Diamond-Based Metal Matrix Composites for Thermal Management Made by Liquid Metal Infiltration — Potential and Limits

2008 ◽  
Vol 59 ◽  
pp. 111-115 ◽  
Author(s):  
Ludger Weber ◽  
Reza Tavangar

Diamond-based metal matrix composites have been made based on pure Al and eutectic Ag-3Si alloy by gas pressure infiltration into diamond powder beds with the aim to maximize thermal conductivity and to explore the range of coefficient of thermal expansion (CTE) that can be covered. The resulting composites covered roughly the range between 60 and 75 vol-% of diamond content. For the Al-based composites a maximum thermal conductivity at room temperature of 7.6 W/cmK is found while for the Ag-3Si based composites an unprecedented value of 9.7 W/cmK was achieved. The CTE at room temperature varied as a function of the diamond volume fraction between 3.3 and 7.0 ppm/K and 3.1 and 5.7 ppm/K for the Al-based and the Ag-3Si-based composites, respectively. The CTE was further found to vary quite significantly with temperature for the Al-based composites while the variation with temperature was less pronounced for the Ag-3Si-based composites. The results are compared with prediction by analytical modeling using the differential effective medium scheme for thermal conductivity and the Schapery bounds for the CTE. For the thermal conductivity good agreement is found while for the CTE a transition of the experimental data from Schapery’s upper to Schapery’s lower bound is observed as volume fraction increases. While the thermophysical properties are quite satisfactory, there is a trade-off to be made in these materials between high thermal conductivity and low CTE on the one side and surface quality and machinability on the other.

1993 ◽  
Vol 8 (5) ◽  
pp. 1169-1173 ◽  
Author(s):  
William B. Johnson ◽  
B. Sonuparlak

Diamond particles are unique fillers for metal matrix composites because of their extremely high modulus, high thermal conductivity, and low coefficient of thermal expansion. Diamond reinforced aluminum metal matrix composites were prepared using a pressureless metal infiltration process. The diamond particulates are coated with SiC prior to infiltration to prevent the formation of Al4C3, which is a product of the reaction between aluminum and diamond. The measured thermal conductivity of these initial diamond/Al metal matrix composites is as high as 259 W/m-K. The effects of coating thickness on the physical properties of the diamond/Al metal matrix composite, including Young's modulus, 4-point bend strength, coefficient of thermal expansion, and thermal conductivity, are presented.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2143
Author(s):  
Shaimaa I. Gad ◽  
Mohamed A. Attia ◽  
Mohamed A. Hassan ◽  
Ahmed G. El-Shafei

In this paper, an integrated numerical model is proposed to investigate the effects of particulate size and volume fraction on the deformation, damage, and failure behaviors of particulate-reinforced metal matrix composites (PRMMCs). In the framework of a random microstructure-based finite element modelling, the plastic deformation and ductile cracking of the matrix are, respectively, modelled using Johnson–Cook constitutive relation and Johnson–Cook ductile fracture model. The matrix-particle interface decohesion is simulated by employing the surface-based-cohesive zone method, while the particulate fracture is manipulated by the elastic–brittle cracking model, in which the damage evolution criterion depends on the fracture energy cracking criterion. A 2D nonlinear finite element model was developed using ABAQUS/Explicit commercial program for modelling and analyzing damage mechanisms of silicon carbide reinforced aluminum matrix composites. The predicted results have shown a good agreement with the experimental data in the forms of true stress–strain curves and failure shape. Unlike the existing models, the influence of the volume fraction and size of SiC particles on the deformation, damage mechanism, failure consequences, and stress–strain curve of A359/SiC particulate composites is investigated accounting for the different possible modes of failure simultaneously.


Author(s):  
Ryan Hahnlen ◽  
Marcelo J. Dapino

Shape memory and superelastic NiTi are often utilized for their large strain recovery and actuation properties. The objective of this research is to utilize the stresses generated by pre-strained NiTi as it is heated in order to tailor the CTE of metal-matrix composites. The composites studied consist of an Al 3003-H18 matrix with embedded NiTi ribbons fabricated through an emerging rapid prototyping process called Ultrasonic Additive Manufacturing (UAM). The thermally-induced strain of the composites is characterized and results show that the two key parameters in adjusting the effective CTE are the NiTi volume fraction and prestrain of the embedded NiTi. From the observed behavior, a constitutive composite model is developed based constitutive SMA models and strain matching composite models. Additional composites were fabricated to characterize the NiTi-Al interface through EDS and DSC. These methods were used to investigate the possibility of metallurgical bonding between the ribbon and matrix and determine interface shear strength. Interface investigation indicates that mechanical coupling is accomplished primarily through friction and the shear strength of the interface is 7.28 MPa. Finally, using the developed model, a composite was designed and fabricated to achieve a near zero CTE. The model suggests that the finished composite will have a zero CTE at a temperature of 135°C.


2010 ◽  
Vol 150-151 ◽  
pp. 144-149
Author(s):  
Hong Wei Xing ◽  
Jin Song Zhang ◽  
Xiao Ming Cao

Copper matrix composites reinforced with 3D-SiC network (15v% and 20v% SiC) were fabricated by squeezing copper alloy into 3D-SiC network preforms. The thermo-physical properties of the copper matrix composites were investigated. The specific heat capacities of the composites were about 0.39~0.50 J•g-1•K-1. The coefficients of thermal expansion (CTEs) of the composites were found to be lower than 6.9×10-6 -1 at Room Temperature. The composites exhibited high thermal stability for 3D-SiC network advent. The thermal conductivity of the composites was in the range of 50~80W•m−1•K−1. The thermo-physical properties of Cu matrix composites had a great relationship with the structures of 3D-SiC network preforms. The thermal conductivity of the composites decreased with an increase in the volume fraction of SiC or the structures of the limbs changing compacted, but the CTEs were not completely according this rule.


2005 ◽  
Vol 475-479 ◽  
pp. 3335-3338
Author(s):  
F. Alhama ◽  
Diego Alcaraz ◽  
S. Gómez-Lopera

A simple model based on the network simulation method is proposed to estimate numerically the thermal conductivity of particulate reinforced metal-matrix composites. The estimation is carried out running the model in the standard Pspice code, the computing time being negligible. The 3-D solid is discretized in 1000 cubic volume elements which represent an acceptable approximation of the shape of the particles. For each reinforcement percentage and each combination of matrix and reinforcement more than 200 tests were carried out, so that the results may be considered close to the exact values. The limit values are scarcely influenced by the effect of the 3-D geometry and basically depend on the amount of the reinforcement. Applications to aluminum and titanium matrix composites reinforced with different types of particles are presented covering a wide range of reinforcement percentages.


2003 ◽  
Vol 18 (4) ◽  
pp. 855-860 ◽  
Author(s):  
Gary L. Eesley ◽  
Alaa Elmoursi ◽  
Nilesh Patel

Kinetic spray deposition provides a new means for producing composite materials with tailored physical properties. We report on measurements of the thermal conductivity and thermal-expansion coefficient for several compositional variations of kinetically sprayed Al–SiC metal-matrix composites. As a result of the deposition process, inclusion of SiC particles saturates in the 30–40% volume fraction range.


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