scholarly journals Trends of anthropogenic CO<sub>2</sub> storage in North Atlantic water masses

2010 ◽  
Vol 7 (5) ◽  
pp. 1789-1807 ◽  
Author(s):  
F. F. Pérez ◽  
M. Vázquez-Rodríguez ◽  
H. Mercier ◽  
A. Velo ◽  
P. Lherminier ◽  
...  

Abstract. A high-quality inorganic carbon system database, spanning over three decades (1981–2006) and comprising of 13 cruises, has allowed the applying of the φC°T method and coming up with estimates of the anthropogenic CO2 (Cant) stored in the main water masses of the North Atlantic. In the studied region, strong convective processes convey surface properties, like Cant, into deeper ocean layers and grants this region an added oceanographic interest from the point of view of air-sea CO2 exchanges. Generally, a tendency for decreasing Cant storage rates towards the deep layers has been observed. In the Iberian Basin, the North Atlantic Deep Water has low Cant concentrations and negligible storage rates, while the North Atlantic Central Water in the upper layers shows the largest Cant values and the largest annual increase of its average concentration (1.13 ± 0.14 μmol kg−1 yr−1). This unmatched rate of change in the Cant concentration of the warm upper limb of the Meridional Overturning Circulation decreases towards the Irminger basin (0.68 ± 0.06 μmol kg−1 yr−1) due to the lowering of the buffering capacity. The mid and deep waters in the Irminger Sea show rather similar Cant concentration rates of increase (between 0.33 and 0.45 μmol kg−1 yr−1), whereas in the Iceland basin these layers seem to have been less affected by Cant. Overall, the Cant storage rates in the North Atlantic subpolar gyre during the first half of the 1990s, when a high North Atlantic Oscillation (NAO) phase was dominant, are ~48% higher than during the 1997–2006 low NAO phase that followed. This result suggests that a net decrease in the strength of the North Atlantic sink of atmospheric CO2 has taken place during the present decade. The changes in deep-water ventilation are the main driving processes causing this weakening of the North Atlantic CO2 sink.

2010 ◽  
Vol 7 (1) ◽  
pp. 165-202
Author(s):  
F. F. Pérez ◽  
M. Vázquez-Rodríguez ◽  
H. Mercier ◽  
A. Velo ◽  
P. Lherminier ◽  
...  

Abstract. A high-quality inorganic carbon system database spanning over three decades (1981–2006) and comprising 13 cruises has allowed applying the φCT° method and coming up with accurate estimates of the anthropogenic CO2 (Cant) stored in the main water masses of the North Atlantic. In the studied region, strong convective processes convey surface properties, like Cant, into deeper ocean layers and confer this region an added oceanographic interest from the point of view of air-sea CO2 exchanges. Commonly, a tendency for decreasing Cant storage rates towards the deep layers has been observed. In the Iberian Basin, the deep waters (North Atlantic Deep Water) have low Cant values and negligible Cant storage rates, while the North Atlantic Central Water in the upper layers shows the largest Cant concentrations and capacity to increase its storage on a yearly basis (1.13±0.14 μmol kg−1 yr−1). This unmatched Cant storage capacity of the warm upper limb of the Meridional Overturning Circulation weakens towards the Irminger basin (0.68±0.06 μmol kg−1 yr−1) due to the lowering of the buffering capacity. The mid and deep waters in the Irminger Sea show rather homogeneous Cant storage rates (between 0.33 and 0.45 μmol kg−1 yr−1), whereas in the Iceland basin these layers seem to have been less affected by Cant. The Cant storage rates in the study region during the 1991–1997 high NAO (North Atlantic Oscillation) phase are ~48% higher than during the 1997–2006 low NAO phase that followed. This result suggests that a net decrease in the strength of the North Atlantic sink of atmospheric CO2has taken place during the present decade. The changes in deep-water ventilation together with a detrimental renewal of the main water masses are likely the main driving processes causing this weakening of the North Atlantic CO2sink.


1998 ◽  
Vol 180 ◽  
pp. 163-167
Author(s):  
Antoon Kuijpers ◽  
Jørn Bo Jensen ◽  
Simon R . Troelstra ◽  
And shipboard scientific party of RV Professor Logachev and RV Dana

Direct interaction between the atmosphere and the deep ocean basins takes place today only in the Southern Ocean near the Antarctic continent and in the northern extremity of the North Atlantic Ocean, notably in the Norwegian–Greenland Sea and Labrador Sea. Cooling and evaporation cause surface waters in the latter region to become dense and sink. At depth, further mixing occurs with Arctic water masses from adjacent polar shelves. Export of these water masses from the Norwegian–Greenland Sea (Norwegian Sea Overflow Water) to the North Atlantic basin occurs via two major gateways, the Denmark Strait system and the Faeroe– Shetland Channel and Faeroe Bank Channel system (e.g. Dickson et al. 1990; Fig.1). Deep convection in the Labrador Sea produces intermediate waters (Labrador Sea Water), which spreads across the North Atlantic. Deep waters thus formed in the North Atlantic (North Atlantic Deep Water) constitute an essential component of a global ‘conveyor’ belt extending from the North Atlantic via the Southern and Indian Oceans to the Pacific. Water masses return as a (warm) surface water flow. In the North Atlantic this is the Gulf Stream and the relatively warm and saline North Atlantic Current. Numerous palaeo-oceanographic studies have indicated that climatic changes in the North Atlantic region are closely related to changes in surface circulation and in the production of North Atlantic Deep Water. Abrupt shut-down of the ocean-overturning and subsequently of the conveyor belt is believed to represent a potential explanation for rapid climate deterioration at high latitudes, such as those that caused the Quaternary ice ages. Here it should be noted, that significant changes in deep convection in Greenland waters have also recently occurred. While in the Greenland Sea deep water formation over the last decade has drastically decreased, a strong increase of deep convection has simultaneously been observed in the Labrador Sea (Sy et al. 1997).


2018 ◽  
Vol 14 (11) ◽  
pp. 1639-1651 ◽  
Author(s):  
Gloria M. Martin-Garcia ◽  
Francisco J. Sierro ◽  
José A. Flores ◽  
Fátima Abrantes

Abstract. The southwestern Iberian margin is highly sensitive to changes in the distribution of North Atlantic currents and to the position of oceanic fronts. In this work, the evolution of oceanographic parameters from 812 to 530 ka (MIS20–MIS14) is studied based on the analysis of planktonic foraminifer assemblages from site IODP-U1385 (37∘34.285′ N, 10∘7.562′ W; 2585 m b.s.l.). By comparing the obtained results with published records from other North Atlantic sites between 41 and 55∘ N, basin-wide paleoceanographic conditions are reconstructed. Variations of assemblages dwelling in different water masses indicate a major change in the general North Atlantic circulation during MIS16, coinciding with the definite establishment of the 100 ky cyclicity associated with the mid-Pleistocene transition. At the surface, this change consisted in the redistribution of water masses, with the subsequent thermal variation, and occurred linked to the northwestward migration of the Arctic Front (AF), and the increase in the North Atlantic Deep Water (NADW) formation with respect to previous glacials. During glacials prior to MIS16, the NADW formation was very weak, which drastically slowed down the surface circulation; the AF was at a southerly position and the North Atlantic Current (NAC) diverted southeastwards, developing steep south–north, and east–west, thermal gradients and blocking the arrival of warm water, with associated moisture, to high latitudes. During MIS16, the increase in the meridional overturning circulation, in combination with the northwestward AF shift, allowed the arrival of the NAC to subpolar latitudes, multiplying the moisture availability for ice-sheet growth, which could have worked as a positive feedback to prolong the glacials towards 100 ky cycles.


2021 ◽  
Author(s):  
Philippe Miron ◽  
Maria J. Olascoaga ◽  
Francisco J. Beron-Vera ◽  
Kimberly L. Drouin ◽  
M. Susan Lozier

&lt;p&gt;The North Atlantic Deep Water (NADW) flows equatorward along the Deep Western Boundary Current (DWBC) as well as interior pathways and is a critical part of the Atlantic Meridional Overturning Circulation. Its upper layer, the Labrador Sea Water (LSW), is formed by open-ocean deep convection in the Labrador and Irminger Seas while its lower layers, the Iceland&amp;#8211;Scotland Overflow Water (ISOW) and the Denmark Strait Overflow Water (DSOW), are formed north of the Greenland&amp;#8211;Iceland&amp;#8211;Scotland Ridge.&lt;/p&gt;&lt;p&gt;In recent years, more than two hundred acoustically-tracked subsurface floats have been deployed in the deep waters of the North Atlantic. &amp;#160;Studies to date have highlighted water mass pathways from launch locations, but due to limited float trajectory lengths, these studies have been unable to identify pathways connecting &amp;#160;remote regions.&lt;/p&gt;&lt;p&gt;This work presents a framework to explore deep water pathways from their respective sources in the North Atlantic using Markov Chain (MC) modeling and Transition Path Theory (TPT). Using observational trajectories released as part of OSNAP and the Argo projects, we constructed two MCs that approximate the lower and upper layers of the NADW Lagrangian dynamics. The reactive NADW pathways&amp;#8212;directly connecting NADW sources with a target at 53&amp;#176;N&amp;#8212;are obtained from these MCs using TPT.&lt;/p&gt;&lt;p&gt;Preliminary results show that twenty percent more pathways of the upper layer(LSW) reach the ocean interior compared to &amp;#160;the lower layer (ISOW, DSOW), which mostly flows along the DWBC in the subpolar North Atlantic. Also identified are the Labrador Sea recirculation pathways to the Irminger Sea and the direct connections from the Reykjanes Ridge to the eastern flank of the Mid&amp;#8211;Atlantic Ridge, both previously observed. Furthermore, we quantified the eastern spread of the LSW to the area surrounding the Charlie&amp;#8211;Gibbs Fracture Zone and compared it with previous analysis. Finally, the residence time of the upper and lower layers are assessed and compared to previous observations.&lt;/p&gt;


2018 ◽  
Vol 15 (7) ◽  
pp. 2075-2090 ◽  
Author(s):  
Maribel I. García-Ibáñez ◽  
Fiz F. Pérez ◽  
Pascale Lherminier ◽  
Patricia Zunino ◽  
Herlé Mercier ◽  
...  

Abstract. We present the distribution of water masses along the GEOTRACES-GA01 section during the GEOVIDE cruise, which crossed the subpolar North Atlantic Ocean and the Labrador Sea in the summer of 2014. The water mass structure resulting from an extended optimum multiparameter (eOMP) analysis provides the framework for interpreting the observed distributions of trace elements and their isotopes. Central Waters and Subpolar Mode Waters (SPMW) dominated the upper part of the GEOTRACES-GA01 section. At intermediate depths, the dominant water mass was Labrador Sea Water, while the deep parts of the section were filled by Iceland–Scotland Overflow Water (ISOW) and North-East Atlantic Deep Water. We also evaluate the water mass volume transports across the 2014 OVIDE line (Portugal to Greenland section) by combining the water mass fractions resulting from the eOMP analysis with the absolute geostrophic velocity field estimated through a box inverse model. This allowed us to assess the relative contribution of each water mass to the transport across the section. Finally, we discuss the changes in the distribution and transport of water masses between the 2014 OVIDE line and the 2002–2010 mean state. At the upper and intermediate water levels, colder end-members of the water masses replaced the warmer ones in 2014 with respect to 2002–2010, in agreement with the long-term cooling of the North Atlantic Subpolar Gyre that started in the mid-2000s. Below 2000 dbar, ISOW increased its contribution in 2014 with respect to 2002–2010, with the increase being consistent with other estimates of ISOW transports along 58–59° N. We also observed an increase in SPMW in the East Greenland Irminger Current in 2014 with respect to 2002–2010, which supports the recent deep convection events in the Irminger Sea. From the assessment of the relative water mass contribution to the Atlantic Meridional Overturning Circulation (AMOC) across the OVIDE line, we conclude that the larger AMOC intensity in 2014 compared to the 2002–2010 mean was related to both the increase in the northward transport of Central Waters in the AMOC upper limb and to the increase in the southward flow of Irminger Basin SPMW and ISOW in the AMOC lower limb.


2020 ◽  
Author(s):  
Jasmin M. Link ◽  
Norbert Frank

&lt;p&gt;Glacial Termination V is one of the most extreme glacial-interglacial transitions of the past 800 ka [1]. However, the changes in orbital forcing from Marine Isotope Stage (MIS) 12 to 11 are comparatively weak. In addition, MIS 11c is exceptionally distinct compared to other interglacials with for example a longer duration [2] and a higher-than-present sea level [3] despite a relative low incoming insolation. Therefore, the term &amp;#8220;MIS 11 paradox&amp;#8221; was coined [4]. However, only little is known about the Atlantic overturning circulation during this time interval [e.g. 5,6].&lt;/p&gt;&lt;p&gt;Here, we present Atlantic-wide deep water circulation patterns spanning the glacial maximum of MIS 12, Termination V, and MIS 11. Therefore, sediment cores throughout the Atlantic were analyzed regarding their Nd isotopic composition of authigenic coatings to reconstruct the provenance of the prevailing bottom water masses.&lt;/p&gt;&lt;p&gt;During the glacial maximum of MIS 12, the deep Atlantic Ocean was bathed with a higher amount of southern sourced water compared to the following interglacial. Termination V is represented by a sharp transition in the high-accumulating sites from the North Atlantic with a switch to northern sourced water masses. MIS 11 is characterized through an active deep water formation in the North Atlantic with active overflows from the Nordic Seas, only disrupted by a short deterioration. A strong export of northern sourced water masses to the South Atlantic points to an overall strong overturning circulation.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;[1] Lang and Wolff 2011, Climate of the Past 7: 361-380.&lt;/p&gt;&lt;p&gt;[2] Candy et al. 2014, Earth-Science Reviews 128: 18-51.&lt;/p&gt;&lt;p&gt;[3] Dutton et al. 2015, Science 349: aaa4019.&lt;/p&gt;&lt;p&gt;[4] Berger and Wefer 2003, Geophysical Monograph 137: 41-60.&lt;/p&gt;&lt;p&gt;[5] Dickson et al. 2009, Nature Geoscience 2: 428-433.&lt;/p&gt;&lt;p&gt;[6] V&amp;#225;zquez Riveiros et al. 2013, EPSL 371-372: 258-268.&lt;/p&gt;


2019 ◽  
Author(s):  
Jianjun Zou ◽  
Xuefa Shi ◽  
Aimei Zhu ◽  
Selvaraj Kandasamy ◽  
Xun Gong ◽  
...  

Abstract. Lower glacial atmospheric CO2 concentrations have been attributed to carbon sequestration in deep oceans. However, potential roles of voluminous subtropical North Pacific in modulating atmospheric CO2 levels on millennial timescale are poorly constrained. Further, an increase in respired CO2 concentration in the glacial deep ocean due to biological pump generally is coeval with less oxygenation in the subsurface layer. This link thus offers a chance to visit oceanic ventilation and the coeval export productivity based on redox-controlled sedimentary geochemical parameters. Here we investigate a suite of sediment geochemical proxies to understand the sedimentary oxygenation variations in the subtropical North Pacific (core CSH1) over the last 50 thousand years (ka). Our results suggest that sedimentary oxygenation at mid-depths of the subtropical North Pacific intensifies during the episodes of late glacial (50–25 ka), Last Glacial Maximum (LGM) and also the interval after 8.5 ka, especially pronounced for the North Atlantic millennial-scale abrupt cold events of the Younger Dryas, Heinrich Stadial (HS) 1 and 2. On the other hand, oxygen-depleted seawater is found during the Bölling-Alleröd (B/A) and Preboreal. Our findings of enhanced sedimentary oxygenation in the subtropical North Pacific is aligned with intensified formation of North Pacific Intermediate Water (NPIW) during cold spells, while the ameliorated sedimentary oxygenation seems to be linked with the intensified Kuroshio Current since 8.5 ka. In our results, diminished sedimentary oxygenation during the B/A indicates an enhanced CO2 sequestration at mid-depth waters, along with slight increase in atmospheric CO2 concentration. Mechanistically, we speculate that these millennial-scale changes were linked to the strength of North Atlantic Deep Water, leading to intensification of NPIW formation and enhanced abyss flushing during deglacial cold and warm intervals, respectively. Enhanced formation of NPIW seem to be driven by the perturbation of sea ice formation and sea surface salinity oscillation in high latitude North Pacific through atmospheric and oceanic teleconnection. During the B/A, decreased sedimentary oxygenation likely resulted from an upward penetration of aged deep water into the intermediate-depth in the North Pacific, corresponding to a resumption of Atlantic Meridional Overturning Circulation.


2016 ◽  
Author(s):  
Pierre Burckel ◽  
Claire Waelbroeck ◽  
Yiming Luo ◽  
Didier Roche ◽  
Sylvain Pichat ◽  
...  

Abstract. We reconstruct the geometry and strength of the Atlantic Meridional Overturning Circulation during Heinrich Stadial 2 and three Greenland interstadials of the 20–50 ka period based on the comparison of new and published sedimentary 231Pa/230Th data with simulated sedimentary 231Pa/230Th. We show that the deep Atlantic circulation during these interstadials was very different from that of the Holocene. Northern-sourced waters likely circulated above 2500 m depth, with a flow rate lower than that of the present day North Atlantic Deep Water (NADW). Southern-sourced deep waters most probably flowed northwards below 4000 m depth into the North Atlantic basin, and then southwards as a return flow between 2500 and 4000 m depth. The flow rate of this southern-sourced deep water was likely larger than that of the modern Antarctic Bottom Water (AABW). At the onset of Heinrich Stadial 2, the structure of the AMOC significantly changed. The deep Atlantic was probably directly affected by a southern sourced water mass below 2500 m depth, while a slow southward flowing water mass originating from the North Atlantic likely influenced depths between 1500 and 2500 m down to the equator.


2021 ◽  
Vol 18 (5) ◽  
pp. 1689-1701
Author(s):  
Jon Olafsson ◽  
Solveig R. Olafsdottir ◽  
Taro Takahashi ◽  
Magnus Danielsen ◽  
Thorarinn S. Arnarson

Abstract. The North Atlantic north of 50∘ N is one of the most intense ocean sink areas for atmospheric CO2 considering the flux per unit area, 0.27 Pg-C yr−1, equivalent to −2.5 mol C m−2 yr−1. The northwest Atlantic Ocean is a region with high anthropogenic carbon inventories. This is on account of processes which sustain CO2 air–sea fluxes, in particular strong seasonal winds, ocean heat loss, deep convective mixing, and CO2 drawdown by primary production. The region is in the northern limb of the global thermohaline circulation, a path for the long-term deep-sea sequestration of carbon dioxide. The surface water masses in the North Atlantic are of contrasting origins and character, with the northward-flowing North Atlantic Drift, a Gulf Stream offspring, on the one hand and on the other hand the cold southward-moving low-salinity Polar and Arctic waters with signatures from Arctic freshwater sources. We have studied by observation the CO2 air–sea flux of the relevant water masses in the vicinity of Iceland in all seasons and in different years. Here we show that the highest ocean CO2 influx is to the Arctic and Polar waters, respectively, -3.8±0.4 and -4.4±0.3 mol C m−2 yr−1. These waters are CO2 undersaturated in all seasons. The Atlantic Water is a weak or neutral sink, near CO2 saturation, after poleward drift from subtropical latitudes. These characteristics of the three water masses are confirmed by data from observations covering 30 years. We relate the Polar Water and Arctic Water persistent undersaturation and CO2 influx to the excess alkalinity derived from Arctic sources. Carbonate chemistry equilibrium calculations clearly indicate that the excess alkalinity may support at least 0.058 Pg-C yr−1, a significant portion of the North Atlantic CO2 sink. The Arctic contribution to the North Atlantic CO2 sink which we reveal was previously unrecognized. However, we point out that there are gaps and conflicts in the knowledge about the Arctic alkalinity and carbonate budgets and that future trends in the North Atlantic CO2 sink are connected to developments in the rapidly warming and changing Arctic. The results we present need to be taken into consideration for the following question: will the North Atlantic continue to absorb CO2 in the future as it has in the past?


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