Electrochemical Characteristics of 410 Stainless Steel Produced by MIM Process through EIS Method under SSRT Test

2012 ◽  
Vol 706-709 ◽  
pp. 2008-2013
Author(s):  
Satoshi Sunada ◽  
Norio Nunomura ◽  
Kazuhiko Majima
Keyword(s):  
Aqueous Solution ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Deionized Water ◽  
Electrochemical Characteristics ◽  
Transfer Resistance ◽  
Impurities And Defects

In this experiment two kinds of 410L stainless steel, i.e., the first one is prepared by the I/M process and the second one is prepared by MIM process were used, and their corrosion behavior under stress in deionized water and the aqueous solution of 0.01kmol·m-3HCl+1.72mol·m-3MgCl2 (pH=2.33) has been investigated by Electrochemical Impedance Spectroscopy (hereafter shortened as EIS) under Slow Strain Rate Tensile (hereafter shortened as SSRT) test. The charge transfer resistance (Rct) of the I/M specimen is larger than that of the MIM specimen irrespective of under stress or non-stress, which means that the I/M specimen has the better corrosion resistance than the MIM specimen in the 0.01kmol·m-3HCl+1.72mol·m-3MgCl2 (pH=2.33) solution. It was also confirmed from the fracture surface observation that hydrogen embrittlement occurred on the MIM specimen in the aqueous solution of 0.01kmol·m-3HCl+1.72mol·m-3MgCl2 (pH=2.33). This result would be confirmed to be due to the existing impurities and defects in the MIM specimen.

scholarly journals Corrosion and Electrochemical Impedance Spectroscopy of Thin TiALN and TiCN PVD Coatings for Protection of Ballast Water Screen Filters

2021 ◽  
Vol 58 (2) ◽  
pp. 64-78
Author(s):  
R. Kalnina ◽  
V. Priednieks ◽  
K. Lukins ◽  
A. Gasparjans ◽  
A. Rijkure
Keyword(s):  
Stainless Steel ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Surface Passivation ◽  
Electrochemical Impedance ◽  
Protective Coatings ◽  
Corrosion Behaviour ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Ticn Coating

Abstract The electrochemical impedance spectroscopy (EIS) and corrosion behaviour of physical vapour deposited (PVD) TiAlN and TiCN coatings of 50 µm mesh shaped AISI 316 stainless steel were estimated under simulated marine conditions (3.5 wt. % NaCl solution). The coatings were prepared by creating adhesive Cr-CrN interlayer with the thickness of about 0.3 µm. The obtained thicknesses of produced coatings were measured to be in a range between 2 and 3.5 µm. The presence of protective coatings leads to corrosion potential (Ecorr ) shifting to more positive values as compared to the bare stainless steel. This effect indicates higher protection efficiency of coated steel under marine conditions. The protective behaviour of produced coating leads to the decreased corrosion current density (jcorr ) by indicating up to 40-fold higher polarization resistance as compared to resistance of the naturally formed oxide layer over the stainless steel. The Nyquist and Bode plots were obtained with the help of EIS measurements by applying alternating potential amplitude of 10 mV on observed Ecorr . The obtained plots were fitted by appropriate equivalent circuits to calculate pore resistance, charge transfer resistance and capacitance. The present study reveals that pore resistance was the highest in the case of TiCN coating (Rpore =3.22 kΩ·cm2). The increase in duration of the immersion up to 24 h leads to change in the capacitive behaviour of the coatings caused by the penetration of the aqueous solution into pore system of TiCN coating with low wettability and surface passivation of reactive TiAlN coating. The presence of defects was confirmed by examining the obtained samples with the help of the scanning electron microscope.

scholarly journals Corrosion behaviors of 316 stainless steel and Inconel 625 alloy in chloride molten salts for solar energy storage

2020 ◽  
Vol 39 (1) ◽  
pp. 340-350
Author(s):  
Mingjing Wang ◽  
Song Zeng ◽  
Huihui Zhang ◽  
Ming Zhu ◽  
Chengxin Lei ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Molten Salt ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Inconel 625 ◽  
Transfer Resistance ◽  
316 Stainless Steel ◽  
Corrosion Rates ◽  
Inconel 625 Alloy ◽  
Corrosion Behaviors

AbstractCorrosion behaviors of 316 stainless steel (316 ss) and Inconel 625 alloy in molten NaCl–KCl–ZnCl2 at 700°C and 900°C were investigated by immersion tests and electrochemical methods, including potentiodynamic polarization and electrochemical impedance spectroscopy. X-ray diffraction and scanning electron microscopy/energy dispersive spectroscopy were used to analyze the phases and microstructures of the corrosion products. Inconel 625 alloy and 316 ss exhibited high corrosion rates in molten chlorides, and the corrosion rates of these two alloys accelerated when the temperature increased from 700°C to 900°C. The results of the electrochemical tests showed that both alloys exhibited active corrosion in chloride molten salt, and the current density of 316 ss in chloride molten salt at 700°C was 2.756 mA/cm−2, which is about three times the value for Inconel 625 alloy; and the values of the charge transfer resistance (Rt) for Inconel 625 were larger than those for 316 ss. The corrosion of these two alloys is owing to the preferred oxidation of Cr in chloride molten salt, and the corrosion layer was mainly ZnCr2O4 which was loose and porous and showed poor adherence to metal.

scholarly journals Deciphering the Disaggregation Mechanism of Amyloid Beta Aggregate by 4-(2-Hydroxyethyl)-1-Piperazinepropanesulfonic Acid Using Electrochemical Impedance Spectroscopy

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 788
Author(s):  
Hien T. Ngoc Le ◽  
Sungbo Cho
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Specific Binding ◽  
Amyloid Β ◽  
Electrochemical Measurement ◽  
Charge Transfer Resistance ◽  
Chemical Agent ◽  
Transfer Resistance ◽  
K Value

Aggregation of amyloid-β (aβ) peptides into toxic oligomers, fibrils, and plaques is central in the molecular pathogenesis of Alzheimer’s disease (AD) and is the primary focus of AD diagnostics. Disaggregation or elimination of toxic aβ aggregates in patients is important for delaying the progression of neurodegenerative disorders in AD. Recently, 4-(2-hydroxyethyl)-1-piperazinepropanesulfonic acid (EPPS) was introduced as a chemical agent that binds with toxic aβ aggregates and transforms them into monomers to reduce the negative effects of aβ aggregates in the brain. However, the mechanism of aβ disaggregation by EPPS has not yet been completely clarified. In this study, an electrochemical impedimetric immunosensor for aβ diagnostics was developed by immobilizing a specific anti-amyloid-β (aβ) antibody onto a self-assembled monolayer functionalized with a new interdigitated chain-shaped electrode (anti-aβ/SAM/ICE). To investigate the ability of EPPS in recognizing AD by extricating aβ aggregation, commercially available aβ aggregates (aβagg) were used. Electrochemical impedance spectroscopy was used to probe the changes in charge transfer resistance (Rct) of the immunosensor after the specific binding of biosensor with aβagg. The subsequent incubation of the aβagg complex with a specific concentration of EPPS at different time intervals divulged AD progression. The decline in the Rct of the immunosensor started at 10 min of EPPS incubation and continued to decrease gradually from 20 min, indicating that the accumulation of aβagg on the surface of the anti-aβ/SAM/ICE sensor has been extricated. Here, the kinetic disaggregation rate k value of aβagg was found to be 0.038. This innovative study using electrochemical measurement to investigate the mechanism of aβagg disaggregation by EPPS could provide a new perspective in monitoring the disaggregation periods of aβagg from oligomeric to monomeric form, and then support for the prediction and handling AD symptoms at different stages after treatment by a drug, EPPS.

scholarly journals Effects of NiSO4 Concentration on the Coloring Performance and Corrosion Resistance of the Colored Film on 304 Stainless Steel

Coatings ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 598
Author(s):  
Wenwei Li ◽  
Jun-e Qu ◽  
Zhiyong Cao ◽  
Hairen Wang
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Negative Impact ◽  
304 Stainless Steel ◽  
Nacl Solution ◽  
Time Curve ◽  
Steel Surfaces

The colored films were successfully prepared on the 304 stainless steel surfaces in coloring solutions with different NiSO4 contents. The purpose of this study was to investigate the effects of NiSO4 in the coloring solution on the coloring performance of 304 stainless steel and corrosion resistance of the obtained colored film in NaCl solution. The coloring rate was determined from coloring potential-time curve, and the protection properties of the color films in a 3.5% NaCl solution were characterized by potentiodynamic polarization scan, electrochemical impedance spectroscopy, and wear resistance test. The results showed that adding NiSO4 could accelerate the coloring process but brought about a negative impact on the surface’s corrosion resistance.

scholarly journals Investigation of Temperature and Aging Effects in Nanostructured Dye Solar Cells Studied by Electrochemical Impedance Spectroscopy

2009 ◽  
Vol 2009 ◽  
pp. 1-15 ◽  
Author(s):  
Minna Toivola ◽  
Janne Halme ◽  
Lauri Peltokorpi ◽  
Peter Lund
Keyword(s):  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Aging Effects ◽  
Transfer Resistance ◽  
Deterioration Rate ◽  
Dye Solar Cells ◽  
Effects Of Aging

Effects of aging and cyclically varying temperature on the electrical parameters of dye solar cells were analyzed with electrochemical impedance spectroscopy. Photoelectrode total resistance increased as a function of time due to increasing electron transport resistance in theTiO2film. On the other hand, photoelectrode recombination resistance was generally larger, electron lifetimes in theTiO2were film longer, and charge transfer resistance on the counter electrode was smaller after the temperature treatments than before them. These effects correlated with the slower deterioration rate of the temperature-treated cells, in comparison to the reference cells.

scholarly journals Yeast Propagation Control: Low Frequency Electrochemical Impedance Spectroscopy as an Alternative for Cell Counting Chambers in Brewery Applications

Chemosensors ◽  
2020 ◽  
Vol 8 (2) ◽  
pp. 27
Author(s):  
Georg Christoph Brunauer ◽  
Oliver Spadiut ◽  
Alfred Gruber ◽  
Christoph Slouka
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Pathogen Detection ◽  
Electrochemical Impedance ◽  
Low Frequency ◽  
Charge Transfer Resistance ◽  
Cell Counting ◽  
Delayed Response ◽  
Transfer Resistance ◽  
Cell Counts

Electrochemical impedance spectroscopy is a powerful tool in life science for cell and pathogen detection, as well as for cell counting. The measurement principles and techniques using impedance spectroscopy are highly diverse. Differences can be found in used frequency range (β or α regime), analyzed quantities, like charge transfer resistance, dielectric permittivity of double layer capacitance and in off- or online usage. In recent contributions, applications of low-frequency impedance spectroscopy in the α regime were tested for determination of cell counts and metabolic burden in Escherichia coli and Saccharomyces cerevisiae. The established easy to use methods showed reasonable potential in the lab scale, especially for S. cerevisiae. However, until now, measurements for cell counts in food science are generally based on Thoma cell counting chambers. These microscopic cell counting methods decelerate an easy and quick prediction of yeast viability, as they are labor intensive and result in a time delayed response signal. In this contribution we tested our developed method using low frequency impedance spectroscopy locally at an industrial brewery propagation site and compared results to classic cell counting procedures.

scholarly journals Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4507 ◽  
Author(s):  
Yusuke Abe ◽  
Natsuki Hori ◽  
Seiji Kumagai
Keyword(s):  
Charge Transfer ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Performance Degradation ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Charge Discharge

Lithium-ion batteries (LIBs) using a LiFePO4 cathode and graphite anode were assembled in coin cell form and subjected to 1000 charge-discharge cycles at 1, 2, and 5 C at 25 °C. The performance degradation of the LIB cells under different C-rates was analyzed by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. The most severe degradation occurred at 2 C while degradation was mitigated at the highest C-rate of 5 C. EIS data of the equivalent circuit model provided information on the changes in the internal resistance. The charge-transfer resistance within all the cells increased after the cycle test, with the cell cycled at 2 C presenting the greatest increment in the charge-transfer resistance. Agglomerates were observed on the graphite anodes of the cells cycled at 2 and 5 C; these were more abundantly produced in the former cell. The lower degradation of the cell cycled at 5 C was attributed to the lowered capacity utilization of the anode. The larger cell voltage drop caused by the increased C-rate reduced the electrode potential variation allocated to the net electrochemical reactions, contributing to the charge-discharge specific capacity of the cells.

Thermal transitions in hydrated layer-by-layer assemblies observed using electrochemical impedance spectroscopy

Soft Matter ◽  
2014 ◽  
Vol 10 (34) ◽  
pp. 6467-6476 ◽  
Author(s):  
Choonghyun Sung ◽  
Katelin Hearn ◽  
Jodie Lutkenhaus
Keyword(s):  
Charge Transfer ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Thermal Transition ◽  
Layer By Layer ◽  
Thermal Transitions ◽  
Transfer Resistance ◽  
Hydrated Layer

Layer-by-layer assemblies exhibit increased conductivity and decreased charge transfer resistance upon heating through the thermal transition.

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