Synthesis of Precipitated Calcium Carbonate Using a Limestone and its Application in Paper Filler and Coating Color

2007 ◽  
Vol 544-545 ◽  
pp. 881-884 ◽  
Author(s):  
Sang Hwan Cho ◽  
Jin Koo Park ◽  
Seung Kwan Lee ◽  
Sung Min Joo ◽  
Im Ho Kim ◽  
...  

Homogeneous precipitated calcium carbonate(PCC) was synthesized by calcinations, hydration and carbonation of limestone which has been deposited in Danyang, Korea. In the reaction process, shapes(scalenohedral and cubic) and sizes(0.2~0.3μm and 2.0μm) of the powder were controlled by reaction temperature. Synthesized PCC was applied to hand-made paper as filler and coated paper. For the prepared papers, physical/optical properties(brightness, whiteness, opacity, roughness, gloss, tensile strength, internal tearing strength, stiffness, bursting strength) and printability(ink gloss, ink set-off, dry pick, wet pick) were characterized

TAPPI Journal ◽  
2011 ◽  
Vol 10 (7) ◽  
pp. 29-34
Author(s):  
TEEMU PUHAKKA ◽  
ISKO KAJANTO ◽  
NINA PYKÄLÄINEN

Cracking at the fold is a quality defect sometimes observed in coated paper and board. Although tensile and compressive stresses occur during folding, test methods to measure the compressive strength of a coating have not been available. Our objective was to develop a method to measure the compressive strength of a coating layer and to investigate how different mineral coatings behave under compression. We used the short-span compressive strength test (SCT) to measure the in-plane compressive strength of a free coating layer. Unsupported free coating films were prepared for the measurements. Results indicate that the SCT method was suitable for measuring the in-plane compressive strength of a coating layer. Coating color formulations containing different kaolin and calcium carbonate minerals were used to study the effect of pigment particles’ shape on the compressive and tensile strengths of coatings. Latices having two different glass transition temperatures were used. Results showed that pigment particle shape influenced the strength of a coating layer. Platy clay gave better strength than spherical or needle-shaped carbonate pigments. Compressive and tensile strength decreased as a function of the amount of calcium carbonate in the coating color, particularly with precipitated calcium carbonate. We also assessed the influence of styrene-butadiene binder on the compressive strength of the coating layer, which increased with the binder level. The compressive strength of the coating layer was about three times the tensile strength.


2013 ◽  
Vol 395-396 ◽  
pp. 577-581
Author(s):  
Quan Xiao Liu ◽  
Yan Na Yin ◽  
Wen Cai Xu

The X-ray diffraction of hydrated calcium silicate is analyzed and is applied in papermaking. It shows that hydrated calcium silicate have certain crystalline state. The tensile strength, tearing strength and folding strength of paper decrease in different degree with the increase of dosage of hydrated calcium silicate while the whiteness and the printing color density of paper improve. T tensile strength and folding strength of paper decrease in varying degrees with the increase of dosage of PAM while the tearing strength of paper and the whiteness improve. And the printing color density of paper is the same.


TAPPI Journal ◽  
2011 ◽  
Vol 10 (2) ◽  
pp. 17-24 ◽  
Author(s):  
ALESSANDRA GERLI ◽  
LEENDERT C. EIGENBROOD ◽  
SANNA NURMI

Various uncoated woodfree papers produced on a pilot paper machine were characterized for picking resistance, using an IGT printability tester, and standard sheet properties. The papers were produced with and without surface sizing or a debonding agent, with different filler types (ground calcium carbonate [GCC] or precipitated calcium carbonate [PCC]) and levels (20% and 25%), and by varying the calendering conditions. The goal was to assess the relationship between surface strength of these sheets and their bulk strength properties, such as tensile strength and internal bond. Variables such as the use of a debonding agent or the application of surface size had equal effect on picking resistance and tensile strength. Increase of filler content in paper or replacement of GCC with PCC reduced picking resistance, tensile strength, and internal bond. Increase of the calendering load, for both GCC and PCC sheets, reduced picking resistance but left tensile strength and internal bond unaffected. Picking resistance of the 25% PCC-containing sheets was affected at a significantly larger extent by an increase in calendering load than picking resistance of the 25% GCC-containing sheets. These results point out that the surface of a highly filled PCC sheet is particularly sensitive to surface damage by calendering.


2014 ◽  
Vol 910 ◽  
pp. 266-269 ◽  
Author(s):  
Jia Horng Lin ◽  
Jing Chzi Hsieh ◽  
Jia Hsun Li ◽  
Wen Hao Hsing ◽  
Ching Wen Lou

Geotextile has been commonly used in civil and geotechnical engineering applications, and the majority of geotextiles is made of nonwoven fabrics. Therefore, this study combines crimped polyester (PET) fibers, recycled Kevlar unidirectional selvage fibers, and low-melting-point PET (LPET) fibers to form PET/Kevlar/LPET nonwoven geotextiles, and then examines how various neelde-punch depths influence mechanical properties of the resulting nonwoven geotextiles. The tensile strength, tearing strength, bursting strength, and static puncture resistance of the nonwoven fabrics increase as a result of an increase of 0.3 cm to 0.5 cm in needle-punch depth. However, an increase of 0.5 cm to 0.7 cm causes a slight decrease in all aforementioned properties.


2014 ◽  
Vol 68 (6) ◽  
Author(s):  
Kamel Mohamadzadeh-Saghavaz ◽  
Hossein Resalati ◽  
Ali Ghasemian

AbstractA cellulose-PCC composite was synthesised using the CaCl2 reaction with dimethyl carbonate (DMC) under alkaline conditions and in the presence of cellulose fibrils made from highly refined bleached softwood kraft pulp. The results showed that the ash content in the synthesised cellulose-PCC composite increased by increasing the reaction temperature from 25°C to 70°C, the reaction time from 3.5 min to 7.5 min and the cellulose consistency from 0.05 % to 0.1 %. The ratio of calcium carbonate generated to the calcium chloride used initially was increased by increasing the reaction temperature and time. The XRD pattern of the cellulose-PCC composite indicated no modification micro-crystal habit of the deposited CaCO3. The SEM images showed that the cellulose-PCC composite filler had a rhombohedral shape as opposed to the scalenohedral shape of common PCC. The paper filled with the cellulose-PCC composite had much higher bursting and tensile strengths, at a tearing strength similar to common PCC.


2016 ◽  
Vol 697 ◽  
pp. 113-118
Author(s):  
Hui Yan Zeng ◽  
Zi Ling Yan ◽  
Meng Ran Jiao ◽  
Dong Dong Xu ◽  
Jiu Xin Jiang

An entirely novel preparation method of calcium carbonate (CaCO3) from calcium hydrogen carbonate (Ca (HCO3)2) solution was presented and named as thermal decomposition. The variation of the polymorphs and morphologies of CaCO3 particles with reaction temperature was investigated. XRD result indicates that high temperature favors the formation of calcite. Cubic or rhombohedra calcite crystals, lamellar and spherical vaterite crystals and rod– and needle–like aragonite crystals are found in powder synthesized at different temperatures. The reaction process was also discussed in the present work.


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