scholarly journals Crystal-melt ± fluid equilibria versus late-stage fluid - rock interaction in granitoid rocks of the South Mountian Batholith, Nova Scotia: whole rock geochemistry and oxygen isotope evidence

10.4138/1643 ◽  
1988 ◽  
Vol 24 (1) ◽  
Author(s):  
Daniel J. Kontak ◽  
David F. Strong ◽  
Robert Kerrich
1980 ◽  
Vol 17 (1) ◽  
pp. 132-141 ◽  
Author(s):  
F. J. Longstaffe ◽  
T. E. Smith ◽  
K. Muehlenbachs

The oxygen isotope ratios for 127 rocks and coexisting minerals from Paleozoic granitoids and clastic metasedimentary rocks of southwestern Nova Scotia have been measured. The whole-rock δ18O values for samples of the South Mountain batholith range from 10.1–12.0‰.But discrete granitoid plutons, located to the south of the South Mountain batholith, have lower δ18O values (7.8–10.4‰). Coexisting minerals from the Nova Scotia granitoids are near isotopic equilibrium, indicating that the whole-rock δ18O values primarily reflect the δ18O of the magma, rather than secondary alteration processes. The Meguma Group clastic metasedimentary rocks that host the Nova Scotia granitoids range in δ18O from 10.1–12.9‰. These clastic metasedimentary rocks show no systematic geographic variation in δ18O. The greenschist facies Meguma Group rocks that host the South Mountain batholith have similar δ18O values to the amphibolite facies equivalents located about the southern discrete plutons. Large scale isotopic exchange between the Meguma Group and the South Mountain batholith, or the southern plutons, is not evident.The relatively high δ18O values of the peraluminous South Mountain batholith (10.1–12.0‰) indicate that it formed by anatexis of 18O-rich clastic metasedimentary rocks. The southern plutons were also derived by partial melting of clastic metasedimentary rocks, but their lower δ18O values reflect exchange of the source material with a low 18O reservoir (mafic magmas?) prior to, or during anatexis.The sheared Brenton pluton is much lower in δ18O (5.0‰) than any of the other rocks, probably because of exchange with low 18O fluids during shearing.


2011 ◽  
Vol 49 (2) ◽  
pp. 417-439 ◽  
Author(s):  
J. S. Lackey ◽  
S. Erdmann ◽  
J. S. Hark ◽  
R. M. Nowak ◽  
K. E. Murray ◽  
...  

1997 ◽  
Vol 109 (10) ◽  
pp. 1279-1293 ◽  
Author(s):  
Keith Benn ◽  
Richard J. Horne ◽  
Daniel J. Kontak ◽  
Geoffrey S. Pignotta ◽  
Neil G. Evans

2021 ◽  
Vol 176 (7) ◽  
Author(s):  
Thomas Bovay ◽  
Daniela Rubatto ◽  
Pierre Lanari

AbstractDehydration reactions in the subducting slab liberate fluids causing major changes in rock density, volume and permeability. Although it is well known that the fluids can migrate and interact with the surrounding rocks, fluid pathways remain challenging to track and the consequences of fluid-rock interaction processes are often overlooked. In this study, we investigate pervasive fluid-rock interaction in a sequence of schists and mafic felses exposed in the Theodul Glacier Unit (TGU), Western Alps. This unit is embedded within metaophiolites of the Zermatt-Saas Zone and reached eclogite-facies conditions during Alpine convergence. Chemical mapping and in situ oxygen isotope analyses of garnet from the schists reveal a sharp chemical zoning between a xenomorphic core and a euhedral rim, associated to a drop of ~ 8‰ in δ18O. Thermodynamic and δ18O models show that the large amount of low δ18O H2O required to change the reactive bulk δ18O composition cannot be produced by dehydration of the mafic fels from the TGU only, and requires a large contribution of the surrounding serpentinites. The calculated time-integrated fluid flux across the TGU rocks is 1.1 × 105 cm3/cm2, which is above the open-system behaviour threshold and argues for pervasive fluid flow at kilometre-scale under high-pressure conditions. The transient rock volume variations caused by lawsonite breakdown is identified as a possible trigger for the pervasive fluid influx. The calculated schist permeability at eclogite-facies conditions (~ 2 × 10–20 m2) is comparable to the permeability determined experimentally for blueschist and serpentinites.


1996 ◽  
Vol 46 (1) ◽  
pp. 19-26 ◽  
Author(s):  
B. Brandon Curry ◽  
Milan J. Pavich

A10Be inventory and14C ages of material from a core from northernmost Illinois support previous interpretations that this area was ice free from ca. 155,000 to 25,000 yr ago. During much of this period, from about 155,000 to 55,000 yr ago, 10Be accumulated in the argillic horizon of the Sangamon Geosol. Wisconsinan loess, containing inherited 10Be, was deposited above the Sangamon Geosol from ca. 55,000 to 25,000 yr ago and was subsequently buried by late Wisconsinan till deposited by the Lake Michigan Lobe of the Laurentide Ice Sheet. The Sangamonian interglacial stage has been correlated narrowly to marine oxygen isotope substage 5e; our data indicate instead that the Sangamon Geosol developed during late stage 6, all of stages 5 and 4, and early stage 3.


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