Preparation and Properties of Composite Antibacterial Agent Containing Copper and Zinc Ions

2009 ◽  
Vol 79-82 ◽  
pp. 965-968
Author(s):  
Shu Xia Ren ◽  
Hui Fang Yang ◽  
Xiu Shu Tian ◽  
Yan Fang Li

The composite antibacterial agents were prepared with Medical stone containing Cu2+ and Zn2+ by liquid ion-exchange reaction. The ion exchange capacity of the as-prepared Medical stone composite antibacterial agents (MSAA) products were investigated by ICP-AES, and the antibacterial activities of the agents were tested by Bacteriastasis ratio, and the structures were characterized by XRD and SEM. The results show that the conditions of preparation, such as pH, concentrations of copper and zinc ions, reaction time and reaction temperature, have important influences on the ion exchange of MSAA. The maximum ion exchange capacity have been obtained when 0.2mol/l Cu2+ and 0.6 mol /l Zn2+ reacted with Medical stone powers in the solution with pH values of 8 for 8 hours at 50 °C. Meanwhile good antibacterial activities and safety are also gained. The reasons for causing the above results are that copper and zinc ions can enter the framework of Medical stone through ion exchanging and adsorption, and are released slowly owing to its porosity.

2012 ◽  
Vol 510 ◽  
pp. 757-761 ◽  
Author(s):  
Shu’e Duan ◽  
Yun Hui Zhai ◽  
Ying Juan Qu

In this paper a novel colorless and salt-tolerant silver-histidine complex doped montmorillonite (Na-MMT) antibacterial agent (SHMMT) power was synthesized by ion exchange reaction using silver-histidine complex ion [Ag (his)] + as precursor, and characterized by atomic absorption spectrophotometer (AAS) and power X-ray diffraction (XRD). The antibacterial activities against Pseudoalteromonas carrageenovora were examined by a modified broth dilution test and the plate counting method. The salt-tolerant property was determined by the antibacterial activities of the sea water soaked SHMMT. The results showed that the Ag loading amount of SHMMT powder reached 1.7mmol/g, far more than the cationic exchange capacity (CEC) of Na-MMT. SHMMT powder had high bacterial activity eventhough it was soaked in the sea water for 30 days. 1


1976 ◽  
Vol 54 (12) ◽  
pp. 1892-1898 ◽  
Author(s):  
J. P. Rawat ◽  
Pritam Singh Thind

Eight samples of ferric phosphates have been prepared at different pH values under different conditions. This material shows cation exchange properties. Ferric phosphate prepared by ferric nitrate and ammonium dihydrogen phosphate at pH 1 is the most stable and shows the maximum ion exchange capacity, hence, this sample is studied in detail. The mole ratio of Fe3+:PO43− is 1:2. The ion exchange capacity depends upon temperature and hydrated radii, and these relations are discussed. Certain important separations are achieved on the ferric phosphate column. Its oxidation properties are also qualitatively investigated with some reducing agents.


1992 ◽  
Vol 57 (9) ◽  
pp. 1905-1914
Author(s):  
Miroslav Bleha ◽  
Věra Šumberová

The equilibrium sorption of uni-univalent electrolytes (NaCl, KCl) in heterogeneous cation exchange membranes with various contents of the ion exchange component and in ion exchange membranes Ralex was investigated. Using experimental data which express the concentration dependence of equilibrium sorption, validity of the Donnan relation for the systems under investigation was tested and values of the Glueckauf inhomogeneity factor for Ralex membranes were determined. Determination of the equilibrium sorption allows the effect of the total content of internal water and of the ion-exchange capacity on the distribution coefficients of the electrolyte to be determined.


2012 ◽  
Vol 511 ◽  
pp. 105-108
Author(s):  
Jin He Jiang

Mg1.5Mn0.5Ti0.75O4 was prepared by a coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigation by X-ray, saturation capacity of exchange, and Kd measurement. The acid treatments of Mg1.5Mn0.5Ti0.75O4 caused Mg2+ extractions of more than 72%, while the dissolutions of Mn4+ and Ti4+ were less than 8.2%. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 10.6mmol/g for Li+.


Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 914 ◽  
Author(s):  
Lucia Mazzapioda ◽  
Stefania Panero ◽  
Maria Assunta Navarra

Nafion composite membranes, containing different amounts of mesoporous sulfated titanium oxide (TiO2-SO4) were prepared by solvent-casting and tested in proton exchange membrane fuel cells (PEMFCs), operating at very low humidification levels. The TiO2-SO4 additive was originally synthesized by a sol-gel method and characterized through x-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and ion exchange capacity (IEC). Peculiar properties of the composite membranes, such as the thermal transitions and ion exchange capacity, were investigated and here discussed. When used as an electrolyte in the fuel cell, the composite membrane guaranteed an improvement with respect to bare Nafion systems at 30% relative humidity and 110 °C, exhibiting higher power and current densities.


2005 ◽  
Vol 51 (11) ◽  
pp. 63-70 ◽  
Author(s):  
H. Inan ◽  
B. Beler Baykal

Ammonium selective natural zeolite clinoptilolite is suggested as a possible support material for nitrifying biofilms to help improve effluent ammonium quality through its high capacity of ammonium removal in the process of ion exchange. This will especially be helpful in cases where the biofilter receives peak or variable loads routinely or occasionally. At the time of peak loads or shocks of ammonium, ion exchange capacity will provide a buffer for the effluent ammonium quality. Data to support this suggestion is presented.


2005 ◽  
Vol 30 (1) ◽  
pp. 51-58 ◽  
Author(s):  
C. U. Ferreira ◽  
J. E. Gonçalves ◽  
Y. V. Kholin ◽  
Y. Gushikem

The porous mixed oxide SiO2/TiO2/Sb2O5 obtained by the sol-gel processing method presented a good ion exchange property and a high exchange capacity towards the Li+, Na+ and K+ ions. In the H+/M+ ion exchange process, the H+ / Na+ could be described as presenting an ideal character. The ion exchange equilibria of Li+ and K+ were quantitatively described with the help of the model of fixed tetradentate centers. The results of simulation evidence that for the H+ / Li+ exchange the usual situation takes place: the affinity of the material to the Li+ ions is decreased with increasing the degree of ion exchange. On the contrary, for K+ the effects of positive cooperativity, that facilitate the H+ / K+ exchange, were revealed.


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