scholarly journals Long-term trends in aerosol and precipitation composition over the western North Atlantic Ocean at Bermuda

2014 ◽  
Vol 14 (5) ◽  
pp. 7025-7066 ◽  
Author(s):  
W. C. Keene ◽  
J. L. Moody ◽  
J. N. Galloway ◽  
J. M. Prospero ◽  
O. R. Cooper ◽  
...  
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Flow Regimes ◽  
The United States ◽  
Open Ocean ◽  
Anthropogenic Sources ◽  
Trade Wind ◽  
Chemical Compositions ◽  
Near Surface

Abstract. Since the 1980s, emissions of SO2 and NOx (NO + NO2) from anthropogenic sources in the United States (US) and Europe have decreased significantly suggesting that the export of oxidized S and N compounds from surrounding continents to the atmosphere overlying North Atlantic Ocean (NAO) has also decreased. The chemical compositions of aerosols and precipitation sampled daily on Bermuda (32.27° N, 64.87° W) from 1989 to 1997 and from 2006 to 2009 were evaluated to quantify the magnitudes, significance, and implications of associated tends in atmospheric composition. The chemical data were stratified based on FLEXPART retroplumes into four discrete transport regimes: westerly flow from the eastern North America (NEUS/SEUS); easterly trade-wind flow from northern Africa and the subtropical NAO (Africa); long, open-ocean, anticyclonic flow around the Bermuda High (Oceanic); and transitional flow from the relatively clean open ocean to the polluted northeastern US (North). Based on all data, annual average concentrations of non-sea-salt (nss) SO42- associated with aerosols and annual VWA concentrations in precipitation decreased significantly (by 22 and 49%, respectively) whereas annual VWA concentrations of NH4+ in precipitation increased significantly (by 70%). Corresponding trends in aerosol and precipitation NO3- and of aerosol NH4+ were insignificant. Nss SO42- in precipitation under NEUS/SEUS and Oceanic flow decreased significantly (61% each) whereas corresponding trends in particulate nss SO42- under both flow regimes were insignificant. Trends for precipitation were driven in part by decreasing emissions of SO2 over upwind continents and associated decreases in anthropogenic contributions to nss SO42- concentrations. Under NEUS/SEUS and Oceanic flow, the ratio of anthropogenic to biogenic contributions to to nss SO42- in the column scavenged by precipitation were relatively greater than those in near surface aerosol, which implies that, for these flow regimes, precipitation is a better indicator of overall anthropogenic impacts on the lower troposphere. Particulate nss SO42- under African flow also decreased significantly (34%) whereas the corresponding decrease in nss SO42- associated with precipitation was marginally insignificant. We infer that these trends were driven in part by reductions in the emissions and transport of oxidized S compounds from Europe. The lack of significant trends in NO3- associated with aerosols and precipitation under NEUS/SEUS flow is notable in light of the large decrease (39%) in NOx emissions in the US over the period of record. Rapid chemical processing of oxidized N in marine air contributed to this lack of correspondence. Decreasing ratios of nss SO42- to NH4+ and the significant decreasing trend in precipitation acidity (37%) indicate that the total amount of acidity in the multiphase gas-aerosol system in the western NAO troposphere decreased over the period of record. Decreasing aerosol acidities would have shifted the phase partitioning of total NH3 (NH3 + particulate NH4+) towards the gas phase thereby decreasing the atmospheric lifetime of total NH3 against wet plus dry deposition. The trend of increasing NH4+ in precipitation at Bermuda over the period of record suggests that NH3 emissions from surrounding continents also increased. Decreasing particulate nss SO42- in near-surface air under NEUS/SEUS flow over the period of record suggests a lower limit for net warming in the range of 0.1–0.3 W m-2 resulting from the decreased shortwave scattering and absorption by nss SO42- and associated aerosol constituents.

scholarly journals Long-term trends in aerosol and precipitation composition over the western North Atlantic Ocean at Bermuda

2014 ◽  
Vol 14 (15) ◽  
pp. 8119-8135 ◽  
Author(s):  
W. C. Keene ◽  
J. L. Moody ◽  
J. N. Galloway ◽  
J. M. Prospero ◽  
O. R. Cooper ◽  
...  
Keyword(s):  
North America ◽  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Flow Regimes ◽  
Open Ocean ◽  
Anthropogenic Sources ◽  
Trade Wind ◽  
Eastern North America ◽  
Near Surface

Abstract. Since the 1980s, emissions of SO2 and NOx (NO + NO2) from anthropogenic sources in the United States (US), Canada, and Europe have decreased significantly suggesting that the export of oxidized S and N compounds from surrounding continents to the atmosphere overlying the North Atlantic Ocean (NAO) has also decreased. The chemical compositions of aerosols and precipitation sampled daily on Bermuda (32.27° N, 64.87° W) from 1989 to 1997 and from 2006 to 2009 were evaluated to quantify the magnitudes, significance, and implications of associated tends in atmospheric composition. The chemical data were stratified based on FLEXPART (FLEXible PARTicle dispersion model) retroplumes into four discrete transport regimes: westerly flow from eastern North America (NEUS/SEUS); easterly trade-wind flow from northern Africa and the subtropical NAO (Africa); long, open-ocean, anticyclonic flow around the Bermuda High (Oceanic); and transitional flow from the relatively clean open ocean to the polluted eastern North America (North). Based on all data, annual average concentrations of non-sea-salt (nss) SO42– associated with aerosols and annual volume-weighted-average (VWA) concentrations in precipitation decreased significantly (by 22% and 49%, respectively) whereas annual VWA concentrations of NH4+ in precipitation increased significantly (by 70%). Corresponding trends in aerosol and precipitation NO3– and of aerosol NH4+ were insignificant. Nss SO42– in precipitation under NEUS/SEUS and Oceanic flow decreased significantly (61% each) whereas corresponding trends in particulate nss SO42– under both flow regimes were insignificant. Trends in precipitation composition were driven in part by decreasing emissions of SO2 over upwind continents and associated decreases in anthropogenic contributions to nss SO42– concentrations. Under NEUS/SEUS and Oceanic flow, the ratio of anthropogenic to biogenic contributions to nss SO42– in the column scavenged by precipitation were relatively greater than those in near surface aerosol, which implies that, for these flow regimes, precipitation is a better indicator of overall anthropogenic impacts on the lower troposphere. Particulate nss SO42– under African flow also decreased significantly (34%) whereas the corresponding decrease in nss SO42– associated with precipitation was insignificant. We infer that these trends were driven in part by reductions in the emissions and transport of oxidized S compounds from Europe. The lack of significant trends in NO3– associated with aerosols and precipitation under NEUS/SEUS flow is notable in light of the large decrease (37%) in NOx emissions in the US and Canada over the period of record. Rapid chemical processing of oxidized N in marine air contributed to this lack of correspondence. Decreasing ratios of nss SO42– to NH4+ and the significant decreasing trend in precipitation acidity (37%) indicate that the total amount of acidity in the multiphase gas–aerosol system in the western NAO troposphere decreased over the period of record. Decreasing aerosol acidities would have shifted the phase partitioning of total NH3 (NH3 + particulate NH4+ towards the gas phase thereby decreasing the atmospheric lifetime of total NH3 against wet plus dry deposition. The trend of increasing NH4+ in precipitation at Bermuda over the period of record suggests that NH3 emissions from surrounding continents also increased. Decreasing particulate nss SO42– in near-surface air under NEUS/SEUS flow over the period of record implies that the corresponding shortwave scattering and absorption by nss S and associated aerosols constituents also decreased. These changes in radiative transfer suggest a corresponding lower limit for net warming over the period in the range of 0.1–0.3 W m–2.

scholarly journals Effect of a Variable Eddy Transfer Coefficient in an Eddy-Permitting Model of the Subpolar North Atlantic Ocean

2005 ◽  
Vol 35 (3) ◽  
pp. 289-307 ◽  
Author(s):  
Daniel Deacu ◽  
Paul G. Myers
Keyword(s):  
Atlantic Ocean ◽  
Transfer Coefficient ◽  
North Atlantic ◽  
General Circulation ◽  
North Atlantic Ocean ◽  
Negative Impact ◽  
Labrador Sea ◽  
Western Boundary ◽  
Near Surface ◽  
Eastern North Atlantic

Abstract The effect of using a variable eddy transfer coefficient for the Gent–McWilliams (GM) parameterization in a (1/3)°-resolution ocean model of the subpolar North Atlantic Ocean is investigated. Results from four experiments with different implementations of this coefficient are compared among themselves as well as with two control experiments. A series of improvements have been obtained in all of the experiments that use a low level of explicit horizontal tracer diffusion. These include a better representation of the overflow waters originating from the Nordic seas, leading to a more realistic deep western boundary current and to increased eddy activity in the deep ocean in the eastern North Atlantic. In the same experiments, the GM velocities “help” the Labrador Sea Water to spread from the deep convection region to the currents that surround it without incurring significant spurious diapycnal mixing. Thus, two classical pathways for the spreading of this water are established. Moreover, the simulated Labrador Current and the near-surface circulation in the eastern North Atlantic are in better agreement with flow patterns inferred from observations. The increased release of available potential energy obtained in the experiments with variable eddy transfer coefficients is responsible for the simulation of a flow that varies less in time. An overly strong countercurrent still occurs in the Labrador Sea in these experiments, and it has a negative impact on the pathway of the North Atlantic Current in the “Northwest Corner” and on the hydrography of the Labrador Sea. Nonetheless and overall, the use of the variable eddy transfer coefficient has led to better representations of the general circulation and hydrography in the subpolar North Atlantic.

scholarly journals Air-sea exchange of acetone, acetaldehyde, DMS and isoprene at a UK coastal site.

2021 ◽  
Author(s):  
Daniel Phillips ◽  
Frances Hopkins ◽  
Thomas Bell ◽  
Charel Wohl ◽  
Claire Reeves ◽  
...  
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
Atmospheric Chemistry ◽  
North Atlantic Ocean ◽  
Open Water ◽  
Proton Transfer Reaction ◽  
Gas Transfer ◽  
Gaseous Emissions ◽  
Near Surface ◽  
Direct Measurements

<p>Volatile organic compounds (VOCs) are ubiquitous in the atmosphere and are important for atmospheric chemistry. Large uncertainties remain in the role of the ocean in the atmospheric VOC budget because of poorly constrained marine sources and sinks. There are very few direct measurements of air-sea VOC fluxes near the coast, where natural marine emissions could influence coastal air quality (i.e. ozone (O<sub>3</sub>), aerosols) and terrestrial gaseous emissions could be taken up by the coastal seas.</p><p>To address this, we present air–sea fluxes of acetone, acetaldehyde and dimethylsulfide (DMS) at the coastal Penlee Point Atmospheric Observatory (PPAO) in the South-West UK during the spring (Apr-May 2018). Fluxes are quantified simultaneously by eddy covariance (EC) using a proton transfer reaction quadrupole mass spectrometer. Comparisons are made between two wind sectors representative of different air-water exchange regimes: the open water sector facing the North Atlantic Ocean and the fetch-limited Plymouth Sound fed by two estuaries.</p><p>Mean EC (± 1 standard error) fluxes of acetone, acetaldehyde and DMS from the open-water wind sector were ‑8.01±0.77, ‑1.55±1.44 and 4.67±0.56 μmol m<sup>-2</sup> d<sup>-1</sup> respectively (- sign indicates air-to-sea deposition). These measurements are generally comparable (same order of magnitude) to previous measurements in the Eastern North Atlantic Ocean at the same latitude. In comparison, the terrestrially influenced Plymouth Sound wind sector showed respective fluxes of -12.93±1.37, -4.45±1.73 and 1.75±0.80 μmol m<sup>-2</sup> d<sup>-1</sup>. The greater deposition fluxes of acetaldehyde and acetone within the Plymouth Sound were largely driven by higher atmospheric concentrations from the terrestrial wind sector. The reduced DMS emission from the Plymouth Sound was caused by a combination of lower wind speed and likely lower dissolved concentrations as a result of the freshwater estuarine influence (i.e. dilution).</p><p>In addition, we measured the near surface seawater concentrations of acetone, acetaldehyde, DMS and isoprene from a marine station 6 km offshore. Comparisons are made between EC fluxes from the open water and diffusive VOC fluxes calculated with a two-layer (TL) model of gas transfer using air/water concentrations. The calculated TL fluxes are largely consistent with our direct measurements in the directions and magnitudes of fluxes. Generally, the TL model predicted acetone and acetaldehyde fluxes that were ~12–33 % higher (greater deposition) than the EC measurements. This could be due to sea surface processes that produce these carbonyl compounds that were not accounted for by the TL technique.</p>

scholarly journals Air-sea fluxes of biogenic bromine from the tropical and North Atlantic Ocean

2009 ◽  
Vol 9 (5) ◽  
pp. 1805-1816 ◽  
Author(s):  
L. J. Carpenter ◽  
C. E. Jones ◽  
R. M. Dunk ◽  
K. E. Hornsby ◽  
J. Woeltjen
Keyword(s):  
Atlantic Ocean ◽  
Coastal Upwelling ◽  
North Atlantic Ocean ◽  
Open Ocean ◽  
Anthropogenic Sources ◽  
Coastal Regions ◽  
Power Stations ◽  
Eastern Atlantic Ocean ◽  
Elevated Surface ◽  
June July

Abstract. Air-sea fluxes and bulk seawater and atmospheric concentrations of bromoform (CHBr3) and dibromomethane (CH2Br2) were measured during two research cruises in the northeast Atlantic (53–59° N, June–July 2006) and tropical eastern Atlantic Ocean including over the African coastal upwelling system (16–35° N May–June 2007). Saturations and sea-air fluxes of these compounds generally decreased in the order coastal > upwelling > shelf > open ocean, and outside of coastal regions, a broad trend of elevated surface seawater concentrations with high chlorophyll-a was observed. We show that upwelling regions (coastal and equatorial) represent regional hot spots of bromocarbons, but are probably not of major significance globally, contributing at most a few percent of the total global emissions of CHBr3 and CH2Br2. From limited data from eastern Atlantic coastlines, we tentatively suggest that globally, coastal oceans (depth <180 m) together contribute ~2.5 (1.4–3.5) Gmol Br yr−1 of CHBr3, excluding influences from anthropogenic sources such as coastal power stations. This flux estimate is close to current estimates of the total open ocean source. We also show that the concentration ratio of CH2Br2/CHBr3 in seawater is a strong function of concentration (and location), with a lower CH2Br2/CHBr3 ratio found in coastal regions near to macroalgal sources.

Stock identification of the sciaenid fish Micropogonias undulatus in the western North Atlantic Ocean using parasites as biological tags

2007 ◽  
Vol 81 (2) ◽  
pp. 155-167 ◽  
Author(s):  
Tiffany G. Baker ◽  
Serge Morand ◽  
Charles A. Wenner ◽  
William A. Roumillat ◽  
Isaure de Buron
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
The United States ◽  
Atlantic Croaker ◽  
South Atlantic Bight ◽  
Stock Structure ◽  
Micropogonias Undulatus ◽  
Cape Hatteras ◽  
Biological Tags

AbstractProper fisheries management of the Atlantic croaker Micropogonias undulatus is necessary in the United States due to the commercial and recreational importance of this fish species. Croaker stock structure in the western North Atlantic has been investigated in the past by various authors, with inconclusive results. In this study, macroparasites were used as biological tags to identify putative croaker stocks in the area between New Jersey and Florida, which encompasses the Mid Atlantic Bight and the South Atlantic Bight separated at Cape Hatteras, North Carolina. The macroparasite community of the fish was identified, showing the presence of 30 species in four phyla, of which several were new host records, and one species, a monogenean, was new to science. A canonical correspondence analysis was applied to determine the variables responsible for parasite species composition, to resolve the question of croaker stock structure in the western North Atlantic Ocean. This analysis showed that latitude was the deciding variable delineating the parasite community composition of the Atlantic croaker. Among the 30 parasites, 15 were identified as putative tags according to qualitative criteria, and then 10 out of those 15 were selected as being appropriate tags using quantitative criteria. These parasite tags support the presence of two stocks roughly separated at the known biogeographical barrier at Cape Hatteras.

Island in the Stream: Oceanography and Fisheries of the Charleston Bump

2001 ◽  
Keyword(s):  
Atlantic Ocean ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Single Species ◽  
Common Species ◽  
Open Ocean ◽  
Commercially Important ◽  
In Situ Observations ◽  
Charleston Bump

<em>Abstract.</em>—Recent observations from trawling and submersibles have shown several species of cephalopods to be common in slope-waters of the western North Atlantic Ocean. The slope-water cephalopods include the commercially-important genus <em> Illex</em>, taxonomy of which remains troubling in the area off Charleston because of the possibility that <em> I. oxygonius </em>is a hybrid. Other common species include another ommastrephid <em> Ornithoteuthis antillarum</em>, single species of <em> Mastigoteuthis</em>, <em> Brachioteuthis</em>, and <em> Pholidoteuthis</em>, several cranchiids, histioteuthids, and sepiolids, two octopodids, the pelagic incirrate octopod <em> Haliphron atlanticus</em>, and the cirrate octopod <em> Stauroteuthis syrtensis</em>. Behavior and distribution of these species contrast with those of truly open-ocean cephalopods, which also are present in slope waters. In-situ observations have shown that several of the squids are more strongly associated with the bottom than was previously supposed and that many of the slope-water cephalopods exhibit unexpected behaviors.

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