Some solubility studies in the system thorium carbonate-sodium carbonate-sodium bicarbonate-sodium sulphate-water

1958 ◽  
Author(s):  
J C Ingles ◽  
F J Kelly
Keyword(s):  
Sodium Bicarbonate ◽  
Sodium Carbonate ◽  
Sodium Sulphate ◽  
Solubility Studies ◽  
Sulphate Water

Sodium salt scaling in black liquor evaporators and the effects of the addition of tall oil brine

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Erik Karlsson ◽  
Anders Åkesjö
Keyword(s):  
Sodium Carbonate ◽  
Sodium Salt ◽  
Black Liquor ◽  
Sodium Sulphate ◽  
Salt Solutions ◽  
Tall Oil ◽  
Sulphate Content ◽  
Inhibition Effect ◽  
Salt Scaling ◽  
Primary Nucleation

AbstractSodium salt scaling, i. e. the formation of doubles salts comprised of sodium, carbonate and sulphate on the heat transfer surfaces, is a common problem that occurs during black liquor evaporation. In this study, experimental results are presented that provide new insights into the formation and composition of such scales and how they are influenced by the addition of tall oil brine. It was found that increased content of sodium carbonate and sodium sulphate in the black liquor increased scaling, while the ratio between carbonate and sulphate had a lesser influence than reported in other studies. Black liquor created loose clay-like scales comprised of aggregated crystals and black liquor, whereas salt solutions created hard mineral-like scales. The scales formed by both the black liquor and the salt solution showed a tendency to fall off during formation after primary nucleation. It was also found that both tall oil soap and alkalized tall oil brine could inhibit the formation of scales. The inhibition effect is stronger if adding the soap or brine just before scaling starts, but also depends on the amount added, the sodium carbonate and sodium sulphate content in the liquor as well as other factors.

scholarly journals Defining features in the kinetics of sodium carbonate-bicarbonate solution carbonization and the quality of the resulting sodium bicarbonate crystals

2021 ◽  
Vol 4 (10(112)) ◽  
pp. 38-44
Author(s):  
Mykola Porokhnia ◽  
Musii Tseitlin ◽  
Svitlana Bukhkalo ◽  
Vladimir Panasenko ◽  
Tetiana Novozhylova
Keyword(s):  
Carbon Dioxide ◽  
Sodium Bicarbonate ◽  
Sodium Carbonate ◽  
Diffusion Resistance ◽  
Crystal Formation ◽  
Gas Velocity ◽  
Laboratory Equipment ◽  
Gas Consumption ◽  
Kinetics Of

This paper reports a study into the influence of temperature and gas consumption on the carbonization kinetics (saturation with carbon dioxide) of sodium carbonate-bicarbonate solution. The study also examined the quality and speed of crystal formation in this process. This research is predetermined by the environmental problems faced by modern enterprises that produce purified sodium bicarbonate – an insufficient degree of carbonization and, as a result, excessive air pollution with carbon dioxide, which did not participate in the reaction during the process. This study addresses these particular issues. As a result of using specialized laboratory equipment, it was found that an increase in the absorbent temperature from 79 to 85 °C leads to a decrease in the maximum degree of carbonization of the solution from 64 to 59 %. In contrast, the quality of the resulting sodium bicarbonate crystals improves but only in the range from 79 to 82 °C. With a further increase in temperature, the quality stabilizes. It is shown that the carbonization rate increases with increasing specific consumption of the absorbent (carbon dioxide) and is characterized by a negative correlation with the value of oversaturation of the absorbent in terms of NaНCO3. The quality of sodium bicarbonate crystals decreases with increasing gas velocity. Thus, it was reasonable to assume that the established dependence of the kinetics of carbonization of Na2CO3 and NaНCO3 solution on the gas velocity in the apparatus is explained by the inhibition of СО2 absorption, which is caused by the diffusion resistance of sodium bicarbonate crystallization. To improve the quality of crystals and the productivity of carbonization by reducing the supersaturation in terms of NaНCO3, it is recommended to introduce a seed crystal in the zone of binding of crystals in the carbonization columns.

Alkali investigations in the Sudan

1925 ◽  
Vol 15 (4) ◽  
pp. 407-419 ◽  
Author(s):  
A. F. Joseph
Keyword(s):  
Sodium Carbonate ◽  
Clay Soil ◽  
Salt Content ◽  
Sodium Sulphate ◽  
Water Soluble ◽  
Soluble Salts ◽  
Nile Water ◽  
Heavy Clay ◽  
Alkali Salts ◽  
Very High

(1) The cotton growing area in the Gezira consists of a heavy clay soil, the proportion of clay being about 50–60 per cent. in the upper layers with a maximum at about the 4th foot.(2) The water soluble salts amount to about 0·2 per cent. The proportion is highest at about the 3rd to 5th foot. The alkalinity (pH) is highest at the 2nd foot.(3) In the first 2 feet, the salts consist mainly of sodium carbonate and the third and fourth of sodium sulphate.(4) The irrigation (Blue Nile) water is of excellent quality as judged by its natural chemical composition. The concentrated water, however, contains a very high proportion of alkali salts. It is estimated that a season of normal irrigation would cause an increase of 0·01 per cent. in the alkali content of the first 4 feet of soil.(5) The sodium salts can readily act on the clay and the sodium clay so formed hydrolyses with the formation of sodium carbonate.(6) Samples taken at the same time from good and bad plots in the same area show a strong correlation between salt content and cropyielding power. There is also a correlation between pH and fertility.(7) In the same season and in the same area, virgin (i.e. unirrigated) plots give a higher yield than those which have been previously under the same system of cultivation.

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