Modified Starch Highly Porous Materials

2021 ◽  
Vol 899 ◽  
pp. 80-85
Author(s):  
Ekaterina A. Kachalova ◽  
Ivan R. Lednev ◽  
R.S. Kovylin ◽  
L.A. Smirnova
Keyword(s):  
Graft Polymerization ◽  
Modified Starch ◽  
Acid Solutions ◽  
Highly Porous Materials ◽  
Aqueous Acid ◽  
Wide Range ◽  
High Sorption ◽  
And Storage ◽  
Highly Porous ◽  
Sorption Characteristics

A technique for starch modification by graft polymerization of acrylamide has been developed. The obtained copolymer is soluble in a wide range of pH 2 - 12. The modification of starch made it possible to freely combine it with aqueous acid solutions of chitosan, in order to achieve a synergistic effect of their properties. A porous material based on modified starch and its mixtures with chitosan, which has high sorption characteristics, has been developed. The resulting material is promising as a sorbent of heavy metal ions and packing materials for transportation and storage.

Conventional and novel processing methods for cellular ceramics

2005 ◽  
Vol 364 (1838) ◽  
pp. 109-124 ◽  
Author(s):  
Paolo Colombo
Keyword(s):  
Hollow Spheres ◽  
Processing Methods ◽  
Gas Streams ◽  
Highly Porous Materials ◽  
Wide Range ◽  
Recent Developments ◽  
Innovative Materials ◽  
Novel Processing ◽  
Highly Porous ◽  
Insight Into

Cellular ceramics are a class of highly porous materials that covers a wide range of structures, such as foams, honeycombs, interconnected rods, interconnected fibres, interconnected hollow spheres. Recently, there has been a surge of activity in this field, because these innovative materials have started to be used as components in special and advanced engineering applications. These include filtering liquids and particles in gas streams, porous burners, biomedical devices, lightweight load-bearing structures, etc. Improvements in conventional processing methods and the development of innovative fabrication approaches are required because of the increasing specific demands on properties and morphology (cell size, size distribution and interconnection) for these materials, which strictly depend on the application considered. This paper will cover the main fabrication methods for cellular ceramics, focusing primarily on foams, offering some insight into novel fabrication processes and recent developments.

scholarly journals Advances in Enzyme and Ionic Liquid Immobilization for Enhanced in MOFs for Biodiesel Production

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3512
Author(s):  
Reem Shomal ◽  
Babatunde Ogubadejo ◽  
Toyin Shittu ◽  
Eyas Mahmoud ◽  
Wei Du ◽  
...  
Keyword(s):  
Organic Ligands ◽  
Biodiesel Production ◽  
Catalyst Stability ◽  
Promising Candidate ◽  
Catalytic Systems ◽  
Highly Porous Materials ◽  
High Tunability ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Highly Porous

Biodiesel is a promising candidate for sustainable and renewable energy and extensive research is being conducted worldwide to optimize its production process. The employed catalyst is an important parameter in biodiesel production. Metal–organic frameworks (MOFs), which are a set of highly porous materials comprising coordinated bonds between metals and organic ligands, have recently been proposed as catalysts. MOFs exhibit high tunability, possess high crystallinity and surface area, and their order can vary from the atomic to the microscale level. However, their catalytic sites are confined inside their porous structure, limiting their accessibility for biodiesel production. Modification of MOF structure by immobilizing enzymes or ionic liquids (ILs) could be a solution to this challenge and can lead to better performance and provide catalytic systems with higher activities. This review compiles the recent advances in catalytic transesterification for biodiesel production using enzymes or ILs. The available literature clearly indicates that MOFs are the most suitable immobilization supports, leading to higher biodiesel production without affecting the catalytic activity while increasing the catalyst stability and reusability in several cycles.

scholarly journals Recent Insights into Anthocyanin Pigmentation, Synthesis, Trafficking, and Regulatory Mechanisms in Rice (Oryza sativa L.) Caryopsis

Biomolecules ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 394 ◽  
Author(s):  
Enerand Mackon ◽  
Guibeline Charlie Jeazet Dongho Epse Mackon ◽  
Yafei Ma ◽  
Muhammad Haneef Kashif ◽  
Niyaz Ali ◽  
...  
Keyword(s):  
Food Industry ◽  
Anthocyanin Biosynthesis ◽  
Oryza Sativa L ◽  
Anthocyanin Synthesis ◽  
Pigmented Rice ◽  
Complex Processes ◽  
Natural Colorants ◽  
Wide Range ◽  
Anthocyanin Production ◽  
And Storage

Anthocyanins are antioxidants used as natural colorants and are beneficial to human health. Anthocyanins contribute to reactive oxygen species detoxification and sustain plant growth and development under different environmental stresses. They are phenolic compounds that are broadly distributed in nature and are responsible for a wide range of attractive coloration in many plant organs. Anthocyanins are found in various parts of plants such as flowers, leaves, stems, shoots, and grains. Considering their nutritional and health attributes, anthocyanin-enriched rice or pigmented rice cultivars are a possible alternative to reduce malnutrition around the globe. Anthocyanin biosynthesis and storage in rice are complex processes in which several structural and regulatory genes are involved. In recent years, significant progress has been achieved in the molecular and genetic mechanism of anthocyanins, and their synthesis is of great interest to researchers and the scientific community. However, limited studies have reported anthocyanin synthesis, transportation, and environmental conditions that can hinder anthocyanin production in rice. Rice is a staple food around the globe, and further research on anthocyanin in rice warrants more attention. In this review, metabolic and pre-biotic activities, the underlying transportation, and storage mechanisms of anthocyanins in rice are discussed in detail. This review provides potential information for the food industry and clues for rice breeding and genetic engineering of rice.

Sediment slugs: large-scale fluctuations in fluvial sediment transport rates and storage volumes

1995 ◽  
Vol 19 (4) ◽  
pp. 500-519 ◽  
Author(s):  
A.P. Nicholas ◽  
P.J. Ashworth ◽  
M.J. Kirkby ◽  
M.G. Macklin ◽  
T. Murray
Keyword(s):  
Sediment Transport ◽  
Sediment Supply ◽  
Fluvial Systems ◽  
Event Scale ◽  
Fluvial Sediment ◽  
Sediment Routing ◽  
Basin Scale ◽  
Wide Range ◽  
And Storage ◽  
Fluvial Sediment Transport

Variations in fluvial sediment transport rates and storage volumes have been described previously as sediment waves or pulses. These features have been identified over a wide range of temporal and spatial scales and have been categorized using existing bedform classifications. Here we describe the factors controlling the generation and propagation of what we term sediment slugs. These can be defined as bodies of clastic material associated with disequilibrium conditions in fluvial systems over time periods above the event scale. Slugs range in magnitude from unit bars (Smith, 1974) up to sedimentary features generated by basin-scale sediment supply disturbances (Trimble, 1981). At lower slug magnitudes, perturbations in sediment transport are generated by local riverbank and/or bed erosion. Larger-scale features result from the occurrence of rare high- magnitude geomorphic events, and the impacts on water and sediment production of tectonics, glaciation, climate change and anthropogenic influences. Simple sediment routing functions are presented which may be used to describe the propagation of sediment slugs in fluvial systems. Attention is drawn to components of the fluvial system where future research is urgently required to improve our quantitative understanding of drainage-basin sediment dynamics.

scholarly journals Voltammetric oxidation of dipyridamole in aqueous acid solutions

2000 ◽  
Vol 11 (2) ◽  
pp. 148-153 ◽  
Author(s):  
Marilza Castilho ◽  
Luiz E. Almeida ◽  
Marcel Tabak ◽  
Luiz H. Mazo
Keyword(s):  
Acid Solutions ◽  
Aqueous Acid

scholarly journals Bio-Templating: An Emerging Synthetic Technique for Catalysts. A Review

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1364
Author(s):  
M. Carmen Herrera-Beurnio ◽  
Jesús Hidalgo-Carrillo ◽  
Francisco J. López-Tenllado ◽  
Juan Martin-Gómez ◽  
Rafael C. Estévez ◽  
...  
Keyword(s):  
Active Sites ◽  
Experimental Studies ◽  
Functional Materials ◽  
Inorganic Materials ◽  
Hierarchical Organization ◽  
Materials Synthesis ◽  
Energy Capture ◽  
Wide Range ◽  
Mineralization Processes ◽  
And Storage

In the last few years, researchers have focused their attention on the synthesis of new catalyst structures based on or inspired by nature. Biotemplating involves the transfer of biological structures to inorganic materials through artificial mineralization processes. This approach offers the main advantage of allowing morphological control of the product, as a template with the desired morphology can be pre-determined, as long as it is found in nature. This way, natural evolution through millions of years can provide us with new synthetic pathways to develop some novel functional materials with advantageous properties, such as sophistication, miniaturization, hybridization, hierarchical organization, resistance, and adaptability to the required need. The field of application of these materials is very wide, covering nanomedicine, energy capture and storage, sensors, biocompatible materials, adsorbents, and catalysis. In the latter case, bio-inspired materials can be applied as catalysts requiring different types of active sites (i.e., redox, acidic, basic sites, or a combination of them) to a wide range of processes, including conventional thermal catalysis, photocatalysis, or electrocatalysis, among others. This review aims to cover current experimental studies in the field of biotemplating materials synthesis and their characterization, focusing on their application in heterogeneous catalysis.

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