scholarly journals Air-sea fluxes of biogenic bromine from the tropical and North Atlantic Ocean

2009 ◽  
Vol 9 (5) ◽  
pp. 1805-1816 ◽  
Author(s):  
L. J. Carpenter ◽  
C. E. Jones ◽  
R. M. Dunk ◽  
K. E. Hornsby ◽  
J. Woeltjen
Keyword(s):  
Atlantic Ocean ◽  
Coastal Upwelling ◽  
North Atlantic Ocean ◽  
Open Ocean ◽  
Anthropogenic Sources ◽  
Coastal Regions ◽  
Power Stations ◽  
Eastern Atlantic Ocean ◽  
Elevated Surface ◽  
June July

Abstract. Air-sea fluxes and bulk seawater and atmospheric concentrations of bromoform (CHBr3) and dibromomethane (CH2Br2) were measured during two research cruises in the northeast Atlantic (53–59° N, June–July 2006) and tropical eastern Atlantic Ocean including over the African coastal upwelling system (16–35° N May–June 2007). Saturations and sea-air fluxes of these compounds generally decreased in the order coastal > upwelling > shelf > open ocean, and outside of coastal regions, a broad trend of elevated surface seawater concentrations with high chlorophyll-a was observed. We show that upwelling regions (coastal and equatorial) represent regional hot spots of bromocarbons, but are probably not of major significance globally, contributing at most a few percent of the total global emissions of CHBr3 and CH2Br2. From limited data from eastern Atlantic coastlines, we tentatively suggest that globally, coastal oceans (depth <180 m) together contribute ~2.5 (1.4–3.5) Gmol Br yr−1 of CHBr3, excluding influences from anthropogenic sources such as coastal power stations. This flux estimate is close to current estimates of the total open ocean source. We also show that the concentration ratio of CH2Br2/CHBr3 in seawater is a strong function of concentration (and location), with a lower CH2Br2/CHBr3 ratio found in coastal regions near to macroalgal sources.

scholarly journals Air-sea fluxes of biogenic bromine from the tropical and North Atlantic Ocean

2008 ◽  
Vol 8 (5) ◽  
pp. 18409-18435 ◽  
Author(s):  
L. J. Carpenter ◽  
C. E. Jones ◽  
R. M. Dunk ◽  
K. E. Hornsby
Keyword(s):  
Atlantic Ocean ◽  
Coastal Upwelling ◽  
North Atlantic Ocean ◽  
Limited Data ◽  
Strong Function ◽  
Eastern Atlantic Ocean ◽  
Elevated Surface ◽  
June July ◽  
Global Emissions ◽  
Atmospheric Concentrations

Abstract. Air-sea fluxes and bulk seawater and atmospheric concentrations of bromoform (CHBr3) and dibromomethane (CH2Br2) were measured during two research cruises in the northeast Atlantic (53–59° N, June–July 2006) and tropical eastern Atlantic Ocean including over the African coastal upwelling system (16–35° N May–June 2007). Saturations and sea-air fluxes of these compounds generally decrease in the order coastal>upwelling>shelf>open ocean, and a broad trend of elevated surface seawater concentrations with high chlorophylla was observed. From limited data from eastern Atlantic coastlines, we tentatively suggest that globally, coastal and coastally-influenced waters together contribute ~2.4 Gmol Br yr−1 (24–56%) of CHBr3. We show that upwelling regions (coastal and equatorial) represent regional hot spots of bromocarbons, but are probably not of major significance globally, contributing only a few percent of the total global emissions of CHBr3 and CH2Br2. We also show that the concentration ratio of CH2Br2/CHBr3 in seawater is a strong function of concentration (and location), with a lower CH2Br2/CHBr3 ratio found in coastal regions near to macroalgal sources.

scholarly journals Long-term trends in aerosol and precipitation composition over the western North Atlantic Ocean at Bermuda

2014 ◽  
Vol 14 (5) ◽  
pp. 7025-7066 ◽  
Author(s):  
W. C. Keene ◽  
J. L. Moody ◽  
J. N. Galloway ◽  
J. M. Prospero ◽  
O. R. Cooper ◽  
...  
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Flow Regimes ◽  
The United States ◽  
Open Ocean ◽  
Anthropogenic Sources ◽  
Trade Wind ◽  
Chemical Compositions ◽  
Near Surface

Abstract. Since the 1980s, emissions of SO2 and NOx (NO + NO2) from anthropogenic sources in the United States (US) and Europe have decreased significantly suggesting that the export of oxidized S and N compounds from surrounding continents to the atmosphere overlying North Atlantic Ocean (NAO) has also decreased. The chemical compositions of aerosols and precipitation sampled daily on Bermuda (32.27° N, 64.87° W) from 1989 to 1997 and from 2006 to 2009 were evaluated to quantify the magnitudes, significance, and implications of associated tends in atmospheric composition. The chemical data were stratified based on FLEXPART retroplumes into four discrete transport regimes: westerly flow from the eastern North America (NEUS/SEUS); easterly trade-wind flow from northern Africa and the subtropical NAO (Africa); long, open-ocean, anticyclonic flow around the Bermuda High (Oceanic); and transitional flow from the relatively clean open ocean to the polluted northeastern US (North). Based on all data, annual average concentrations of non-sea-salt (nss) SO42- associated with aerosols and annual VWA concentrations in precipitation decreased significantly (by 22 and 49%, respectively) whereas annual VWA concentrations of NH4+ in precipitation increased significantly (by 70%). Corresponding trends in aerosol and precipitation NO3- and of aerosol NH4+ were insignificant. Nss SO42- in precipitation under NEUS/SEUS and Oceanic flow decreased significantly (61% each) whereas corresponding trends in particulate nss SO42- under both flow regimes were insignificant. Trends for precipitation were driven in part by decreasing emissions of SO2 over upwind continents and associated decreases in anthropogenic contributions to nss SO42- concentrations. Under NEUS/SEUS and Oceanic flow, the ratio of anthropogenic to biogenic contributions to to nss SO42- in the column scavenged by precipitation were relatively greater than those in near surface aerosol, which implies that, for these flow regimes, precipitation is a better indicator of overall anthropogenic impacts on the lower troposphere. Particulate nss SO42- under African flow also decreased significantly (34%) whereas the corresponding decrease in nss SO42- associated with precipitation was marginally insignificant. We infer that these trends were driven in part by reductions in the emissions and transport of oxidized S compounds from Europe. The lack of significant trends in NO3- associated with aerosols and precipitation under NEUS/SEUS flow is notable in light of the large decrease (39%) in NOx emissions in the US over the period of record. Rapid chemical processing of oxidized N in marine air contributed to this lack of correspondence. Decreasing ratios of nss SO42- to NH4+ and the significant decreasing trend in precipitation acidity (37%) indicate that the total amount of acidity in the multiphase gas-aerosol system in the western NAO troposphere decreased over the period of record. Decreasing aerosol acidities would have shifted the phase partitioning of total NH3 (NH3 + particulate NH4+) towards the gas phase thereby decreasing the atmospheric lifetime of total NH3 against wet plus dry deposition. The trend of increasing NH4+ in precipitation at Bermuda over the period of record suggests that NH3 emissions from surrounding continents also increased. Decreasing particulate nss SO42- in near-surface air under NEUS/SEUS flow over the period of record suggests a lower limit for net warming in the range of 0.1–0.3 W m-2 resulting from the decreased shortwave scattering and absorption by nss SO42- and associated aerosol constituents.

scholarly journals Long-term trends in aerosol and precipitation composition over the western North Atlantic Ocean at Bermuda

2014 ◽  
Vol 14 (15) ◽  
pp. 8119-8135 ◽  
Author(s):  
W. C. Keene ◽  
J. L. Moody ◽  
J. N. Galloway ◽  
J. M. Prospero ◽  
O. R. Cooper ◽  
...  
Keyword(s):  
North America ◽  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Flow Regimes ◽  
Open Ocean ◽  
Anthropogenic Sources ◽  
Trade Wind ◽  
Eastern North America ◽  
Near Surface

Abstract. Since the 1980s, emissions of SO2 and NOx (NO + NO2) from anthropogenic sources in the United States (US), Canada, and Europe have decreased significantly suggesting that the export of oxidized S and N compounds from surrounding continents to the atmosphere overlying the North Atlantic Ocean (NAO) has also decreased. The chemical compositions of aerosols and precipitation sampled daily on Bermuda (32.27° N, 64.87° W) from 1989 to 1997 and from 2006 to 2009 were evaluated to quantify the magnitudes, significance, and implications of associated tends in atmospheric composition. The chemical data were stratified based on FLEXPART (FLEXible PARTicle dispersion model) retroplumes into four discrete transport regimes: westerly flow from eastern North America (NEUS/SEUS); easterly trade-wind flow from northern Africa and the subtropical NAO (Africa); long, open-ocean, anticyclonic flow around the Bermuda High (Oceanic); and transitional flow from the relatively clean open ocean to the polluted eastern North America (North). Based on all data, annual average concentrations of non-sea-salt (nss) SO42– associated with aerosols and annual volume-weighted-average (VWA) concentrations in precipitation decreased significantly (by 22% and 49%, respectively) whereas annual VWA concentrations of NH4+ in precipitation increased significantly (by 70%). Corresponding trends in aerosol and precipitation NO3– and of aerosol NH4+ were insignificant. Nss SO42– in precipitation under NEUS/SEUS and Oceanic flow decreased significantly (61% each) whereas corresponding trends in particulate nss SO42– under both flow regimes were insignificant. Trends in precipitation composition were driven in part by decreasing emissions of SO2 over upwind continents and associated decreases in anthropogenic contributions to nss SO42– concentrations. Under NEUS/SEUS and Oceanic flow, the ratio of anthropogenic to biogenic contributions to nss SO42– in the column scavenged by precipitation were relatively greater than those in near surface aerosol, which implies that, for these flow regimes, precipitation is a better indicator of overall anthropogenic impacts on the lower troposphere. Particulate nss SO42– under African flow also decreased significantly (34%) whereas the corresponding decrease in nss SO42– associated with precipitation was insignificant. We infer that these trends were driven in part by reductions in the emissions and transport of oxidized S compounds from Europe. The lack of significant trends in NO3– associated with aerosols and precipitation under NEUS/SEUS flow is notable in light of the large decrease (37%) in NOx emissions in the US and Canada over the period of record. Rapid chemical processing of oxidized N in marine air contributed to this lack of correspondence. Decreasing ratios of nss SO42– to NH4+ and the significant decreasing trend in precipitation acidity (37%) indicate that the total amount of acidity in the multiphase gas–aerosol system in the western NAO troposphere decreased over the period of record. Decreasing aerosol acidities would have shifted the phase partitioning of total NH3 (NH3 + particulate NH4+ towards the gas phase thereby decreasing the atmospheric lifetime of total NH3 against wet plus dry deposition. The trend of increasing NH4+ in precipitation at Bermuda over the period of record suggests that NH3 emissions from surrounding continents also increased. Decreasing particulate nss SO42– in near-surface air under NEUS/SEUS flow over the period of record implies that the corresponding shortwave scattering and absorption by nss S and associated aerosols constituents also decreased. These changes in radiative transfer suggest a corresponding lower limit for net warming over the period in the range of 0.1–0.3 W m–2.

scholarly journals Bromocarbons in the tropical coastal and open ocean atmosphere during the 2009 Prime Expedition Scientific Cruise (PESC-09)

2014 ◽  
Vol 14 (15) ◽  
pp. 8137-8148 ◽  
Author(s):  
M. S. Mohd Nadzir ◽  
S. M. Phang ◽  
M. R. Abas ◽  
N. Abdul Rahman ◽  
A. Abu Samah ◽  
...  
Keyword(s):  
Chlorophyll A ◽  
Statistical Tests ◽  
Open Ocean ◽  
Common Source ◽  
Sampling Point ◽  
Coastal Regions ◽  
Chl A ◽  
June July ◽  
Strait Of Malacca

Abstract. Atmospheric concentrations of very short-lived species (VSLS) bromocarbons, including CHBr3, CH2Br2, CHCl2Br, CHClBr2, and CH2BrCl, were measured in the Strait of Malacca and the South China and Sulu–Sulawesi seas during a two-month research cruise in June–July 2009. The highest bromocarbon concentrations were found in the Strait of Malacca, with smaller enhancements in coastal regions of northern Borneo. CHBr3 was the most abundant bromocarbon, ranging from 5.2 pmol mol−1 in the Strait of Malacca to 0.94 pmol mol−1 over the open ocean. Other bromocarbons showed lower concentrations, in the range of 0.8–1.3 pmol mol−1 for CH2Br2, 0.1–0.5 pmol mol−1 for CHCl2Br, and 0.1–0.4 pmol mol−1 for CHClBr2. There was no significant correlation between bromocarbons and in situ chlorophyll a, but positive correlations with both MODIS and SeaWiFS satellite chlorophyll a. Together, the short-lived bromocarbons contribute an average of 8.9 pmol mol−1 (range 5.2–21.4 pmol mol−1) to tropospheric bromine loading, which is similar to that found in previous studies from global sampling networks (Montzka et al., 2011). Statistical tests showed strong Spearman correlations between brominated compounds, suggesting a common source. Log–log plots of CHBr3/CH2Br2 versus CHBr2Cl/CH2Br2 show that both chemical reactions and dilution into the background atmosphere contribute to the composition of these halocarbons at each sampling point. We have used the correlation to make a crude estimate of the regional emissions of CHBr3 and to derive a value of 32 Gg yr−1 for the Southeast (SE) Asian region (10° N–20° S, 90–150° E). Finally, we note that satellite-derived chlorophyll a (chl a) products do not always agree well with in situ measurements, particularly in coastal regions of high turbidity, meaning that satellite chl a may not always be a good proxy for marine productivity.

scholarly journals Winter- and summertime continental influences on tropospheric O<sub>3</sub> and CO observed by TES over the western North Atlantic Ocean

2010 ◽  
Vol 10 (8) ◽  
pp. 3723-3741 ◽  
Author(s):  
J. Hegarty ◽  
H. Mao ◽  
R. Talbot
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
A Priori ◽  
Distribution Patterns ◽  
Conveyor Belt ◽  
Shallow Convection ◽  
Mixing Ratios ◽  
The Us ◽  
June July

Abstract. The distributions of tropospheric ozone (O3) and carbon monoxide (CO), and the synoptic factors regulating these distributions over the western North Atlantic Ocean during winter and summer were investigated using profile retrievals from the Tropospheric Emission Spectrometer (TES) for 2004–2006. Seasonal composites of TES retrievals, reprocessed to remove the influence of the a priori on geographical and seasonal structure, exhibited strong seasonal differences. At the 681 hPa level during winter months of December, January and February (DJF) the composite O3 mixing ratios were uniformly low (~45 ppbv), but continental export was evident in a channel of enhanced CO (100–110 ppbv) flowing eastward from the US coast. In summer months June, July, and August (JJA) O3 mixing ratios were variable (45–65 ppbv) and generally higher due to increased photochemical production. The summer distribution also featured a channel of enhanced CO (95–105 ppbv) flowing northeastward around an anticyclone and exiting the continent over the Canadian Maritimes around 50° N. Offshore O3-CO slopes were generally 0.15–0.20 mol mol−1 in JJA, indicative of photochemical O3 production. Composites for 4 predominant synoptic patterns or map types in DJF suggested that export to the lower free troposphere (681 hPa level) was enhanced by the warm conveyor belt airstream of mid-latitude cyclones while stratospheric intrusions increased TES O3 levels at 316 hPa. A major finding in the DJF data was that offshore 681 hPa CO mixing ratios behind cold fronts could be enhanced up to >150 ppbv likely by lofting from the surface via shallow convection resulting from rapid destabilization of cold air flowing over much warmer ocean waters. In JJA composites for 3 map types showed that the general export pattern of the seasonal composites was associated with a synoptic pattern featuring the Bermuda High. However, weak cyclones and frontal troughs could enhance offshore 681 hPa CO mixing ratios to >110 ppbv with O3-CO slopes >0.50 mol mol−1 south of 45° N. Intense cyclones, which were not as common in the summer, enhanced export by lofting of boundary layer pollutants from over the US and also provided a possible mechanism for transporting pollutants from boreal fire outflow southward to the US east coast. Overall, for winter and summer the TES retrievals showed substantial evidence of air pollution export to the western North Atlantic Ocean with the most distinct differences in distribution patterns related to strong influences of mid-latitude cyclones in winter and the Bermuda High anticyclone in summer.

scholarly journals Winter- and summertime continental influences on tropospheric O<sub>3</sub> and CO observed by TES over the western North Atlantic Ocean

2009 ◽  
Vol 9 (6) ◽  
pp. 23211-23269
Author(s):  
J. Hegarty ◽  
H. Mao ◽  
R. Talbot
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
A Priori ◽  
Conveyor Belt ◽  
Shallow Convection ◽  
Circulation Patterns ◽  
The Us ◽  
Export Pattern ◽  
June July

Abstract. The distribution of tropospheric O3 and CO and the regulating factors over the western North Atlantic Ocean during winter (December, January, and February, DJF) and summer (June, July, August, JJA) were investigated using retrievals from the Tropospheric Emission Spectrometer (TES) for 2004–2006. Seasonal composites of TES retrievals, reprocessed to remove the artificial geographic and seasonal structure added from the a priori, exhibited strong seasonal differences. At the 681 hPa level during winter composite O3 levels were uniformly low (~45 ppbv), but continental export was evident in a channel of enhanced CO (100–110 ppbv) flowing eastward from the US coast. In summer O3 levels were variable (45–65 ppbv) and generally higher due to increased photochemical production. The main export pathway featured a channel of enhanced CO (95–105 ppbv) flowing northeastward around an anticyclone and exiting the continent over the Canadian Maritimes around 50° N. Offshore O3-CO slopes were generally 0.15–0.20 mol mol−1 in JJA, indicative of photochemical O3 production. Composites for 4 predominant circulation patterns or map types in DJF revealed that export to the lower free troposphere (681 hPa level) was enhanced by the warm conveyor belt (WCB) airstream of cyclones while stratospheric intrusions increased TES O3 levels at 316 hPa. A major finding in the DJF data was that offshore 681 hPa CO levels behind cold fronts could be enhanced up to >150 ppbv likely by lofting from the surface via shallow convection resulting from rapid destabilization of cold air flowing over much warmer ocean waters. In JJA composites for 5 map types showed that the main export pattern of seasonal composites contained the Bermuda High as the dominate feature. However, weak cyclones and frontal troughs could enhance offshore 681 hPa CO levels to greater than 110 ppbv with O3-CO slopes >0.50 mol mol−1 south of 45° N. Intense cyclones, which were not as common in the summer, enhanced export by lofting of boundary layer pollutants from over the US and also provided a possible mechanism for transporting pollutants from boreal fire outflow southward to the US east coast.

Island in the Stream: Oceanography and Fisheries of the Charleston Bump

2001 ◽  
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Single Species ◽  
Common Species ◽  
Open Ocean ◽  
Commercially Important ◽  
In Situ Observations ◽  
Charleston Bump

<em>Abstract.</em>—Recent observations from trawling and submersibles have shown several species of cephalopods to be common in slope-waters of the western North Atlantic Ocean. The slope-water cephalopods include the commercially-important genus <em> Illex</em>, taxonomy of which remains troubling in the area off Charleston because of the possibility that <em> I. oxygonius </em>is a hybrid. Other common species include another ommastrephid <em> Ornithoteuthis antillarum</em>, single species of <em> Mastigoteuthis</em>, <em> Brachioteuthis</em>, and <em> Pholidoteuthis</em>, several cranchiids, histioteuthids, and sepiolids, two octopodids, the pelagic incirrate octopod <em> Haliphron atlanticus</em>, and the cirrate octopod <em> Stauroteuthis syrtensis</em>. Behavior and distribution of these species contrast with those of truly open-ocean cephalopods, which also are present in slope waters. In-situ observations have shown that several of the squids are more strongly associated with the bottom than was previously supposed and that many of the slope-water cephalopods exhibit unexpected behaviors.

scholarly journals Recent Decadal Trend in the North Atlantic Wind Energy Resources

2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Chong Wei Zheng ◽  
Chong Yin Li ◽  
Xin Li
Keyword(s):  
Atlantic Ocean ◽  
Wind Energy ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Climatic Trend ◽  
The North ◽  
Increasing Trend ◽  
The North Atlantic ◽  
The North Atlantic Oscillation ◽  
June July

This study presents the climatic trend of the North Atlantic wind energy using cross-calibrated, multiplatform (CCMP) wind data for the period 1988–2011. Results show the following. (1) The North Atlantic WPD exhibited a significant increasing trend of 4.45  (W/m2)/yr over the past 24 years. (2) The variation in the North Atlantic Ocean WPD shows a noticeable regional difference. More than half of the North Atlantic Ocean has a significantly increasing trend in WPD. The increasing trend in the mid-high latitudes is stronger than that in the low latitudes, and the trend is stronger in the west than in the east. The area with the strongest increasing trend is located along the southern coast of Greenland of 35 (W/m2)/yr. (3) There is a noticeable seasonal difference in the variation of WPD. The strongest increasing trend occurs in December-January-February (DJF), followed by September-October-November (SON) and March-April-May (MAM), and the weakest occurs in June-July-August (JJA). The increasing trend in different areas is dominated by different seasons. (4) There is no leading or lagging correlation between WPD and the North Atlantic Oscillation (NAO). However, there is a noticeable negative correlation between the Niño3 index and WPD in most of the North Atlantic.

A Hemisessile Sea Anemone from the Porcupine Abyssal Plain, North Atlantic Ocean: Iosactis Vagabunda gen. nov., sp. nov.

1997 ◽  
Vol 77 (4) ◽  
pp. 1011-1025 ◽  
Author(s):  
Karin Riemann-Zürneck
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic Ocean ◽  
Benthic Fauna ◽  
Time Lapse ◽  
Abundant Species ◽  
Sea Anemone ◽  
Abyssal Plain ◽  
The North ◽  
New Family ◽  
Eastern Atlantic Ocean

The Porcupine Abyssal Plain in the north-eastern Atlantic Ocean is subject to periodical deposition of phytodetritus and has a highly diverse benthic fauna dependent on this source of organic matter. Among the most abundant species from the northern study site of the Institute of Oceanographic Sciences Deacon Laboratory (IOSDL) at ~48°50′N 16°30′W, 4850 m, is Iosactis vagabunda gen. nov., sp. nov. (Cnidaria: Actiniaria, Iosactiidae fam. nov.), a small endomyarian sea anemone. The fact that this species is a burrower, with a smooth, unspecialized column, and a rounded aboral end provided with a central pit, makes it stand out from the other families of endomyarian anemones and prompted the establishment of the new family Iosactiidae. There is evidence that the closest relatives of the new family are the ‘deep water actiniids’ (e.g. Bolocera, Liponema, Leipsiceras), and the Andresiidae. Long-term in situ time-lapse photographs indicate a unique behaviour of this anemone in that it moves out of its hole at times, presumably exhibiting a hemisessile lifestyle in this peculiar abyssal habitat.

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