinement. EDS analysis showed that SnS nanoparticles (NPs) grown in absence of TEA were highly stoichiometric whereas in TEA capped samples, the atomic concentration of S is slightly higher than that of Sn. As-synthesized SnS nanocrystals displayed strong absorption in the visible and near-infrared spectral regions followed by a blue shift of their absorption edge on increasing the TEA concentration. These nanoparticles were used to prepare SnS paste which was deposited on conducting glass substrates to obtain thin films for photovoltaic applications. The crystallinity, morphology, chemical composition and optical properties of annealed SnS films were investigated.


2002 ◽  
Vol 106 (28) ◽  
pp. 6533-6540 ◽  
Author(s):  
Stefan Franzen ◽  
Jacob C. W. Folmer ◽  
Wilhelm R. Glomm ◽  
Ryan O'Neal

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Luca Tomarchio ◽  
Salvatore Macis ◽  
Lorenzo Mosesso ◽  
Loi T. Nguyen ◽  
Antonio Grilli ◽  
...  

AbstractWe report on the optical properties from terahertz (THz) to Near-Infrared (NIR) of the layered magnetic compound CrI3 at various temperatures, both in the paramagnetic and ferromagnetic phase. In the NIR spectral range, we observe an insulating electronic gap around 1.1 eV which strongly hardens with decreasing temperature. The blue shift observed represents a record in insulating materials and it is a fingerprint of a strong electron-phonon interaction. Moreover, a further gap hardening is observed below the Curie temperature, indicating the establishment of an effective interaction between electrons and magnetic degrees of freedom in the ferromagnetic phase. Similar interactions are confirmed by the disappearance of some phonon modes in the same phase, as expected from a spin-lattice interaction theory. Therefore, the optical properties of CrI3 reveal a complex interaction among electronic, phononic and magnetic degrees of freedom, opening many possibilities for its use in 2-Dimensional heterostructures.


2019 ◽  
Vol 12 (9) ◽  
pp. 3923-3938 ◽  
Author(s):  
Titta Majasalmi ◽  
Ryan M. Bright

Abstract. Vegetation optical properties have a direct impact on canopy absorption and scattering and are thus needed for modeling surface fluxes. Although plant functional type (PFT) classification varies between different land surface models (LSMs), their optical properties must be specified. The aim of this study is to revisit the “time-invariant optical properties table” of the Simple Biosphere (SiB) model (later referred to as the “SiB table”) presented 30 years ago by Dorman and Sellers (1989), which has since been adopted by many LSMs. This revisit was needed as many of the data underlying the SiB table were not formally reviewed or published or were based on older papers or on personal communications (i.e., the validity of the optical property source data cannot be inspected due to missing data sources, outdated citation practices, and varied estimation methods). As many of today's LSMs (e.g., the Community Land Model (CLM), the Jena Scheme of Atmosphere Biosphere Coupling in Hamburg (JSBACH), and the Joint UK Land Environment Simulator (JULES)) either rely on the optical properties of the SiB table or lack references altogether for those they do employ, there is a clear need to assess (and confirm or correct) the appropriateness of those being used in today's LSMs. Here, we use various spectral databases to synthesize and harmonize the key optical property information of PFT classification shared by many leading LSMs. For forests, such classifications typically differentiate PFTs by broad geo-climatic zones (i.e., tropical, boreal, temperate) and phenology (i.e., deciduous vs. evergreen). For short-statured vegetation, such classifications typically differentiate between crops, grasses, and photosynthetic pathway. Using the PFT classification of the CLM (version 5) as an example, we found the optical properties of the visible band (VIS; 400–700 nm) to fall within the range of measured values. However, in the near-infrared and shortwave infrared bands (NIR and SWIR; e.g., 701–2500 nm, referred to as “NIR”) notable differences between CLM default and measured values were observed, thus suggesting that NIR optical properties are in need of an update. For example, for conifer PFTs, the measured mean needle single scattering albedo (SSA, i.e., the sum of reflectance and transmittance) estimates in NIR were 62 % and 78 % larger than the CLM default parameters, and for PFTs with flat leaves, the measured mean leaf SSA values in NIR were 20 %, 14 %, and 19 % larger than the CLM defaults. We also found that while the CLM5 PFT-dependent leaf angle values were sufficient for forested PFTs and grasses, for crop PFTs the default parameterization appeared too vertically oriented, thus warranting an update. In addition, we propose using separate bark reflectance values for conifer and deciduous PFTs and demonstrate how shoot-level clumping correction can be incorporated into LSMs to mitigate violations of turbid media assumption and Beer's law caused by the nonrandomness of finite-sized foliage elements.


2020 ◽  
pp. 2150009
Author(s):  
Shadeeb Hossain

This paper highlights on the coronavirus outbreak caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). At the time of writing this paper, there has been over 6 million confirmed cases worldwide. It is a person–person transmittable infection but there have been cases of asymptomatic carriers. Hence, development of an effective biosensing diagnostic tool can curb its rapid transmission rate. The first part of the paper highlights on the SARS-CoV-2 structure and its resemblance to SARS-CoV. The second part of the paper analyzes on the potential application of gold and silver nanoparticles to generate a red shift that had enhanced the calorimetric property of the MERS-CoV analysis due to transition in its optical property. Other electrochemical techniques that utilized the application of gold nanoparticles are also reviewed. Gold and silver nanoparticles (AuNP and Ag NP) can accelerate the sensitivity upon electrodeposition on the diagnostic tool.


NANO ◽  
2015 ◽  
Vol 10 (02) ◽  
pp. 1550021 ◽  
Author(s):  
Zhankui Cui ◽  
Senlin Li ◽  
Junqiang Zhou ◽  
Jianli Zhang ◽  
Suxiang Ge ◽  
...  

Spherical Bi 2 S 3 nanoparticles (NPs) were prepared by a facile in situ thermal sulfuration method. Different Bi 2 S 3 samples were obtained by controlling the sulfuration time. The products were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), Raman and Fourier-transform infrared (FT-IR) methods. The optical properties were examined by UV-visible-near-infrared (UV-Vis–NIR) and photoluminescence (PL) techniques. The results show that the phase of the products after sulfuration is pure and the spherical shape of Bi NPs has been successfully transmitted to Bi 2 S 3 samples. The light absorption edges exhibit red shift to 1060 nm while the light emission displays blue shift to 868 nm, compared with the energy bandgap of bulk Bi 2 S 3. The reason for the special optical properties of Bi 2 S 3 NPs by this in situ sulfuration route is considered to associate with the defects and quantum size effect of NPs.


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