Growth and Characterization of 420 kg Bulk Multicrystalline Silicon (mc-Si) Ingot Grown by Directional Solidification Process for Photovoltaic Application

2013 ◽  
Vol 873 ◽  
pp. 592-597
Author(s):  
Da Wei Luo

Cast mc-Si ingots are widely used in photovoltaic manufacturing. The utilization rate of industrial polycrystalline silicon ingot only about 70%, most of them are less than 70%, the main influence factors are casting process, raw and auxiliary materials as well as the crucible material. The growth process and the overall characteristics of 420 kg polycrystalline silicon ingot are analyzed and researched in detail. This paper focuses on the distribution characteristics and causes of the casting defect which are analyzed in detail and discussed, at the same time suggestions are given to improve the utilization rate of the ingot.

Aluminum-silicon alloys acquiring extensive industrial attention due to their superior resistance to rate of wear and elevated strength to weight ratio properties. Though the properties of the materials substantially depend on the manufacturing process they involve. Thus many industries focusing on new manufacturing methods to produce high-performance alloys. In this present study, AlSi (16-18) alloys were prepared by new CRSS (combined rheo stir squeeze) casting method with rapid-solidification process under T-6 condition. CRSS-T6 as casting process enhances the microstructural and mechanical properties significantly by 40-70%. Whereas, the maximum value of hardness (179.37) was found with AlSi17Cu3.5Mg0.8 with CRSS-T6. The improvements in hardness and elastic properties were mainly ascribed to size, distribution, and morphology of Si-particles because of its manufacturing process. SEM, advanced metallurgical microstructure and EDS analysis techniques are used for the surface morphologies observation. Moreover, Brinell hardness tester and Tensometer are used for the characterization of mechanical properties


Electronics ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 140
Author(s):  
Lichen Liu ◽  
Ziping Cao ◽  
Min Chen ◽  
Jun Jiang

This paper reports the fabrication and characterization of (Bi0.48Sb1.52)Te3 thick films using a tape casting process on glass substrates. A slurry of thermoelectric (Bi0.48Sb1.52)Te3 was developed and cured thick films were annealed in a vacuum chamber at 500–600 °C. The microstructure of these films was analyzed, and the Seebeck coefficient and electric conductivity were tested. It was found that the subsequent annealing process must be carefully designed to achieve good thermoelectric properties of these samples. Conductive films were obtained after annealing and led to acceptable thermoelectric performance. While the properties of these initial materials are not at the level of bulk materials, this work demonstrates that the low-cost tape casting technology is promising for fabricating thermoelectric modules for energy conversion.


Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1683
Author(s):  
Zuoquan Zhu ◽  
Yaolong He ◽  
Hongjiu Hu ◽  
Fangzhou Zhang

The mechanical behavior of electrode composite during the drying preparation has played a crucial role in the electrochemical performance of lithium-ion batteries (LIBs). Our work aimed at developing an integrated analysis method to study the component distribution, mechanical properties, and internal stress of composite coating in the process of electrode drying. The main influence factors of drying stress were thoroughly investigated. It was found that this present model could capture not only the heterogeneity effect of inactive ingredients but also the porosity-dependent viscoelasticity of electrode composite. Meanwhile, the calculated effective modulus and stress evolution upon drying time were in acceptable accord with the experimental data. Furthermore, the rapid solidification markedly increased the drying stress in electrodes and significantly impaired the tensile strength of electrode composite due to the highly gradient distributed constituents. However, the stress level at high drying temperature could be significantly reduced by an aqueous sodium alginate binder instead of poly(vinylidene fluoride). The obtained results will be a great help in efficiently manufacturing LIB electrodes with adequate mechanical integrity.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Janduir Egito da Silva ◽  
Guilherme Quintela Calixto ◽  
Rodolfo Luiz Bezerra de Araújo Medeiros ◽  
Marcus Antônio de Freitas Melo ◽  
Dulce Maria de Araújo Melo ◽  
...  

AbstractThis study aims to analyze the products of the catalytic pyrolysis of naturally colored cotton residues, type BRS (seeds from Brazil), called BRS-Verde, BRS-Rubi, BRS-Topázio and BRS-Jade. The energy characterization of biomass was evaluated through ultimate and proximate analysis, higher heating value, cellulose, hemicellulose and lignin content, thermogravimetric analysis and apparent density. Analytical pyrolysis was performed at 500 °C in an analytical pyrolyzer from CDS Analytical connected to a gas chromatograph coupled to the mass spectrometer (GC/MS). The pyrolysis vapors were reformed at 300 and 500 °C through thermal and catalytic cracking with zeolites (ZSM-5 and HZSM-5). It has been noticed that pyrolysis vapor reforming at 500 °C promoted partial deoxygenation and cracking reactions, while the catalytic reforming showed better results for the product deoxygenation. The catalyst reforming of pyrolysis products, especially using HZSM-5 at 500 °C, promoted the formation of monoaromatics such as benzene, toluene, xylene and styrene, which are important precursors of polymers, solvents and biofuels. The main influence on the yields of these aromatic products is due to the catalytic activity of ZSM-5 favored by increased temperature that promotes cracking reactions due expanded zeolites channels.


2009 ◽  
Vol 73 (9) ◽  
pp. 732-741 ◽  
Author(s):  
Yoshiko Miyauchi ◽  
Hisao Esaka ◽  
Kei Shinozuka

2010 ◽  
Vol 65 (23) ◽  
pp. 6247-6258 ◽  
Author(s):  
A.C. Ma ◽  
K.C. Williams ◽  
J.M. Zhou ◽  
M.G. Jones

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