Improving Performance of Thermal Modified Wood against Termites with Bicine and Tricine

Author(s):  
Dennis Jones ◽  
Lina Nunes ◽  
Sonia Duarte

The desire to incorporate wood in modern construction has led to a considerable increase in the use of wood modification techniques, and especially thermal modification. However, thermally modified wood has poor performance against termites. The concept of using a combined chemical and thermal modification has been undertaken through the impregnation with either bicine or tricine prior to modification. This paper considers the effects of these chemicals on the activity of termites and considers their mode of action in terms of termite survival and on their effects on the symbiotic protists present within the termite gut.

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2160
Author(s):  
Milan Gaff ◽  
Hana Čekovská ◽  
Jiří Bouček ◽  
Danica Kačíková ◽  
Ivan Kubovský ◽  
...  

This paper deals with the effect of synthetic and natural flame retardants on flammability characteristics and chemical changes in thermally treated meranti wood (Shorea spp.). The basic chemical composition (extractives, lignin, holocellulose, cellulose, and hemicelluloses) was evaluated to clarify the relationships of temperature modifications (160 °C, 180 °C, and 210 °C) and incineration for 600 s. Weight loss, burning speed, the maximum burning rate, and the time to reach the maximum burning rate were evaluated. Relationships between flammable properties and chemical changes in thermally modified wood were evaluated with the Spearman correlation. The thermal modification did not confirm a positive contribution to the flammability and combustion properties of meranti wood. The effect of the synthetic retardant on all combustion properties was significantly higher compared to that of the natural retardant.


2021 ◽  
Vol 18 (1) ◽  
pp. 51-57
Author(s):  
F.A. Faruwa ◽  
K. Duru

The study investigated the use of thermal modification to improve the hygroscopic properties of False Iroko [Antiaris toxicaria (Lesch)]. Samples of Antiaris toxicara Lesch wood were subjected to thermal modification in a furnace at temperatures of 160, 180 and 200°C for 30 and 60 minutes. Results showed that wood properties were improved with exposure to different temperatures. Subsequent to the thermal process, a colour change from pale yellow to darkish brown was observed progressively with increase in temperature, accompanied by a weight loss in the range of 12.08% to 23.67%. The outcome of these treatments resulted in a decrease in volumetric swelling and increase in dimensional stability of modified wood; this can be attributed to observed decrease in moisture intake. The thermal modification of Antiaris toxicara Lesch wood affected the dimensional stability properties. Thus, due to significant changes via modification carried out on the selected species which is classified as lesser utilized wood species, lesser utilized wood,Antiaristoxicara Lesch wood is recommended for use due to its efficient dimensional stability after modification . keywords:, Thermally modified wood ;False Iroko


Holzforschung ◽  
2015 ◽  
Vol 69 (4) ◽  
pp. 405-413 ◽  
Author(s):  
Wang Wang ◽  
Yuan Zhu ◽  
Jinzhen Cao ◽  
Xi Guo

Abstract The aim of this study was to enhance the water repellency and dimensional stability of thermally modified wood by combining the preimpregnation of paraffin wax emulsion. To achieve this, Southern pine (SP; Pinus spp.) samples were first impregnated with paraffin wax emulsion (with 2.0% solid content) and then subjected to thermal modification (TM) in an oven at 180°C and 220°C for 4 and 8 h. The contact angle (CA), surface free energy, water absorption rate (WAR), anti-swelling efficiency (ASE), and bending properties of the control and modified samples were investigated. Moreover, the chemical and morphological alterations were analyzed by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Both the wax impregnation and TM decreased the surface wettability, water absorption, and tangential swelling, while the combination of wax and thermal treatment exhibited the best water repellency and dimensional stability, indicating the synergism between the two procedures. However, the wax preimpregnation did not affect the mechanical properties of thermally modified wood. The FTIR, SEM, and XPS analyses confirmed that the synergistic effect is mainly due to the redistribution of the paraffin wax during TM rather than its impact on the chemical changes caused by thermal degradation.


Holzforschung ◽  
2014 ◽  
Vol 68 (2) ◽  
pp. 239-246 ◽  
Author(s):  
Rebecka Ringman ◽  
Annica Pilgård ◽  
Christian Brischke ◽  
Klaus Richter

Abstract Chemically or physically modified wood materials have enhanced resistance to wood decay fungi. In contrast to treatments with traditional wood preservatives, where the resistance is caused mainly by the toxicity of the chemicals added, little is known about the mode of action of nontoxic wood modification methods. This study reviews established theories related to resistance in acetylated, furfurylated, dimethylol dihydroxyethyleneurea-treated, and thermally modified wood. The main conclusion is that only one theory provides a consistent explanation for the initial inhibition of brown rot degradation in modified wood, that is, moisture exclusion via the reduction of cell wall voids. Other proposed mechanisms, such as enzyme nonrecognition, micropore blocking, and reducing the number of free hydroxyl groups, may reduce the degradation rate when cell wall water uptake is no longer impeded.


BioResources ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. 3224-3234
Author(s):  
Mojgan Vaziri ◽  
Dick Sandberg

This work investigated how thermal modification affects the shear strength of welded joints under different climatic conditions. The order of the thermal modification, before or after the welding, was investigated for its effect on the shear strength of the welded wood. Two groups of thermally modified specimens were prepared in a laboratory kiln under controlled conditions, one thermally modified before welding and the other after welding of the specimens. The shear strength of the specimens were measured at four different moisture contents of 10%, 12%, 16%, and 18%, and the results for the two different approaches were compared. Moreover, observations of the X-ray computed tomography scanning and digital microscopy were used to study the density profile and the structural details of the welded joints. The results showed that thermal treatment of the wood either before or after welding had a negative influence on the shear strength, and the modes of failure of the joints in mechanical tests were in most cases brittle. In the weld interface of the wood modified before welding, a rigid material similar to charcoal was produced as a result of the further degradation of wood by welding pressure and frictional motion. Welding of wood before thermal modification, however, yielded thicker and more densified joints with less susceptibility to higher moisture variations than the joints obtained by welding the thermally modified wood.


2018 ◽  
Vol 7 (4.36) ◽  
pp. 1112 ◽  
Author(s):  
A. R. Shaikhutdinova ◽  
R. R. Safin ◽  
F. V. Nazipova ◽  
S. R. Mukhametzyanov

This paper proposes the use of an array of heat-treated wood of various species to make parametric furniture for the purpose of operation in the exterior, and on objects in conditions of high humidity. The dependence of change in the color range of thermowoods depending on the temperature and duration of treatment is presented. Experiments were carried out to study the biological stability of thermally modified wood treated by various technologies including: vacuum-convective thermal modification in superheated steam, convective thermal modification in high-pressure saturated steam, as well as in hydrophobic liquids, in flue gas and vacuum-conductive thermal-modifying. The degree of resistance of wood was determined, which allows to conclude that the mass losses of heat-treated specimens caused by the destructive action of fungi are significantly lower compared to untreated ones. The researchwas conducted to determine the numerical characteristics of microroughness of the polished surface of wood, thermally modified at different temperatures.   


2019 ◽  
Vol 800 ◽  
pp. 240-245
Author(s):  
Andis Antons ◽  
Dace Cīrule ◽  
Ingeborga Andersone ◽  
Anrijs Verovkins ◽  
Edgars Kuka

Despite intensive research in wood protection, no simple wood treatment method is available for satisfactory wood protection that could ensure appropriate strength and bio-resistance of wood products during their service life. The present study is a part of a project that is aimed to improve wood service properties by combining wood thermal treatment and impregnation with copper containing preservatives. The objective of the present study was to investigate the effect of conventional modifications (thermal modification at relatively mild temperature range (150 - 180°C) and impregnation) and double-treatments (impregnation after thermal treatment and vice versa) on the bending properties of birch (Betula spp.) and pine (Pinussylvestris L.) wood. Bending strength considerably decreased after thermal modification of wood, however MOE values generally did not significantly change. Moreover, impregnation had no effect on the bending properties for both unmodified and thermally modified wood specimens. For double-treatment in which impregnation was carried out before thermal modification no changes in bending strength were observed comparing to thermally modified wood. However, MOE values of these specimens were 10 % for birch and 19 % for pine smaller comparing to just thermally modified wood. The results of double-treatment tests imply that, regarding wood bending properties, wood impregnation after thermal modification is more appropriate.


2018 ◽  
Vol 771 ◽  
pp. 43-48
Author(s):  
Boris V. Krutasov ◽  
Mikhail A. Ylesin ◽  
Nikolay A. Mashin ◽  
Dmitry V. Dubrov

The paper deals with the issues of restoration of the wooden architecture monuments in Western Siberia by using the technology of wood modification. In order to modify the elements of the wooden buildings under restoration the authors studied hydrophobisators based on organic-silicone compounds. We have also defined the compositions and technologies of wood modification at the restoration of the wooden architecture monuments. Thermally modified wood may be used for restoration and replacement of the base courses of the wooden buildings.


Author(s):  
Dennis Jones ◽  
Dick Sandberg

Wood modification (chemical, thermal, impregnation) represents an assortment of innovative processes continually being adopted in the wood protection sector. COST Action FP1407 “Understanding wood modification through an integrated scientific and environmental impact approach — ModWoodLife” was initiated in 2015, with its 4-year programme aiming to investigate modification processing and products design with emphasis on their environmental impacts. Among the final tasks within COST FP1407 was to re-evaluate the current status of wood modification across the member countries. However, it became clear that activities in other European countries needed to be addressed, and as a result, a more extensive evaluation of wood modification processes across Europe was undertaken, as well as determining the activities globally. This paper outlines some of the recent updates in wood modification, along with summarising data collected by the authors from international colleagues and online sources, so providing an evaluation of the overall global position. These figures suggest that wood modification is undergoing a significant increase in production due to demand, with levels of recent growth seemingly suggesting this will continue for the coming years. Based on data gathered, the global commercial production of modified wood is dominated by thermal modification processes, which produce 1,110,000 m3/year. Among the other commercialised processes, acetylation accounts for 120,000 m3/year and furfurylation 45,000 m3/year. A further global production of around 330,000 m3/year is estimated for other processes, predominantly based on resin-based systems (e.g., Impreg- and Compreg-based processes).


Forests ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 50 ◽  
Author(s):  
Samuel Zelinka ◽  
Leandro Passarini ◽  
Frederick Matt ◽  
Grant Kirker

Thermally modified wood is becoming commercially available in North America for use in outdoor applications. While there have been many studies on how thermal modification affects the dimensional stability, water vapor sorption, and biodeterioration of wood, little is known about whether thermally modified wood is corrosive to metal fasteners and hangers used to hold these members in place. As thermally modified wood is used in outdoor applications, it has the potential to become wet which may lead to corrosion of embedded fasteners. Here, we examine the corrosiveness of thermally modified ash and oak in an exposure test where stainless steel, hot-dip galvanized steel, and carbon steel nails are driven into wood and exposed to a nearly 100% relative humidity environment at 27 °C for one year. The corrosion rates were compared against control specimens of untreated and preservative-treated southern pine. Stainless steel fasteners did not corrode in any specimens regardless of the treatment. The thermal modification increased the corrosiveness of the ash and oak, however, an oil treatment that is commonly applied by the manufacturer to the wood after the heat treatment reduced the corrosiveness. The carbon steel fasteners exhibited higher corrosion rates in the thermally modified hardwoods than in the preservative-treated pine control. Corrosion rates of galvanized fasteners in the hardwoods were much lower than carbon steel fasteners. These data can be used to design for corrosion when building with thermally modified wood, and highlight differences between corrosion of metals embedded in wood products.


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