scholarly journals Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Janduir Egito da Silva ◽  
Guilherme Quintela Calixto ◽  
Rodolfo Luiz Bezerra de Araújo Medeiros ◽  
Marcus Antônio de Freitas Melo ◽  
Dulce Maria de Araújo Melo ◽  
...  
Keyword(s):  
Lignin Content ◽  
Proximate Analysis ◽  
Catalytic Reforming ◽  
Pyrolysis Products ◽  
Heating Value ◽  
Colored Cotton ◽  
Benzene Toluene ◽  
Naturally Colored Cotton ◽  
Main Influence

AbstractThis study aims to analyze the products of the catalytic pyrolysis of naturally colored cotton residues, type BRS (seeds from Brazil), called BRS-Verde, BRS-Rubi, BRS-Topázio and BRS-Jade. The energy characterization of biomass was evaluated through ultimate and proximate analysis, higher heating value, cellulose, hemicellulose and lignin content, thermogravimetric analysis and apparent density. Analytical pyrolysis was performed at 500 °C in an analytical pyrolyzer from CDS Analytical connected to a gas chromatograph coupled to the mass spectrometer (GC/MS). The pyrolysis vapors were reformed at 300 and 500 °C through thermal and catalytic cracking with zeolites (ZSM-5 and HZSM-5). It has been noticed that pyrolysis vapor reforming at 500 °C promoted partial deoxygenation and cracking reactions, while the catalytic reforming showed better results for the product deoxygenation. The catalyst reforming of pyrolysis products, especially using HZSM-5 at 500 °C, promoted the formation of monoaromatics such as benzene, toluene, xylene and styrene, which are important precursors of polymers, solvents and biofuels. The main influence on the yields of these aromatic products is due to the catalytic activity of ZSM-5 favored by increased temperature that promotes cracking reactions due expanded zeolites channels.

Physicochemical characterization of several types of naturally colored cotton fibers from Peru

2018 ◽  
Vol 197 ◽  
pp. 246-252 ◽  
Author(s):  
R.H. Blas-Sevillano ◽  
T. Veramendi ◽  
B. La Torre ◽  
C.E. Velezmoro-Sánchez ◽  
A.I. Oliva ◽  
...  
Keyword(s):  
Physicochemical Characterization ◽  
Cotton Fibers ◽  
Colored Cotton ◽  
Naturally Colored Cotton ◽  
Naturally Colored Cotton Fibers

scholarly journals Pachira aquatica fruits shells valorization: renewables phenolics through analytical pyrolysis study (Py-GC/MS)

2022 ◽  
Vol 52 (2) ◽  
Author(s):  
Luiz Augusto da Silva Correia ◽  
Janduir Egito da Silva ◽  
Guilherme Quintela Calixto ◽  
Dulce Maria de Araújo Melo ◽  
Renata Martins Braga
Keyword(s):  
Bulk Density ◽  
Lignin Content ◽  
Infrared Region ◽  
Volatile Matter ◽  
Pyrolysis Products ◽  
Flash Pyrolysis ◽  
Heating Value ◽  
Energetic Characterization ◽  
Forest Waste ◽  
Phenolic Extract

ABSTRACT: This research valorized Pachira aquatica Aubl.’s fruit shells (PAS) through its energetic characterization and flash pyrolysis for biofuels or chemicals production. The characterization was performed through proximate and ultimate analysis, bulk density, higher heating value (HHV), hemicellulose, cellulose and lignin content, thermogravimetric analysis and absorption spectra in the infrared region obtained by Fourier-transform infrared spectroscopy technique (FTIR). The analytical flash pyrolysis was performed at 500°C in a Py-5200 HP-R coupled to a gas chromatograph (Py-GC/MS). The PAS biomass presents potential for thermochemical energy conversion processes due to its low moisture and ash content, 76.90% of volatile matter, bulk density of 252.6 kg/m3 and HHV of 16.24 MJ/kg. Flash pyrolysis products are mostly phenols or light organic acids derived from the decomposition of polysaccharides. Results confirmed the potential of PAS to produce bio-phenolics, such as 4-methoxyphenol which is an important active ingredient for skin depigmentation used in drugs and cosmetics, and as phenolic extract that can be used as a precursor to resins, applications that convert this forest waste into bio products for industry into a green circular economy.

scholarly journals CARACTERIZAÇÃO FÍSICA E QUÍMICA DA BIOMASSA USADA COMO COMBUSTÍVEL SÓLIDO EM UMA CALDEIRA

Química Nova ◽  
2020 ◽  
Author(s):  
Natália Carvalho ◽  
João Barros ◽  
Diego Silva ◽  
Gabriela Nakashima ◽  
Fábio Yamaji
Keyword(s):  
Chemical Properties ◽  
Chemical Characterization ◽  
Proximate Analysis ◽  
Mechanical Resistance ◽  
Moisture Determination ◽  
Energy Potential ◽  
Heating Value ◽  
Physical And Chemical Characterization ◽  
Physical And Chemical

PHYSICAL AND CHEMICAL CHARACTERIZATION OF BIOMASS USED AS SOLID FUEL IN A BOILER. Biomass is a renewable energy source most used in the world, however, depending on the chemical properties and origin of the material used as biofuel, the amount of ash generated during combustion can be high, harming the energetic harnessing. The objective of this study was to characterize chemically and physically biomass: bark, sawdust, and urban pruning; used for energy generation. Also, part of the study was the physical characterization of briquettes produced from these materials. The analyzes performed to characterize the biomass were: moisture determination, higher heating value, proximate analysis and chemical composition - extractives, lignin and holocellulose contents. Subsequently, the biomass was briquetted and the mechanical properties of the briquettes were tested. The results showed that all biomass (bark, sawdust, and urban pruning) has the energy potential to be used in the industry. T1 briquettes (100% bark) showed the highest mechanical resistance. However, the formation of blends should be sought to minimize the ash content in the boiler. Thus, blends T2 and T3 can be considered as the best alternatives for the company.

scholarly journals Thermal Properties of Residual Agroforestry Biomass of Northern Portugal

Energies ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1418 ◽  
Author(s):  
Teresa Enes ◽  
José Aranha ◽  
Teresa Fonseca ◽  
Domingos Lopes ◽  
Ana Alves ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Chemical Composition ◽  
Agricultural Sector ◽  
Lignin Content ◽  
Chemical Properties ◽  
General Tendency ◽  
Heating Value ◽  
Bioenergy Production ◽  
Soxhlet Method

Biomass from forestry and agricultural sector provides an important contribution to encounter the government’s targets for increasing bioenergy production and utilization. Characterization of agricultural and forest wastes are critical for exploiting and utilizing them for energy purpose. In the present work agricultural and forest wastes and shrubs were sampled in two sites in north Portugal (Ave and Sabor basin) and subjected to Higher Heating Value (HHV) and chemical composition quantification. The HHV was evaluated according to the methodology described in Standard DD CEN/TS14918:2005. For the lignin content, the procedure was made by the Klason method and the extractives content was determined with the Soxhlet method. For agricultural and forest wastes the HHV values are identical with a range of 17 to 21 MJ·kg−1. However, shrubs biomass presentx slightly higher and statistically different values from agricultural and forest wastes, varying between 19 and 21 MJ·kg−1. Forest wastes contain higher levels of holocellulose compared to agricultural wastes and, with respect to extractive contents, this trend is the reverse. There is a general tendency for the woody components present thermo-chemical properties more suited for energy purposes, than the residues formed by the branches and leaves.

Biomass Briquette Characterization for Downdraft Gasification

2014 ◽  
Vol 592-594 ◽  
pp. 2442-2446
Author(s):  
Gajanan Namdeorao Shelke ◽  
P. Mahanta
Keyword(s):  
Rice Husk ◽  
Proximate Analysis ◽  
Heating Value ◽  
Downdraft Gasifier ◽  
Ultimate Analysis ◽  
Saw Dust

The present study involves the preparation and characterization of the biomass briquettes made from saw dust and rice husk. Five samples with different compositions were prepared using the old news papers as the binder for both the biomass. Ultimate analysis, proximate analysis, heating value and handling characteristic of all the samples were determined. It was observed that the compositions of the biomass sawdust (BMS)-15 and biomass rice husk (BMR)-15 are suitable for the downdraft gasifier.

scholarly journals CARACTERIZAÇÃO DO RESÍDUO DE MDF E SEU APROVEITAMENTO NA PRODUÇÃO DE PELLETS

Nativa ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 300
Author(s):  
Thammi Queuri Gomes Da Cunha ◽  
Pedro Vilela Gondim Barbosa ◽  
Pedro Augusto Fonseca Lima ◽  
Thalles Santiago Pimentel ◽  
Lucas Lemes de Souza Peixoto ◽  
...  
Keyword(s):  
Mechanical Characteristics ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Fixed Carbon ◽  
Heating Value ◽  
High Heating Value ◽  
Energetic Characterization ◽  
Quality Specifications ◽  
Volatile Materials

O processamento dos painéis de MDF, para a fabricação de móveis, gera uma grande quantidade de resíduos que constituem passivo ambiental, podendo ser utilizados para geração de energia. O objetivo deste trabalho foi avaliar as características do resíduo de MDF e seu aproveitamento na produção de pellets, visando a aplicação energética. A caracterização energética do resíduo foi realizada por meio da química imediata (teores de cinzas, voláteis e carbono fixo) e do poder calorífico superior. Além disso, foram produzidos e avaliados pellets (características energéticas e físico-mecânicas). A avaliação das características do resíduo: poder calorífico superior (4427,8 kcal.kg-1) e química imediata (carbono fixo, materiais voláteis e cinzas foram 16,3; 82,3 e 1,4%, respectivamente) e dos pellets de MDF: densidade aparente (1,15 g.cm-3), a granel (0,61 g.cm-3), energética (2,6 a 5,5 Gcal.m-3) e durabilidade (99,87%) indicaram a viabilidade técnica do aproveitamento do material como fonte energética. As características energéticas e físico-mecânicas dos pellets de MDF atenderam as especificações de qualidade exigidas nas normas internacionais de comercialização, exceto para o diâmetro médio.Palavras-chave: materiais densificados, potencial energético, painéis. CHARACTERIZATION OF MDF RESIDUE AND ITS USE IN PELLET PRODUCTION ABSTRACT:The processing of MDF panels, for the manufacture of furniture, generates a large amount of residues that constitutes an environmental liability, and can be used for power generation. The objective of this work was to evaluate the characteristics of the MDF residue and its use in the production of pellets, aiming at the energetic application. The energetic characterization of the residue was carried out by means of the proximate analysis (ash, volatile and fixed carbon contents), calorific value. In addition, pellets were produced and evaluated (energy and physico-mechanical characteristics). The evaluation of the characteristics of the residue: high heating value  (4427.8 kcal kg-1) and proximate analysis (fixed carbon, volatile materials and ash were 16.3, 82.3 and 1.4%, respectively) and pellets: density (1.15 g cm -3), bulk density (0.61 g cm -3), energy density (2.6-5.5 Gcal m-3) and durability (99.87 %) indicated the technical feasibility of using the material as an energy source. The energy and physical-mechanical characteristics of MDF pellets met the quality specifications required by international marketing standards, except for the average diameter.Keywords: densified materials, energetic potential, panels. DOI:

Evaluasi Prediksi Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Proksimat

2020 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Made Dirgantara ◽  
Karelius Karelius ◽  
Marselin Devi Ariyanti, Sry Ayu K. Tamba
Keyword(s):  
Renewable Energy ◽  
Natural Gas ◽  
Key Words ◽  
Critical Analysis ◽  
Fossil Fuels ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Heating Value ◽  
Bomb Calorimeter ◽  
Hhv Prediction

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat  Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate 

Characterization of Vacuum Pyrolysis Products from Phenolic Resin Laminate Substrate

2010 ◽  
Vol 38 (1) ◽  
pp. 72-76
Author(s):  
Wen-Biao WU ◽  
Ke-Qiang QIU ◽  
Cheng-Long LI ◽  
Xiao-Qun XU
Keyword(s):  
Phenolic Resin ◽  
Pyrolysis Products ◽  
Vacuum Pyrolysis

scholarly journals Fabrication and Characterization of Electrospun Poly(acrylonitrile-co-Methyl Acrylate)/Lignin Nanofibers: Effects of Lignin Type and Total Polymer Concentration

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 992
Author(s):  
Suchitha Devadas ◽  
Saja M. Nabat Al-Ajrash ◽  
Donald A. Klosterman ◽  
Kenya M. Crosson ◽  
Garry S. Crosson ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Lignin Content ◽  
Polymer Concentration ◽  
Weight Ratio ◽  
Electrospun Nanofibers ◽  
Polymer Content ◽  
Blend Ratio ◽  
Blend Ratios ◽  
Poly Acrylonitrile

Lignin macromolecules are potential precursor materials for producing electrospun nanofibers for composite applications. However, little is known about the effect of lignin type and blend ratios with synthetic polymers. This study analyzed blends of poly(acrylonitrile-co-methyl acrylate) (PAN-MA) with two types of commercially available lignin, low sulfonate (LSL) and alkali, kraft lignin (AL), in DMF solvent. The electrospinning and polymer blend solution conditions were optimized to produce thermally stable, smooth lignin-based nanofibers with total polymer content of up to 20 wt % in solution and a 50/50 blend weight ratio. Microscopy studies revealed that AL blends possess good solubility, miscibility, and dispersibility compared to LSL blends. Despite the lignin content or type, rheological studies demonstrated that PAN-MA concentration in solution dictated the blend’s viscosity. Smooth electrospun nanofibers were fabricated using AL depending upon the total polymer content and blend ratio. AL’s addition to PAN-MA did not affect the glass transition or degradation temperatures of the nanofibers compared to neat PAN-MA. We confirmed the presence of each lignin type within PAN-MA nanofibers through infrared spectroscopy. PAN-MA/AL nanofibers possessed similar morphological and thermal properties as PAN-MA; thus, these lignin-based nanofibers can replace PAN in future applications, including production of carbon fibers and supercapacitors.

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