Process Operation Map for Assessment of ideal Configuration and Behaviour

2019 ◽  
pp. 341-346
Author(s):  
T. Steckel
Keyword(s):  
2021 ◽  
Vol 5 (2) ◽  
pp. 20
Author(s):  
Mateus Paiva ◽  
Admilson Vieira ◽  
Helder T. Gomes ◽  
Paulo Brito

In the evaluation of gasification processes, estimating the composition of the fuel gas for different conditions is fundamental to identify the best operating conditions. In this way, modeling and simulation of gasification provide an analysis of the process performance, allowing for resource and time savings in pilot-scale process operation, as it predicts the behavior and analyzes the effects of different variables on the process. Thus, the focus of this work was the modeling and simulation of biomass gasification processes using the UniSim Design chemical process software, in order to satisfactorily reproduce the operation behavior of a downdraft gasifier. The study was performed for two residual biomasses (forest and agricultural) in order to predict the produced syngas composition. The reactors simulated gasification by minimizing the free energy of Gibbs. The main operating parameters considered were the equivalence ratio (ER), steam to biomass ratio (SBR), and gasification temperature (independent variables). In the simulations, a sensitivity analysis was carried out, where the effects of these parameters on the composition of syngas, flow of syngas, and heating value (dependent variables) were studied, in order to maximize these three variables in the process with the choice of the best parameters of operation. The model is able to predict the performance of the gasifier and it is qualified to analyze the behavior of the independent parameters in the gasification results. With a temperature between 850 and 950 °C, SBR up to 0.2, and ER between 0.3 and 0.5, the best operating conditions are obtained for maximizing the composition of the syngas in CO and H2.


1995 ◽  
Vol 28 (6) ◽  
pp. 1-15
Author(s):  
G. van Straten ◽  
A.J.B. van Boxtel

2004 ◽  
Vol 2004 (10) ◽  
pp. 233-237
Author(s):  
Scott E. Parker ◽  
Gary C. Deis ◽  
Phillip Quigley ◽  
D.G. Woodward ◽  
Kurtis J. Montegna

2013 ◽  
Vol 2013 ◽  
pp. 1-10
Author(s):  
K. Moon ◽  
Ganesh R. Kale

Combined (steam and CO2) reforming is one of the methods to produce syngas for different applications. An energy requirement analysis of steam reforming to dry reforming with intermediate steps of steam reduction and equivalent CO2addition to the feed fuel for syngas generation has been done to identify condition for optimum process operation. Thermodynamic equilibrium data for combined reforming was generated for temperature range of 400–1000°C at 1 bar pressure and combined oxidant (CO2+ H2O) stream to propane (fuel) ratio of 3, 6, and 9 by employing the Gibbs free energy minimization algorithm of HSC Chemistry software 5.1. Total energy requirement including preheating and reaction enthalpy calculations were done using the equilibrium product composition. Carbon and methane formation was significantly reduced in combined reforming than pure dry reforming, while the energy requirements were lower than pure steam reforming. Temperatures of minimum energy requirement were found in the data analysis of combined reforming which were optimum for the process.


1995 ◽  
Vol 28 (9) ◽  
pp. 215-228
Author(s):  
E.D. Gilles ◽  
G. Lauschke ◽  
A. Kienle ◽  
M. Storz

2015 ◽  
Vol 1130 ◽  
pp. 214-217
Author(s):  
Catherine Joulian ◽  
Jérôme Jacob ◽  
Mickaël Beaulieu ◽  
Patrick d’Hugues ◽  
Anne Gwénaëlle Guézennec

In bioleaching processes, gas transfer is often considered as one of the key mechanisms that will influence the leaching efficiency and more precisely the leaching rate. Oxygen can be a limiting factor in bacterial leaching because of its low solubility. One way to overcome this phenomenon consists in increasing the oxygen partial pressure in the gas stream supplied to the leach pulp. The primary objective of this work was to investigate the use of oxygen-enriched gas in bioleaching stirred reactors and its impact on the consortium dynamics. First tests were performed at lab scale in four successive series of 2-L bioreactors alimented either with air or with oxygen enriched gas. The microbial consortium used has proven its efficiency on several ores such as cobaltiferous pyrite and polymetallic ores in former research projects (BioMine, BioShale, ProMine). The community diversity was remarkably reproducible irrespective of the type of gas supply, in each of the successive series of reactors. Only minor changes occurred after subculturing from one batch series to the next one, highlighting the high stability of the established consortium. Different oxygen partial pressures (from 20% to 50%) were then tested in a 20-L continuous reactors pilot experiment. There was no impact on the community diversity, showing the high tolerance to oxygen of the bioleaching strains and their capacity to easily survive 50% oxygen input. The bioleaching efficiency in terms of rate and metal leaching did not seem to be changed. The use of enriched oxygen gas is not detrimental to the bioleaching strains and may be used in order to improve process operation (gas transfer, heat management...).


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