Hydrogen Accumulation in Technically Pure Titanium Alloy at Saturation from Gas Atmosphere

2014 ◽  
Vol 880 ◽  
pp. 68-73 ◽  
Author(s):  
Viktor N. Kudiiarov ◽  
Andrey M. Lider ◽  
Sergey Y. Harchenko
Keyword(s):  
Activation Energy ◽  
Titanium Alloy ◽  
Thermal Desorption ◽  
Hydrogen Concentration ◽  
Pure Titanium ◽  
Thermal Desorption Spectroscopy ◽  
Sorption Process ◽  
Hydrogen Saturation ◽  
Gas Atmosphere ◽  
Hydrogen Accumulation

This paper presents experimental results of study of hydrogen accumulation in technically pure titanium alloy at saturation from gas atmosphere. Automated complex Gas Reaction Controller has been used for hydrogen saturation from gas atmosphere. Temperatures increasing from 350 °C to 500 °C allow increase hydrogen sorption process and as a result significantly increase hydrogen concentration in technically pure titanium alloy. At hydrogen saturation from gas atmosphere at temperature 500 °C increasing of saturation time from 10 minutes to 120 minutes leads to hydrogen concentration increasing from 0.1 wt.% to 1 wt.% and increasing of hydrides volume content throughout the samples. The activation energy for hydrogen evolution has been estimated by thermal desorption spectroscopy method by equal 102 kJ/mol.

scholarly journals Hydrogen accumulation and distribution during the saturation of a VT1-0 titanium alloy by an electrolytic method and from a gas atmosphere

2014 ◽  
Vol 59 (9) ◽  
pp. 1378-1382 ◽  
Author(s):  
V. N. Kudiyarov ◽  
A. M. Lider ◽  
N. S. Pushilina ◽  
N. A. Timchenko
Keyword(s):  
Titanium Alloy ◽  
Gas Atmosphere ◽  
Hydrogen Accumulation

scholarly journals Improved Accuracy of Thermal Desorption Spectroscopy by Specimen Cooling during Measurement of Hydrogen Concentration in a High-Strength Steel

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1252 ◽  
Author(s):  
Eric Fangnon ◽  
Evgenii Malitckii ◽  
Yuriy Yagodzinskyy ◽  
Pedro Vilaça
Keyword(s):  
Thermal Desorption ◽  
Hydrogen Concentration ◽  
High Strength Steel ◽  
Vacuum Chamber ◽  
Thermal Desorption Spectroscopy ◽  
High Strength ◽  
Steel Sample ◽  
Martensitic Steels ◽  
Hydrogen Flux ◽  
Redistribution Of Hydrogen

Thermal desorption spectroscopy (TDS) is a powerful method for the measurement of hydrogen concentration in metallic materials. However, hydrogen loss from metallic samples during the preparation of the measurement poses a challenge to the accuracy of the results, especially in materials with high diffusivity of hydrogen, like ferritic and ferritic-martensitic steels. In the present paper, the effect of specimen cooling during the experimental procedure, as a tentative to reduce the loss of hydrogen during air-lock vacuum pumping for one high-strength steel of 1400 MPa, is evaluated. The results show, at room temperature, the presence of a continuous outward hydrogen flux accompanied with the redistribution of hydrogen within the measured steel during its exposure to the air-lock vacuum chamber under continuous pumping. Cooling of the steel samples to 213 K during pumping in the air-lock vacuum chamber before TDS measurement results in an increase in the measured total hydrogen concentration at about 14%. A significant reduction in hydrogen loss and redistribution within the steel sample improves the accuracy of hydrogen concentration measurement and trapping analysis in ferritic and martensitic steels.

Investigation of Hydrogen Distribution from the Surface to the Depth in Technically Pure Titanium Alloy with the Help of Glow Discharge Optical Emission Spectroscopy

2013 ◽  
Vol 302 ◽  
pp. 92-96 ◽  
Author(s):  
A.M. Lider ◽  
N.S. Pushilina ◽  
V.N. Kudiiarov ◽  
M. Kroening
Keyword(s):  
Titanium Alloy ◽  
Glow Discharge ◽  
Emission Spectroscopy ◽  
Optical Emission Spectroscopy ◽  
Pure Titanium ◽  
Optical Emission ◽  
Operating Parameters ◽  
Hydrogen Distribution ◽  
Optimal Operating ◽  
Hydrogen Saturation

Optimal operating parameters for the study of titanium-hydrogen system with the help of glow discharge optical emission spectroscopy have been selected. Hydrogen distribution from the surface to the depth in technically pure titanium alloy after electrochemical hydrogen saturation has been studied.

scholarly journals Investigation of the Pressure Dependent Hydrogen Solubility in a Martensitic Stainless Steel Using a Thermal Agile Tubular Autoclave and Thermal Desorption Spectroscopy

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 231
Author(s):  
Patrick Fayek ◽  
Sebastian Esser ◽  
Vanessa Quiroz ◽  
Chong Dae Kim
Keyword(s):  
Stainless Steel ◽  
Thermal Desorption ◽  
Hydrogen Diffusion ◽  
Martensitic Stainless Steel ◽  
Thermal Desorption Spectroscopy ◽  
Hydrogen Uptake ◽  
Hydrogen Solubility ◽  
Automotive Components ◽  
Set Up ◽  
Service Application

Hydrogen is nowadays in focus as an energy carrier that is locally emission free. Especially in combination with fuel-cells, hydrogen offers the possibility of a CO2 neutral mobility, provided that the hydrogen is produced with renewable energy. Structural parts of automotive components are often made of steel, but unfortunately they may show degradation of the mechanical properties when in contact with hydrogen. Under certain service conditions, hydrogen uptake into the applied material can occur. To ensure a safe operation of automotive components, it is therefore necessary to investigate the time, temperature and pressure dependent hydrogen uptake of certain steels, e.g., to deduct suitable testing concepts that also consider a long term service application. To investigate the material dependent hydrogen uptake, a tubular autoclave was set-up. The underlying paper describes the set-up of this autoclave that can be pressurised up to 20 MPa at room temperature and can be heated up to a temperature of 250 °C, due to an externally applied heating sleeve. The second focus of the paper is the investigation of the pressure dependent hydrogen solubility of the martensitic stainless steel 1.4418. The autoclave offers a very fast insertion and exertion of samples and therefore has significant advantages compared to commonly larger autoclaves. Results of hydrogen charging experiments are presented, that were conducted on the Nickel-martensitic stainless steel 1.4418. Cylindrical samples 3 mm in diameter and 10 mm in length were hydrogen charged within the autoclave and subsequently measured using thermal desorption spectroscopy (TDS). The results show how hydrogen sorption curves can be effectively collected to investigate its dependence on time, temperature and hydrogen pressure, thus enabling, e.g., the deduction of hydrogen diffusion coefficients and hydrogen pre-charging concepts for material testing.

scholarly journals Hot Deformation Behavior and Hot Rolling Properties of a Nano-Y2O3 Addition Near-α Titanium Alloy

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 837
Author(s):  
Zhuangzhuang Zheng ◽  
Yuyong Chen ◽  
Fantao Kong ◽  
Xiaopeng Wang ◽  
Yucheng Yu
Keyword(s):  
Activation Energy ◽  
Titanium Alloy ◽  
Hot Rolling ◽  
Deformation Behavior ◽  
Processing Map ◽  
Dynamic Recovery ◽  
Alloy Sheet ◽  
Hot Deformation Behavior ◽  
Hot Processing Map ◽  
Y2o3 Addition

The hot deformation behavior and hot rolling based on the hot processing map of a nano-Y2O3 addition near-α titanium alloy were investigated. The isothermal compression tests were conducted at various deformation temperatures (950⁠–1070 °C) and strain rates (0.001–1 s−1), up to a true strain of 1.2. The flow stress was strongly dependent on deformation temperature and strain rate, decreasing with increased temperature and decreased strain rate. The average activation energy was 657.8 kJ/mol and 405.9 kJ/mol in (α + β) and β region, respectively. The high activation energy and peak stress were contributed to the Y2O3 particles and refractory elements comparing with other alloys and composites. The deformation mechanisms in the (α + β) region were dynamic recovery and spheroidization of α phase, while the β phase field was mainly controlled by the dynamic recrystallization and dynamic recovery of β grains. Moreover, the constitutive equation based on Norton–Hoff equation and hot processing map were also obtained. Through the optimal processing window determined by the hot processing map at true strains of 0.2, 0.4 and 0.6, the alloy sheet with multi-pass hot rolling (1050 °C/0.03–1 s−1) was received directly from the as-cast alloy. The ultimate tensile strength and yield strength of the alloy sheet were 1168 MPa and 1091 MPa at room temperature, and 642 MPa and 535 MPa at 650 °C, respectively, which performs some advantages in current research.

Sign in / Sign up

Export Citation Format

Share Document