Second Phase Evolution in a Yttria-Sintered Aluminum Nitride Ceramic

2001 ◽  
Vol 383 ◽  
pp. 55-70
Author(s):  
Mehrdad Zarinejad ◽  
Robin A.L. Drew
2021 ◽  
Author(s):  
Nikola Stanković ◽  
Vesna Cvetkov ◽  
Vladica Cvetković

<p>We report updated results of our ongoing research on constraining geodynamic conditions associated with the final closure of the Vardar branch of the Tethys Ocean by means of application of numerical simulations (previous interim results reported in EGU2020-5919).</p><p>The aim of our numerical study is to test the hypothesis that a single eastward subduction in the Jurassic is a valid explanation for the occurrence of three major, presently observed geological entities that are left behind after the closure of the Vardar Tethys. These include: ophiolite-like igneous rocks of the Sava-Vardar zone and presumably subduction related Timok Magmatic Complex, both Late Cretaceous in age as well as Jurassic ophiolites obducted onto the Adriatic margin. In our simulations we initiate an intraoceanic subduction in the Early/Middle Jurassic, which eventually transitions into an oceanic closure and subsequent continental collision processes.</p><p>In the scope of our study numerical simulations are performed by solving a set of partial differential equations: the continuity equation, the Navier-Stokes equations and the temperature equation. To this end we used I2VIS thermo-mechanical code which utilizes marker in cell approach with finite difference discretization of equations on a staggered grid [Gerya et al., 2000; Gerya&Yuen, 2003].</p><p>The 2D model consists of two continental plates separated by two oceanic slabs connected at a mid-oceanic ridge. Intraoceanic subduction is initiated along the ridge by assigning a weak zone beneath the ridge. Time-dependent boundary conditions for velocity are imposed on the simulation in order to model a transient spreading period. The change of sign in plate velocities is found to be useful for both obtaining obduction / ophiolite emplacement [Duretz et al., 2016] and causing back-arc extension. Changes in velocities are linear in time. Simulations follow a three-phase evolution of velocity boundary conditions consisting of two convergent phases separated by a single divergent phase where spreading regime is dominant. Effect of duration and magnitude of the second phase on model evolution is also explored.</p><p>Our so far obtained simulations were able to reproduce the westward obduction and certain extension processes along the active (European) margin, which match the existing geological relationships. However, the simulations involve an unreasonably short geodynamic event (cca 15-20 My) and we are working on solving this problem with new simulations. </p>


2008 ◽  
Vol 368-372 ◽  
pp. 970-972 ◽  
Author(s):  
Yan Xiong ◽  
Zheng Yi Fu ◽  
Hao Wang

Effect of adding up to 5wt% CaF2 on the densification and microstructural development of hot pressed aluminum nitride (AlN) was investigated. SEM investigation showed that the grain size of the sintered sample decreases with the increasing content of CaF2. Secondary-phase evolution paths converge from CA6 to CA phase above 1650°C. TEM micrographs showed that formed secondary phases could evaporate from sintered bodies at higher temperatures in the carbon-containing nitrogen atmosphere and the residuals were mainly distributed at triple grain junctions, keeping direct connections of AlN grains. Translucnet AlN ceramics were prepared using CaF2 additive sintered at 1850°C for 5 h.


2009 ◽  
Vol 6 ◽  
pp. 115-122 ◽  
Author(s):  
Dachamir Hotza ◽  
Adrian Leo ◽  
Jaka Sunarso ◽  
João C. Diniz da Costa

This work investigates the effect of nanosized Al2O3 addition on the sinterability of YSZ electrolyte. (1−x)YSZ + Al2O3 ceramics with compositions x = 0 to 0.01 were prepared by the conventional mixed oxide route from a commercial powder suspension (particle size <50 nm), and sintered at 1200 to 1500°C for 2 hours in air. Densification, phase evolution, and microstructure were characterized by SEM/EDS and XRD. An improvement in sintered density was observed for the samples with 0.2 to 0.5 mol% Al2O3, though depending on the sintering temperature. Only cubic zirconia was detected as crystalline phase, although XRD features suggested chemical interactions depending upon the amount of Al2O3. The grain size of YSZ was homogeneous and no second phase segregation was detected in the tested range of incorporated nano-Al2O3 and sintering temperatures.


2007 ◽  
Vol 539-543 ◽  
pp. 281-286 ◽  
Author(s):  
A. Miroux ◽  
Zacharias J. Lok ◽  
Knut Marthinsen ◽  
Sybrand van der Zwaag

The complete evolution of solute content and second phases during full-scale industrial processing of AA3103 sheets has been measured. During pre-heating, dispersoids, which appear as plates or small polyhedra grow and the Mn solute content decreases. During subsequent breakdown rolling the dispersoid number-density increases significantly. The measured decrease of solute Mn after hot rolling and coil cooling is attributed to constituent particle growth, whereas the solute depletion during the final back-annealing is mainly caused by the growth of the dispersoids. These observations are compared to the predictions obtained by a semi-physical model for precipitation. Although simulations have been performed without any retro-fitting, for hot rolling the results compare quantitatively well with experiment, while for coil cooling and back annealing the modelled Mn solute depletion is underestimated. The precipitation process is found to be very sensitive to the microstructure, which illustrates the importance of coupling precipitation models with work hardening and softening models to obtain reliable predictions.


2014 ◽  
Vol 602-603 ◽  
pp. 565-569
Author(s):  
Chang Lu Fu ◽  
Shang Hua Wu ◽  
Yan Ling Cheng ◽  
Jun Yu Fu ◽  
Ruo Jun Wu ◽  
...  

In this paper, the aluminum nitride (AlN) was fabricated by pressureless sintering with YF3 and various silicon compounds as the sintering aids. The phase, microstructure, density and thermal conductivity were characterized by XRD, SEM and laser thermal diffusivity method. The sample densities were detected varied from 3.17 to 3.30g/cm3 and room-temperature thermal conductivity varied from 196 to 233 W/m·K. Samples sintered with YF3 additives have the highest thermal conductivity. The sintering aids with SiO2, Si3N4 and SiC would decrease the density and the thermal conductivity obviously, and also change the fracture mode from the intergranular to transgranular , which is a key for the toughness of the AlN substrate.


2005 ◽  
Vol 23 (4-6) ◽  
pp. 382-385 ◽  
Author(s):  
Shoichi Kume ◽  
Masaki Yasuoka ◽  
Naoki Omura ◽  
Koji Watari

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