Expeditious and enhanced sequestration of heavy metal ions from aqueous environment by papaya peel carbon: a green and low cost adsorbent

2021 ◽  
Vol 210 ◽  
pp. 365-376
Author(s):  
Jyoti Mittal ◽  
Rais Ahmad ◽  
Asna Mariyam ◽  
V.K. Gupta ◽  
Alok Mittal
2012 ◽  
Vol 12 (2/3/4) ◽  
pp. 318 ◽  
Author(s):  
Ali Ahmadpour ◽  
Tahereh Rohani Bastami ◽  
Masumeh Tahmasbi ◽  
Mohammad Zabihi

Nanomaterials ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 315 ◽  
Author(s):  
Musa Yahaya Pudza ◽  
Zurina Zainal Abidin ◽  
Suraya Abdul Rashid ◽  
Faizah Md Yasin ◽  
A. S. M. Noor ◽  
...  

The materials and substances required for sustainable water treatment by adsorption technique, are still being researched widely by distinguished classes of researchers. Thus, the need to synthesize substances that can effectively clean up pollutants from the environment cannot be overemphasized. So far, materials in bulk forms that are rich in carbon, such as biochar and varieties of activated carbon have been used for various adsorptive purposes. The use of bulk materials for such purposes are not efficient due to minimal surface areas available for adsorption. This study explores the adsorption task at nano dimension using carbon dots (CDs) from tapioca. The properties of carbon structure and its influence on the adsorptive efficacy of carbon nanoparticles were investigated by energy-dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), high resolution transmission electron microscopy (HrTEM), and atomic force microscopy (AFM). The results implied carbon present in CDs are good adsorbents for effective adsorption of heavy metal ions (lead) with removal efficiency of 80.6% in aqueous environment. The adsorption process as explored by both Langmuir and Freundlich isotherms have proven favorability of the adsorption process. Langmuir form two and three have correlation coefficients R2 at 0.9922 and 0.9912, respectively. The Freundlich isotherm confirms CDs as having defined surface heterogeneity and the exponential distribution of active sites. The adsorption of lead unto CDs obeyed the second order kinetic model with coefficient of determination, R2 of 0.9668 and 0.9996 at an initial lead concentration of 20 mg/L and 100 mg/L, respectively. The findings validated the efficiency of CDs derived from tapioca as an excellent material for further utilization in the environmental fields of wastewater pollution detection and clean up, bio-imaging, and chemical sensing applications.


Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 291 ◽  
Author(s):  
Dongxiao Ouyang ◽  
Yuting Zhuo ◽  
Liang Hu ◽  
Qiang Zeng ◽  
Yuehua Hu ◽  
...  

Tailings generated from mineral processing have attracted worldwide concerns due to creating serious environmental pollution. In this work, porous adsorbents were prepared as a porous block by using silicate tailings, which can adsorb heavy metal ions from the solution and are easy to separate. The synthesized silicate porous material (SPM) was characterized by X-ray diffraction (XRD), Brunner–Emmet–Teller (BET), and scanning electron microscope (SEM). The material presented a surface area of 3.40 m2⸱g−1, a porosity of 54%, and the compressive strength of 0.6 MPa. The maximum adsorption capacities of Pb2+, Cd2+, and Cu2+ by SPM were 44.83 mg·g−1, 35.36 mg·g−1, and 32.26 mg·g−1, respectively. The experimental data were fitted well by the Freundlich and Langmuir adsorption models. The kinetics of the adsorption process were fitted well by the pseudo-first order kinetic equation. These results show that the porous materials prepared with silicate tailings could act as an effective and low-cost adsorbent for the removal of heavy metal ions from wastewater. This study may provide a new thought on the high-value utilization of tailing for alleviating environmental pressure.


2017 ◽  
Vol 20 (1) ◽  
pp. 013-020 ◽  
Author(s):  
Xuhui Ma ◽  
Shipeng Zhao ◽  
Shuping Zhang

Electrochemical sensors can detect the heavy metal ions in seawater quickly, conveniently and accurately with the advantages such as the fast detection speed, the simple operability and the low cost. The ionic liquid [Emim]CH3SO3 showed excellent electrochemical performance and could meet the initial application requirements as electrochemical sensors. The characters of the ionic liquids [Emim]CH3SO3 and [Emim]PF6 which include IR, LC-MS, conductivity, electrochemical window and viscosity were detected. The influ-ence of trace impurity on the conductivity of the ionic liquids was investigated. Results suggested that the conductivity of the ionic liquids increased with the concentration of the added organic solvents. In addition, though the conductivity of the ionic liquids increased with temperature, there is no significant difference in the influence of the same impurity at varying temperatures. Muti Walls Carbon Nanotubes (MWCNTs) are appropriate materials which are commonly used materials for electrochemical sensor applications. The effect of theImidaz-olium-based ionic liquids on the performance of the conductivity of the MWCNTs was studied. It was found that Ionic liquid is an excellent extraction agent for metal ions and its presence in the sensor system improves significantly the detection of heavy metal ions.


2017 ◽  
Vol 5 (7) ◽  
pp. 3434-3446 ◽  
Author(s):  
Mingyue Zhang ◽  
Lihua Song ◽  
Haifeng Jiang ◽  
Shu Li ◽  
Yifei Shao ◽  
...  

In order to achieve the reutilization of waste biomass soybean dregs, a low-cost hydrogel, soybean dregs–poly(acrylic acid) (SESD–PAA) was prepared through a one-step reaction.


RSC Advances ◽  
2021 ◽  
Vol 11 (60) ◽  
pp. 37851-37865
Author(s):  
Zhanghong Wang ◽  
Kun Qin ◽  
Zhikang Wang ◽  
Dekui Shen ◽  
Chunfei Wu

The coked catalysts derived from catalytic reforming of the pyrolysis volatiles of polyethylene, lignin and their mixture were developed as low-cost and high-efficient carbon materials-containing composites to remove heavy metal ions from water.


2019 ◽  
Vol 28 (4) ◽  
pp. 2949-2959 ◽  
Author(s):  
Xin Xu ◽  
Xiaofeng Liu ◽  
Myounghak Oh ◽  
Junboum Park

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