scholarly journals Twenty years of ground-based NDACC FTIR spectrometry at Izaña Observatory – overview and long-term comparison to other techniques

2021 ◽  
Vol 21 (20) ◽  
pp. 15519-15554
Author(s):  
Omaira E. García ◽  
Matthias Schneider ◽  
Eliezer Sepúlveda ◽  
Frank Hase ◽  
Thomas Blumenstock ◽  
...  
Keyword(s):  
Climate Models ◽  
Measurement Techniques ◽  
Temporal Stability ◽  
Carbonyl Sulfide ◽  
Quality Measurement ◽  
Atmospheric Composition ◽  
Climate Feedback ◽  
Data Sets ◽  
Instrumental Performance

Abstract. High-resolution Fourier transform infrared (FTIR) solar observations are particularly relevant for climate studies, as they allow atmospheric gaseous composition and multiple climate processes to be monitored in detail. In this context, the present paper provides an overview of 20 years of FTIR measurements taken in the framework of the NDACC (Network for the Detection of Atmospheric Composition Change) from 1999 to 2018 at the subtropical Izaña Observatory (IZO, Spain). Firstly, long-term instrumental performance is comprehensively assessed, corroborating the temporal stability and reliable instrumental characterization of the two FTIR spectrometers installed at IZO since 1999. Then, the time series of all trace gases contributing to NDACC at IZO are presented (i.e. C2H6, CH4, ClONO2, CO, HCl, HCN, H2CO, HF, HNO3, N2O, NO2, NO, O3, carbonyl sulfide (OCS), and water vapour isotopologues H216O, H218O, and HD16O), reviewing the major accomplishments drawn from these observations. In order to examine the quality and long-term consistency of the IZO FTIR observations, a comparison of those NDACC products for which other high-quality measurement techniques are available at IZO has been performed (i.e. CH4, CO, H2O, NO2, N2O, and O3). This quality assessment was carried out on different timescales to examine what temporal signals are captured by the FTIR records, and to what extent. After 20 years of operation, the IZO NDACC FTIR observations have been found to be very consistent and reliable over time, demonstrating great potential for climate research. Long-term NDACC FTIR data sets, such as IZO, are indispensable tools for the investigation of atmospheric composition trends, multi-year phenomena, and complex climate feedback processes, as well as for the validation of past and present space-based missions and chemistry climate models.

scholarly journals Twenty years of ground-based NDACC FTIR spectrometry at Izaña Observatory – overview and long-term comparison to other techniques

2021 ◽  
Author(s):  
Omaira E. García ◽  
Matthias Schneider ◽  
Eliezer Sepúlveda ◽  
Frank Hase ◽  
Thomas Blumenstock ◽  
...  
Keyword(s):  
Climate Models ◽  
Measurement Techniques ◽  
Temporal Stability ◽  
Quality Measurement ◽  
Atmospheric Composition ◽  
Climate Feedback ◽  
Data Sets ◽  
Instrumental Performance ◽  
Instrumental Characterisation

Abstract. High-resolution Fourier Transform InfraRed (FTIR) solar observations are particularly relevant for climate studies, as they allow atmospheric gaseous composition and multiple climate processes to be monitored in detail. In this context, the present paper provides an overview of 20 years of FTIR measurements taken in the framework of the NDACC (Network for the Detection of Atmospheric Composition Change) from 1999 to 2018 at the subtropical Izaña Observatory (IZO, Spain). Firstly, long-term instrumental performance is comprehensively assessed, corroborating the temporal stability and reliable instrumental characterisation of the two FTIR spectrometers installed at IZO since 1999. Then, the time series of all trace gases contributing to NDACC at IZO are presented (i.e. C2H6, CH4, ClONO2, CO, HCl, HCN, H2CO, HF, HNO3, N2O, NO2, NO, O3, OCS, and water vapour isotopologues H216O, H218O, and HD16O), reviewing the major accomplishments drawn from these observations. In order to examine the quality and long-term consistency of the IZO FTIR observations, a comparison of those NDACC products for which other high-quality measurement techniques are available at IZO has been performed (i.e. CH4, CO, H2O, NO2, N2O, and O3). This quality assessment was carried out on different timescales to examine what temporal signals, and to what extent, are captured by the FTIR records. After 20 years of operation, the IZO NDACC FTIR observations have been found to be very consistent and reliable over time, demonstrating great potential for climate research. Long-term NDACC FTIR data sets, such as IZO, are indispensable tools for the investigation of atmospheric composition trends, multi-year phenomena and complex climate feedback processes, as well as for the validation of past and present space-based missions and chemistry climate models.

scholarly journals Compatibility of different measurement techniques. Long-term global solar radiation observations at Izaña Observatory

2016 ◽  
Author(s):  
Rosa Delia García ◽  
Emilio Cuevas ◽  
Omaira Elena García ◽  
Ramon Ramón ◽  
Pedro Miguel Romero-Campos ◽  
...  
Keyword(s):  
Time Series ◽  
Solar Radiation ◽  
Sunshine Duration ◽  
Measurement Techniques ◽  
Temporal Stability ◽  
Global Solar Radiation ◽  
Surface Radiation ◽  
Multifilter Rotating Shadowband Radiometer ◽  
High Consistency

Abstract. A 1-year intercomparison of classical and modern radiation and sunshine duration instruments has been performed at Izaña Atmospheric Observatory (IZO) located in Tenerife (Canary Islands, Spain) starting on July 17, 2014. We compare global solar radiation (GSR) records measured with a CM-21 pyranometer Kipp & Zonen, taken in the framework of the Baseline Surface Radiation Network, with those measured with a Multifilter Rotating Shadowband Radiometer (MFRSR), and a bimetallic pyranometer (PYR), and GSR estimated from sunshine duration performed by a Campbell-Stokes sunshine recorder (CS) and a Kipp & Zonen sunshine duration sensor (CSD). Given the GSR BSRN records are subject of strict quality controls (based on principles of physical limits and comparison with the LibRadtran model), they have been used as reference in the intercomparison study. We obtain an overall root mean square error (RMSE) of ~0.9 MJm2 (4 %) for GSR PYR and GSR MFRSR, 1.9 MJm2 (7 %) and 1.2 MJm2 (5 %) for GSR CS and GSR CSD, respectively. Factors such as temperature, fraction of the clear sky, relative humidity and the solar zenith angle have shown to moderately affect the GSR observations. As application of the methodology developed in this work, we have re-evaluated the GSR time series between 1977 and 1991 obtained with two PYRs at IZO. By comparing with coincident GSR estimates from SD observations, we probe the high consistency of those measurements and their temporal stability. These results demonstrate that 1) the continuous-basis intercomparison of different GSR techniques offers important diagnostics for identifying inconsistencies between GSR data records, and 2) the GSR measurements performed with classical and more simple instruments are consistent with more modern techniques and, thus, valid to recover GSR time series and complete worldwide distributed GSR data. The intercomparison and quality assessment of these different techniques have allowed to obtain a complete and consistent long-term global solar radiation series (1977–2015) at Izaña.

scholarly journals Accomplishments of the MUSICA project to provide accurate, long-term, global and high-resolution observations of tropospheric {H<sub>2</sub>O,<i>δ</i>D} pairs – a review

2016 ◽  
Vol 9 (7) ◽  
pp. 2845-2875 ◽  
Author(s):  
Matthias Schneider ◽  
Andreas Wiegele ◽  
Sabine Barthlott ◽  
Yenny González ◽  
Emanuel Christner ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Measurement Techniques ◽  
Remote Sensing Data ◽  
Global Scale ◽  
Horizontal Resolution ◽  
Atmospheric Composition ◽  
Remote Sensing Techniques ◽  
Middle Infrared

Abstract. In the lower/middle troposphere, {H2O,δD} pairs are good proxies for moisture pathways; however, their observation, in particular when using remote sensing techniques, is challenging. The project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water) addresses this challenge by integrating the remote sensing with in situ measurement techniques. The aim is to retrieve calibrated tropospheric {H2O,δD} pairs from the middle infrared spectra measured from ground by FTIR (Fourier transform infrared) spectrometers of the NDACC (Network for the Detection of Atmospheric Composition Change) and the thermal nadir spectra measured by IASI (Infrared Atmospheric Sounding Interferometer) aboard the MetOp satellites. In this paper, we present the final MUSICA products, and discuss the characteristics and potential of the NDACC/FTIR and MetOp/IASI {H2O,δD} data pairs. First, we briefly resume the particularities of an {H2O,δD} pair retrieval. Second, we show that the remote sensing data of the final product version are absolutely calibrated with respect to H2O and δD in situ profile references measured in the subtropics, between 0 and 7 km. Third, we reveal that the {H2O,δD} pair distributions obtained from the different remote sensors are consistent and allow distinct lower/middle tropospheric moisture pathways to be identified in agreement with multi-year in situ references. Fourth, we document the possibilities of the NDACC/FTIR instruments for climatological studies (due to long-term monitoring) and of the MetOp/IASI sensors for observing diurnal signals on a quasi-global scale and with high horizontal resolution. Fifth, we discuss the risk of misinterpreting {H2O,δD} pair distributions due to incomplete processing of the remote sensing products.

scholarly journals Past changes in the vertical distribution of ozone – Part 1: Measurement techniques, uncertainties and availability

2014 ◽  
Vol 7 (5) ◽  
pp. 1395-1427 ◽  
Author(s):  
B. Hassler ◽  
I. Petropavlovskikh ◽  
J. Staehelin ◽  
T. August ◽  
P. K. Bhartia ◽  
...  
Keyword(s):  
Stratospheric Ozone ◽  
Measurement Techniques ◽  
United Nations Environment Programme ◽  
Critical Examination ◽  
Profile Measurement ◽  
Data Sets ◽  
Data Set ◽  
Ozone Profile ◽  
Measurement Uncertainties

Abstract. Peak stratospheric chlorofluorocarbon (CFC) and other ozone depleting substance (ODS) concentrations were reached in the mid- to late 1990s. Detection and attribution of the expected recovery of the stratospheric ozone layer in an atmosphere with reduced ODSs as well as efforts to understand the evolution of stratospheric ozone in the presence of increasing greenhouse gases are key current research topics. These require a critical examination of the ozone changes with an accurate knowledge of the spatial (geographical and vertical) and temporal ozone response. For such an examination, it is vital that the quality of the measurements used be as high as possible and measurement uncertainties well quantified. In preparation for the 2014 United Nations Environment Programme (UNEP)/World Meteorological Organization (WMO) Scientific Assessment of Ozone Depletion, the SPARC/IO3C/IGACO-O3/NDACC (SI2N) Initiative was designed to study and document changes in the global ozone profile distribution. This requires assessing long-term ozone profile data sets in regards to measurement stability and uncertainty characteristics. The ultimate goal is to establish suitability for estimating long-term ozone trends to contribute to ozone recovery studies. Some of the data sets have been improved as part of this initiative with updated versions now available. This summary presents an overview of stratospheric ozone profile measurement data sets (ground and satellite based) available for ozone recovery studies. Here we document measurement techniques, spatial and temporal coverage, vertical resolution, native units and measurement uncertainties. In addition, the latest data versions are briefly described (including data version updates as well as detailing multiple retrievals when available for a given satellite instrument). Archive location information for each data set is also given.

scholarly journals Using XCO<sub>2</sub> retrievals for assessing the long-term consistency of NDACC/FTIR data sets

2014 ◽  
Vol 7 (10) ◽  
pp. 10513-10558
Author(s):  
S. Barthlott ◽  
M. Schneider ◽  
F. Hase ◽  
A. Wiegele ◽  
E. Christner ◽  
...  
Keyword(s):  
Total Carbon ◽  
Atmospheric Composition ◽  
Data Sets ◽  
Mauna Loa ◽  
Simple Regression Model ◽  
Good Consistency ◽  
Term Data

Abstract. Within the NDACC (Network for the Detection of Atmospheric Composition Change), more than 20 FTIR (Fourier–Transform InfraRed) spectrometers, spread worldwide, provide long-term data records of many atmospheric trace gases. We present a method that uses measured and modelled XCO2 for assessing the consistency of these data records. Our NDACC XCO2 retrieval setup is kept simple so that it can easily be adopted for any NDACC/FTIR-like measurement made since the late 1950s. By a comparison to coincident TCCON (Total Carbon Column Observing Network) measurements, we empirically demonstrate the useful quality of this NDACC XCO2 product (empirically obtained scatter between TCCON and NDACC is about 4‰ for daily mean as well as monthly mean comparisons and the bias is 25‰). As XCO2 model we developed and used a simple regression model fitted to CarbonTracker results and the Mauna Loa CO2 in-situ records. A comparison to TCCON data suggests an uncertainty of the model for monthly mean data of below 3‰. We apply the method to the NDACC/FTIR spectra that are used within the project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water) and demonstrate that there is a good consistency for these globally representative set of spectra measured since 1996: the scatter between the modelled and measured XCO2 on a yearly time scale is only 3‰.

scholarly journals Evaluation of new laser spectrometer techniques for in-situ carbon monoxide measurements

2012 ◽  
Vol 5 (10) ◽  
pp. 2555-2567 ◽  
Author(s):  
C. Zellweger ◽  
M. Steinbacher ◽  
B. Buchmann
Keyword(s):  
Carbon Monoxide ◽  
Measurement Techniques ◽  
Field Measurements ◽  
Current Data ◽  
Atmospheric Composition ◽  
Environmental Research ◽  
Spectroscopic Techniques ◽  
New Techniques

Abstract. Long-term time series of the atmospheric composition are essential for environmental research and thus require compatible, multi-decadal monitoring activities. The current data quality objectives of the World Meteorological Organization (WMO) for carbon monoxide (CO) in the atmosphere are very challenging to meet with the measurement techniques that have been used until recently. During the past few years, new spectroscopic techniques came to market with promising properties for trace gas analytics. The current study compares three instruments that have recently become commercially available (since 2011) with the best currently available technique (Vacuum UV Fluorescence) and provides a link to previous comparison studies. The instruments were investigated for their performance regarding repeatability, reproducibility, drift, temperature dependence, water vapour interference and linearity. Finally, all instruments were examined during a short measurement campaign to assess their applicability for long-term field measurements. It could be shown that the new techniques perform considerably better compared to previous techniques, although some issues, such as temperature influence and cross sensitivities, need further attention.

scholarly journals Updated tropospheric chemistry reanalysis and emission estimates, TCR-2, for 2005–2018

2020 ◽  
Vol 12 (3) ◽  
pp. 2223-2259 ◽  
Author(s):  
Kazuyuki Miyazaki ◽  
Kevin Bowman ◽  
Takashi Sekiya ◽  
Henk Eskes ◽  
Folkert Boersma ◽  
...  
Keyword(s):  
Transport Model ◽  
Horizontal Resolution ◽  
Tropospheric Chemistry ◽  
Atmospheric Composition ◽  
Data Sets ◽  
Vertical Profiles ◽  
Chemical Transport Model ◽  
Near Surface ◽  
Key Species

Abstract. This study presents the results from the Tropospheric Chemistry Reanalysis version 2 (TCR-2) for the period 2005–2018 at 1.1∘ horizontal resolution obtained from the assimilation of multiple updated satellite measurements of ozone, CO, NO2, HNO3, and SO2 from the OMI, SCIAMACHY, GOME-2, TES, MLS, and MOPITT satellite instruments. The reanalysis calculation was conducted using a global chemical transport model MIROC-CHASER and an ensemble Kalman filter technique that optimizes both chemical concentrations of various species and emissions of several precursors, which was efficient for the correction of the entire tropospheric profile of various species and its year-to-year variations. Comparisons against independent aircraft, satellite, and ozonesonde observations demonstrate the quality of the reanalysis fields for numerous key species on regional and global scales, as well as for seasonal, yearly, and decadal scales, from the surface to the lower stratosphere. The multi-constituent data assimilation brought the model vertical profiles and interhemispheric gradient of OH closer to observational estimates, which was important in improving the description of the oxidation capacity of the atmosphere and thus vertical profiles of various species. The evaluation results demonstrate the capability of the chemical reanalysis to improve understanding of the processes controlling variations in atmospheric composition, including long-term changes in near-surface air quality and emissions. The estimated emissions can be employed for the elucidation of detailed distributions of the anthropogenic and biomass burning emissions of co-emitted species (NOx, CO, SO2) in all major regions, as well as their seasonal and decadal variabilities. The data sets are available at https://doi.org/10.25966/9qgv-fe81 (Miyazaki et al., 2019a).

scholarly journals Relative drifts and stability of satellite and ground-based stratospheric ozone profiles at NDACC lidar stations

2012 ◽  
Vol 5 (6) ◽  
pp. 1301-1318 ◽  
Author(s):  
P. J. Nair ◽  
S. Godin-Beekmann ◽  
L. Froidevaux ◽  
L. E. Flynn ◽  
J. M. Zawodny ◽  
...  
Keyword(s):  
Stratospheric Ozone ◽  
Measurement Techniques ◽  
Data Sets ◽  
Data Set ◽  
Meteorological Observatory ◽  
The Stability ◽  
Combined Time Series ◽  
Relative Differences ◽  
Term Data

Abstract. The long-term evolution of stratospheric ozone at different stations in the low and mid-latitudes is investigated. The analysis is performed by comparing the collocated profiles of ozone lidars, at the northern mid-latitudes (Meteorological Observatory Hohenpeißenberg, Haute-Provence Observatory, Tsukuba and Table Mountain Facility), tropics (Mauna Loa Observatory) and southern mid-latitudes (Lauder), with ozonesondes and space-borne sensors (SBUV(/2), SAGE II, HALOE, UARS MLS and Aura MLS), extracted around the stations. Relative differences are calculated to find biases and temporal drifts in the measurements. All measurement techniques show their best agreement with respect to the lidar at 20–40 km, where the differences and drifts are generally within ±5% and ±0.5% yr−1, respectively, at most stations. In addition, the stability of the long-term ozone observations (lidar, SBUV(/2), SAGE II and HALOE) is evaluated by the cross-comparison of each data set. In general, all lidars and SBUV(/2) exhibit near-zero drifts and the comparison between SAGE II and HALOE shows larger, but insignificant drifts. The RMS of the drifts of lidar and SBUV(/2) is 0.22 and 0.27% yr−1, respectively at 20–40 km. The average drifts of the long-term data sets, derived from various comparisons, are less than ±0.3% yr−1 in the 20–40 km altitude at all stations. A combined time series of the relative differences between SAGE II, HALOE and Aura MLS with respect to lidar data at six sites is constructed, to obtain long-term data sets lasting up to 27 years. The relative drifts derived from these combined data are very small, within ±0.2% yr−1.

scholarly journals Intercomparison of vertically resolved merged satellite ozone data sets: interannual variability and long-term trends

2015 ◽  
Vol 15 (6) ◽  
pp. 3021-3043 ◽  
Author(s):  
F. Tummon ◽  
B. Hassler ◽  
N. R. P. Harris ◽  
J. Staehelin ◽  
W. Steinbrecht ◽  
...  
Keyword(s):  
Interannual Variability ◽  
Atmospheric Chemistry ◽  
Lower Stratosphere ◽  
Piecewise Linear ◽  
Atmospheric Composition ◽  
Data Sets ◽  
Ozone Data ◽  
Long Term Trends ◽  
Clear Shift

Abstract. In the framework of the SI2N (SPARC (Stratosphere-troposphere Processes And their Role in Climate)/IO3C (International Ozone Commission)/IGACO-O3 (Integrated Global Atmospheric Chemistry Observations – Ozone)/NDACC (Network for the Detection of Atmospheric Composition Change)) initiative, several long-term vertically resolved merged ozone data sets produced from satellite measurements have been analysed and compared. This paper presents an overview of the methods, assumptions, and challenges involved in constructing such merged data sets, as well as the first thorough intercomparison of seven new long-term satellite data sets. The analysis focuses on the representation of the annual cycle, interannual variability, and long-term trends for the period 1984–2011, which is common to all data sets. Overall, the best agreement amongst data sets is seen in the mid-latitude lower and middle stratosphere, with larger differences in the equatorial lower stratosphere and the upper stratosphere globally. In most cases, differences in the choice of underlying instrument records that were merged produced larger differences between data sets than the use of different merging techniques. Long-term ozone trends were calculated for the period 1984–2011 using a piecewise linear regression with a change in trend prescribed at the end of 1997. For the 1984–1997 period, trends tend to be most similar between data sets (with largest negative trends ranging from −4 to −8% decade−1 in the mid-latitude upper stratosphere), in large part due to the fact that most data sets are predominantly (or only) based on the SAGE-II record. Trends in the middle and lower stratosphere are much smaller, and, particularly for the lower stratosphere, large uncertainties remain. For the later period (1998–2011), trends vary to a greater extent, ranging from approximately −1 to +5% decade−1 in the upper stratosphere. Again, middle and lower stratospheric trends are smaller and for most data sets not significantly different from zero. Overall, however, there is a clear shift from mostly negative to mostly positive trends between the two periods over much of the profile.

scholarly journals Using XCO<sub>2</sub> retrievals for assessing the long-term consistency of NDACC/FTIR data sets

2015 ◽  
Vol 8 (3) ◽  
pp. 1555-1573 ◽  
Author(s):  
S. Barthlott ◽  
M. Schneider ◽  
F. Hase ◽  
A. Wiegele ◽  
E. Christner ◽  
...  
Keyword(s):  
Total Carbon ◽  
Atmospheric Composition ◽  
Data Sets ◽  
Mauna Loa ◽  
Simple Regression Model ◽  
Good Consistency ◽  
Term Data

Abstract. Within the NDACC (Network for the Detection of Atmospheric Composition Change), more than 20 FTIR (Fourier-transform infrared) spectrometers, spread worldwide, provide long-term data records of many atmospheric trace gases. We present a method that uses measured and modelled XCO2 for assessing the consistency of these NDACC data records. Our XCO2 retrieval setup is kept simple so that it can easily be adopted for any NDACC/FTIR-like measurement made since the late 1950s. By a comparison to coincident TCCON (Total Carbon Column Observing Network) measurements, we empirically demonstrate the useful quality of this suggested NDACC XCO2 product (empirically obtained scatter between TCCON and NDACC is about 4‰ for daily mean as well as monthly mean comparisons, and the bias is 25‰). Our XCO2 model is a simple regression model fitted to CarbonTracker results and the Mauna Loa CO2 in situ records. A comparison to TCCON data suggests an uncertainty of the model for monthly mean data of below 3‰. We apply the method to the NDACC/FTIR spectra that are used within the project MUSICA (multi-platform remote sensing of isotopologues for investigating the cycle of atmospheric water) and demonstrate that there is a good consistency for these globally representative set of spectra measured since 1996: the scatter between the modelled and measured XCO2 on a yearly time scale is only 3‰.

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