The Removal of Deinking Wastewater Using Neutralization, Activated Carbon, and Hydrogen Peroxide Oxidation

2013 ◽  
Vol 779-780 ◽  
pp. 1547-1551
Author(s):  
Xiu Guo Lu ◽  
Feng Li ◽  
Pei Pei Yan ◽  
Yan Jiao Che
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Active Carbon ◽  
Mass Fraction ◽  
Carbon Powder ◽  
Peroxide Oxidation ◽  
Active Carbon Powder ◽  
Color Unit ◽  
Catalytic Experiment ◽  
Hydrogen Peroxide Oxidation

Treatment of deinking wastewater with neutralization, activated carbon, and hydrogen peroxide oxidation is investigated. Discusses the various factors of the neutralization experiment and catalytic experiment on the influence of the experimental results. The results show that for the 20mL deinking wastewater, first neutralize it to pH=4 with dilute sulfuric acid, then the mass fraction of 0.8mLH2O2 (mass fraction of 30%) and 0.8g active carbon powder in oxidative 19min under conditions of pH=3 with an optimum addition of 0.8mg H2O2 (30%) as well as 0.8g active carbon powder, the CODcr can be reduced from 31000mg/L to 2300 mg/L, and the color unit can be reduced from 15000 to 0 after treatment ,its CODcr and color unit decrease significantly and the removal rates reach 90% and 100% respectively.

Phenol Degradation by Catalytic Wet Hydrogen Peroxide Oxidation on Fe/Active Carbon Catalyst

2012 ◽  
Vol 433-440 ◽  
pp. 147-152
Author(s):  
Ying Chun Yang ◽  
Yuan Gang Lu ◽  
Zhi Xiang Ye ◽  
Li Ping He ◽  
Jing Yu
Keyword(s):  
Hydrogen Peroxide ◽  
Active Carbon ◽  
Degradation Rate ◽  
Ph Value ◽  
Phenol Degradation ◽  
Kinetic Studies ◽  
Reaction Rate Constant ◽  
Peroxide Oxidation ◽  
Hydrogen Peroxide Oxidation ◽  
Degradation Reaction

A catalyst based on Fe/active carbon (Fe/AC) and H2O2 as oxidant for the catalytic wet hydrogen peroxide oxidation of phenol in aqueous solution was investigated. The results indicate that the degradation rate of phenol(20mg/L) reach 90.5% in the presence of Fe/AC(2g/L) and hydrogen peroxide (0.5 %) at pH value 7 after 5 hours under normal temperature and atmospheric pressure. Kinetic studies of the degradation reaction show that the degradation rate of phenol nearly follows the first-order reaction. The reaction rate constant and activity energy are 0.4162 min-1 and 23.64 kJ/mol at 25°C, respectively.

Crystal and solution structure of (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile

1989 ◽  
Vol 54 (12) ◽  
pp. 3253-3259
Author(s):  
Jaroslav Podlaha ◽  
Miloš Buděšínský ◽  
Jana Podlahová ◽  
Jindřich Hašek
Keyword(s):  
Hydrogen Peroxide ◽  
Solution Structure ◽  
Peroxide Oxidation ◽  
X Ray ◽  
X Ray Crystallography ◽  
Nmr Study ◽  
Hydrogen Peroxide Oxidation ◽  
Unusual Product ◽  
C Nmr

The unusual product of the reaction of 2-chloroacrylonitrile with ethane thiol and following hydrogen peroxide oxidation was found to be (E)-1,2-bis(ethylsulphonyl)cyclobutane-1,2-dicarbonitrile by means of X-ray crystallography. 1H and 13C NMR study of this compound has proven the same conformation of the molecule in solution.

scholarly journals Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen2NH3NCS]2+: The Preparation and Properties of trans-[Coen2NH3CN]2+

1973 ◽  
Vol 51 (24) ◽  
pp. 4152-4158 ◽  
Author(s):  
Albert Richard Norris ◽  
James William Lennox Wilson
Keyword(s):  
Hydrogen Peroxide ◽  
Spectral Properties ◽  
Peroxide Oxidation ◽  
Reaction Conditions ◽  
Thiocyanate Ion ◽  
Hydrogen Peroxide Oxidation ◽  
Percent Conversion ◽  
Cis And Trans ◽  
In Cis

The hydrogen peroxide oxidation of thiocyanate ion in cis- and trans-[Coen2NH3NCS]2+ leads to the formation of the corresponding cis- and trans-cyanoammine- and diamminebis(ethylenediamine)cobalt-(III) complexes. The spectral properties of the previously unreported trans-[Coe2NH3CN]2+ are reported and compared to the spectral properties of the cis-isomer.Observations are made concerning the reaction conditions which favor a high percent conversion of trans-[Coen2NH3NCS]2+ to trans-[Coen2NH3CN]2+.

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