Photocatalytic Degradation of Methylene Blue Using Porphyrin/TiO2 Complexes Activated by Visible Light

2008 ◽  
Vol 47-50 ◽  
pp. 471-474 ◽  
Author(s):  
Ming Yi Chang ◽  
Chen Yu Chang ◽  
Yung Hsu Hsieh ◽  
Kuo Shan Yao ◽  
Ta Chih Cheng ◽  
...  

The use of TiO2 as photocatalyst to degrade the organic compounds is an effective method of oxidation process and has been widely studied in environmental engineering. However, TiO2 absorbed the UV light which is only small part of sunlight reaching earth surface to activate photocatalytic procedure is a major disadvantage. Therefore, studies on the development of new TiO2 that its photocatalytic activity can be activated by visible light which is the major part of sunlight will be valuable for field application. In this study, we evaluate the photocatalytic degrading efficiency of porphyrins/TiO2 complexes on the organic pollutants under irradiation with visible light (λ= 419 nm). The results showed that the photodecomposition efficiency of methylene blue were up to 95% and 90% respectively after using NiTPP/TiO2 and ZnTPP/TiO2 irradiated with visible light for 6 h. These evidences reveal that the system of porphyrin/TiO2 complexes has significantly high efficiency of photocatalytic degradation under visible light irradiation.

RSC Advances ◽  
2021 ◽  
Vol 11 (30) ◽  
pp. 18519-18524
Author(s):  
Haicheng Li ◽  
Linlin Zang ◽  
Fengtong Shen ◽  
Libin Wang ◽  
Liguo Sun ◽  
...  

Tubular g-C3N4 grown on a carbon framework increased the surface area of bulk g-C3N4, enhanced the absorption of visible light and promoted the photocatalytic performance.


Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1499
Author(s):  
Ying Ma ◽  
Liyiming Tao ◽  
Shi Bai ◽  
Anming Hu

Green synthesis of metal nanoparticles has been gaining great interest due to the increasing need for eco-friendly manufacturing and application of nanomaterials. Metal nanoparticles, especially silver nanoparticles, are widely used in water treatments and as environmental remedy. Here we present a method to synthesize silver nanoparticles at room temperature using green tea extract under visible light irradiation, along with an application for enhanced photocatalytic degradation on methylene blue (MB) dye. Ag nanoparticles were synthesized under different photoreduction times and then further characterized. The photocatalytic rate of synthesized nanoparticles was also investigated and compared with TiO2 nanowires under UV and visible light irradiations. The results showed that Ag nanoparticles can directly degrade MB dye through plasmonic excitation and electron transferring under visible light, and Ag nanoparticles can further enhance TiO2 photonic degradation by enhanced e-h separation with UV and/or a wide band light, including UV light. Ag nanoparticles under visible light photoreduction for 0.5 h presented better behavior for two kinds of plasmonic enhanced photodegradation; the average size of the nanoparticles is about 30 nm. Therefore, the green synthesized Ag nanoparticles exhibit promising prospects in chemical and biological pollutant treatment.


2016 ◽  
Vol 13 (1) ◽  
pp. 110-116 ◽  
Author(s):  
Rani P. Barkul ◽  
Farah-Naaz A. Shaikh ◽  
Sagar D. Delekar ◽  
Meghshyam K. Patil

RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6383-6394 ◽  
Author(s):  
Haishuai Li ◽  
Linlin Cai ◽  
Xin Wang ◽  
Huixian Shi

A noval ternary nanocomposite AgCl/Ag3PO4/g-C3N4 was successfully synthesized for photocatalytic degradation of methylene blue, methylparaben and inactivation of E. coli under visible light irradiation, showing excellent photocatalytic degradation performance and stability.


2021 ◽  
Vol 6 (29) ◽  
pp. 7295-7305
Author(s):  
Jing Xu ◽  
Zhihao Ren ◽  
Xiaoyuan Qiu ◽  
Pengfei Zhu ◽  
Dandan Chen ◽  
...  

2014 ◽  
Vol 29 (20) ◽  
pp. 2473-2482 ◽  
Author(s):  
Yingchang Ke ◽  
Hongxu Guo ◽  
Dongfang Wang ◽  
Jianhua Chen ◽  
Wen Weng

Abstract


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