A Study on the Weatherability of Weathering Steel after Atmospheric Corrosion

2012 ◽  
Vol 479-481 ◽  
pp. 574-577
Author(s):  
Zhi Fen Wang ◽  
Jian Rong Liu ◽  
Li Xin Wu ◽  
Hai E Huang ◽  
Qian Xue Zhou

The weatherability of a weathering steel W450QN was compared with a carbon steel Q345 after 5 years atmospheric corrosion. The results indicated that the corrosion resistance was better for W450QN than Q345 based on the corrosion rate. The characteristics of the rust layers indicated the rust layer on W450QN was denser and thicker than that of Q345. The rust layers were mainly composed of goethite (α-FeOOH) with a few of lepidocrocite (γ-FeOOH). W450QN had better weatherability attributed to the alloying elements of copper, chromium and phosphorus enriched in the rust layer.

2012 ◽  
Vol 629 ◽  
pp. 240-244
Author(s):  
Zhi Fen Wang ◽  
Jian Rong Liu ◽  
Li Xin Wu ◽  
Yi Qiang Sun ◽  
Rong Dong Han

The corrosion resistances of a weathering steel SPA-H and a carbon steel Q345 after atmospheric corrosion rests of two cities were measured. The results showed that the corrosion resistance was better for SPA-H than Q345 based on the corrosion rate. The corrosion rates of two steels at Qionghai city were lower than those of Jiangjin city. The characterization of the rusts showed the rust layer on SPA-H was denser and thinner than that of Q345. The rust layers were mainly composed of goethite (α-FeOOH) with a few of lepidocrocite (γ-FeOOH). SPA-H had better weatherability attributed to the alloying elements of copper, chromium and phosphorus enriched in the rust layer. The environment factor such as the sedimentation of SO2 has more effect on the corrosion rates than other factors such as alloy elements.


2016 ◽  
Vol 63 (4) ◽  
pp. 295-300 ◽  
Author(s):  
Lihua Gong ◽  
Qing Xing ◽  
Huihuang Wang

Purpose The purpose of this paper is to investigate the effect of welding procedure on the corrosion behaviors of weathering steel 09CuPCrNi in marine atmospheric environment. The corrosion processes of weathering steel 09CuPCrNi and its welded joints in marine atmospheric environment were simulated by a salt spray dry-wet test. Design/methodology/approach The corrosion behaviors of the base metal and the welded joints at corrosion times of 2, 4, 8, 12, 24 weeks were investigated by weight loss test, electrochemical techniques, scanning electron microscope (SEM) and electron probe micro-analyzer (EPMA). The corrosion rates, as well as the morphologies and electrochemical characteristics of corrosion products, the distribution of major alloying elements in rust layer were obtained. The influence of welding on the atmospheric corrosion of 09CuPCrNi was studied. Findings The results indicate that the corrosion rate of the 09CuPCrNi welded joints decreases gradually with the corrosion time, and the major alloying elements are enriched in the inner rust layer, which are similar to that of the base metal. In the early stage during the corrosion process, the welded joints with inhomogeneous structure show the poorer corrosion resistance than that of the base metal. However, it looks the opposite way around in the late corrosion stage, when the uniform corrosion products with even thickness of the base metal tend to detach from the substrate easier and earlier and resulting in cracks, which increase the corrosion rate comparatively with that of the welded joints. Originality/value 09CuPCrNi low alloy steel is a kind of typical weathering steel developed in China which is similar to Corten A developed by USA. Nowadays, 09CuPCrNi low alloy steel is widely adopted in many fields which require welding processes. In the past years, the research of weathering steel welded joints was mainly concentrated on the strength, toughness and weldability. Less work has been done to investigate the difference of corrosion evolution and characteristics between the base metal and its welded joints. Thus, the main objective of the present work was to analyze the influence of welding on the atmospheric corrosion.


Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 517
Author(s):  
Bin Sun ◽  
Lei Cheng ◽  
Chong-Yang Du ◽  
Jing-Ke Zhang ◽  
Yong-Quan He ◽  
...  

The atmospheric corrosion behavior of a hot-rolled strip with four types (I–IV) of oxide scale was investigated using the accelerated wet–dry cycle corrosion test. Corrosion resistance and porosity of oxide scale were studied by potentiometric polarization measurements. Characterization of samples after 80 cycles of the wet–dry corrosion test showed that scale comprised wüstite and magnetite had strongest corrosion resistance. Oxide scale composed of inner magnetite/iron (>70%) and an outer magnetite layer had the weakest corrosion resistance. The corrosion kinetics (weight gain) of each type of oxide scale followed an initial linear and then parabolic (at middle to late corrosion) relationship. This could be predicted by a simple kinetic model which showed good agreement with the experimental results. Analysis of the potentiometric polarization curves, obtained from oxide coated steel electrodes, revealed that the type I oxide scale had the highest porosity, and the corrosion mechanism resulted from the joint effects of electrochemical behavior and the porosity of the oxide scale. In the initial stage of corrosion, the corrosion product nucleated and an outer rust layer formed. As the thickness of outer rust layer increased, the corrosion product developed on the scale defects. An inner rust layer then formed in the localized pits as crack growth of the scale. This attacked the scale and expanded into the substrate during the later stage of corrosion. At this stage, the protective effect of the oxide scale was lost.


2011 ◽  
Vol 18 (6) ◽  
pp. 67-73 ◽  
Author(s):  
Feng-yi Mi ◽  
Xiang-dong Wang ◽  
Zhi-pu Liu ◽  
Bing Wang ◽  
Yun Peng ◽  
...  

2014 ◽  
Vol 507 ◽  
pp. 258-262
Author(s):  
Ping Wang ◽  
Zhao Hui Yin ◽  
Han Tao Ren ◽  
Song Xu

The rate of carbon steel in SO2 Atmospheric Corrosion was modeled by grey model GM (1, 1). The accuracy and rationality of prediction model have been evaluated. The result indicated that the model had a better fitting accuracy. By comparing the calculated values with a predicted atmospheric corrosion rate of carbon steel after 264h, it showed that its relative error has been just 0.5619% which had higher forecast reliability.


2020 ◽  
Vol 4 (1) ◽  
Author(s):  
Baozhuang Sun ◽  
Xiaomei Zuo ◽  
Xuequn Cheng ◽  
Xiaogang Li

AbstractThe corrosion of alloy steels with different amounts of Cr was studied using electrochemical tests, wet–dry cycle corrosion, X-ray diffraction, and Kelvin probe force microscopy. The results show that the content of Cr is positively correlated with the corrosion resistance of bare steel, but the corrosion resistance of atmospheric corrosion does not show the same pattern. The atmospheric corrosion resistance of Cr-containing steel exhibits three different stages with the change of Cr element content. When the Cr content is in the range of 1–4%, the corrosion rate is high and does not change within the Cr content. As the Cr content was further increased from 4 to 7%, the corrosion rate exhibited a linear decrease and then drops rapidly when the Cr content reaches 8%. These three different corrosion rate stages are related to the influence of Cr content on Fe3O4 content in the rust layer.


1970 ◽  
Vol 22 ◽  
pp. 34-40
Author(s):  
J. Bhattarai ◽  
A. Kafle ◽  
N. P. Bhattarai

The passivation behavior of carbon steel rods of Nepal is studied in 1 M HCl, 0.5 M NaCl and 1 M NaOH solutions at 25°C, open to air using corrosion tests and electrochemical measurements. The corrosion rate of all the examined steel rods is significantly lower in 1 M NaOH solution (about 10-3 mm/y) than those in 0.5 M NaCl (about 10-2 mm/y) and 1 M HCl (about 101-102 mm/y) solutions. The corrosion rate of SR71 steel rod is remarkably lower (3.65 mm/y) than those of other four different steel rods (3-4 x 102 mm/y) of Nepal in 1 M HCl solution. The ennoblement of the open circuit potentials of all the examined steel rod specimens is clearly observed in 1 M NaOH solution than those in 0.5 M NaCl and 1 M HCl solutions. The open circuit potentials of the steel rods are in the passive potential regions of the iron wire in 1 M NaOH solution. Therefore, steel rods of different companies of Nepal showed significantly high corrosion resistance in 1 M NaOH solution at 25°C.DOI: 10.3126/jncs.v22i0.520Journal of Nepal Chemical SocietyVol. 22, 2007 pp.34-40


Atmósfera ◽  
2017 ◽  
Vol 30 (1) ◽  
pp. 53-61 ◽  
Author(s):  
John Fredy Ríos Rojas ◽  
◽  
David Aperador Rodríguez ◽  
Edwin Arbey Hernández García ◽  
Carlos Enrique Arroyave Posada ◽  
...  

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