scholarly journals Transparent Exopolymer Particles (TEP), phytoplankton and picocyanobacteria a littoral-to-pelagic depth-gradient in a large subalpine lake

Author(s):  
Cristiana Callieri ◽  
J. Salvador Hernández-Avilés ◽  
Ester M. Eckert ◽  
Michela Rogora ◽  
Gabriele Tartari ◽  
...  

Transparent Exopolymer Particles (TEP) play an important role in the organic carbon cycle of many aquatic systems but the production and distribution of TEP have been studied mainly in the marine environment, neglecting the large oligotrophic lakes. We selected Lake Maggiore, one of the most important freshwater reserve in Northern Italy, to study the horizontal and vertical distribution of TEP and of its possible drivers. Samplings along a transect in the Borromeo basin were performed in May, July and September 2019. Total Organic Carbon (TOC), TEP, chlorophyll-a (Chl) of different algal groups, picocyanobacteria, bacteria and eukaryotes counting, were measured at six stations and five depths. Our study showed that TEP exhibited a clear vertical heterogeneity from surface to the bottom related to the autotrophic microorganisms that are the main source of TEP and are prevalent in the euphotic zone of the lake. On the other hand, TEP was fairly evenly distributed along the horizontal transect from littoral to pelagic zone, although patches were present in spring, when TEP concentrations were low. In contrast to TEP, TOC and to a lesser extent Chl and bacteria showed horizontal heterogeneity, in some months. In Lake Maggiore TEP indeed was an important fraction of Total Organic Carbon (TOC), making up to 54% of TOC (in carbon units: 910 µg C L-1) and it was significantly correlated with Chl. The highest TEP concentration (1.44 mg GX eq L-1) was measured in September 2019, in coincidence with an episode of superficial foam appearance. Considering the biomass as Chl concentrations, the algal group mostly related to TEP was that of brown algae, particularly diatoms; but considering the numbers, the picocyanobacteria and bacteria were more significantly correlated to TEP. The presence of pennate diatoms in May and July, with their TEP-related chlorophyll, did not produce TEP in as high concentration as that observed in September in the presence of centric diatoms and of very high numbers of picocyanobacteria and bacteria.

2021 ◽  
Vol 325 ◽  
pp. 08013
Author(s):  
Mawar Towan Lestari Ramli ◽  
Hendra Amijaya ◽  
Akmaluddin

Research on the Late Miocene of Pandua Formation shale in Andowia area, Southeast Sulawesi is fundamental because it is considered to have the potential as a source rock in Manui Basin. This study aimed to determine the lithofacies and its potential as petroleum source rock using megascopic, petrographic, and total organic carbon analyses in Pandua Formation shale. Based on the megascopic and petrographic analysis of outcrops, the shale can be subdivided into 11 lithofacies consists of clayey shale, massive claystone, clastic detritus-rich claystone, massive mudstone, mica-rich mudstone, iron oxide-rich mudstone, low-angle laminated mudstone, massive siltstone, carbon-rich massive siltstone, laminated siltstone, and carbon-rich laminated siltstone. The results of the analysis of 19 samples of shale showed that the total organic carbon (TOC) content was classified as poor to excellent (<0.5%- >4%). The lithofacies with a high concentration of TOC are carbon-rich massive siltstone and carbon-rich laminated siltstone. Both lithofacies were categorized as potentially excellent source rock which the TOC value content is 5.78% and 5.74%.The result implies the better understanding of the depositional environment and hydrocarbon accumulation potential of the Manui basin for future exploration.


2017 ◽  
Vol 13 (3) ◽  
pp. 167
Author(s):  
Husnah Husnah ◽  
Eko Prianto ◽  
Siti Nurul Aida

Sungai Musi merupakan sungai besar mengaliri wilayah Sumatera Selatan, Lampung, dan Bengkulu , dan bervariasi dalam pemanfaatannya, khususnya di bagian hilir, didominasi oleh kegiatan industri yang membuang limbahnya ke Sungai Musi. Kajian pengaruh industri terhadap Sungai Musi telah dilakukan, namun sebatas analisis fisik dan kimia lingkungan dan belum mengarah kepada pengaruhnya terhadap organisme air. Organisme air adalah indikator penting perubahan lingkungan karena organisme khususnya organisme dasar (benthos) menyimpan sejarah proses-proses terjadi di perairan. Riset yang bertujuan untuk mengetahui kualitas perairan Sungai Musi bagian hilir ditinjau dari karakteristik fisik dan kimia dan struktur makrozoobenthos telah dilakukan di Sungai Musi, Sumatera Selatan pada bulan Mei dan September 2006. Riset dilakukan bersifat survei lapangan. Delapan stasiun ditentukan di Sungai Musi bagian hilir berdasarkan pada perbedaan mikrohabitat. Stasiun riset masing masing antara lain Sejagung, Pulokerto, Jembatan Ampera, Sebokor, Pulau Burung, Upang, Pulau Payung, dan Sungsang. Pada masing masing stasiun, dilakukan pengambilan contoh air untuk parameter fisika, kimia, dan makrobenthos. Contoh air diambil dari atas perahu motor pada kedalaman 1,0 m dari permukaan air dengan menggunakan kemmerer water sampler. Sebagian contoh dianalisis di lapangan (suhu, pH, dan oksigen terlarut) dan sebagian lagi yaitu jumlah padatan tersesuspensi (total suspended solids), jumlah padatan terlarut (total dissolved solids), jumlah karbon organik (total organic carbon), organik karbon terlarut (dissolved organic carbon), konsumsi oksigen biologi (biochemical oxygen demand), nitrat, dan fosfat dianalisis di laboratorium kimia. Contoh makrozoobenthos diambil pada 10 titik di masing-masing stasiun, dengan menggunakan ekman dredge dengan bukaan mulut 400 cm2. Contoh makrobenthos pada masingmasing titik tersebut disortir dengan menggunakan saringan dan kemudian digabungkan (dikomposit) dan diawetkan dengan formalin 10%. Data kualitas air dianalisis dengan principle component analysis dan kelimpahan makrozoobenthos dianalisis dengan analisis cluster. Kualitas perairan di Sungai Musi bagian hilir dikelompokkan atas 2 yang mengalami tekanan berat yaitu dari Sejagung sampai dengan Pulau Burung dan tekanan ringan yaitu dari Upang sampai dengan Muara Sungai Musi. Kelompok pertama dicirikan oleh nilai konsentrasi total dissolved solids, total organic carbon, dan dissolved organic carbon yang tinggi diiringi dengan kelimpahan makrozoobenhthos yang rendah serta didominasi oleh Tubifex sp. Kelompok ke-2 dari Upang sampai dengan Muara Sungai Musi dicirikan oleh nilai konsentrasi total suspended solids yang tinggi, dengan kelimpahan makrozoobenthos yang tinggi dan didominasi oleh Gammarus. Musi River is a large river , crossing three provinces, South Sumatra, Lampung and Bengkulu, and differeing in types and levels of its resources ultization, particularly at the down stream of Musi River, mostly dominated by industries activities producing a waste which flows to the river. Several studies on the effect of industries on the Musi River have been conducted , however , limmieted on physical dan chemical aspects of the water, not yet to evaluate its effect on aquatic organism. Aquatic organism such macrozoobenthos is important indicator of environmental changes since this organism records the history of processes occurred in the water. Study to assess water quality of the down stream Musi River based on physical, chemical water characteristics and macrozoobenthos community structure was conducted at may and september 2006 in Musi River located in South Sumatera Province of Indonesia. The study used inventory field survey. Eight sampling sites; Sejagung, Pulokerto, Jembatan Ampera, Sebokor, Pulau Burung, Upang, Pulau Payung, and Sungsang were selected based on the microhabitat difference. water sampling for physical and chemical parameters and sediment, and  macrozoobenthos were carried in each sampling site. Water sample was collected at a depth of 1.0 m from the water surface by using kemmerer water sampler. Some water quality parameters such as temperature, pH, and dissolved oxygen) were directly analyzed in the field, while the others such as total suspended solids, total dissolved solids, total organic carbon, dissolved organic carbon, biochemical oxygen demand, nitrate, and phosphate were analyzed in laboratory. Macrozoobenthos was collected at ten sampling points in each sampling sites using Ekman Dredge of 400 cm2 mouth opening. Macrozoobenthos from ten sampling points was composited, sorted and preserved with formalin 10%. Water quality parameters were analyzed with principle component analysis while macrozoobenthos abundance was analyzed with cluster. Results revealed that water quality at the down stream Musi River was classified into two groups. The first group was the heavy degraded sites from Sejagung to Pulau Burung, characterized by having high concentration of total dissolved solids, total organic carbon, and dissolved organic carbon, low abundance of macrozoobenthos with Tubifex sp. as the dominant species. The second group was light degraded sites from Upang to the mouth of Musi River, characterized by high concentration of total suspended solids and high macrozoobenthos abundance with Gammarus sp. as the dominant species.


2018 ◽  
Vol 20 (2) ◽  
pp. 181-187 ◽  

Polycyclic aromatic hydrocarbons (PAHs) are a group of quotidian organic compounds having between two and six condensed aromatic rings braced in angular, cluster or linear forms possessing hydrogen and carbon atoms only. This work aims to evaluate the physicochemical characteristics of soil as determinants of PAHs distribution and fate. The study area is situated on the Benin River beneath the convergence of Jamieson River and River Ethiope. The weather and climatic conditions of the area are of the Niger Delta region. Sixteen priority PAHs were determined in ten sample stations. Upon extraction, purification and quantification of PAHs was done using GC-FID. According to the methods of Walkey-Blacks, Black and Bouyoucus, soil total organic carbon, pH and texture were analyzed respectively. Four replicate samples were chosen to create a composite and used as quality control. Kruskal-Wallis test with tied rank was used to determine a causative correlation between soil physicochemical parameters and ∑PAHs. Results showed that the study area is contaminated with high concentration of PAHs ranging from 60.76 – 271.11 239 µg.g-1 with higher percentages of HPAHs i.e. PAHs with LogKow > 4.0. It is observed that observed alkaline pH favour significant fungal, asperigellus and microbial degradation of PAHs, and hinder photo-catalytic degradation. However, acidification with elemental sulfur, ferrous sulfate and aluminum sulfate could enhance photo-catalytic degradation. Results of TOC and soil structure do not favour significant degradation of HPAHs. Kruskal-Wallis tied rank test revealed that there was a positive significant difference between pH, TOC, percentage clay, and silt fractions with ∑PAHs concentrations since calculated K is greater than critical K0.05, P<0.05 except percentage of sand fractions and ∑PAHs with P>0.05. A substantial percentage of these PAHs have no anthropic origin and are characterized as having high lipo-affinity, semi-volatility and resistance to biotic and/or abiotic transformations. Due to edaphic factors the observed HPAHs may partially degrade with the consequent formation of highly toxic by-products. Therefore, oral or dermal ingestion of soil in the study area may cause significant exposure of the human population to these PAHs. Risk assessment and probable toxicity effects on animal diversity should be carried out in soil samples of the study area.


2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Markus Heryanto Langsa

<p>Penelitian ini bertujuan untuk menentukan senyawa organik khususnya organic karbon terlarut (DOC) dari dua spesies daun tumbuhan (<em>wandoo eucalyptus </em>and <em>pinus radiate, conifer</em>) yang larut dalam air selama periode 5 bulan leaching eksperimen. Kecepatan melarutnya senyawa organic ditentukan secara kuantitatif dan kualitatif menggunakan kombinasi dari beberapa teknik diantaranya Total Organic Carbon (TOC) analyser, Ultraviolet-Visible (UV-VIS) spektrokopi dan pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS).</p><p>Hasil analisis DOC dan UV menunjukkan peningkatan yang tajam dari kelarutan senyawa organic di awal periode pengamatan yang selanjutnya berkurang seiring dengan waktu secara eksponensial. Jumlah relatif senyawa organic yang terlarut tergantung pada luas permukaan, aktifitas mikrobiologi dan jenis sampel tumbuhan (segar atau kering) yang digunakan. Fluktuasi profil DOC dan UV<sub>254</sub> disebabkan oleh aktifitas mikrobiologi. Diperoleh bahwa daun kering lebih mudah terdegradasi menghasilkan senyawa organic dalam air dibandingkan dengan daun segar. Hasil pyrolysis secara umum menunjukkan bahwa senyawa hidrokarbon aromatic dan fenol (dan turunannya) lebih banyak ditemukan pada residue sampel setelah proses leaching kemungkinan karena adanya senyawa lignin atau aktifitas humifikasi mikrobiologi membuktikan bahwa senyawa-senyawa tersebut merupakan komponen penting dalam proses karakterisasi DOC.</p>


Geology ◽  
2020 ◽  
Author(s):  
C.R. Woltz ◽  
S.M. Porter ◽  
H. Agić ◽  
C.M. Dehler ◽  
C.K. Junium ◽  
...  

Much of our understanding of early eukaryote diversity and paleoecology comes from the record of organic-walled microfossils in shale, yet the conditions controlling their preservation are not well understood. It has been suggested that high concentrations of total organic carbon (TOC) inhibit the preservation of organic fossils in shale, and although this idea is supported anecdotally, it has never been tested. Here we compared the presence, preservational quality, and assemblage diversity of organic-walled microfossils to TOC concentrations of 346 shale samples that span the late Paleoproterozoic to middle Neoproterozoic in age. We found that fossil-bearing samples have significantly lower median TOC values (0.32 wt%, n = 189) than those containing no fossils (0.72 wt%, n = 157). Preservational quality, measured by the loss of surface pattern, density of pitting, and deterioration of wall margin, decreases as TOC increases. Species richness negatively correlates with TOC within the ca. 750 Ma Chuar Group (Arizona, USA), but no relationship is observed in other units. These results support the hypothesis that high TOC content either decreases the preservational quality or inhibits the preservation of organic-walled microfossils altogether. However, it is also possible that other causal factors, including sedimentation rate and microbial degradation, account for the correlation between fossil preservation and TOC. We expect that as TOC varies in space and time, so too does the probability of finding well-preserved fossils. A compilation of 13,940 TOC values spanning Earth history suggests significantly higher median TOC levels in Mesoproterozoic versus Neoproterozoic shale, potentially biasing the interpreted pattern of increased eukaryotic diversity in the Tonian.


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