scholarly journals CO, NO<sub>x</sub> and <sup>13</sup>CO<sub>2</sub> as tracers for fossil fuel CO<sub>2</sub>: results from a pilot study in Paris during winter 2010

2013 ◽  
Vol 13 (15) ◽  
pp. 7343-7358 ◽  
Author(s):  
M. Lopez ◽  
M. Schmidt ◽  
M. Delmotte ◽  
A. Colomb ◽  
V. Gros ◽  
...  
Keyword(s):  
Co2 Emission ◽  
Liquid Fuel ◽  
Fossil Fuel ◽  
Emission Inventories ◽  
Gas Combustion ◽  
Air Mass ◽  
Diurnal Cycles ◽  
Fossil Fuel Consumption ◽  
Plant Respiration ◽  
Air Mass Origin

Abstract. Measurements of the mole fraction of the CO2 and its isotopes were performed in Paris during the MEGAPOLI winter campaign (January–February 2010). Radiocarbon (14CO2) measurements were used to identify the relative contributions of 77% CO2 from fossil fuel consumption (CO2ff from liquid and gas combustion) and 23% from biospheric CO2 (CO2 from the use of biofuels and from human and plant respiration: CO2bio). These percentages correspond to average mole fractions of 26.4 ppm and 8.2 ppm for CO2ff and CO2bio, respectively. The 13CO2 analysis indicated that gas and liquid fuel contributed 70% and 30%, respectively, of the CO2 emission from fossil fuel use. Continuous measurements of CO and NOx and the ratios CO/CO2ff and NOx/CO2ff derived from radiocarbon measurements during four days make it possible to estimate the fossil fuel CO2 contribution over the entire campaign. The ratios CO/CO2ff and NOx/CO2ff are functions of air mass origin and exhibited daily ranges of 7.9 to 14.5 ppb ppm−1 and 1.1 to 4.3 ppb ppm−1, respectively. These ratios are consistent with different emission inventories given the uncertainties of the different approaches. By using both tracers to derive the fossil fuel CO2, we observed similar diurnal cycles with two maxima during rush hour traffic.

scholarly journals Isotope- and tracer-based measurements of fossil fuel and biospheric carbon dioxide in Paris during winter 2010

2013 ◽  
Vol 13 (1) ◽  
pp. 2371-2414 ◽  
Author(s):  
M. Lopez ◽  
M. Schmidt ◽  
M. Delmotte ◽  
A. Colomb ◽  
V. Gros ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emission ◽  
Liquid Fuel ◽  
Fossil Fuel ◽  
Emission Inventories ◽  
Gas Combustion ◽  
Air Mass ◽  
Fossil Fuel Consumption ◽  
Plant Respiration ◽  
Air Mass Origin

Abstract. Measurements of the mole fraction of the CO2 and its isotopes were performed in Paris during the MEGAPOLI winter campaign (January–February 2010). Radiocarbon (14CO2) measurements were used to identify the relative contributions of 77% CO2 from fossil fuel consumption (CO2ff from liquid and gas combustion) and 23% from biospheric CO2 (CO2 from the use of biofuels and from human and plant respiration: CO2bio). These percentages correspond to average mole fractions of 26.4 ppm and 8.2 ppm for CO2ff and CO2bio, respectively. The 13CO2 analysis indicated that gas and liquid fuel contributed 70% and 30%, respectively, of the CO2 emission from fossil fuel use. Continuous measurements of CO and NOx and the ratios CO/CO2ff and NOx/CO2ff derived from radiocarbon measurements during four days make it possible to estimate the fossil fuel CO2 contribution over the entire campaign. The ratios CO/CO2ff and NOx/CO2ff are functions of air mass origin and exhibited daily ranges of 7.9 to 14.5 ppb ppm−1 and 1.1 to 4.3 ppb ppm−1, respectively. These ratios are sufficiently consistent with different emission inventories given the uncertainties of the different approaches.

scholarly journals Long-term real-time chemical characterization of submicron aerosols at Montsec (southern Pyrenees, 1570 m a.s.l.)

2015 ◽  
Vol 15 (6) ◽  
pp. 2935-2951 ◽  
Author(s):  
A. Ripoll ◽  
M. C. Minguillón ◽  
J. Pey ◽  
J. L. Jimenez ◽  
D. A. Day ◽  
...  
Keyword(s):  
Real Time ◽  
Long Range ◽  
Chemical Characterization ◽  
Western Mediterranean ◽  
Continuous Increase ◽  
Air Mass ◽  
Air Masses ◽  
Diurnal Cycles ◽  
Western Mediterranean Basin ◽  
Air Mass Origin

Abstract. Real-time measurements of inorganic (sulfate, nitrate, ammonium, chloride and black carbon (BC)) and organic submicron aerosols (particles with an aerodynamic diameter of less than 1 μm) from a continental background site (Montsec, MSC, 1570 m a.s.l.) in the western Mediterranean Basin (WMB) were conducted for 10 months (July 2011–April 2012). An aerosol chemical speciation monitor (ACSM) was co-located with other online and offline PM1 measurements. Analyses of the hourly, diurnal, and seasonal variations are presented here, for the first time, for this region. Seasonal trends in PM1 components are attributed to variations in evolution of the planetary boundary layer (PBL) height, air mass origin, and meteorological conditions. In summer, the higher temperature and solar radiation increases convection, enhancing the growth of the PBL and the transport of anthropogenic pollutants towards high altitude sites. Furthermore, the regional recirculation of air masses over the WMB creates a continuous increase in the background concentrations of PM1 components and causes the formation of reservoir layers at relatively high altitudes. The combination of all these atmospheric processes results in a high variability of PM1 components, with poorly defined daily patterns, except for the organic aerosols (OA). OA was mostly composed (up to 90%) of oxygenated organic aerosol (OOA), split in two types: semivolatile (SV-OOA) and low-volatility (LV-OOA), the rest being hydrocarbon-like OA (HOA). The marked diurnal cycles of OA components regardless of the air mass origin indicates that they are not only associated with anthropogenic and long-range-transported secondary OA (SOA) but also with recently produced biogenic SOA. Very different conditions drive the aerosol phenomenology in winter at MSC. The thermal inversions and the lower vertical development of the PBL leave MSC in the free troposphere most of the day, being affected by PBL air masses only after midday, when the mountain breezes transport emissions from the adjacent valleys and plains to the top of the mountain. This results in clear diurnal patterns of both organic and inorganic concentrations. OA was also mainly composed (71%) of OOA, with contributions from HOA (5%) and biomass burning OA (BBOA; 24%). Moreover, in winter sporadic long-range transport from mainland Europe is observed. The results obtained in the present study highlight the importance of SOA formation processes at a remote site such as MSC, especially in summer. Additional research is needed to characterize the sources and processes of SOA formation at remote sites.

scholarly journals Importance of fossil fuel emission uncertainties over Europe for CO<sub>2</sub> modeling: model intercomparison

2011 ◽  
Vol 11 (13) ◽  
pp. 6607-6622 ◽  
Author(s):  
P. Peylin ◽  
S. Houweling ◽  
M. C. Krol ◽  
U. Karstens ◽  
C. Rödenbeck ◽  
...  
Keyword(s):  
Inverse Modeling ◽  
Fossil Fuel ◽  
Transport Model ◽  
Carbon Sink ◽  
Temporal Distribution ◽  
Co2 Concentration ◽  
Emission Inventories ◽  
Transport Models ◽  
Diurnal Cycles ◽  
Fossil Fuel Emission

Abstract. Inverse modeling techniques used to quantify surface carbon fluxes commonly assume that the uncertainty of fossil fuel CO2 (FFCO2) emissions is negligible and that intra-annual variations can be neglected. To investigate these assumptions, we analyzed the differences between four fossil fuel emission inventories with spatial and temporal differences over Europe and their impact on the model simulated CO2 concentration. Large temporal flux variations characterize the hourly fields (~40 % and ~80 % for the seasonal and diurnal cycles, peak-to-peak) and annual country totals differ by 10 % on average and up to 40 % for some countries (i.e., the Netherlands). These emissions have been prescribed to seven different transport models, resulting in 28 different FFCO2 concentrations fields. The modeled FFCO2 concentration time series at surface sites using time-varying emissions show larger seasonal cycles (+2 ppm at the Hungarian tall tower (HUN)) and smaller diurnal cycles in summer (−1 ppm at HUN) than when using constant emissions. The concentration range spanned by all simulations varies between stations, and is generally larger in winter (up to ~10 ppm peak-to-peak at HUN) than in summer (~5 ppm). The contribution of transport model differences to the simulated concentration std-dev is 2–3 times larger than the contribution of emission differences only, at typical European sites used in global inversions. These contributions to the hourly (monthly) std-dev's amount to ~1.2 (0.8) ppm and ~0.4 (0.3) ppm for transport and emissions, respectively. First comparisons of the modeled concentrations with 14C-based fossil fuel CO2 observations show that the large transport differences still hamper a quantitative evaluation/validation of the emission inventories. Changes in the estimated monthly biosphere flux (Fbio) over Europe, using two inverse modeling approaches, are relatively small (less that 5 %) while changes in annual Fbio (up to ~0.15 % GtC yr−1) are only slightly smaller than the differences in annual emission totals and around 30 % of the mean European ecosystem carbon sink. These results point to an urgent need to improve not only the transport models but also the assumed spatial and temporal distribution of fossil fuel emission inventories.

Monthly, global emissions of carbon dioxide from fossil fuel consumption

Tellus B ◽  
2011 ◽  
Vol 63 (3) ◽  
Author(s):  
R. J. Andres ◽  
J. S. Gregg ◽  
L. Losey ◽  
G. Marland ◽  
T. A. Boden
Keyword(s):  
Carbon Dioxide ◽  
Fuel Consumption ◽  
Fossil Fuel ◽  
Fossil Fuel Consumption ◽  
Global Emissions

scholarly journals Using Quantile Regression to Analyze the Relationship between Socioeconomic Indicators and Carbon Dioxide Emissions in G20 Countries

2021 ◽  
Vol 13 (13) ◽  
pp. 7011
Author(s):  
Abdulaziz A. Alotaibi ◽  
Naif Alajlan
Keyword(s):  
Carbon Dioxide ◽  
Quantile Regression ◽  
Fuel Consumption ◽  
Co2 Emissions ◽  
Fossil Fuel ◽  
Trade Openness ◽  
Policy Coordination ◽  
Socioeconomic Indicators ◽  
Control Variables ◽  
Fossil Fuel Consumption

Numerous studies addressed the impacts of social development and economic growth on the environment. This paper presents a study about the inclusive impact of social and economic factors on the environment by analyzing the association between carbon dioxide (CO2) emissions and two socioeconomic indicators, namely, Human Development Index (HDI) and Legatum Prosperity Index (LPI), under the Environmental Kuznets Curve (EKC) framework. To this end, we developed a two-stage methodology. At first, a multivariate model was constructed that accurately explains CO2 emissions by selecting the appropriate set of control variables based on model quality statistics. The control variables include GDP per capita, urbanization, fossil fuel consumption, and trade openness. Then, quantile regression was used to empirically analyze the inclusive relationship between CO2 emissions and the socioeconomic indicators, which revealed many interesting results. First, decreasing CO2 emissions was coupled with inclusive socioeconomic development. Both LPI and HDI had a negative marginal relationship with CO2 emissions at quantiles from 0.2 to 1. Second, the EKC hypothesis was valid for G20 countries during the study period with an inflection point around quantile 0.15. Third, the fossil fuel consumption had a significant positive relation with CO2 emissions, whereas urbanization and trade openness had a negative relation during the study period. Finally, this study empirically indicates that effective policies and policy coordination on broad social, living, and economic dimensions can lead to reductions in CO2 emissions while preserving inclusive growth.

scholarly journals Cleaning up the air: Effectiveness of air quality policy for SO<sub>2</sub> and NO<sub><i>x</i></sub> emissions in China

2016 ◽  
Author(s):  
Ronald J. van der A ◽  
Bas Mijling ◽  
Jieying Ding ◽  
Maria Elissavet Koukouli ◽  
Fei Liu ◽  
...  
Keyword(s):  
Air Quality ◽  
Fuel Consumption ◽  
Fossil Fuel ◽  
Transport Sector ◽  
Nox Emissions ◽  
So2 Emissions ◽  
Provincial Level ◽  
Fossil Fuel Consumption ◽  
Public Data ◽  
Quality Policy

Abstract. Air quality observations by satellite instruments are spatially consistent, and have a regular temporal resolution, which make them very useful in studying long-term trends in atmospheric species. To monitor air quality trends in China for the period 2005–2015 we derive SO2 columns and NOx emissions on a provincial level with an unprecedented accuracy. To put these trends into perspective they are compared with public data on energy consumption and the environmental policies of China. We distinguish the effect of air quality regulations from economic growth by comparing them relatively to fossil fuel consumption. Pollutant levels, per unit of fossil fuel, are used to assess the effectiveness of air quality regulations. We note that the desulphurisation regulations enforced in 2005–2006 only had a significant effect in the years 2008–2009 when a much stricter control of the actual use of the installations began. For national NOx emissions a distinct decreasing trend is only visible since 2012, but the emission peak year differs from province to province. Unlike SO2, emissions of NOx are highly related to traffic. Furthermore, regulations for NOx emissions are partly decided on a provincial level. The last three years show both a reduction in SO2 and NOx emissions per fossil fuel unit, since the authorities have implemented several new environmental regulations. Despite an increasing fossil fuel consumption and a growing transport sector, the effects of air quality policy in China are clearly visible. Without the air quality regulations the concentration of SO2 would be almost 3 times higher and the NO2 concentrations would be at least 30 % higher than they are today in China.

A four-year size-segregated characterization study of particles PM10, PM2.5 and PM1 depending on air mass origin at Melpitz

2010 ◽  
Vol 44 (2) ◽  
pp. 164-173 ◽  
Author(s):  
G. Spindler ◽  
E. Brüggemann ◽  
T. Gnauk ◽  
A. Grüner ◽  
K. Müller ◽  
...  
Keyword(s):  
Air Mass ◽  
Characterization Study ◽  
Air Mass Origin
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