scholarly journals Assessment of wood burning versus fossil fuel contribution to wintertime black carbon and carbon monoxide concentrations in Athens, Greece

2017 ◽  
Author(s):  
Athina-Cerise Kalogridis ◽  
Stergios Vratolis ◽  
Eleni Liakakou ◽  
Evangelos Gerasopoulos ◽  
Nikolaos Mihalopoulos ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Black Carbon ◽  
Fossil Fuel ◽  
Road Traffic ◽  
Monitoring Site ◽  
Wood Burning ◽  
Independent Evaluation ◽  
Range Transport ◽  
Ambient Concentrations ◽  
Co Concentrations

Abstract. The scope of this study was to estimate the contribution of fossil fuel and wood burning combustion to black carbon (BC) and carbon monoxide (CO) during wintertime, in Athens. For that purpose, in-situ measurements of equivalent Black Carbon (eBC) and CO were simultaneously conducted in a suburban and an urban background monitoring site in Athens during three months of winter 2014–2015. For the deconvolution of eBC into eBC emitted from fossil fuel (BCff) and wood burning (BCwb), a method based on the spectral dependency of the absorption of pure black carbon and brown carbon was used. Thereafter, BCwb and BCff estimated fractions were used along with measured CO concentrations in a multiple regression analysis, in order to quantify the contribution of each one of the combustion sources to the ambient CO levels. For an independent evaluation of the results, we additionally estimated the wood-burning and fossil fuel contribution to CO, calculated on the basis of their CO/NOx emission ratios. The results indicate that during wintertime BC and CO are mainly emitted by local sources within the Athens Metropolitan Area (AMA), and are only occasionally affected by long-range transport. Fossil fuel combustion, mainly from road traffic, is found to be the major contributor to both eBC in PM2.5 and CO ambient concentrations in AMA. However, wintertime wood burning makes a significant contribution of about 30 % to the observed eBC and the CO concentrations (on average, 11 % and 16 % of total CO in the two sites, respectively). Both, BC and CO from biomass burning (BCwb and COwb, respectively) present a clear diurnal pattern with highest concentrations during night, supporting the local domestic heating as their main source.

scholarly journals Assessment of wood burning versus fossil fuel contribution to wintertime black carbon and carbon monoxide concentrations in Athens, Greece

2018 ◽  
Vol 18 (14) ◽  
pp. 10219-10236 ◽  
Author(s):  
Athina-Cerise Kalogridis ◽  
Stergios Vratolis ◽  
Eleni Liakakou ◽  
Evangelos Gerasopoulos ◽  
Nikolaos Mihalopoulos ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Black Carbon ◽  
Fossil Fuel ◽  
Road Traffic ◽  
Monitoring Site ◽  
Night Time ◽  
Urban Background ◽  
Wood Burning ◽  
Ambient Concentrations ◽  
Co Concentrations

Abstract. The scope of this study was to estimate the contribution of fossil fuel and wood burning combustion to black carbon (BC) and carbon monoxide (CO) during wintertime, in Athens. For that purpose, in situ measurements of equivalent black carbon (eBC) and CO were simultaneously conducted in a suburban and an urban background monitoring site in Athens during the 3 months of winter 2014–2015. For the deconvolution of eBC into eBC emitted from fossil fuel (BCff) and wood burning (BCwb), a method based on the spectral dependency of the absorption of pure black carbon and brown carbon was used. Thereafter, BCwb and BCff estimated fractions were used along with measured CO concentrations in a multiple regression analysis, in order to quantify the contribution of each one of the combustion sources to the ambient CO levels. For a comparative analysis of the results, we additionally estimated the wood burning and fossil fuel contribution to CO, calculated on the basis of their CO ∕ NOx emission ratios. The results indicate that during wintertime BC and CO are mainly emitted by local sources within the Athens Metropolitan Area (AMA). Fossil fuel combustion, mainly from road traffic, is found to be the major contributor to both eBC in PM2.5 and CO ambient concentrations in AMA. However, wintertime wood burning makes a significant contribution to the observed eBC (of about 30 %) and CO concentrations (on average, 11 and 16 % of total CO in the suburban and urban background sites respectively). Both BC and CO from biomass burning (BCwb and COwb, respectively) present a clear diurnal pattern, with the highest concentrations during night-time, supporting the theory of local domestic heating being their main source.

scholarly journals Modelled black carbon radiative forcing and atmospheric lifetime in AeroCom Phase II constrained by aircraft observations

2014 ◽  
Vol 14 (22) ◽  
pp. 12465-12477 ◽  
Author(s):  
B. H. Samset ◽  
G. Myhre ◽  
A. Herber ◽  
Y. Kondo ◽  
S.-M. Li ◽  
...  
Keyword(s):  
Black Carbon ◽  
Phase Ii ◽  
Radiative Forcing ◽  
Fossil Fuel ◽  
Global Climate ◽  
Aircraft Measurement ◽  
Atmospheric Lifetime ◽  
Range Transport ◽  
Aircraft Observations ◽  
Measurement Campaigns

Abstract. Atmospheric black carbon (BC) absorbs solar radiation, and exacerbates global warming through exerting positive radiative forcing (RF). However, the contribution of BC to ongoing changes in global climate is under debate. Anthropogenic BC emissions, and the resulting distribution of BC concentration, are highly uncertain. In particular, long-range transport and processes affecting BC atmospheric lifetime are poorly understood. Here we discuss whether recent assessments may have overestimated present-day BC radiative forcing in remote regions. We compare vertical profiles of BC concentration from four recent aircraft measurement campaigns to simulations by 13 aerosol models participating in the AeroCom Phase II intercomparison. An atmospheric lifetime of BC of less than 5 days is shown to be essential for reproducing observations in remote ocean regions, in line with other recent studies. Adjusting model results to measurements in remote regions, and at high altitudes, leads to a 25% reduction in AeroCom Phase II median direct BC forcing, from fossil fuel and biofuel burning, over the industrial era. The sensitivity of modelled forcing to BC vertical profile and lifetime highlights an urgent need for further flight campaigns, close to sources and in remote regions, to provide improved quantification of BC effects for use in climate policy.

Year-long variability of the fossil fuel and wood burning black carbon components at a rural site in southern Delhi outskirts

2019 ◽  
Vol 216 ◽  
pp. 11-25 ◽  
Author(s):  
U.C. Dumka ◽  
D.G. Kaskaoutis ◽  
P.C.S. Devara ◽  
R. Kumar ◽  
S. Kumar ◽  
...  
Keyword(s):  
Black Carbon ◽  
Fossil Fuel ◽  
Rural Site ◽  
Wood Burning

scholarly journals Modeled black carbon radiative forcing and atmospheric lifetime in AeroCom Phase II constrained by aircraft observations

2014 ◽  
Vol 14 (14) ◽  
pp. 20083-20115 ◽  
Author(s):  
B. H. Samset ◽  
G. Myhre ◽  
A. Herber ◽  
Y. Kondo ◽  
S.-M. Li ◽  
...  
Keyword(s):  
Black Carbon ◽  
Phase Ii ◽  
Radiative Forcing ◽  
Fossil Fuel ◽  
Global Climate ◽  
Aircraft Measurement ◽  
Atmospheric Lifetime ◽  
Range Transport ◽  
Aircraft Observations ◽  
Measurement Campaigns

Abstract. Atmospheric black carbon (BC) absorbs solar radiation, and exacerbates global warming through exerting positive radiative forcing (RF). However, the contribution of BC to ongoing changes in global climate is under debate. Anthropogenic BC emissions, and the resulting distribution of BC concentration, are highly uncertain. In particular, long range transport and processes affecting BC atmospheric lifetime are poorly understood. Here we discuss whether recent assessments may have overestimated present day BC radiative forcing in remote regions. We compare vertical profiles of BC concentration from four recent aircraft measurement campaigns to simulations by 13 aerosol models participating in the AeroCom Phase II intercomparision. An atmospheric lifetime of BC of less than 5 days is shown to be essential for reproducing observations in remote ocean regions, in line with other recent studies. Adjusting model results to measurements in remote regions, and at high altitudes, leads to a 25% reduction in AeroCom Phase II median direct BC forcing, from fossil fuel and biofuel burning, over the industrial era. The sensitivity of modeled forcing to BC vertical profile and lifetime highlights an urgent need for further flight campaigns, close to sources and in remote regions, to provide improved quantification of BC effects for use in climate policy.

scholarly journals On the wintertime low bias of Northern Hemisphere carbon monoxide in global model studies

2014 ◽  
Vol 14 (1) ◽  
pp. 245-301 ◽  
Author(s):  
O. Stein ◽  
M. G. Schultz ◽  
I. Bouarar ◽  
H. Clark ◽  
V. Huijnen ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Dry Deposition ◽  
Road Traffic ◽  
Monitoring Network ◽  
Anthropogenic Emissions ◽  
Boreal Winter ◽  
Model Bias ◽  
Near Surface ◽  
Northern Hemispheric ◽  
Co Concentrations

Abstract. The uncertainties in the global budget of carbon monoxide (CO) are assessed to explain causes for the long-standing issue of Northern Hemispheric wintertime underestimation of CO concentrations in global models. With a series of MOZART sensitivity simulations for the year 2008, the impacts from changing a variety of surface sources and sinks were analyzed. The model results were evaluated with monthly averages of surface station observations from the global CO monitoring network as well as with total columns observed from satellites and with vertical profiles from measurements on passenger aircraft. Our basic simulation using MACCity anthropogenic emissions underestimated Northern Hemispheric near-surface CO concentrations on average by more than 20 ppb from December to April with the largest bias over Europe of up to 75 ppb in January. An increase in global biomass burning or biogenic emissions of CO or volatile organic compounds (VOC) is not able to reduce the annual course of the model bias and yields too high concentrations over the Southern Hemisphere. Raising global annual anthropogenic emissions results in overestimations of surface concentrations in most regions all-year-round. Instead, our results indicate that anthropogenic emissions in the MACCity inventory are too low for the industrialized countries during winter and spring. Thus we found it necessary to adjust emissions seasonally with regionally varying scaling factors. Moreover, exchanging the original resistance-type dry deposition scheme with a parameterization for CO uptake by oxidation from soil bacteria and microbes reduced the boreal winter dry deposition fluxes and could partly correct for the model bias. When combining the modified dry deposition scheme with increased wintertime road traffic emissions over Europe and North America (factors up to 4.5 and 2, respectively) we were able to optimize the match to surface observations and to reduce the model bias significantly with respect to the satellite and aircraft observations. A reason for the apparent underestimation of emissions may be an exaggerated downward trend in the RCP8.5 scenario in these regions between 2000 and 2010, as this scenario was used to extrapolate the MACCity emissions from their base year 2000. This factor is potentially amplified by a lack of knowledge about the seasonality of emissions. A methane lifetime of 9.7 yr for our basic model and 9.8 yr for the optimized simulation agrees well with current estimates of global OH, but we cannot exclude a potential effect from errors in the geographical and seasonal distribution of OH concentrations. Finally, underestimated emissions from anthropogenic VOCs can also account for a small part of the missing CO concentrations.

scholarly journals A 2.5 year's source apportionment study of black carbon from wood burning and fossil fuel combustion at urban and rural sites in Switzerland

2011 ◽  
Vol 4 (7) ◽  
pp. 1409-1420 ◽  
Author(s):  
H. Herich ◽  
C. Hueglin ◽  
B. Buchmann
Keyword(s):  
Black Carbon ◽  
Source Apportionment ◽  
Cross Sections ◽  
Light Absorption ◽  
Fossil Fuel ◽  
Data Sets ◽  
Near Ultraviolet ◽  
Wood Burning ◽  
Multi Wavelength ◽  
Rural Sites

Abstract. The contributions of fossil fuel (FF) and wood burning (WB) emissions to black carbon (BC) have been investigated in the recent past by analysis of multi-wavelength aethalometer data. This approach utilizes the stronger light absorption of WB aerosols in the near ultraviolet compared to the light absorption of aerosols from FF combustion. Here we present 2.5 years of seven-wavelength aethalometer data from one urban and two rural background sites in Switzerland measured from 2008–2010. The contribution of WB and FF to BC was directly determined from the aerosol absorption coefficients of FF and WB aerosols which were calculated by using confirmed Ångstrom exponents and aerosol light absorption cross-sections that were determined for all sites. Reasonable separation of total BC into contributions from FF and WB was achieved for all sites and seasons. The obtained WB contributions to BC are well correlated with measured concentrations of levoglucosan and potassium while FF contributions to BC correlate nicely with NOx. These findings support our approach and show that the applied source apportionment of BC is well applicable for long-term data sets. During winter, we found that BC from WB contributes on average 24–33 % to total BC at the considered measurement sites. This is a noticeable high fraction as the contribution of wood burning to the total final energy consumption is in Switzerland less than 4 %.

scholarly journals A method to dynamically constrain black carbon aerosol sources with online monitored potassium

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Huang Zheng ◽  
Shaofei Kong ◽  
Nan Chen ◽  
Zewei Fan ◽  
Ying Zhang ◽  
...  
Keyword(s):  
Black Carbon ◽  
Source Identification ◽  
Fossil Fuel ◽  
Pearson Correlation ◽  
Pearson Correlation Coefficient ◽  
Fossil Fuel Combustion ◽  
Wood Burning ◽  
Study Results ◽  
Black Carbon Aerosol ◽  
Aerosol Sources

AbstractThe result of Aethalometer model to black carbon (BC) source apportionment is highly determined by the absorption Ångström exponent (α) of aerosols from fossil fuel combustion (αff) and wood burning (αwb). A method using hourly measured potassium to calculate the αff and αwb values was developed in this study. Results showed that the optimal αff and αwb were 1.09 and 1.79 for the whole dataset. The optimal α values in the diurnal resolution were also calculated with αff and αwb varied in 1.02 –1.19 and 1.71–1.90, respectively. Using the dynamic α values, the Pearson correlation coefficient between BC and potassium from wood burning substantially improved compared to the results derived from the fixed α values. The method developed in this study is expected to provide more reasonable BC source identification results, which are helpful for air quality, climate, and human health modeling studies.

Considerations on Ambient Levels of Ozone Concentrations and Relationship with NOx in an Urban Environment

2017 ◽  
Vol 68 (4) ◽  
pp. 824-829
Author(s):  
Cornel Ianache ◽  
Laurentiu Predescu ◽  
Mirela Predescu ◽  
Dumitru Dumitru
Keyword(s):  
Nitrogen Oxides ◽  
Urban Areas ◽  
Road Traffic ◽  
Temporal Distribution ◽  
Ground Level ◽  
Distinct Pattern ◽  
Weekend Effect ◽  
Monitoring Site ◽  
Ground Level Ozone ◽  
Ozone Concentrations

The serious air pollution problem has determined public concerns, worldwide. One of the main challenges for countries all over the world is caused by the elevated levels of ground-level ozone (O3) concentrations and its anthropogenic precursors. Ploiesti city, as one of the major urban area of Romania, is facing the same situation. This research aims to investigate spatial and temporal distribution characteristics of O3 in relationship with nitrogen oxides (NOx) using statistical analysis methods. Hourly O3 and NOx measurements were collected during 2014 year in Ploiesti. The results obtained showed that the ozone spatial distribution was non-normal for each month in 2014. The diurnal cycle of ground-level ozone concentrations showed a mid-day peak, while NOx diurnal variations presented 2 daily peaks, one in the morning (7:00 a.m.) and one in the afternoon (between 5:00 and 7:00 p.m.). In addition, it was observed a distinct pattern of weekly variations for O3 and NOx. Like in many other urban areas, the results indicated the presence of the �ozone weekend effect� in Ploiesti during the 2014 year, ozone concentrations being slightly higher on weekends compared to weekdays. For the same monitoring site, the nitrogen oxides were less prevalent on Saturdays and Sundays, probably due to reducing of road traffic and other pollution-generating activities on weekends than during the week.

scholarly journals Regional variability in black carbon and carbon monoxide ratio from long-term observations over East Asia: assessment of representativeness for black carbon (BC) and carbon monoxide (CO) emission inventories

2020 ◽  
Vol 20 (1) ◽  
pp. 83-98 ◽  
Author(s):  
Yongjoo Choi ◽  
Yugo Kanaya ◽  
Seung-Myung Park ◽  
Atsushi Matsuki ◽  
Yasuhiro Sadanaga ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
South Korea ◽  
East Asia ◽  
Black Carbon ◽  
North Korea ◽  
Northeast China ◽  
Emission Inventory ◽  
East China ◽  
Co Emission

Abstract. The black carbon (BC) and carbon monoxide (CO) emission ratios were estimated and compiled from long-term, harmonized observations of the ΔBC∕ΔCO ratios under conditions unaffected by wet deposition at four sites in East Asia, including two sites in South Korea (Baengnyeong and Gosan) and two sites in Japan (Noto and Fukuoka). Extended spatio-temporal coverage enabled estimation of the full seasonality and elucidation of the emission ratio in North Korea for the first time. The estimated ratios were used to validate the Regional Emission inventory in ASia (REAS) version 2.1 based on six study domains (“East China”, “North China”, “Northeast China”, South Korea, North Korea, and Japan). We found that the ΔBC∕ΔCO ratios from four sites converged into a narrow range (6.2–7.9 ng m−3 ppb−1), suggesting consistency in the results from independent observations and similarity in source profiles over the regions. The BC∕CO ratios from the REAS emission inventory (7.7 ng m−3 ppb−1 for East China – 23.2 ng m−3 ppb−1 for South Korea) were overestimated by factors of 1.1 for East China to 3.0 for South Korea, whereas the ratio for North Korea (3.7 ng m−3 ppb−1 from REAS) was underestimated by a factor of 2.0, most likely due to inaccurate emissions from the road transportation sector. Seasonal variation in the BC∕CO ratio from REAS was found to be the highest in winter (China and North Korea) or summer (South Korea and Japan), whereas the measured ΔBC∕ΔCO ratio was the highest in spring in all source regions, indicating the need for further characterization of the seasonality when creating a bottom-up emission inventory. At levels of administrative districts, overestimation in Seoul, the southwestern regions of South Korea, and Northeast China was noticeable, and underestimation was mainly observed in the western regions in North Korea, including Pyongyang. These diagnoses are useful for identifying regions where revisions in the inventory are necessary, providing guidance for the refinement of BC and CO emission rate estimates over East Asia.

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