scholarly journals TOC intercomparison of Brewer, Dobson and BTS Solar at Hohenpeißenberg and Davos 2019/2020

2021 ◽  
Author(s):  
Ralf Zuber ◽  
Ulf Köhler ◽  
Luca Egli ◽  
Mario Ribnitzky ◽  
Wolfgang Steinbrecht ◽  
...  
Keyword(s):  
Standard Deviation ◽  
Total Ozone ◽  
Retrieval Algorithm ◽  
Spectral Measurements ◽  
Measurement Campaign ◽  
Stratospheric Temperature ◽  
Retrieval Algorithms ◽  
One Year ◽  
Double Monochromator ◽  
Ozone Column

Abstract. In the 2019/2020 measurement campaign at Hohenpeißenberg (Germany) and Davos (Switzerland) we compared the well-established Dobson and Brewer spectrometers (single and double monochromator Brewer) with newer BTS array spectroradiometer based systems in terms of total ozone column (TOC) determination. The aim of this study is to validate the BTS performance in a longer-term TOC analysis over more than one year with seasonal and weather influences. Two different BTS setups have been used. A fibre coupled entrance optic version by PMOD/WRC called Koherent and a diffusor optic which proved to be simpler in terms of calibration from Gigahertz-Optik GmbH called BTS Solar. The array-spectrometer based BTS systems have been traceable calibrated to National Metrology Institutes (NMI) and the used TOC retrieval algorithms are based on spectral measurements in the range of 305 nm and 350 nm instead of single wavelength measurements as for Brewer or Dobson. The two BTS based systems, however, used fundamentally different retrieval algorithms for the TOC assessment, whereby the retrieval of the BTS solar turned out to achieve significantly smaller seasonal drifts. The intercomparison showed a deviation of the BTS Solar to Brewers of < 0.1 % with an expanded standard deviation of < 1.5 % within the whole measurement campaign. Koherent showed a deviation of 1.7 % with an expanded standard deviation of 2.7 % mostly given by a significant seasonal drift. Resulting, the BTS Solar performance is comparable to Brewers at the comparison in Hohenpeißenberg. The slant path slope is in-between double monochromator and single monochromator Brewer. Koherent shows a strong seasonal variation in Davos due to the sensitivity of its ozone retrieval algorithm to stratospheric temperature similar to the Dobson results.

scholarly journals Total ozone column intercomparison of Brewers, Dobsons, and BTS-Solar at Hohenpeißenberg and Davos in 2019/2020

2021 ◽  
Vol 14 (7) ◽  
pp. 4915-4928
Author(s):  
Ralf Zuber ◽  
Ulf Köhler ◽  
Luca Egli ◽  
Mario Ribnitzky ◽  
Wolfgang Steinbrecht ◽  
...  
Keyword(s):  
Seasonal Variation ◽  
Standard Deviation ◽  
Total Ozone ◽  
Retrieval Algorithm ◽  
Measurement Campaign ◽  
Total Ozone Column ◽  
Stratospheric Temperature ◽  
Retrieval Algorithms ◽  
Double Monochromator ◽  
Ozone Column

Abstract. During the 2019/2020 measurement campaign at Hohenpeißenberg (Germany) and Davos (Switzerland) we compared the well-established Dobson and Brewer spectrometers (single- and double-monochromator Brewer) with newer BTS array-spectroradiometer-based systems in terms of total ozone column (TOC) determination. The aim of this study is to validate the BTS performance in a longer-term TOC analysis over more than 1 year with seasonal and weather influences. Two different BTS setups have been used – a fibre-coupled entrance optic version by PMOD/WRC called Koherent and a diffusor optic version from Gigahertz Optik GmbH called BTS-Solar, which proved to be simpler in terms of calibration. The array-spectrometer-based BTS systems have been calibrated with traceability to NMI, and both versions of TOC retrieval algorithms are based on spectral measurements in the range of 305 to 350 nm instead of single-wavelength or wavelength pair measurements as per Brewer or Dobson. The two BTS-based systems, however, used fundamentally different retrieval algorithms for the TOC assessment, whereby the retrieval of the BTS-Solar turned out to achieve significantly smaller seasonal drifts. The intercomparison showed a difference of the BTS-Solar to Brewers of < 0.1 % with an expanded standard deviation (k=2) of < 1.5 % over the whole measurement campaign. Koherent showed a difference of 1.7 % with an expanded standard deviation (k=2) of 2.7 % mostly caused by a significant seasonal variation. To summarize, the BTS-Solar performed at the level of Brewers in the comparison in Hohenpeißenberg. The BTS-Solar showed very small dependence on the slant path column compared to the double-monochromator Brewer and performed better than the single-monochromator Brewer. Koherent showed a strong seasonal variation in Davos due to the sensitivity of its ozone retrieval algorithm to stratospheric temperature.

scholarly journals Retrieval of stratospheric and tropospheric BrO columns from multi-axis DOAS measurements at Reunion Island (21° S, 56° E)

2007 ◽  
Vol 7 (3) ◽  
pp. 8261-8308 ◽  
Author(s):  
N. Theys ◽  
M. Van Roozendael ◽  
F. Hendrick ◽  
C. Fayt ◽  
C. Hermans ◽  
...  
Keyword(s):  
Measurement Data ◽  
Retrieval Algorithm ◽  
Reunion Island ◽  
Spectral Measurements ◽  
Réunion Island ◽  
One Year ◽  
Chemical Fields ◽  
Latitudinal Band ◽  
Observation Period ◽  
Good Agreement

Abstract. Spectral measurements of BrO using zenith-sky and off-axis viewing geometries are combined in a linear multiple regression retrieval algorithm to provide stratospheric and tropospheric BrO vertical columns. One year of measurement data are investigated over Reunion-Island (20.9° S, 55.5° E), from July 2004 to July 2005. No seasonal variations of the retrieved BrO columns could be observed, in line with previous studies. A comparison between the stratospheric columns retrieved at 45°, 80°, 85°, 87.5° and 92.5° solar zenith angles and photochemical simulations initialized by chemical fields from the 3-D-CTM SLIMCAT and further constrained by observed NO2 profiles shows a good agreement only by considering a contribution from the very short-lived organic bromine substances to the stratospheric inorganic bromine budget, of 6 to 8 pptv. Furthermore, stratospheric BrO profiles retrieved from late twilight zenith-sky observations are consistent with a total inorganic bromine (Bry) loading of approximately 23 pptv. This represents 6 to 7 pptv more than can be supplied by long-lived organic bromine sources, and therefore supports an added contribution from very short-lived organic bromine substances as recently suggested in several other studies. Moreover strong evidences are presented for the existence of a substantial amount of BrO in the tropical free-troposphere, around 6 km altitude, possibly supplied by the decomposition of short-lived biogenic bromine organic compounds. Tropospheric BrO vertical columns of 1.1±0.45×1013 molec/cm2 are derived for the entire observation period. Comparisons between ground-based BrO vertical columns and total BrO columns derived from SCIAMACHY (onboard the ENVISAT satellite) nadir observations in a latitudinal band centered around 21° S present a good level of consistency, which further strengthens the conclusions of our study.

scholarly journals Retrieval of stratospheric and tropospheric BrO columns from multi-axis DOAS measurements at Reunion Island (21° S, 56° E)

2007 ◽  
Vol 7 (18) ◽  
pp. 4733-4749 ◽  
Author(s):  
N. Theys ◽  
M. Van Roozendael ◽  
F. Hendrick ◽  
C. Fayt ◽  
C. Hermans ◽  
...  
Keyword(s):  
Measurement Data ◽  
Retrieval Algorithm ◽  
Reunion Island ◽  
Spectral Measurements ◽  
Réunion Island ◽  
One Year ◽  
Chemical Fields ◽  
Latitudinal Band ◽  
Observation Period ◽  
Good Agreement

Abstract. Spectral measurements of BrO using zenith-sky and off-axis viewing geometries are combined in a linear multiple regression retrieval algorithm to provide stratospheric and tropospheric BrO vertical columns. One year of measurement data are investigated over Reunion-Island (20.9° S, 55.5° E), from August 2004 to June 2005. A comparison between the stratospheric columns retrieved at 45°, 80°, 85°, 87.5° and 92.5° solar zenith angles and photochemical simulations initialized by chemical fields from the 3-D-CTM SLIMCAT and further constrained by observed NO2 profiles shows a good agreement only by considering a contribution from the very short-lived organic bromine substances to the stratospheric inorganic bromine budget, of 6 to 8 pptv. Furthermore, stratospheric BrO profiles retrieved from late twilight zenith-sky observations are consistent with a total inorganic bromine (Bry) loading of approximately 23 pptv. This represents 6 to 7 pptv more than can be supplied by long-lived organic bromine sources, and therefore supports an added contribution from very short-lived organic bromine substances as recently suggested in several other studies. Moreover strong evidences are presented for the existence of a substantial amount of BrO in the tropical free-troposphere, around 6 km altitude, possibly supplied by the decomposition of short-lived biogenic bromine organic compounds. Tropospheric BrO vertical columns of 1.1±0.45×1013 molec/cm² are derived for the entire observation period. Comparisons between ground-based BrO vertical columns and total BrO columns derived from SCIAMACHY (onboard the ENVISAT satellite) nadir observations in a latitudinal band centered around 21° S present a good level of consistency, which further strengthens the conclusions of our study.

scholarly journals Extended and refined multi sensor reanalysis of total ozone for the period 1970–2012

2015 ◽  
Vol 8 (3) ◽  
pp. 3283-3319 ◽  
Author(s):  
R. J. van der A ◽  
M. A. F. Allaart ◽  
H. J. Eskes
Keyword(s):  
Data Assimilation ◽  
Total Ozone ◽  
Transport Model ◽  
Forecast Error ◽  
Satellite Observations ◽  
Weather Forecasts ◽  
Stratospheric Temperature ◽  
The Individual ◽  
Data Assimilation Technique ◽  
Ozone Column

Abstract. The ozone multi-sensor reanalysis (MSR) is a multi-decadal ozone column data record constructed using all available ozone column satellite datasets, surface Brewer and Dobson observations and a data assimilation technique with detailed error modelling. The result is a high-resolution time series of 6 hourly global ozone column fields and forecast error fields that may be used for ozone trend analyses as well as detailed case studies. The ozone MSR is produced in two steps. First, the latest reprocessed versions of all available ozone column satellite datasets are collected, and are corrected for biases as function of solar zenith angle, viewing angle, time (trend), and stratospheric temperature using Brewer/Dobson ground measurements from the World Ozone and Ultraviolet Radiation Data Centre (WOUDC; http://www.woudc.org/). Subsequently the debiased satellite observations are assimilated within the ozone chemistry and data assimilation model TMDAM driven by meteorological analyses of the European Centre for Medium-Range Weather Forecasts (ECMWF). The MSR2 (MSR version 2) reanalysis upgrade described in this paper consists of an ozone record for the 43 year period 1970–2012. The chemistry-transport model and data assimilation system have been adapted to improve the resolution, error modelling and processing speed. BUV satellite observations have been included for the period 1970–1977. The total record is extended with 13 years compared to the first version of the ozone multi sensor reanalysis, the MSR1. The latest total ozone retrievals of 15 satellite instruments are used: BUV-Nimbus4, TOMS-Nimbus7, TOMS-EP, SBUV-7, -9, -11, -14, -16, -17, -18, -19, GOME, SCIAMACHY, OMI and GOME-2. The resolution of the model runs, assimilation and output is increased from 2° x 3° to 1° x 1°. The analysis is driven by three-hourly meteorology from the ERA-interim reanalysis of ECMWF starting from 1979, and ERA-40 before that date. The chemistry parameterization has been updated. The performance of the MSR2 analysis is studied with the help of observation-minus-forecast (OmF) departures from the data assimilation, by comparisons with the individual station observations and with ozone sondes. The OmF statistics show that the mean bias of the MSR2 analyses is less than 1% with respect to debiased satellite observations after 1979.

scholarly journals NDACC UV-visible total ozone measurements: improved retrieval and comparison with correlative satellite and ground-based observations

2010 ◽  
Vol 10 (8) ◽  
pp. 20405-20460
Author(s):  
F. Hendrick ◽  
J.-P. Pommereau ◽  
F. Goutail ◽  
R. D. Evans ◽  
D. Ionov ◽  
...  
Keyword(s):  
Cross Sections ◽  
Total Ozone ◽  
Complete Removal ◽  
Temperature Correction ◽  
Atmospheric Composition ◽  
Vertical Column ◽  
Stratospheric Temperature ◽  
Uv Visible ◽  
Ozone Column

Abstract. Accurate long-term monitoring of total ozone is one of the most important requirements for identifying possible natural or anthropogenic changes in the composition of the stratosphere. For this purpose, the NDACC (Network for the Detection of Atmospheric Composition Change) UV-visible Working Group has made recommendations for improving and homogenizing the retrieval of total ozone columns from twilight zenith-sky visible spectrometers. These instruments, deployed all over the world in about 35 stations, allow measurements of total ozone twice daily with little sensitivity to stratospheric temperature and cloud cover. The NDACC recommendations address both the DOAS retrieval parameters and the calculation of air mass factors (AMF) needed for the conversion of O3 slant column densities into vertical column amounts. The most important improvement is the use of O3 AMF look-up tables calculated using the TOMS V8 O3 profile climatology, that allows accounting for the dependence of the O3 AMF on the seasonal and latitudinal variations of the O3 vertical distribution. To investigate their impact on the retrieved ozone columns, the recommendations have been applied to measurements from the NDACC/SAOZ (Système d'Analyse par Observation Zénithale) network. The revised SAOZ ozone data from eight stations covering all latitude regions have been compared to TOMS, GOME-GDP4, SCIAMACHY-TOSOMI, OMI-TOMS, and OMI-DOAS satellite overpass observations, as well as to those of collocated Dobson and Brewer instruments. A significant improvement is obtained after applying the new O3 AMFs, although systematic seasonal differences between SAOZ and all other instruments remain. These are shown to mainly originate from i) the temperature dependence of the ozone absorption cross sections in the UV being not or improperly corrected by some retrieval algorithms, and ii) the longitudinal differences in tropospheric ozone column being ignored by zonal climatologies. For those measurements sensitive to stratospheric temperature like TOMS, OMI-TOMS, Dobson and Brewer, the application of a temperature correction results in the almost complete removal of the seasonal difference with SAOZ, improving significantly the consistency between all ground-based and satellite total ozone observations.

scholarly journals Trends of tropical tropospheric ozone from twenty years of European satellite measurements and perspectives for Sentinel-5 Precursor

2016 ◽  
Author(s):  
Klaus-Peter Heue ◽  
Melanie Coldewey-Egbers ◽  
Andy Delcloo ◽  
Christophe Lerot ◽  
Diego Loyola ◽  
...  
Keyword(s):  
Tropospheric Ozone ◽  
Total Ozone ◽  
Atlantic Coast ◽  
Convective Cloud ◽  
Differential Method ◽  
Retrieval Algorithm ◽  
Data Set ◽  
Cloud Data ◽  
One Year ◽  
The Individual

Abstract. In preparation of the TROPOMI/S5P launch in autumn 2016 a tropospheric ozone retrieval based on the convective cloud differential method was developed. For intensive tests we applied the algorithm to the total ozone columns and cloud data of the satellites GOME, SCIAMACHY, OMI, GOME-2A and GOME-2B. Thereby a time series of 20 years (1995–2015) of tropospheric ozone columns was retrieved. To have a consistent total ozone data set for all sensors one common retrieval algorithm, namely GODFITv3, has been applied to all sensors and the L1 reflectances have also been soft calibrated. These data were input into the tropospheric ozone retrieval. However, the Tropical Tropospheric Ozone Columns (TTOC) for the individual instruments still showed small differences and therefore we harmonised the data set. For this purpose a multi-variant function was fitted to the averaged difference between SCIAMACHY's TTOC and those from the other sensors. The original TTOC was corrected by the fitted offset. GOME-2B data were corrected relative to the harmonised data from OMI and GOME-2A. The harmonisation leads to a better agreement between the different instruments. Also a direct comparison of the TTOCs in the overlapping periods proves that GOME-2A agrees much better with SCIAMACHY after the harmonisation. The improvements for OMI were small. The GOME and SCIAMACHY data overlap for one year for the complete tropics, this turned out to be insufficient to extrapolate back until 1995. Based on the harmonised observations, we created a merged data product, containing the TTOC from July 1995 to Dec. 2015. A first application of this 20 years record is a trend analysis. The global tropical trend is 0.75 &amp;pm; 0.12 DU decade−1. Regionally the trends reaches up to 1.8 DU decade−1 like on the African Atlantic coast, over the Western Pacific the tropospheric ozone declined over the last 20 years with up to 0.8 DU decade−1. The tropical tropospheric data record will be extended in the future with the TROPOMI/S5P data, where the TTOC is part of the operational products.

scholarly journals Extended and refined multi sensor reanalysis of total ozone for the period 1970–2012

2015 ◽  
Vol 8 (7) ◽  
pp. 3021-3035 ◽  
Author(s):  
R. J. van der A ◽  
M. A. F. Allaart ◽  
H. J. Eskes
Keyword(s):  
Data Assimilation ◽  
Satellite Data ◽  
Zenith Angle ◽  
Total Ozone ◽  
Transport Model ◽  
Forecast Error ◽  
Satellite Observations ◽  
Data Sets ◽  
Stratospheric Temperature ◽  
Ozone Column

Abstract. The ozone multi-sensor reanalysis (MSR) is a multi-decadal ozone column data record constructed using all available ozone column satellite data sets, surface Brewer and Dobson observations and a data assimilation technique with detailed error modelling. The result is a high-resolution time series of 6-hourly global ozone column fields and forecast error fields that may be used for ozone trend analyses as well as detailed case studies. The ozone MSR is produced in two steps. First, the latest reprocessed versions of all available ozone column satellite data sets are collected and then are corrected for biases as a function of solar zenith angle (SZA), viewing zenith angle (VZA), time (trend), and stratospheric temperature using surface observations of the ozone column from Brewer and Dobson spectrophotometers from the World Ozone and Ultraviolet Radiation Data Centre (WOUDC). Subsequently the de-biased satellite observations are assimilated within the ozone chemistry and data assimilation model TMDAM. The MSR2 (MSR version 2) reanalysis upgrade described in this paper consists of an ozone record for the 43-year period 1970–2012. The chemistry transport model and data assimilation system have been adapted to improve the resolution, error modelling and processing speed. Backscatter ultraviolet (BUV) satellite observations have been included for the period 1970–1977. The total record is extended by 13 years compared to the first version of the ozone multi sensor reanalysis, the MSR1. The latest total ozone retrievals of 15 satellite instruments are used: BUV-Nimbus4, TOMS-Nimbus7, TOMS-EP, SBUV-7, -9, -11, -14, -16, -17, -18, -19, GOME, SCIAMACHY, OMI and GOME-2. The resolution of the model runs, assimilation and output is increased from 2° × 3° to 1° × 1°. The analysis is driven by 3-hourly meteorology from the ERA-Interim reanalysis of the European Centre for Medium-Range Weather Forecasts (ECMWF) starting from 1979, and ERA-40 before that date. The chemistry parameterization has been updated. The performance of the MSR2 analysis is studied with the help of observation-minus-forecast (OmF) departures from the data assimilation, by comparisons with the individual station observations and with ozone sondes. The OmF statistics show that the mean bias of the MSR2 analyses is less than 1 % with respect to de-biased satellite observations after 1979.

scholarly journals Total ozone column from Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) measurements using the broadband weighting function fitting approach (WFFA)

2021 ◽  
Vol 14 (8) ◽  
pp. 5771-5789
Author(s):  
Andrea Orfanoz-Cheuquelaf ◽  
Alexei Rozanov ◽  
Mark Weber ◽  
Carlo Arosio ◽  
Annette Ladstätter-Weißenmayer ◽  
...  
Keyword(s):  
Total Ozone ◽  
Weighting Function ◽  
Optical Absorption Spectroscopy ◽  
Retrieval Algorithm ◽  
Polar Regions ◽  
Total Ozone Column ◽  
Function Fitting ◽  
Ozone Column ◽  
Good Agreement ◽  
Column Product

Abstract. A scientific total ozone column product from Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) observations and the retrieval algorithm are presented. The retrieval employs the weighting function fitting approach (WFFA), a modification of the weighting function differential optical absorption spectroscopy (WFDOAS) technique. The total ozone columns retrieved with WFFA are in very good agreement with other datasets. A mean difference of 0.3 % with respect to ground-based Brewer and Dobson measurements is observed. Seasonal and latitudinal variations are well represented and in agreement with other satellite datasets. The comparison of our product with the operational product of OMPS-NM indicates a mean bias of around zero. The comparison with the Tropospheric Monitoring Instrument products (S5P/TROPOMI) OFFL and WFDOAS shows a persistent negative bias of about −0.6 % for OFFL and −2.5 % for WFDOAS. Larger differences are only observed in the polar regions. This data product is intended to be used for trend analysis and the retrieval of tropospheric ozone combined with the OMPS limb profiler data.

scholarly journals Direct-sun total ozone data from a Bentham spectroradiometer: methodology and comparison with satellite observations

2012 ◽  
Vol 5 (6) ◽  
pp. 8131-8160 ◽  
Author(s):  
M. Antón ◽  
R. Román ◽  
A. Valenzuela ◽  
F. J. Olmo ◽  
L. Alados-Arboledas
Keyword(s):  
Total Ozone ◽  
High Reliability ◽  
Surface Ozone ◽  
Lower Troposphere ◽  
Spectral Measurements ◽  
Retrieval Method ◽  
Stable Pattern ◽  
Differential Behavior ◽  
Relative Differences ◽  
Ozone Column

Abstract. A methodology to obtain the total ozone column (TOC) from the direct-solar spectral measurements of a Bentham spectroradiometer located at Granada (Spain) is presented in this paper. The method relies on the differential absorption technique using two pairs of direct irradiance at adjacent wavelengths between 305 and 340 nm. The extraterrestrial constant was determined from the extrapolation to zero air mass of each wavelength pair (Langley plot method). We checked the strong influence of the cloud cover on the Bentham TOC measurements using simultaneous sky images taken with an All-sky camera. Thus, reliable TOC data are exclusively obtained during cloud-free conditions or partly cloudy conditions without the solar disk obstructed. In this work, the hourly TOC averages retrieved by the Bentham instrument with a~standard deviation smaller than 3% (~ 10 Dobson Unit) are selected as high-quality TOC data. The analysis of the diurnal TOC variations during cloud-free days showed a differential behavior between the morning and afternoon periods. Thus, while the mornings exhibit an almost stable pattern, the afternoons displays a monotonic TOC increase which could be related to photochemical processes in the lower troposphere associated with the formation of surface ozone. Finally, the Bentham TOC measurements were validated against the satellite data derived from three satellite instruments: OMI, GOME and SCIAMACHY. The mean absolute values of the relative differences between satellite and ground-based data were smaller than 3% which highlight the high reliability of the retrieval method proposed in this paper to derive TOC data.

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