Research on the Recovery of Secondary Iron-Bearing Dust in Direct Reduction of Carbon Composite Pellets

2012 ◽  
Vol 524-527 ◽  
pp. 2031-2036
Author(s):  
Yi Shan Li ◽  
Zheng Liang Xue ◽  
En Tang ◽  
Qiang Liu ◽  
Wei Xiang Wang ◽  
...  

In order to recover secondary iron-bearing dust, with converter sludge, mill scale, gravitational ash, casthouse ash as raw materials, high basicity carbon composite pellets are prepared to make iron nuggets through self-reduction at high temperature. The study demonstrates that: The effectively separation of iron and slag, naturally pulverization of the slag phase, and good surface quality of bigger, glosser and brighter iron nuggets can be obtained with reduction temperature 1400 °C,C/O molar ratio 1.1,as well as basicity above 1.8 in this process; The iron phase is not generated well and proportion of small size iron nuggets increases when C/O molar ratio is increased; With C/O molar ratio increases or temperature rises, CO generated increases in direct reduction, which strengthen the reducibility atmosphere in the pellets, beneficial to the processing of desulfuration and dephosphorization; Rising temperature accelerates the generation of molten iron, so that, the fixed carbon contacts with the molten iron longer, which increasing the carbon in iron nuggets. More carbon is provided for the carburizing reaction for the sake of increasing C/O molar ratio, as a result of making more carbon in iron nuggets.

2019 ◽  
Vol 41 (17) ◽  
pp. 2240-2252 ◽  
Author(s):  
Zongliang Zuo ◽  
Qingbo Yu ◽  
Huaqing Xie ◽  
Fan Yang ◽  
Zhicheng Han ◽  
...  

2021 ◽  
Vol 118 (6) ◽  
pp. 602
Author(s):  
Rui Mao ◽  
Fei Wang ◽  
Yuan Xu ◽  
Kun Ren ◽  
Guangwei Wang

Blast furnace dust (BFD) and converter sludge (CS) were used as raw materials for preparing of cold bonded pellets (CBPs). The results showed that BFD contained high content of C, Fe and harmful element of Zn. Conversely, the CS had more Fe and Ca content and less Zn. BFD particles are mostly large and irregular in shape with poor hydrophilicity, whereas CS particles are generally smaller spherical and could bond together easily. Additionally, the main factors influencing the performance of CBPs are the binder, moisture, and pressing pressure. By controlling the mixing ratio of BFD and CS, selecting the appropriate binder and binder amount, and controlling the moisture and pressure, CBPs with a compressive strength and a falling strength of up to 142.7 N and 8.34 times, respectively, can be prepared, thus meeting the requirements of the rotary hearth furnace and the OxyCup production process.


Metals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1404
Author(s):  
Seongrim Song ◽  
Youngjo Kang

Recently, direct reduced iron (DRI) has been highlighted as a promising iron source for electric arc furnace (EAF)-based steelmaking. The two typical production methods for DRI are gas-based reduction and reduction using carbon composite pellets. While the gas-based reduction is strongly dependent on the reliable supply of hydrocarbon fuel, reduction using ore-coal composite pellets has relatively low productivity due to solid–solid reactions. To overcome the limitations of the above two processes, and to achieve a more efficient direct reduction process of iron ore, the possibility of combining these two methods was investigated. The experiments focused on performing an initial direct reduction using ore-coal composite pellets followed by a second stage gas reduction. It was assumed that the initial reduction of the carbon composite pellets would enhance the efficiency of the subsequent reduction by gas and the total reduction efficiency. The porosity, as well as the carbon efficiency for direct reduction, were measured to determine the optimal conditions for the initial reduction, such as the size ratio of ore and coal particles. Thereafter, further reduction by the reducing gas was carried out to verify the effect of the preliminary reduction. The reduction kinetics of the reducing gas was also discussed.


2019 ◽  
Vol 23 (5 Part A) ◽  
pp. 2569-2576
Author(s):  
Yi Man ◽  
Jun-Xiao Feng ◽  
Yan-Yang Wang

The effects of reduction temperature, particle size, pellet diameter, and the ratio on the reduction rate in red mud-coal composite pellets were studied. The iron phase change of the reduction under different temperatures was analyzed applying X-ray diffraction technique. The microstructure of reduction was investigated using scanning electron microscope. The conclusion of the study is that the reduction reaction rate increased rapidly with the increase of reduction temperature. The reduction of Fe2O3 forming Fe3O4 started under 700?. At 1100?, the red mud-coal composite pellets with carbon and oxygen mole ratio 1:1 obtained a good reduction result. The appearance of metal iron and the clear porous structure indicated that the reduction had developed to a high degree.


Author(s):  
P.I. Loboda ◽  
Younes Razaz ◽  
S. Grishchenko

Purpose. To substantiate the efficiency of processing hematite raw materials at the Krivoy Rog Mining and Processing Plant of Oxidized Ores using the direct reduction technology itmk3®. Metodology. Analysis of the results of the itmk3® direct restoration technology developed by Kobe Steel Ltd., Japan and Hares Engineering GmbX, Austria, with a view to using it to process Krivbass hematite ores into granulated iron (so-called “nuggets”). Findings. The involvement in the production of hematite ores (oxidized quartzite) of Krivbass with high iron content, but with low magnetic properties for their processing into granular cast iron is grounded. Originality. The use of itmk3® direct reduction technology from Kobe Steel Ltd., Japan and Hares Engineering GmbH, Austria for the processing of Krivbass hematite ores into granular cast iron is justified for the first time. Practical value. The efficiency of the use of hematite ores (oxidized quartzite) has been substantiated, which can significantly reduce the costs in the mining cycle for the economical production of metallurgical products.


2014 ◽  
Vol 906 ◽  
pp. 66-71
Author(s):  
Zhen Quan Li ◽  
Qiang Zhen ◽  
Ya Li Wang

High purity ZrSiO4 powder were synthesized using Si (C2H5O)4 and ZrOCl2·8H2O as raw materials by the sol-gel method, LiCl was added as mineralizer to promote crystallization of zircon. The influences of molar ratio of Zr:Si, calcined time and calcined temperature on the synthesis of ZrSiO4 powder were investigated. XRD, SEM and TEM were used to characterize the powders. It was found that when the molar ratio of Zr:Si was 1:1.2, the calcined temperature was 1600°C and the calcined time was 4h, the high purity ZrSiO4 ultrafine powder was obtained. The ZrSiO4 formation began at 1300°C and when the gel was calcined at 1600°Cfor 4 h, the formation rate of ZrSiO4 was up to 95%. SEM and TEM studies reveal a homogeneous product with particle sizes on the order of 0.1-1μm. The IR emissivity of ultrafine ZrSiO4 is 0.892 at the whole wavelength range, and that is up to 0.951 at the wavelength range of 8-14 μm.


1977 ◽  
Vol 63 (14) ◽  
pp. 2269-2277
Author(s):  
Dentaro KANEKO ◽  
Yoshio KIMURA ◽  
Mamoru ONODA ◽  
Isao FUJITA

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