High Dielectric Constant of Silver Nanowires–Epoxy Composites

2016 ◽  
Vol 848 ◽  
pp. 9-12 ◽  
Author(s):  
Yue Guang Chen ◽  
Shi Jiao Wang

Silver nanowires–epoxy composites were prepared via cryomilling dispersion and hot-press forming process. The microstructure of the silver nanowires was studied by SEM. Dependence of dielectric properties of the composites on volume fraction of silver nanowires and frequency was investigated RF impedance material analyzer. The percolation threshold of the composites was 0.16, the value of the dielectric constant of the composite was as high as 100.

2012 ◽  
Vol 496 ◽  
pp. 263-267
Author(s):  
Rui Li ◽  
Jian Zhong Pei ◽  
Yan Wei Li ◽  
Xin Shi ◽  
Qun Le Du

A novel all-polymeric material with high dielectric constant (k) has been developed by blending poly (vinylidene fluoride) (PVDF) with polyamide-6 (PA6). The dependence of the dielectric properties on frequency and polymer volume fraction was investigated. When the volume fraction of PA6 is 20%, the dielectric property is better than others. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. The XRD demonstrate that the PA6 and PVDF affect the crystalline behavior of each component. Furthermore, the stable dielectric constants of the blends could be tuned by adjusting the content of the polymers. The created high-k all-polymeric blends represent a novel type of material that are simple technology and easy to process, and is of relatively high dielectric constant, applications as flexible electronics.


2011 ◽  
Vol 1312 ◽  
Author(s):  
Xiaobing Shan ◽  
Lin Zhang ◽  
Z.-Y. Cheng

AbstractA high dielectric constant was observed in 0-3 composites using P(VDF-TrFE) copolymer as matrix and CaCu3TiO4 (CCTO) ceramic powders as fillers with a composition of 50 vol% CCTO. CCTO-P(VDF-TrFE) 0-3 composites with a CCTO content from 0 to 50 vol% were prepared and their dielectric properties, including frequency dependence and temperature dependence of the dielectric constant and loss, were characterized. It was experimentally observed that the hot-press process, inlcuding the configuration and hot-press time, has a strong influence on the dielectric properties of the composites. Additionally, the influence of the CCTO partice size on the dielectric properties of the composites was studied.


2007 ◽  
Vol 280-283 ◽  
pp. 115-118
Author(s):  
Jian Fei Wang ◽  
Yuan Hua Lin ◽  
Yu Chen ◽  
Lei Jiang ◽  
Ce Wen Nan

NiO-NiTiO3 composite ceramics were prepared by the conventional solid state reaction process and dielectric properties were investigated as a function of frequency and temperature. The results indicate that all samples showed high dielectric constant ~103 at 0.1 kHz, but a remarkable decrease of the dielectric loss appeared when the volume fraction of NiTiO3 phase reached 42.4%. Relaxor-like peaks were observed in the temperature dependence of the dielectric constant with ceramics having low composition of NiTiO3 phase (≤21.2%). The possible response mechanism associated with the microstructure and the associated defects of the composites was discussed.


2017 ◽  
Vol 898 ◽  
pp. 2101-2106
Author(s):  
Zhong Yang Wang ◽  
Xin Yan Li ◽  
Run Hua Fan ◽  
Pei Tao Xie ◽  
Kai Sun ◽  
...  

Conductor–insulator composites have been extensive researched for high dielectric constant. Most of them concentrated on metal polymers or metal ceramics. Barium titanate–carbon fibers composites were prepared by using a solid state reaction process with carbon fibers contents ranging from7 vol% to 23 vol%. Due to the high-aspect-ratio of carbon fiber, it was easy to produce a conducting network at much lower volume fraction. FESEM images illustrated that the carbon fibers influenced the densification and microstructure of the ceramics. Besides, addition of carbon fibers led to increase in dielectric permittivity, also had effects on the dielectric loss and ac conductivity. The dielectric and conductivity properties as a function of carbon fibers volume fraction were explained by the percolation theory.


2013 ◽  
Vol 802 ◽  
pp. 134-138 ◽  
Author(s):  
Worawut Makcharoen

The CaCu3Ti4O12(CCTO) has the advantage for the various applications especially for capacitive elements in microelectronic devices over the ferroelectric materials including BaTiO3. CCTO is a ceramic compound with a high dielectric constant but it has a high loss tangent at room temperature. In this work, the Influences of PtO2doping on the dielectric properties of CaCu3Ti4O12(CCTO) ceramics were investigate. The ceramics CCTO and PtO2doping CCTO were studied by X- ray diffraction, scanning electron microscopy. The dielectric properties have been measured as a function of temperature and frequency range 0.1 - 500 kHz. The XRD shows the CCTO structure does not changes after doping with platinum. The results show that PtO2doped can reduce the mean grain sizes of CCTO, but the dielectric constant still remained a height. The samples of 2.0 mol% Pt-doped have exhibited high dielectric constant of about 22,000 and the loss tangent about 0.7 at room temperature and frequency at 10 kHz. The reduced of the loss tangent could be interpreted with the internal barrier layer capacitor model (IBLC)


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