Investigation of ZnO Buffer for the Optical and Electrical Characteristics of Polymer/Carbon Nanotube Composite Sol Deposited on Flexible Substrates

2013 ◽  
Vol 747 ◽  
pp. 526-529
Author(s):  
Bo Yuan Su ◽  
Meng Chun Chen ◽  
Sheng Yuan Chu ◽  
Yang Der Juang

In this paper, the carbon nanotube was well dispersed into the poly (3,4-ethylenedioxythiophene) poly (styrenesulfonate) (PEDOTPSS) solution with a best concentration of 4 mg/ml. The prepared sol was spun on poly (ether sulfone) (PES) substrates, showing sheet resistance as low as 19.8 Ω/sq and the high average transmittance over 90 %. The change in optical and electrical properties due to poly (ether sulfone) (PES) substrate was investigated to understand the failure mechanisms. For realizing the bending effect on electrical performance, the pre-deposited ZnO buffer was introduced to improve the deterioration during the repeated bending test. The composite polymer enhanced the electrical conductivity with less detrimental effect on the optical transparency, which suggests the potential transparent conductive films for use in developing optical and electrical device.

Author(s):  
Samarjeet Singh Siwal ◽  
Adesh Kumar Saini ◽  
Saptak Rarotra ◽  
Qibo Zhang ◽  
Vijay Kumar Thakur

Abstract Carbon nanotube (CNT)-doped transparent conductive films (TCFs) is an encouraging option toward generally utilized indium tin oxide-depended TCFs for prospective stretchable optoelectronic materials. Industrial specifications of TCFs involve not just with high electrical performance and transparency but also amidst environmental resistance and mechanical characteristic; those are usually excused within the research background. Though the optoelectronic properties of these sheets require to be developed to match the necessities of various strategies. While, the electrical stability of single-walled CNT TCFs is essentially circumscribed through the inherent resistivity of single SWCNTs and their coupling confrontation in systems. The main encouraging implementations, CNT-doped TCFs, is a substitute system during approaching electronics to succeed established TCFs, that utilize indium tin oxide. Here we review, a thorough summary of CNT-based TCFs including an overview, properties, history, synthesis protocol covering patterning of the films, properties and implementation. There is the attention given on the optoelectronic features of films and doping effect including applications for sophisticated purposes. Concluding notes are given to recommend a prospective investigation into this field towards real-world applicability. Graphic abstract This graphical abstract shows the overview of different properties (mechanical, electrical, sensitivity and transportation), synthesis protocols and designing (dry and wet protocol, designing by surface cohesive inkjet-printed and the support of polymers), doping effect (general doping, metal halides, conductive polymers and graphene for transparent electrodes) and implementations (sensing panels, organic light-emitting diodes devices, thin-film transistors and bio-organic interface) of carbon nanotubes transparent conductive films.


2020 ◽  
Vol 1 (2) ◽  
Author(s):  
Ashish Kumar ◽  
Wen-Hsi Lee

 In this study, we fabricate Si/SiGe core-shell Junctionless accumulation mode (JAM)FinFET devices through a rapid and novel process with four main steps, i.e. e-beam lithography definition, sputter deposition, alloy combination annealing, and chemical solution etching. The height of Si core is 30 nm and the thickness of Si/SiGe core-shell is about 2 nm. After finishing the fabrication of devices, we widely studied the electrical characteristics of poly Si/SiGe core-shell JAM FinFET transistors from a view of different Lg and Wch. A poly-Si/SiGe core -shell JAMFETs was successfully demonstrated and it also exhibits  a superior subthreshold swing of 81mV/dec and high on/off ratio > 105 when annealing for 1hr at 600°C. The thermal diffusion process condition for this study are 1hr at 600°C and 6hr at 700°C for comparison. The annealing condition at 700oC for 6 hours shows undesired electrical characteristics against the other. Results suggests that from over thermal budget causes a plenty of Ge to precipitate against to form SiGe thin film. Annealing JAMFETs at low temperature shows outstanding Subthreshold swing and better swing condition when compared to its counterpart i.e. at higher temperature. This new process can still fabricate a comparable performance to classical planar FinFET in driving current. 


2020 ◽  
Vol 9 (1) ◽  
pp. 478-488 ◽  
Author(s):  
Yun-Fei Zhang ◽  
Fei-Peng Du ◽  
Ling Chen ◽  
Ka-Wai Yeung ◽  
Yuqing Dong ◽  
...  

AbstractElectroactive hydrogels have received increasing attention due to the possibility of being used in biomimetics, such as for soft robotics and artificial muscles. However, the applications are hindered by the poor mechanical properties and slow response time. To address these issues, in this study, supramolecular ionic polymer–carbon nanotube (SIPC) composite hydrogels were fabricated via in situ free radical polymerization. The polymer matrix consisted of carbon nanotubes (CNTs), styrene sulfonic sodium (SSNa), β-cyclodextrin (β-CD)-grafted acrylamide, and ferrocene (Fc)-grafted acrylamide, with the incorporation of SSNa serving as the ionic source. On applying an external voltage, the ions accumulate on one side of the matrix, leading to localized swelling and bending of the structure. Therefore, a controllable and reversible actuation can be achieved by changing the applied voltage. The tensile strength of the SIPC was improved by over 300%, from 12 to 49 kPa, due to the reinforcement effect of the CNTs and the supramolecular host–guest interactions between the β-CD and Fc moieties. The inclusion of CNTs not only improved the tensile properties but also enhanced the ion mobility, which lead to a faster electromechanical response. The presented electro-responsive composite hydrogel shows a high potential for the development of robotic devices and soft smart components for sensing and actuating applications.


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