scholarly journals Using <sup>226</sup>Ra and <sup>228</sup>Ra isotopes to distinguish water mass distribution in the Canadian Arctic Archipelago

2020 ◽  
Vol 17 (20) ◽  
pp. 4937-4959
Author(s):  
Chantal Mears ◽  
Helmuth Thomas ◽  
Paul B. Henderson ◽  
Matthew A. Charette ◽  
Hugh MacIntyre ◽  
...  
Keyword(s):  
Water Exchange ◽  
Water Mass ◽  
Dissolved Inorganic Carbon ◽  
Canadian Arctic ◽  
Atlantic Water ◽  
Total Alkalinity ◽  
The Arctic ◽  
Future Research ◽  
Canadian Arctic Archipelago ◽  
Wide Range

Abstract. As a shelf-dominated basin, the Arctic Ocean and its biogeochemistry are heavily influenced by continental and riverine sources. Radium isotopes (226Ra, 228Ra, 224Ra, and 223Ra), are transferred from the sediments to seawater, making them ideal tracers of sediment–water exchange processes and ocean mixing. As the two long-lived isotopes of the radium quartet, 226Ra and 228Ra (226Ra with a t1∕2 of 1600 years and 228Ra with a t1∕2 of 5.8 years) can provide insight into the water mass compositions, distribution patterns, as well as mixing processes and their associated timescales throughout the Canadian Arctic Archipelago (CAA). The wide range of 226Ra and 228Ra activities, as well as of the 228Ra∕226Ra, measured in water samples collected during the 2015 GEOTRACES cruise, complemented by additional chemical tracers – dissolved inorganic carbon (DIC), total alkalinity (AT), barium (Ba), and the stable oxygen isotope composition of water (δ18O) – highlight the dominant biogeochemical, hydrographic, and bathymetric features of the CAA. Bathymetric features, such as the continental shelf and shallow coastal sills, are critical in modulating circulation patterns within the CAA, including the bulk flow of Pacific waters and the inhibited eastward flow of denser Atlantic waters through the CAA. Using a principal component analysis, we unravel the dominant mechanisms and apparent water mass end-members that shape the tracer distributions. We identify two distinct water masses located above and below the upper halocline layer throughout the CAA and distinctly differentiate surface waters in the eastern and western CAA. Furthermore, we highlight water exchange across 80∘ W, inferring a draw of Atlantic water (originating from Baffin Bay) into the CAA. This underscores the presence of an Atlantic water “U-turn” located at Barrow Strait, where the same water mass is seen along the northernmost edge at 80∘ W as well as along the southeasternmost confines of Lancaster Sound. Overall, this study provides a stepping stone for future research initiatives within the Canadian Arctic Archipelago, revealing how quantifying disparities in the distributions of radioactive tracers can provide valuable information on water mass distributions, flow patterns, and mixing within vulnerable areas such as the CAA.

scholarly journals Using <sup>226</sup>Ra and <sup>228</sup>Ra isotopes to distinguish water mass distribution in the Canadian Arctic Archipelago

2020 ◽  
Author(s):  
Chantal Mears ◽  
Helmuth Thomas ◽  
Paul B. Henderson ◽  
Matthew A. Charette ◽  
Hugh MacIntyre ◽  
...  
Keyword(s):  
Water Exchange ◽  
Water Mass ◽  
Dissolved Inorganic Carbon ◽  
Canadian Arctic ◽  
Atlantic Water ◽  
Radioactive Isotopes ◽  
Total Alkalinity ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
Wide Range

Abstract. As a shelf dominated basin, the Arctic Ocean and its biogeochemistry are heavily influenced by continental and riverine sources. Radium isotopes (226Ra, 228Ra, 224Ra, 223Ra), are transferred from the sediments to seawater, making them ideal tracers of sediment-water exchange processes and ocean mixing. 226Ra and 228Ra are the two longer-lived isotopes of the Radium Quartet (226Ra, t1/2 = 1600 y and 228Ra, t1/2 = 5.8 y). Because of their long half-lives they can provide insight into the water mass compositions, distribution patterns, as well as mixing processes and the associated timescales throughout the Canadian Arctic Archipelago (CAA). The wide range of 226Ra, 228Ra, and of the 228Ra / 226Ra ratio, measured in water samples collected during the 2015 GEOTRACES cruise, complemented by additional chemical tracers (dissolved inorganic carbon (DIC), total alkalinity (AT), barium (Ba), and the stable oxygen isotope composition of water (δ18O)) highlight the dominant biogeochemical, hydrographic and bathymetric features of the CAA. Bathymetric features, such as the continental shelf and shallow coastal sills, are critical in modulating circulation patterns within the CAA, including the bulk flow of Pacific waters and the inhibited eastward flow of denser Atlantic waters through the CAA. Using a Principal Component Analysis, we unravel the dominant mechanisms and the apparent water mass end-members that shape the tracer distributions. We identify two distinct water masses located above and below the upper halocline layer throughout the CAA, as well as distinctly differentiate surface waters in the eastern and western CAA. Furthermore, we identify water exchange across 80° W, inferring a draw of Atlantic water, originating from Baffin Bay, into the CAA. In other words, this implies the presence of an Atlantic water U-turn located at Barrow Strait, where the same water mass is seen along the northernmost edge at 80° W as well as along south-easternmost confines of Lancaster Sound. Overall, this study provides a stepping stone for future research initiatives within the Canadian Arctic Archipelago, revealing how quantifying disparities in radioactive isotopes can provide valuable information on the potential effects of climate change within vulnerable areas such as the CAA.

scholarly journals The recent state and variability of the carbonate system of the Canadian Arctic Archipelago and adjacent basins in the context of ocean acidification

2020 ◽  
Vol 17 (14) ◽  
pp. 3923-3942
Author(s):  
Alexis Beaupré-Laperrière ◽  
Alfonso Mucci ◽  
Helmuth Thomas
Keyword(s):  
Ocean Acidification ◽  
Dissolved Inorganic Carbon ◽  
Canadian Arctic ◽  
Canada Basin ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
Potential Threat ◽  
Carbonate System ◽  
System Parameters ◽  
Spatial Coverage

Abstract. Ocean acidification driven by the uptake of anthropogenic CO2 by the surface oceans constitutes a potential threat to the health of marine ecosystems around the globe. The Arctic Ocean is particularly vulnerable to acidification and thus is an ideal region to study the progression and effects of acidification before they become globally widespread. The appearance of undersaturated surface waters with respect to the carbonate mineral aragonite (ΩA<1), an important threshold beyond which the calcification and growth of some marine organisms might be hindered, has recently been documented in the Canada Basin and adjacent Canadian Arctic Archipelago (CAA), a dynamic region with an inherently strong variability in biogeochemical processes. Nonetheless, few of these observations were made in the last 5 years and the spatial coverage in the latter region is poor. We use a dataset of carbonate system parameters measured in the CAA and its adjacent basins (Canada Basin and Baffin Bay) from 2003 to 2016 to describe the recent state of these parameters across the Canadian Arctic and investigate the amplitude and sources of the system's variability over more than a decade. Our findings reveal that, in the summers of 2014 to 2016, the ocean surface across our study area served as a net CO2 sink and was partly undersaturated with respect to aragonite in the Canada Basin and the Queen Maud Gulf, the latter region exhibiting undersaturation over its entire water column at some locations. We estimate, using measurements made across several years, that approximately a third of the interannual variability in surface dissolved inorganic carbon (DIC) concentrations in the CAA results from fluctuations in biological activity. In consideration of the system's variability resulting from these fluctuations, we derive times of emergence of the anthropogenic ocean acidification signal for carbonate system parameters in the study area.

scholarly journals Regional variability of acidification in the Arctic: a sea of contrasts

2014 ◽  
Vol 11 (2) ◽  
pp. 293-308 ◽  
Author(s):  
E. E. Popova ◽  
A. Yool ◽  
Y. Aksenov ◽  
A. C. Coward ◽  
T. R. Anderson
Keyword(s):  
Climate Change ◽  
Primary Production ◽  
Arctic Ocean ◽  
Canadian Arctic ◽  
Atmospheric Co2 ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
Regional Variability ◽  
The Arctic Ocean ◽  
The Impact

Abstract. The Arctic Ocean is a region that is particularly vulnerable to the impact of ocean acidification driven by rising atmospheric CO2, with potentially negative consequences for calcifying organisms such as coccolithophorids and foraminiferans. In this study, we use an ocean-only general circulation model, with embedded biogeochemistry and a comprehensive description of the ocean carbon cycle, to study the response of pH and saturation states of calcite and aragonite to rising atmospheric pCO2 and changing climate in the Arctic Ocean. Particular attention is paid to the strong regional variability within the Arctic, and, for comparison, simulation results are contrasted with those for the global ocean. Simulations were run to year 2099 using the RCP8.5 (an Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5) scenario with the highest concentrations of atmospheric CO2). The separate impacts of the direct increase in atmospheric CO2 and indirect effects via impact of climate change (changing temperature, stratification, primary production and freshwater fluxes) were examined by undertaking two simulations, one with the full system and the other in which atmospheric CO2 was prevented from increasing beyond its preindustrial level (year 1860). Results indicate that the impact of climate change, and spatial heterogeneity thereof, plays a strong role in the declines in pH and carbonate saturation (Ω) seen in the Arctic. The central Arctic, Canadian Arctic Archipelago and Baffin Bay show greatest rates of acidification and Ω decline as a result of melting sea ice. In contrast, areas affected by Atlantic inflow including the Greenland Sea and outer shelves of the Barents, Kara and Laptev seas, had minimal decreases in pH and Ω because diminishing ice cover led to greater vertical mixing and primary production. As a consequence, the projected onset of undersaturation in respect to aragonite is highly variable regionally within the Arctic, occurring during the decade of 2000–2010 in the Siberian shelves and Canadian Arctic Archipelago, but as late as the 2080s in the Barents and Norwegian seas. We conclude that, for future projections of acidification and carbonate saturation state in the Arctic, regional variability is significant and needs to be adequately resolved, with particular emphasis on reliable projections of the rates of retreat of the sea ice, which are a major source of uncertainty.

scholarly journals Calcium carbonate saturation in the surface water of the Arctic Ocean: undersaturation in freshwater influenced shelves

2009 ◽  
Vol 6 (11) ◽  
pp. 2421-2431 ◽  
Author(s):  
M. Chierici ◽  
A. Fransson
Keyword(s):  
Calcium Carbonate ◽  
Surface Water ◽  
Cold Water ◽  
Dissolved Inorganic Carbon ◽  
Chukchi Sea ◽  
Total Alkalinity ◽  
The Arctic ◽  
Subsurface Water ◽  
Chukchi Peninsula ◽  
Bering Strait

Abstract. In the summer of 2005, we sampled surface water and measured pH and total alkalinity (AT) underway aboard IB Oden along the Northwest Passage from Cape Farewell (South Greenland) to the Chukchi Sea. We investigated the variability of carbonate system parameters, focusing particularly on carbonate concentration [CO32−] and calcium carbonate saturation states, as related to freshwater addition, biological processes and physical upwelling. Measurements on AT, pH at 15°C, salinity (S) and sea surface temperature (SST), were used to calculate total dissolved inorganic carbon (CT), [CO32−] and the saturation of aragonite (ΩAr) and calcite (ΩCa) in the surface water. The same parameters were measured in the water column of the Bering Strait. Some surface waters in the Canadian Arctic Archipelago (CAA) and on the Mackenzie shelf (MS) were found to be undersaturated with respect to aragonite (ΩAr<1). In these areas, surface water was low in AT and CT (<1500 μmol kg−1) relative to seawater and showed low [CO32−]. The low saturation states were probably due to the likely the effect of dilution due to freshwater addition by sea ice melt (CAA) and river runoff (MS). High AT and CT and low pH, corresponded with the lowest [CO32−], ΩAr and ΩCa, observed near Cape Bathurst and along the South Chukchi Peninsula. This was linked to the physical upwelling of subsurface water with elevated CO2. The highest surface ΩAr and ΩCa of 3.0 and 4.5, respectively, were found on the Chukchi Sea shelf and in the cold water north of Wrangel Island, which is heavily influenced by high CO2 drawdown and lower CT from intense biological production. In the western Bering Strait, the cold and saline Anadyr Current carries water that is enriched in AT and CT from enhanced organic matter remineralization, resulting in the lowest ΩAr (~1.2) of the area.

scholarly journals Inorganic carbon fluxes on the Mackenzie Shelf of the Beaufort Sea

2017 ◽  
Author(s):  
Jacoba Mol ◽  
Helmuth Thomas ◽  
Paul G. Myers ◽  
Xianmin Hu ◽  
Alfonso Mucci
Keyword(s):  
Sea Ice ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Beaufort Sea ◽  
Total Alkalinity ◽  
The Arctic ◽  
Surface Mixed Layer ◽  
Saturation State ◽  
Carbon Transfer ◽  
Mackenzie Shelf

Abstract. The Mackenzie Shelf in the southeastern Beaufort Sea is a region that has experienced large changes in the past several decades as warming, sea-ice loss, and increased river discharge have altered carbon cycling. Upwelling and downwelling events are common on the shelf, caused by strong, fluctuating along-shore winds, resulting in cross-shelf Ekman transport, and an alternating estuarine and anti-estuarine circulation. Downwelling carries inorganic carbon and other remineralization products off the shelf and into the deep basin for possible long-term storage in the world oceans. Upwelling carries dissolved inorganic carbon (DIC) and nutrient-rich waters from the Pacific-origin upper halocline layer (UHL) onto the shelf. Profiles of DIC and total alkalinity (TA) taken in August and September of 2014 are used to investigate the cycling of inorganic carbon on the Mackenzie Shelf. The along-shore transport of water and the cross-shelf transport of inorganic carbon are quantified using velocity field output from a simulation of the Arctic and Northern Hemisphere Atlantic (ANHA4) configuration of the Nucleus of European Modelling of the Ocean (NEMO) framework. A strong upwelling event prior to sampling on the Mackenzie Shelf is analyzed and the resulting influence on the carbonate system, including the saturation state of waters with respect to aragonite and pH, is investigated. TA and the oxygen isotope ratio of water (δ18O) are used to examine water-mass distributions in the study area and to investigate the influence of Pacific Water, Mackenzie River freshwater, and sea-ice melt on carbon dynamics and air-sea fluxes of carbon dioxide (CO2) in the surface mixed layer. Understanding carbon transfer in this seasonally dynamic environment is key to quantify the importance of Arctic shelf regions to the global carbon cycle and provide a basis for understanding how it will respond to the aforementioned climate-induced changes.

ADDITIONAL HEAT FLOW DETERMINATIONS IN THE AREA OF MOULD BAY, ARCTIC CANADA

1966 ◽  
Vol 3 (2) ◽  
pp. 237-246 ◽  
Author(s):  
W. S. B. Paterson ◽  
L. K. Law
Keyword(s):  
Heat Flow ◽  
Canadian Arctic ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
General Area ◽  
Geothermal Heat ◽  
Field Methods ◽  
The Mean ◽  
Water Depths ◽  
Made In

Seven determinations of geothermal heat flow were made in the general area of southern Prince Patrick Island in the Canadian Arctic Archipelago. Measurements were made from sea ice in water depths of between 200 and 600 m. The mean heat flow for the two stations on the continental shelf in the Arctic Ocean was 0.46 ± 0.08 μcal cm−2 s−1. The mean heat flow for the five stations in the channels to the east of Mould Bay was 1.46 ± 0.16 μcal cm−2 s−1. The instrument and field methods are described. Errors due to the instrument and to the environment are discussed.

scholarly journals Arctic marine secondary organic aerosol contributes significantly to summertime particle size distributions in the Canadian Arctic Archipelago

2019 ◽  
Vol 19 (5) ◽  
pp. 2787-2812 ◽  
Author(s):  
Betty Croft ◽  
Randall V. Martin ◽  
W. Richard Leaitch ◽  
Julia Burkart ◽  
Rachel Y.-W. Chang ◽  
...  
Keyword(s):  
Particle Size ◽  
Size Distribution ◽  
Secondary Organic Aerosol ◽  
Canadian Arctic ◽  
Particle Growth ◽  
Organic Aerosol ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
Size Distributions ◽  
Fractional Error

Abstract. Summertime Arctic aerosol size distributions are strongly controlled by natural regional emissions. Within this context, we use a chemical transport model with size-resolved aerosol microphysics (GEOS-Chem-TOMAS) to interpret measurements of aerosol size distributions from the Canadian Arctic Archipelago during the summer of 2016, as part of the “NETwork on Climate and Aerosols: Addressing key uncertainties in Remote Canadian Environments” (NETCARE) project. Our simulations suggest that condensation of secondary organic aerosol (SOA) from precursor vapors emitted in the Arctic and near Arctic marine (ice-free seawater) regions plays a key role in particle growth events that shape the aerosol size distributions observed at Alert (82.5∘ N, 62.3∘ W), Eureka (80.1∘ N, 86.4∘ W), and along a NETCARE ship track within the Archipelago. We refer to this SOA as Arctic marine SOA (AMSOA) to reflect the Arctic marine-based and likely biogenic sources for the precursors of the condensing organic vapors. AMSOA from a simulated flux (500 µgm-2day-1, north of 50∘ N) of precursor vapors (with an assumed yield of unity) reduces the summertime particle size distribution model–observation mean fractional error 2- to 4-fold, relative to a simulation without this AMSOA. Particle growth due to the condensable organic vapor flux contributes strongly (30 %–50 %) to the simulated summertime-mean number of particles with diameters larger than 20 nm in the study region. This growth couples with ternary particle nucleation (sulfuric acid, ammonia, and water vapor) and biogenic sulfate condensation to account for more than 90 % of this simulated particle number, which represents a strong biogenic influence. The simulated fit to summertime size-distribution observations is further improved at Eureka and for the ship track by scaling up the nucleation rate by a factor of 100 to account for other particle precursors such as gas-phase iodine and/or amines and/or fragmenting primary particles that could be missing from our simulations. Additionally, the fits to the observed size distributions and total aerosol number concentrations for particles larger than 4 nm improve with the assumption that the AMSOA contains semi-volatile species: the model–observation mean fractional error is reduced 2- to 3-fold for the Alert and ship track size distributions. AMSOA accounts for about half of the simulated particle surface area and volume distributions in the summertime Canadian Arctic Archipelago, with climate-relevant simulated summertime pan-Arctic-mean top-of-the-atmosphere aerosol direct (−0.04 W m−2) and cloud-albedo indirect (−0.4 W m−2) radiative effects, which due to uncertainties are viewed as an order of magnitude estimate. Future work should focus on further understanding summertime Arctic sources of AMSOA.

Geomorphic diversity and complexity of the inner shelf, Canadian Arctic Archipelago, based on LiDAR and multibeam sonar surveys

2020 ◽  
Vol 57 (1) ◽  
pp. 123-132
Author(s):  
John Shaw ◽  
D. Patrick Potter ◽  
Yongsheng Wu
Keyword(s):  
Sea Level ◽  
Gas Hydrate ◽  
Canadian Arctic ◽  
Slight Modification ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
Beach Ridge ◽  
Terrestrial Lidar ◽  
Sea Levels ◽  
Glacial Landforms

Data from two surveys by multi-beam sonar and two by marine/terrestrial LiDAR are used to evaluate the geomorphology of the seafloor in littoral areas of the Canadian Arctic Channels, near King William Island, Nunavut. Submarine terrains show well-preserved glacial landforms (drumlins, mega-scale glacial lineations, iceberg-turbated terrain, recessional moraines, and glaciofluvial landforms) with only slight modification by modern processes (wave action and sea-ice activity). At Gjoa Haven the seafloor is imprinted by fields of pits 2 m wide and 0.15 m deep. They may result from gas hydrate dissolution triggered by falling relative sea levels. The Arctic Archipelago displays what might be termed inverted terrains: marine terrains, chiefly beach ridge complexes, exist above modern sea level and well-preserved glacial terrains are present below modern sea level. This is the inverse of the submerging regimes of Atlantic Canada, where glacial terrains exist on land, but below sea level they have been effaced and modified by marine processes down to the lowstand depth.

Recent changes in the exchange of sea ice between the Arctic Ocean and the Canadian Arctic Archipelago

2013 ◽  
Vol 118 (7) ◽  
pp. 3595-3607 ◽  
Author(s):  
Stephen E. L. Howell ◽  
Trudy Wohlleben ◽  
Mohammed Dabboor ◽  
Chris Derksen ◽  
Alexander Komarov ◽  
...  
Keyword(s):  
Sea Ice ◽  
Arctic Ocean ◽  
Canadian Arctic ◽  
The Arctic ◽  
Canadian Arctic Archipelago ◽  
The Arctic Ocean
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