Investigation of the Degradation Mechanism of Platinum-Rhodium Catalytic Wires during Oxidation of Ammonia Process

2015 ◽  
Vol 227 ◽  
pp. 229-232 ◽  
Author(s):  
Jarosław Pura ◽  
Piotr Kwaśniak ◽  
Piotr Wiecinski ◽  
Halina Garbacz ◽  
Joanna Zdunek ◽  
...  

In our investigation we focused on effects of the degradation of Pt-Rh gauzes from three different industrial catalytic systems. The aim of the study was to compare the degree and the mechanism of degradation under different conditions (pressure, temperature, gas flow direction). The investigation was performed on about 80μm diameter wires after long (6 months) exposition to chemically aggressive environment. Microscope observations and microtomography analysis showed that all wires surfaces were strongly developed by etching and deposition processes occurring under extreme conditions. Each wire differed in rate of degradation and morphology of the characteristic cauliflower-shape growths. Also differences in elements distribution on both, surface and cross sections, were observed. Obtained results can be basis of further investigation on improvement of endurance of PtRh alloys in high temperature chemical application.

2019 ◽  
Vol 25 (4) ◽  
pp. 3-8
Author(s):  
Grzegorz Grzesiak ◽  
Jan Walkowicz ◽  
Karol Szafirowicz ◽  
Dawid Jakrzewski

The aim of this work is to verify the possibility of designing an active screen plasma nitriding (ASPN) process with a controlled gas flow direction in order to implement multifunctional hybrid devices. The specimens have been subjected to nitriding processes under the established process conditions in which two different gas flow directions have been used. In the first configuration, the gas has been supplied at the top part of the chamber and pumped out from the bottom part of the chamber. In the second configuration, the gas has been supplied at the bottom part of the chamber and evacuated from its top part. The distribution of hardness and thick-ness of the nitrided layers has been evaluated on the prepared metallographic cross-sections. The results of material tests have been compared with the results of simulation tests showing the circulation of the atmosphere inside the process chamber. The presented research results show that using both gas flow directions and the unconventional shape of the process chamber it is possible to carry out efficient nitriding processes. However, further research is necessary to obtain a homogenous layer in the entire chamber space.


Author(s):  
Nikolay Ivanov ◽  
Vladimir V. Ris ◽  
Nikolay A. Tschur ◽  
Marina Zasimova
Keyword(s):  
Gas Flow ◽  

2021 ◽  
Vol 11 (4) ◽  
pp. 1486
Author(s):  
Cuiping Kuang ◽  
Yuhua Zheng ◽  
Jie Gu ◽  
Qingping Zou ◽  
Xuejian Han

Groins are one of the popular manmade structures to modify the hydraulic flow and sediment response in river training. The spacing between groins is a critical consideration to balance the channel-depth and the cost of construction, which is generally determined by the backflow formed downstream from groins. A series of experiments were conducted using Particle Image Velocimetry (PIV) to observe the influence of groin spacing on the backflow pattern of two bilateral groins. The spacing between groins has significant effect on the behavior of the large-scale recirculation cell behind groins. The magnitude of the wake flow induced by a groin was similar to that induced by another groin on the other side, but the flow direction is opposite. The spanwise velocity near the groin tip dictates the recirculation zone width behind the groins due to the strong links between the spanwise velocity and the contraction ratio of channel cross-sections between groins. Based on previous studies and present experimental results, quantitative empirical relationships are proposed to calculate the recirculation zone length behind groins alternately placed at different spacing along riverbanks. This study provides better understanding and a robust formula to assess the backflow extent of alternate groins and identify the optimum groins array configuration.


1986 ◽  
Vol 251 (6) ◽  
pp. H1324-H1332 ◽  
Author(s):  
A. R. Pries ◽  
K. Ley ◽  
P. Gaehtgens

Microvessel hematocrits and diameters were determined in each vessel segment between bifurcations of three complete microvascular networks in rat mesentery. Classification of the segments as arteriolar, venular, or arteriovenular (av) was based on flow direction at branch points. Photographic and videomicroscopic mapping was used to obtain quantitative information on the architecture and topology of the networks. This topological information allowed the analysis of hematocrit distribution within a series of consecutive-flow cross sections, each of which carried the total flow through the network. The observed reduction of mean hematocrit in the more peripheral cross sections is explained by the presence of a “vessel” and a “network” Fahraeus effect. The vessel Fahraeus effect results from velocity difference between red cells and blood within the individual vessel segments due to the existing velocity and cell concentration profiles. The network Fahraeus effect is based on the velocity difference of red cells and blood caused by velocity and hematocrit heterogeneity between the vessels constituting any of the complete-flow cross sections. The network Fahraeus effect is found to account for approximately 20% of the total hematocrit reduction and increases toward the most distal cross sections.


2017 ◽  
Author(s):  
Yuichi S. Hayakawa ◽  
Hidetsugu Yoshida ◽  
Hiroyuki Obanawa ◽  
Ryutaro Naruhashi ◽  
Koji Okumura ◽  
...  

Abstract. Debris avalanche caused by the sector collapse of a volcanic mountain often forms characteristic depositional landforms including hummocks. Not only sedimentological but also geomorphological analyses of debris avalanche deposits (DAD) are crucial to clarify the size, mechanisms, and processes of the debris avalanche. We investigate the morphology of hummocks newly identified in the DAD at the north-eastern flank of Mt. Erciyes in Kayseri, central Turkey, likely formed in the late Pleistocene. Using a remotely piloted aircraft system (RPAS) and the structure-from-motion multi-view stereo photogrammetry (SfM), we obtained high-definition digital elevation model (DEM) and orthorectified image of the DAD surface with hummocks. Detailed geometric features of the hummocks are investigated using the RPAS-derived high-definition DEM. The source volume of the DAD was also estimated by reconstructing the original shape of the mountain body using a lower-resolution satellite-based DEM. For this, topographic cross sections are examined based on the slopes around the scar that are regarded as the remnant topography preserved since the sector collapse. The spatial distribution of hummocks shows an unusual pattern regarding the distance-size relationships, i.e., anomalously concentrated in a certain distance from the source. The hummocks are found to be aligned toward the flow direction of the debris avalanche, suggesting the extensional regime of the debris avalanche. These facts indicate that this debris avalanche did not follow the typical flow type of debris avalanches observed in the other cases. Instead, the topographic constraints by former caldera wall and fault-induced lineaments could have strongly affected the flow course and pattern in this particular case: The pre-existing caldera wall topography could have acted as the topographic barriers for the debris avalanche to force the initial flow to turn northward, and the flow regime to be once compressional followed by extensional at the narrow and steepened outlet valley. Also, the estimated volume of the DAD 12–15 × 108 m3 gives its mean thickness of 60–75 m, which is much deeper than the reported cases of other DADs. This suggests that the debris avalanche could have flown down to the far downstream areas from the presently-observed limit of the DAD extent. Assessments of the DAD including the results of this study can provide further insights into the risk and mitigation of potential disasters in the study area.


2012 ◽  
Vol 15 (1) ◽  
pp. 19 ◽  
Author(s):  
El-Shazly M. Duraia ◽  
G.W. Beall ◽  
Zulkhair A. Mansurov ◽  
Tatyana A. Shabanova ◽  
Ahmed E. Hannora

Elongated wire-like Zinc oxide, nanocombs and nanocrystals have been successfully synthesized on the silicon substrate from the metallic zinc as a starting material. The annealing temperature was as low as 450 ºC in argon atmosphere mixed with about 3% oxygen. Structural analysis using the X-ray Diffraction (XRD) and Transmission Electron Microscopy (TEM) showed that the existence of two phases; nanowires and crystalline form. Moreover some nanoparticles aggregates were noticed to be attached in the bulk to the sides of the ZnO nanocrystals and sometimes these aggregate attached to the Zinc oxide hexagonal crystal and grow to form nanowire at different angles. Scanning electron microscopy (SEM) investigations for the zinc oxide nanostructure on the silicon substrate showed the formation of the nanocrystals in the gas flow direction and at the low energy sites over the silicon substrate. Photoluminescence (PL) measurements, performed at the room temperature, showed the existence of two basic emissions: narrow ultraviolet (UV) emission at 398 nm which attributed to the near band edge emission of the wide band gap and a very wide, more intensive, green emission at 471 nm corresponds to the crystal defects such as vacancies, interstitial sites in ZnO.


Author(s):  
Hong Xu ◽  
Shuqin Feng ◽  
Liehui Xiao ◽  
Yazhen Hao ◽  
Xiaoze Du

To achieve the near zero emission of wastewater in the flue gas desulfurization (FGD) system in coal-fired power plant and better utilize the exhaust heat from flue gas, a feasible technology of spraying FGD wastewater in the flue duct for evaporation is discussed in the present study. A full-scale influencing factor investigation on the wastewater droplet evaporation performance is established under the Eulerian-Lagrangian model numerically. The dominant factors, including the characters of wastewater droplets, flue gas and the spray nozzles were analyzed under different conditions, respectively. Considering the multiple factors and conditions in the process, a Least-Square support vector machine (LSSVM) model is introduced to predict the evaporation rate based on the numerical results. Conclusions are made that the flue gas temperature and droplet diameter are of great importance in the evaporation process. The spray direction of droplet parallel with the flue gas flow direction is profitable for the dispersion of droplet, resulting the maximal evaporation rate. A double-nozzle arrangement optimized with relatively small flow rate is recommended. The LSSVM model can accurately predict the evaporation rate using the numerical results with different conditions.


2012 ◽  
Vol 226-228 ◽  
pp. 1829-1834 ◽  
Author(s):  
Jing Yuan Tang ◽  
Jian Ming Chen ◽  
Hong Bin Ma ◽  
Guang Yu Tang

The flow field characteristics in U-typed bend has been extensively studied for transit time ultrasonic flowmeters designing, but for the flowmeter with three-Z-shaped round pipe there is still lack of corresponding research. This paper presents a computational fluid dynamics (CFD) approach for modeling of the three-Z-shaped ultrasonic flowmeter and studying of internal fluid field characteristics based on Reynolds stress model (RSM). The fluid velocity profile in the three ultrasound path is obtained using CFD and secondary flow in cross section also is analyzed. The simulation results show that the internal flow fields in the flowmeter are not fully developed turbulence with asymmetric axial velocity distribution and dramatic changes along the flow direction, and there are obvious secondary cross flows on theirs cross-sections. The CFD simulations provide useful insights into the flow field associated with ultrasonic flowmeters design.


ACS Nano ◽  
2009 ◽  
Vol 3 (12) ◽  
pp. 4164-4170 ◽  
Author(s):  
Satoshi Yasuda ◽  
Don N. Futaba ◽  
Takeo Yamada ◽  
Junichi Satou ◽  
Akiyoshi Shibuya ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document