scholarly journals Atmospheric ammonia variability and link with particulate matter formation: a case study over the Paris area

2020 ◽  
Vol 20 (1) ◽  
pp. 577-596 ◽  
Author(s):  
Camille Viatte ◽  
Tianze Wang ◽  
Martin Van Damme ◽  
Enrico Dammers ◽  
Frederik Meleux ◽  
...  

Abstract. The Paris megacity experiences frequent particulate matter (i.e.PM2.5, particulate matter with a diameter less than 2.5 µm) pollution episodes in spring (March–April). At this time of the year, large numbers of the particles consist of ammonium sulfate and nitrate which are formed from ammonia (NH3) released during fertilizer spreading practices and transported from the surrounding areas to Paris. There is still limited knowledge of the emission sources around Paris, their magnitude, and their seasonality. Using space-borne NH3 observation records of 10 years (2008–2017) and 5 years (2013–2017) provided by the Infrared Atmospheric Sounding Interferometer (IASI) and the Cross-Track Infrared Sounder (CrIS) instrument, regional patterns of NH3 variabilities (seasonal and interannual) are derived. Observations reveal identical high seasonal variability with three major NH3 hotspots found from March to August. The high interannual variability is discussed with respect to atmospheric total precipitation and temperature. A detailed analysis of the seasonal cycle is performed using both IASI and CrIS instrument data, together with outputs from the CHIMERE atmospheric model. For 2014 and 2015, the CHIMERE model shows coefficients of determination of 0.58 and 0.18 when compared to IASI and CrIS, respectively. With respect to spatial variability, the CHIMERE monthly NH3 concentrations in spring show a slight underrepresentation over Belgium and the United Kingdom and an overrepresentation in agricultural areas in the French Brittany–Pays de la Loire and Plateau du Jura region, as well as in northern Switzerland. In addition, PM2.5 concentrations derived from the CHIMERE model have been evaluated against surface measurements from the Airparif network over Paris, with which agreement was found (r2 = 0.56) with however an underestimation during spring pollution events. Using HYSPLIT cluster analysis of back trajectories, we show that NH3 total columns measured in spring over Paris are enhanced when air masses originate from the north-east (e.g. the Netherlands and Belgium), highlighting the importance of long-range transport in the NH3 budget over Paris. Variability in NH3 in the north-east region is likely to impact NH3 concentrations in the Parisian region since the cross-correlation function is above 0.3 (at lag = 0 and 1 d). Finally, we quantify the key meteorological parameters driving the specific conditions important for the formation of PM2.5 from NH3 in the Île-de-France region in spring. Data-driven results based on surface PM2.5 measurements from the Airparif network and IASI NH3 measurements show that a combination of the factors such as a low boundary layer of ∼500 m, a relatively low temperature of 5 ∘C, a high relative humidity of 70 %, and wind from the north-east contributes to a positive PM2.5 and NH3 correlation.

2019 ◽  
Author(s):  
Camille Viatte ◽  
Tianze Wang ◽  
Martin Van Damme ◽  
Enrico Dammers ◽  
Frederik Meleux ◽  
...  

Abstract. The Paris megacity experiences frequent particulate matter (PM2.5, PM with a diameter less than 2.5 μm) pollution episodes in springtime (March–April). At this time of the year, large parts of the particles consist of ammonium sulfate and nitrate which are formed from ammonia (NH3) released during fertilizer spreading practices and transported from the surrounding areas to Paris. There is still limited knowledge on the emission sources around Paris, their magnitude and seasonality. Using space-borne NH3 observation records of 10-years (2008–2017) and 5-years (2013–2017) provided by the Infrared Atmospheric Sounding Interferometer (IASI) and the Cross-Track Infrared Sounder (CrIS) instrument, regional pattern of NH3 variabilities (seasonal and inter-annual) are derived. Observations reveal identical high seasonal variabilities with three major NH3 hot spots found from March to August. The high inter-annual variability is discussed with respect to atmospheric total precipitation and temperature. A detailed analysis of the seasonal cycle is performed using both IASI and the CrIS instrument data, together with outputs from the CHIMERE atmospheric model. For months of high NH3 concentrations (March to August) the CHIMERE model shows good correspondence with correlation slopes of 0.98 and 0.71 when comparing with IASI and CrIS, respectively. It is found that the model is only able to reproduce half of the observed atmospheric temporal NH3 variability in the domain. In term of spatial variability, the CHIMERE monthly NH3 concentrations in springtime show a slight underrepresentation over Belgium and the United-Kingdom and overrepresentation in agricultural areas in the French Brittany/Pays de la Loire and Plateau du Jura region, as well as in the north part of Switzerland. Using HYSPLIT cluster analysis of back-trajectories, we show that NH3 total columns measured in spring over Paris are enhanced when air masses are originated from the Northeast (e. g., Netherlands and Belgium), highlighting the long-range transport importance on the NH3 budget over Paris. Finally, we quantify the key meteorological parameters driving the specific conditions important for the PM2.5 formation from NH3 in the Ile-de-France region in springtime. Data-driven results based on surface PM2.5 measurements from the Airparif network and IASI NH3 observations show that a combination of the factors, e. g. a low boundary layer of ~500 m, a relatively low temperature of 5 °C and a high relative humidity of 70 %, contributes to favor PM2.5 and NH3 correlation.


Phytotaxa ◽  
2018 ◽  
Vol 374 (3) ◽  
pp. 185 ◽  
Author(s):  
FABIÁN A. MICHELANGELI ◽  
RENATO GOLDENBERG

We describe six new species of Melastomataceae from the Yanachaga-Chemillén National Park and surrounding areas from the Department of Pasco, Province of Oxapampa in Central Peru. Macrocentrum andinum is the first species of the genus described from the Andes, found along creeks at 400–500 m elev. and characterized by its anysophyllous leaves, pubescent stems and four-merous flowers. Meriania rubriflora is found in forests above 2200 m elev. and it is characterized by stem nodes with stipular flaps, leaves with an acute base and four merous, deep red flowers. Miconia palcazuana is found along rivers and streams at 300–400 m on the eastern flank of the park, and it can be distinguished by its flowers with pink anthers with glands on the connective and narrowly oblanceolate to elliptic-lanceolate leaves. Miconia yanachagaensis grows in the dwarf-sclerophyllous forests at the top of ridges and grasslands over 2800 m elev. and it is characterized by its long dendritic-pedicellate trichomes on the abaxial leaf surface, the stems flattened to terete and the presence of a conspicuous annular nodal line. Triolena rojasae is found growing on rocks along the Palcazú River and its tributaries, and it is characterized by its lanceolate-crenate leaves. Triolena vasquezii grows on the northern end of the Huancabamba canyon and the North East portion of the park and can be distinguished by its pustulate leaves with purple abaxial surface and anthers with two ventral appendages. We also present the first report of the genus Wurdastom for Peru.


Author(s):  
Kristian Svennevig ◽  
Peter Alsen ◽  
Pierpaolo Guarnieri ◽  
Jussi Hovikoski ◽  
Bodil Wesenberg Lauridsen ◽  
...  

The geological map sheet of Kilen in 1:100 000 scale covers the south-eastern part of the Carboniferous– Palaeogene Wandel Sea Basin in eastern North Greenland. The map area is dominated by the Flade Isblink ice cap, which separates several minor isolated landmasses. On the semi-nunatak of Kilen, the map is mainly based on oblique photogrammetry and stratigraphical field work while in Erik S. Henius Land, Nordostrundingen and northern Amdrup Land the map is based on field data collected during previous, 1:500 000 scale regional mapping. Twenty-one Palaeozoic–Mesozoic mappable units were identified on Kilen, while the surrounding areas comprise the Late Cretaceous Nakkehoved Formation to the north-east and the Late Carboniferous Foldedal Formation to the south-west. On Kilen, the description of Jurassic–Cretaceous units follows a recently published lithostratigraphy. The Upper Palaeozoic–lowermost Cretaceous strata comprise seven formations and an informal mélange unit. The overlying Lower–Upper Cretaceous succession comprises the Galadriel Fjeld and Sølverbæk Formations, which are subdivided into six and five units, respectively. In addition, the Quaternary Ymer Formation was mapped on south-east Kilen. The Upper Palaeozoic to Mesozoic strata of Kilen are faulted and folded. Several post-Coniacian NNW–SSE-trending normal faults are identified and found to be passively folded by a later N–S compressional event. A prominent subhorizontal fault, the Central Detachment, separates two thrust sheets, the Kilen Thrust Sheet in the footwall and the Hondal Elv Thrust Sheet in the hanging wall. The style of deformation and the structures found on Kilen are caused by compressional tectonics resulting in post-extensional, presumably Early Eocene, folding and thrusting and basin inversion. The structural history of the surrounding areas and their relation to Kilen await further studies.


Author(s):  
Kristian Svennevig ◽  
Peter Alsen ◽  
Pierpaolo Guarnieri ◽  
Jussi Hovikoski ◽  
Bodil Wesenberg Lauridsen ◽  
...  

NOTE: This Map Description was published in a former series of GEUS Bulletin. Please use the original series name when citing this series, for example: Svennevig, K., Alsen, P., Guarnieri, P., Hovikoski, J., Wesenberg Lauridsen, B., Krarup Pedersen, G., Nøhr-Hansen, H., & Sheldon, E. (2018). Descriptive text to the Geological map of Greenland, 1:100 000, Kilen 81 Ø.1 Syd. Geological Survey of Denmark and Greenland Map Series 8, 1-29. https://doi.org/10.34194/geusm.v8.4526 _______________ The geological map sheet of Kilen in 1:100 000 scale covers the south-eastern part of the Carboniferous–Palaeogene Wandel Sea Basin in eastern North Greenland. The map area is dominated by the Flade Isblink ice cap, which separates several minor isolated landmasses. On the semi-nunatak of Kilen, the map is mainly based on oblique photogrammetry and stratigraphical field work while in Erik S. Henius Land, Nordostrundingen and northern Amdrup Land the map is based on field data collected during previous, 1:500 000 scale regional mapping. Twenty-one Palaeozoic–Mesozoic mappable units were identified on Kilen, while the surrounding areas comprise the Late Cretaceous Nakkehoved Formation to the north-east and the Late Carboniferous Foldedal Formation to the south-west. On Kilen, the description of Jurassic–Cretaceous units follows a recently published lithostratigraphy. The Upper Palaeozoic–lowermost Cretaceous strata comprise seven formations and an informal mélange unit. The overlying Lower–Upper Cretaceous succession comprises the Galadriel Fjeld and Sølverbæk Formations, which are subdivided into six and five units, respectively. In addition, the Quaternary Ymer Formation was mapped on south-east Kilen. The Upper Palaeozoic to Mesozoic strata of Kilen are faulted and folded. Several post-Coniacian NNW–SSE-trending normal faults are identified and found to be passively folded by a later N–S compressional event. A prominent subhorizontal fault, the Central Detachment, separates two thrust sheets, the Kilen Thrust Sheet in the footwall and the Hondal Elv Thrust Sheet in the hanging wall. The style of deformation and the structures found on Kilen are caused by compressional tectonics resulting in post-extensional, presumably Early Eocene, folding and thrusting and basin inversion. The structural history of the surrounding areas and their relation to Kilen await further studies.


2021 ◽  
Vol 2070 (1) ◽  
pp. 012066
Author(s):  
S Aryalakshmi ◽  
Dhanya Madhu

Abstract Heavy rainfall inducing other catastrophic events are frequently experienced globally. Understanding the mechanisms of moisture transport during such events will help in furthering our knowledge about such systems. In the current study, estimation of most likely moisture trajectoriesis performed using back trajectory analyses. Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model available from National Oceanic and Atmospheric Administration’s (NOAA) Air Resources Laboratory (ARL) is used for the purpose. A preliminary analysis is conducted by calculating the frequencies of back trajectories from two locations in Kerala for three heavy rainfall cases. The analysis indicates that both the locations have similar pattern of moisture trajectories during the cases occurring in south west monsoon and pre monsoon periods. However, a change in the behaviour of the trajectories for the two locations is observed for the case during the north east monsoon period. Since this study involved only individual cases, robust conclusions cannot be made based on this for the dynamics of moisture transport for these locations. More detailed analysis will follow this preliminary study in future for the purpose.


1997 ◽  
Vol 9 (3) ◽  
pp. 347-354 ◽  
Author(s):  
Paul C. Augustinus ◽  
Damian B. Gore ◽  
Michelle R. Leishman ◽  
Dan Zwartz ◽  
Eric A. Colhoun

In the Bunger Hills, mapping of glacial drift sheets and examination of striae patterns and other palaeo-ice flow direction indicators show that the largely ice-free region records the imprint of ice sheet expansion(s) during the late Cenozoic. In particular, ice moulded features and striae in southern Bunger Hills suggest formation during at least two episodes of ice sheet expansion, although whether they were formed during separate events or merely different phases of the same expansion of the ice sheet is not able to be discerned at present. The older event relates to thin ice with flow constrained by the topography, whilst the younger event relates to regional expansion of thick ice across the area. Discrimination of the order of emplacement of the cross-cutting striae patterns is possible at a number of sites. Palaeo-ice flow indicators confirm that ice sheet expansion over southern Bunger Hills was purely from the southern and eastern margins, although minor advances of the north-east flowing Edisto Glacier onto coastal areas occurred following retreat of the last extensive ice sheet phase.


2021 ◽  
Vol 8 (1) ◽  
pp. 26-44
Author(s):  
Vladimir Pokalyuk ◽  
Igor Lomakin ◽  
Valentyn Verkhovtsev ◽  
Vladimir Kochelab

Modern high-precision global digital 3-d models of the relief of the continents and the ocean floor (SRTM, GEBCO) are the objective basis to clarify the structure and features of the organization of the planetary fault network of of the Black Sea region and adjacent areas of the Mediterranean mobile belt and surrounding platform areas, to find out the location of the main transregional supermegalineaments forming the deep structural-tectonic framework of the territory. A complete consistency of the structural plan of faults and fault zones within the sea areas and continental surroundings is established. The structural position of the Black Sea basin as a whole is determined by its location at the intersection area (superposition, interference) of the diagonal (subdiagonal) transcontinental tectonolinament belts: the north-west – Elba-Zagros, Caucasus-Kopetdag, and the north-east – Atlas- Black Sea. The absence of large-scale lateral displacements at the intersection nodes of differently oriented supermegalineament systems indicates the relative autonomous stationarity and inheritance of the formation of the lyneament framework during the entire Mezozoic-Cenozoic and relatively low-shear nature of its implementation. This feature of the Black Sea region structural pattern significantly limits the possibility of using neomobilistic geodynamic models to explain the history of the geological development of the region. The strict consistency and orderliness of the lineament framework can be ensured only by global planetary factors associated with the influence of the rotational regime of the Earth's shells on the stress distribution in the lithosphere.


2003 ◽  
Vol 1 ◽  
pp. 437-458 ◽  
Author(s):  
Tommy Egebjerg Mogensen ◽  
John A. Korstgård

In the Kattegat area, Denmark, the Sorgenfrei–Tornquist Zone, an old crustal weakness zone, was repeatedly reactivated during Triassic, Jurassic and Early Cretaceous times with dextral transtensional movements along the major boundary faults. These tectonic events were minor compared to the tectonic events of the Late Carboniferous – Early Permian and the Late Cretaceous – Early Tertiary, although a dynamic structural and stratigraphic analysis indicates that the Sorgenfrei–Tornquist Zone was active compared to the surrounding areas. At the end of the Palaeozoic, the area was a peneplain. Regional Triassic subsidence caused onlap towards the north-east, where the youngest Triassic sediments overlie Precambrian crystalline basement. During the Early Triassic, several of the major Early Permian faults were reactivated, probably with dextral strike-slip along the Børglum Fault. Jurassic – Early Cretaceous subsidence was restricted primarily to the area between the two main faults in the Sorgenfrei–Tornquist Zone, the Grenå–Helsingborg Fault and the Børglum Fault. This restriction of basin development indicates a change in the regional stress field at the Triassic–Jurassic transition. Middle Jurassic and Late Jurassic – Early Cretaceous subsidence followed the Early Jurassic pattern with local subsidence in the Sorgenfrei–Tornquist Zone, but now even more restricted to within the zone. The subsidence showed a decrease in the Middle Jurassic, and increased again during Late Jurassic – Early Cretaceous times. Small faults were generated internally in the Sorgenfrei–Tornquist Zone during the Mesozoic with a pattern that indicates a broad transfer of strike-slip/oblique-slip motion from the Grenå–Helsingborg Fault to the Børglum Fault.


1977 ◽  
Vol 45 ◽  
pp. 138-190 ◽  
Author(s):  
Anne M. Kahane ◽  
D. David Andrews

This report is a further contribution to the publication of the survey of the country surrounding Veii. The area is bounded in the north by the watershed of the Roman Via Clodia; on the east by the line of the Via Cassia, also a watershed; on the south by the Valle della Torre Spaccata and the stream it joins, the Fosso dell'Acquasona, to the latter's junction with the Fosso Galeria; and on the west by the river known from north to south as the Fosso di Cesano, Rio Galeria, Valle Galeria and Fosso Galeria. It is a compact area as the roads which originate in its north-east corner terminate within it, apart from the cross country Etruscan road which goes off across the Fosso Galeria towards the lower Arrone (Route I) and the Etruscan road down the long ridge to the Via di Boccea crossing of the Fosso Galeria (Route VI), neither of whose onward courses has yet been studied in detail. The Roman road down the last mentioned ridge may have been a useful link in local communication, but it was probably not a through road.


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