A Multiscale Model for Compressive Strength Evolution of Blended Cement Pastes

Author(s):  
V. Šmilauer ◽  
M. Hlobil ◽  
G. Chanvillard
Clay Minerals ◽  
2015 ◽  
Vol 50 (1) ◽  
pp. 133-152 ◽  
Author(s):  
M.H. Cornejo ◽  
J. Elsen ◽  
C. Paredes ◽  
H. Baykara

AbstractThis contribution is the second part of an in-depth study on the hydration and strength evolution of blended cement pastes at a water to binder (W/B) ratio of 0.3, cured by two different methods. The blended cement pastes showed significant hydration up to 7 days, when almost all of the hydration products had already formed; thereafter, carbonation played an important role up to, and possibly beyond, 91 days. Likewise, the hydration of alite (tricalcium silicate, Ca3SiO5, C3S) proceeded up to 14 days and then started to slow down. However, the hydration of belite (dicalcium silicate, Ca2SiO4, C2S) was affected most strongly, as it nearly ceased, under the air-curing conditions. During hydration, some of the blended cement pastes had a larger calcium hydroxide (CH) content than the unblended (plain) ones. The accelerating effects of the addition of supplementary cementitious materials (SCMs), the air-curing conditions and the low W/B ratio may explain these unusual results. Under these experimental conditions, the water incorporated into hydrates was about 50% of the total amount of water used during full hydration of the cement pastes. The pozzolanic reaction predominated during the early ages, but disappeared as time passed. In contrast, the carbonation reaction increased by consuming ∼45% of the total amount of CH produced after aging for 91 days. Only one blended cement paste reached the compressive strength of the plain cements. The blended cement pastes containing 5% of the zeolitic tuffs, Zeo1 or Zeo2, or 10% of the calcareous siltstone, Limo, developed the greatest compressive strength under the experimental conditions used in this study.


2019 ◽  
Vol 967 ◽  
pp. 205-213
Author(s):  
Faiz U.A. Shaikh ◽  
Anwar Hosan

This paper presents the effect of nanosilica (NS) on compressive strength and microstructure of cement paste containing high volume slag and high volume slag-fly ash blend as partial replacement of ordinary Portland cement (OPC). Results show that high volume slag (HVS) cement paste containing 60% slag exhibited about 4% higher compressive strength than control cement paste, while the HVS cement paste containing 70% slag maintained the similar compressive strength to control cement paste. However, about 9% and 37% reduction in compressive strength in HVS cement pastes is observed due to use of 80% and 90% slag, respectively. The high volume slag-fly ash (HVSFA) cement pastes containing total slag and fly ash content of 60% exhibited about 5%-16% higher compressive strength than control cement paste. However, significant reduction in compressive strength is observed in higher slag-fly ash blends with increasing in fly ash contents. Results also show that the addition of 1-4% NS improves the compressive strength of HVS cement paste containing 70% slag by about 9-24%. However, at higher slag contents of 80% and 90% this improvement is even higher e.g. 11-29% and 17-41%, respectively. The NS addition also improves the compressive strength by about 1-59% and 5-21% in high volume slag-fly ash cement pastes containing 21% fly ash+49%slag and 24% fly ash+56%slag, respectively. The thermogravimetric analysis (TGA) results confirm the reduction of calcium hydroxide (CH) in HVS/HVSFA pastes containing NS indicating the formation of additional calcium silicate hydrate (CSH) gels in the system. By combining slag, fly ash and NS in high volumes e.g. 70-80%, the carbon footprint of cement paste is reduced by 66-76% while maintains the similar compressive strength of control cement paste. Keywords: high volume slag, nanosilica, compressive strength, TGA, high volume slag-fly ash blend, CO2 emission.


Fractals ◽  
2017 ◽  
Vol 25 (04) ◽  
pp. 1740003 ◽  
Author(s):  
S. W. TANG ◽  
R. J. CAI ◽  
Z. HE ◽  
X. H. CAI ◽  
H. Y. SHAO ◽  
...  

This paper presents a preliminary work to evaluate the influence of slag and superplasticizer on the early-age hydration of cement pastes by an innovative non-contact impedance measurement, heat evolution method, compressive strength and setting time tests. Besides, the cumulative pore volume obtained from modulus and phase of impedance in different hydration sections is taken to continuously correlate the cumulative heat releasing of cement pastes via the fractal analysis. Retarded phenomena and mechanism of hydration in cement pastes incorporated with slag and superplasticizer are studied, respectively. It is found that the compressive strength and setting time have a good linear relation with the slag amount in blended cement pastes.


2017 ◽  
Vol 1144 ◽  
pp. 54-58
Author(s):  
Zdeněk Prošek ◽  
Karel Šeps ◽  
Jaroslav Topič

This article was focused on the influence of the micronized waste marble powder on mechanical properties of cement pastes. Resulting blended cement was composed of Portland cement CEM I 42.5 R and micronized marble powder with different percentage amounts (0 wt. %, 5 wt. %, 10 wt. % and 15 wt. %). Testing was carried at prismatic samples of dimension 40 × 40 × 160 mm. The investigated mechanical properties were dynamic modulus of elasticity, dynamic shear modulus, flexural strength and compressive strength for the 28 days old samples. The results obtained from these materials were compared with reference material.


2012 ◽  
Vol 535-537 ◽  
pp. 1735-1738 ◽  
Author(s):  
Yan Li ◽  
Dao Sheng Sun ◽  
Xiu Sheng Wu ◽  
Ai Guo Wang ◽  
Wei Xu ◽  
...  

This paper reports the drying shrinkage and compressive strength results of cement pastes with fly ash and silica fume. In this study, Portland cement (PC) was used as the basic cementitious material. Fly ash (FA) and silica fume (SF) were used as cement replacement materials at levels of 0%, 5%, 10%, and 15% , 40%, 35%, 25%, and 15% by weight of the total cementitious material, respectively. The water/cement (PC + FA + SF) ratios (w/c) was 0.28 by weight. The samples produced from fresh pastes were demoulded after a day; then they were cured at 20 ±1°C with 50 ± 3% relative humidity (RH) until the samples were used for drying shrinkage and compressive strength measurement at various ages. The results show that drying shrinkage and compressive strength increase with increasing SF content, and the optimum composition of blended cement pastes is the cement paste with 30% fly ash and 10% silica fume, which possesses lower drying shrinkage values than that of plain cement paste and higher early age strength than that of blended cement pastes with fly ash. Furthermore, a linear relationship is established between compressive strength and drying shrinkage. By comparing the development of compressive strength and the drying shrinkage deformations, it appears possible to predict the drying shrinkage according to the acquired compressive strength.


2008 ◽  
Vol 14 (4) ◽  
pp. 269-275 ◽  
Author(s):  
Z’hor Guemmadi ◽  
Musa Resheidat ◽  
Hacéne Houari ◽  
Belkacem Toumi

The effect of substitution of Portland cement by limestone up to 40% as well as its fineness on the physico‐mechanical properties of fresh and hardened cement pastes is studied. The binder was prepared by substitution of cement by limestone filler. Fillers were chosen of various particle sizes and with percentages from 5 to 40. Test results revealed that the replacement of Portland cement by the finest filler of limestone slightly decreases the consistency and the setting times (initial and final). The total porosity decreases and accordingly the compressive strength is improved with the content and fines of limestone. Although limestone has a little accelerating effect on the hydration process of Portland cement, but acts only as a filler reducing the porosity due to its compact structure, in which the compressive strength of the hardened cement paste is enhanced. The XRD and DTA analyses of samples cured up to 28 days showed that this amelioration is due to formation of new hydrated compounds. It is concluded that an addition of finely ground limestone filler only up to 15% gives a better strength. Santrauka Tirtos šviežios ir sukietėjusios cementinės tešlos, kurioje iki 40 % cemento pakeista įvairaus smulkumo maltu kalkakmeniu, savybės. Rišiklis buvo paruoštas dalį cemento pakeitus maltu kalkakmenio užpildu. Užpildo dalelės buvo įvairaus dydžio, o jų kiekis buvo keičiamas nuo 5 % iki 40 %. Tyrimai parodė, kad priedas leidžia sumažinti vandens kiekį, reikalingą tos pačios konsistencijos mišiniui gauti, taip pat cemento rišimosi pradžiai ir pabaigai paankstinti. Sumažėja cementinio akmens suminis poringumas ir atitinkamai padidėja stipris gniuždant cementinio akmens, kuriame yra kalkakmenio priedų. Nors kalkakmenio priedas nedaug pagreitina portlandcemenčio hidratacijos procesą, tačiau veikia kaip užpildas, sutankinantis struktūrą, dėl to labai padidėja sukietėjusio cementinio akmens stipris gniuždant. Bandinių, išlaikytų 28 dienas, rentgenostruktūrinė ir diferencinė terminė analizė parodė, kad pagerėjimas yra dėl susidariusių naujadarų. Apibendrinant galima teigti, kad 15 % malto kalkakmenio priedas turi didžiausią įtaką stiprumo rezultatams.


2015 ◽  
Vol 668 ◽  
pp. 181-188 ◽  
Author(s):  
Hanan El Nouhy ◽  
Enas Khattab ◽  
Sayieda Zeedan

The aim of this study is to investigate the effects of phosphogypsum on the properties of both cement pastes and mortars. Normal Portland cement CEM Ι 32,5N, Limestone Blended cement CEM ΙΙ B-L32,5N, and Slag cement CEM ΙΙ A-S32,5N were used. These cements were partially substituted by 0,2,4,6,8,10,and 15% of phosphogypsum. The test program was divided to two stages. In the first stage, tests were conducted according to BSEN 196, namely setting times (initial and final), soundness, and compressive strength (at ages 7 and 28 days). In the second stage, X-ray diffraction (XRD), and scanning electron microscope (SEM) were conducted on selected mixes from first stage. The results show that the three types of cements with the various replacement percentages of phosphogypsum met the limit of initial setting time, as well as, provided soundness of 2 mm. Also, in terms of compressive strength, it was proven, that it is possible to partially replace the three tested types of cements by phosphogypsum by up to 8%and 15% with regard to cement/sand ratio of (1:3) and (1:2) respectively.


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