scholarly journals The origin of sea salt in snow on Arctic sea ice and in coastal regions

2004 ◽  
Vol 4 (4) ◽  
pp. 4737-4776 ◽  
Author(s):  
F. Domine ◽  
R. Sparapani ◽  
A. Ianniello ◽  
H. J. Beine

Abstract. Snow, through its trace constituents, can have a major impact on lower tropospheric chemistry, as evidenced by ozone depletion events (ODEs) in oceanic polar areas. These ODEs are caused by the chemistry of bromine compounds, that originate from sea salt bromide. According to current ideas, bromide may be supplied to the snow surface either by upward migration from sea ice or by frost flowers being wind-blown to the snow surface. We investigate here the relative importance of both these processes by analyzing mineral ions in snow samples collected near Alert and Ny-Ålesund (Canadian and European high Arctic) in winter and spring. Vertical ionic profiles in the snowpack on sea ice are measured to test upward migration of sea salt ions and to seek evidence for ion fractionation processes. Time series of the ionic composition of surface snow layers are investigated to quantify wind-transported ions. Upward migration of unfractionated sea salt, to heights of at least 17 cm, was observed in snow sampled in winter, at temperatures near −30°C, leading to Cl− concentration of several hundred µM. Upward migration thus has the potential to supply ions to surface snow layers. Time series show that wind can deposit aerosols to the top few cm of the snow, leading also to Cl− concentrations of several hundred µM, so that both migration from sea ice and wind transport can significantly contribute ions to snow. At Ny-Ålesund, sea salt transported by wind was unfractionated, implying that it does not come from frost flowers. In the Arctic, frost flowers thus do not appear necessary to lead to large sea salt concentrations in surface snow, and to supply the bromide needed for ODEs. The data obtained also indicate that ODEs lead to significant deposition of Br− to snow. We speculate that this can also take place in coastal regions and contribute to propagate ODEs inland. Finally, we stress the need to measure snow physical parameters such as permeability and specific surface area, to understand quantitatively changes in snow chemistry.

2004 ◽  
Vol 4 (9/10) ◽  
pp. 2259-2271 ◽  
Author(s):  
F. Domine ◽  
R. Sparapani ◽  
A. Ianniello ◽  
H. J. Beine

Abstract. Snow, through its trace constituents, can have a major impact on lower tropospheric chemistry, as evidenced by ozone depletion events (ODEs) in oceanic polar areas. These ODEs are caused by the chemistry of bromine compounds that originate from sea salt bromide. Bromide may be supplied to the snow surface by upward migration from sea ice, by frost flowers being wind-blown to the snow surface, or by wind-transported aerosol generated by sea spray. We investigate here the relative importance of these processes by analyzing ions in snow near Alert and Ny-Ålesund (Canadian and European high Arctic) in winter and spring. Vertical ionic profiles in the snowpack on sea ice are measured to test upward migration of sea salt ions and to seek evidence for ion fractionation processes. Time series of the ionic composition of surface snow layers are investigated to quantify wind-transported ions. Upward migration of unfractionated sea salt to heights of at least 17cm was observed in winter snow, leading to Cl- concentration of several hundred µM. Upward migration thus has the potential to supply ions to surface snow layers. Time series show that wind can deposit aerosols to the top few cm of the snow, leading also to Cl- concentrations of several hundred µM, so that both diffusion from sea ice and wind transport can significantly contribute ions to snow. At Ny-Ålesund, sea salt transported by wind was unfractionated, implying that it comes from sea spray rather than frost flowers. Estimations based on our results suggest that the marine snowpack contains about 10 times more Na+ than the frost flowers, so that both the marine snowpack and frost flowers need to be considered as sea salt sources. Our data suggest that ozone depletion chemistry can significantly enhance the Br- content of snow. We speculate that this can also take place in coastal regions and contribute to propagate ODEs inland. Finally, we stress the need to measure snow physical parameters such as permeability and specific surface area to understand quantitatively changes in snow chemistry.


2018 ◽  
Author(s):  
Jiayue Huang ◽  
Lyatt Jaeglé ◽  
Viral Shah

Abstract. Sea salt aerosols (SSA) produced on sea ice surfaces by blowing snow events or lifting of frost flower crystals have been suggested as important sources of SSA during winter over polar regions. The magnitude and relative contribution of blowing snow and frost flower SSA sources, however, remain uncertain. In this study, we use 2007–2009 aerosol extinction coefficients from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument onboard the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite and the GEOS-Chem global chemical transport model to constrain sources of SSA over Arctic and Antarctic sea ice. CALIOP retrievals show elevated levels of aerosol extinctions (10–20 Mm−1) in the lower troposphere (0–2 km) over polar regions during cold months. The standard GEOS-Chem model underestimates the CALIOP aerosol extinctions by 50–70 %. Adding frost flower emissions of SSA fails to explain the CALIOP observations. With blowing snow SSA emissions, the model captures the overall spatial and seasonal variation of CALIOP aerosol extinctions over the polar regions, but overestimates springtime aerosol extinctions over Arctic sea ice and winter-spring extinctions over Antarctic sea ice. We reduce the surface snow salinity over multi-year sea ice and infer the monthly FYI snow salinity required to minimize the discrepancy between CALIOP extinctions and the GEOS-Chem simulation. The empirically-derived snow salinity shows a decreasing trend in between fall and spring. The optimized blowing snow model with inferred snow salinities generally agrees with CALIOP extinction observations to within 10 % over sea ice, but underestimates aerosol extinctions over the regions where frost flowers are expected to have a large influence. Frost flowers could thus contribute indirectly to SSA production by increasing the local surface snow salinity and, therefore, the SSA production from blowing snow. We carry out a case study of an Arctic blowing snow SSA feature predicted by GEOS-Chem and sampled by CALIOP. Using backtrajectories, we link this feature to a blowing snow event which occurred 2 days earlier over first-year sea ice and was also detected by CALIOP.


2020 ◽  
Author(s):  
Reginald Muskett ◽  
Syun-Ichi Akasofu

<p>Arctic sea ice is a key component of the Arctic hydrologic cycle. This cycle is connected to land and ocean temperature variations and Arctic snow cover variations, spatially and temporally. Arctic temperature variations from historical observations shows an early 20th century increase (i.e. warming), followed by a period of Arctic temperature decrease (i.e. cooling) since the 1940s, which was followed by another period of Arctic temperature increase since the 1970s that continues into the two decades of the 21st century. Evidence has been accumulating that Arctic sea ice extent can experience multi-decadal to centennial time scale variations as it is a component of the Arctic Geohydrological System. </p><p><br>We investigate the multi-satellite and sensor daily values of area extent of Arctic sea ice since SMMR on Nimbus 7 (1978) to AMSR2 on GCOM-W1 (2019). From the daily time series we use the first year-cycle as a wave-pattern to compare to all subsequent years-cycles through April 2020 (in progress), and constitute a derivative time series. In this time series we find the emergence of a multi-decadal cycle, showing a relative minimum during the period of 2007 to 2014, and subsequently rising. This may be related to an 80-year cycle (hypothesis). The Earth’s weather system is principally driven the solar radiation and its variations. If the multi-decadal cycle in Arctic sea ice area extent that we interpret continues, it may be linked physically to the Wolf-Gleissberg cycle, a factor in the variations of terrestrial cosmogenic isotopes, ocean sediment layering and glacial varves, ENSO and Aurora.</p><p>Our hypothesis and results give more evidence that the multi-decadal variation of Arctic sea ice area extent is controlled by natural physical processes of the Sun-Earth system. </p>


2012 ◽  
Vol 6 (6) ◽  
pp. 1359-1368 ◽  
Author(s):  
W. N. Meier ◽  
J. Stroeve ◽  
A. Barrett ◽  
F. Fetterer

Abstract. Observations from passive microwave satellite sensors have provided a continuous and consistent record of sea ice extent since late 1978. Earlier records, compiled from ice charts and other sources exist, but are not consistent with the satellite record. Here, a method is presented to adjust a compilation of pre-satellite sources to remove discontinuities between the two periods and create a more consistent combined 59-yr time series spanning 1953–2011. This adjusted combined time series shows more realistic behavior across the transition between the two individual time series and thus provides higher confidence in trend estimates from 1953 through 2011. The long-term time series is used to calculate linear trend estimates and compare them with trend estimates from the satellite period. The results indicate that trends through the 1960s were largely positive (though not statistically significant) and then turned negative by the mid-1970s and have been consistently negative since, reaching statistical significance (at the 95% confidence level) by the late 1980s. The trend for September (when Arctic extent reaches its seasonal minimum) for the satellite period, 1979–2011 is −12.9% decade−1, nearly double the 1953–2011 trend of −6.8% decade−1 (percent relative to the 1981–2010 mean). The recent decade (2002–2011) stands out as a period of persistent decline in ice extent. The combined 59-yr time series puts the strong observed decline in the Arctic sea ice cover during 1979–2011 in a longer-term context and provides a useful resource for comparisons with historical model estimates.


2021 ◽  
Author(s):  
Sean Horvath ◽  
Linette Boisvert ◽  
Chelsea Parker ◽  
Melinda Webster ◽  
Patrick Taylor ◽  
...  

Abstract. Since the early 2000s, sea ice has experienced an increased rate of decline in thickness and extent and transitioned to a seasonal ice cover. This shift to thinner, seasonal ice in the 'New Arctic' is accompanied by a reshuffling of energy flows at the surface. Understanding the magnitude and nature of this reshuffling and the feedbacks therein remains limited. A novel database is presented that combines satellite observations, model output, and reanalysis data with daily sea ice parcel drift tracks produced in a Lagrangian framework. This dataset consists of daily time series of sea ice parcel locations, sea ice and snow conditions, and atmospheric states. Building on previous work, this dataset includes remotely sensed radiative and turbulent fluxes from which the surface energy budget can be calculated. Additionally, flags indicate when sea ice parcels travel within cyclones, recording distance and direction from the cyclone center. The database drift track was evaluated by comparison with sea ice mass balance buoys. Results show ice parcels generally remain within 100km of the corresponding buoy, with a mean distance of 82.6 km and median distance of 54 km. The sea ice mass balance buoys also provide recordings of sea ice thickness, snow depth, and air temperature and pressure which were compared to this database. Ice thickness and snow depth typically are less accurate than air temperature and pressure due to the high spatial variability of the former two quantities when compared to a point measurement. The correlations between the ice parcel and buoy data are high, which highlights the accuracy of this Lagrangian database in capturing the seasonal changes and evolution of sea ice. This database has multiple applications for the scientific community; it can be used to study the processes that influence individual sea ice parcel time series, or to explore generalized summary statistics and trends across the Arctic. Applications such as these may shed light on the atmosphere-snow-sea ice interactions in the changing Arctic environment.


2020 ◽  
Author(s):  
H. Jakob Belter ◽  
Thomas Krumpen ◽  
Luisa von Albedyll ◽  
Tatiana A. Alekseeva ◽  
Sergei V. Frolov ◽  
...  

Abstract. Changes in Arctic sea ice thickness are the result of complex interactions of the dynamic and variable ice cover with atmosphere and ocean. Most of the sea ice exits the Arctic Ocean through Fram Strait, which is why long-term measurements of ice thickness at the end of the Transpolar Drift provide insight into the integrated signals of thermodynamic and dynamic influences along the pathways of Arctic sea ice. We present an updated time series of extensive ice thickness surveys carried out at the end of the Transpolar Drift between 2001 and 2020. Overall, we see a more than 20 % thinning of modal ice thickness since 2001. A comparison with first preliminary results from the international Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) shows that the modal summer thickness of the MOSAiC floe and its wider vicinity are consistent with measurements from previous years. By combining this unique time series with the Lagrangian sea ice tracking tool, ICETrack, and a simple thermodynamic sea ice growth model, we link the observed interannual ice thickness variability north of Fram Strait to increased drift speeds along the Transpolar Drift and the consequential variations in sea ice age and number of freezing degree days. We also show that the increased influence of upward-directed ocean heat flux in the eastern marginal ice zones, termed Atlantification, is not only responsible for sea ice thinning in and around the Laptev Sea, but also that the induced thickness anomalies persist beyond the Russian shelves and are potentially still measurable at the end of the Transpolar Drift after more than a year. With a tendency towards an even faster Transpolar Drift, winter sea ice growth will have less time to compensate the impact of Atlantification on sea ice growth in the eastern marginal ice zone, which will increasingly be felt in other parts of the sea ice covered Arctic.


2020 ◽  
Vol 20 (12) ◽  
pp. 7335-7358 ◽  
Author(s):  
Jiayue Huang ◽  
Lyatt Jaeglé ◽  
Qianjie Chen ◽  
Becky Alexander ◽  
Tomás Sherwen ◽  
...  

Abstract. We use the GEOS-Chem chemical transport model to examine the influence of bromine release from blowing-snow sea salt aerosol (SSA) on springtime bromine activation and O3 depletion events (ODEs) in the Arctic lower troposphere. We evaluate our simulation against observations of tropospheric BrO vertical column densities (VCDtropo) from the GOME-2 (second Global Ozone Monitoring Experiment) and Ozone Monitoring Instrument (OMI) spaceborne instruments for 3 years (2007–2009), as well as against surface observations of O3. We conduct a simulation with blowing-snow SSA emissions from first-year sea ice (FYI; with a surface snow salinity of 0.1 psu) and multi-year sea ice (MYI; with a surface snow salinity of 0.05 psu), assuming a factor of 5 bromide enrichment of surface snow relative to seawater. This simulation captures the magnitude of observed March–April GOME-2 and OMI VCDtropo to within 17 %, as well as their spatiotemporal variability (r=0.76–0.85). Many of the large-scale bromine explosions are successfully reproduced, with the exception of events in May, which are absent or systematically underpredicted in the model. If we assume a lower salinity on MYI (0.01 psu), some of the bromine explosions events observed over MYI are not captured, suggesting that blowing snow over MYI is an important source of bromine activation. We find that the modeled atmospheric deposition onto snow-covered sea ice becomes highly enriched in bromide, increasing from enrichment factors of ∼5 in September–February to 10–60 in May, consistent with composition observations of freshly fallen snow. We propose that this progressive enrichment in deposition could enable blowing-snow-induced halogen activation to propagate into May and might explain our late-spring underestimate in VCDtropo. We estimate that the atmospheric deposition of SSA could increase snow salinity by up to 0.04 psu between February and April, which could be an important source of salinity for surface snow on MYI as well as FYI covered by deep snowpack. Inclusion of halogen release from blowing-snow SSA in our simulations decreases monthly mean Arctic surface O3 by 4–8 ppbv (15 %–30 %) in March and 8–14 ppbv (30 %–40 %) in April. We reproduce a transport event of depleted O3 Arctic air down to 40∘ N observed at many sub-Arctic surface sites in early April 2007. While our simulation captures 25 %–40 % of the ODEs observed at coastal Arctic surface sites, it underestimates the magnitude of many of these events and entirely misses 60 %–75 % of ODEs. This difficulty in reproducing observed surface ODEs could be related to the coarse horizontal resolution of the model, the known biases in simulating Arctic boundary layer exchange processes, the lack of detailed chlorine chemistry, and/or the fact that we did not include direct halogen activation by snowpack chemistry.


2020 ◽  
Author(s):  
Valeria Selyuzhenok ◽  
Denis Demchev ◽  
Thomas Krumpen

<p>Landfast sea ice is a dominant sea ice feature of the Arctic coastal region. As a part of Arctic sea ice cover, landfast ice is an important part of coastal ecosystem, it provides functions as a climate regulator and platform for human activity. Recent changes in sea ice conditions in the Arctic have also affected landfast ice regime. At the same time, industrial interest in the Arctic shelf seas continue to increase. Knowledge on local landfast ice conditions are required to ensure safety of on ice operations and accurate forecasting.  In order to obtain a comprehensive information on landfast ice state we use a time series of wide swath SAR imagery.  An automatic sea ice tracking algorithm was applied to the sequential SAR images during the development stage of landfast ice cover. The analysis of resultant time series of sea ice drift allows to classify homogeneous sea ice drift fields and timing of their attachment to the landfast ice. In addition, the drift data allows to locate areas of formation of grounded sea ice accumulation called stamukha. This information сan be useful for local landfast ice stability assessment. The study is supported by the Russian Foundation for Basic Research (RFBR) grant 19-35-60033.</p>


2014 ◽  
Vol 14 (14) ◽  
pp. 7543-7557 ◽  
Author(s):  
J. Browse ◽  
K. S. Carslaw ◽  
G. W. Mann ◽  
C. E. Birch ◽  
S. R. Arnold ◽  
...  

Abstract. Loss of summertime Arctic sea ice will lead to a large increase in the emission of aerosols and precursor gases from the ocean surface. It has been suggested that these enhanced emissions will exert substantial aerosol radiative forcings, dominated by the indirect effect of aerosol on clouds. Here, we investigate the potential for these indirect forcings using a global aerosol microphysics model evaluated against aerosol observations from the Arctic Summer Cloud Ocean Study (ASCOS) campaign to examine the response of Arctic cloud condensation nuclei (CCN) to sea-ice retreat. In response to a complete loss of summer ice, we find that north of 70° N emission fluxes of sea salt, marine primary organic aerosol (OA) and dimethyl sulfide increase by a factor of ~ 10, ~ 4 and ~ 15 respectively. However, the CCN response is weak, with negative changes over the central Arctic Ocean. The weak response is due to the efficient scavenging of aerosol by extensive drizzling stratocumulus clouds. In the scavenging-dominated Arctic environment, the production of condensable vapour from oxidation of dimethyl sulfide grows particles to sizes where they can be scavenged. This loss is not sufficiently compensated by new particle formation, due to the suppression of nucleation by the large condensation sink resulting from sea-salt and primary OA emissions. Thus, our results suggest that increased aerosol emissions will not cause a climate feedback through changes in cloud microphysical and radiative properties.


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