Spatio-temporal variability of natural organic matter in Lancang River: concentration, sources and destination

2020 ◽  
Author(s):  
Ting Wang
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Natural Organic Matter ◽  
Temporal Variability ◽  
Anthropogenic Activities ◽  
Sharp Decrease ◽  
C3 Plants ◽  
Lancang River ◽  
Spatio Temporal ◽  
The Impact

<p>Natural organic matter (NOM) played an important role in the riverine and global carbon cycle. In order to evaluate the impact of river discharge and anthropogenic activities on the spatio-temporal variability of NOM content and sources in Lancang River, China, a comprehensive study was conducted in two years from the head to the leave-boundary section. As results, the DOC value ranged among 0.91-2.80 mg/L, with sharp decrease in the middle reaches and downstream. While the SOC value significantly enhanced along the water flow, varied from 0.06% to 3.54%. The isotopic composition of organic carbon (δ13C) suggested that predominant contribution of NOM is C3 plants in the upper reach, algae and soil organic matter in the middle reach, and aquatic plants in the downstream. EEM-PARAFAC results proved that NOM in Lancang River is mainly terrestrial organic carbon, while in situ microbial transformed NOM is very low. Moreover, the sharp increase of dissolved CO2 concentration in the lower reaches confirmed the strong respiration of microorganisms due to the higher DO and water temperature, thus resulted in the significantly different fluctuations of DOC and SOC.</p>

The impact of alum coagulation on pharmaceutically active compounds, endocrine disrupting compounds and natural organic matter

2013 ◽  
Vol 13 (5) ◽  
pp. 1348-1357 ◽  
Author(s):  
Sabrina Diemert ◽  
Robert C. Andrews
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
River Water ◽  
Natural Organic Matter ◽  
Endocrine Disrupting Compounds ◽  
Pharmaceutically Active Compounds ◽  
Active Compounds ◽  
Endocrine Disrupting ◽  
Grand River ◽  
The Impact

This study assessed the impact of chemical coagulation using alum on the removal of three endocrine-disrupting compounds (EDCs; bisphenol A, clofibric acid and estriol) and nine pharmaceutically active compounds (PhACs; acetaminophen, carbamazepine, diclofenac, gemfibrozil, ketoprofen, naproxen, pentoxifylline, sulfamethoxazole and sulfachloropyridazine). The impact on natural organic matter (NOM) fractions as determined using liquid chromatography–organic carbon detection (LC–OCD; total dissolved organic carbon (DOC), hydrophobic DOC, biopolymers, humic substances, building blocks, low molecular weight neutrals and acids) was also examined. Three test surface waters were included: Lake Ontario, Grand River and Otonabee River water (Ontario, Canada). Gemfibrozil concentrations were reduced in both Otonabee and Grand River waters. Reductions were noted for carbamazepine and (inconsistently) for acetaminophen, and estrone appeared to increase in concentration in Grand River water with increasing alum doses. NOM removal was primarily attributed to the humic fraction, with small reductions in biopolymers in all of the waters studied.

Advanced oxidation processes: flowsheet options for bulk natural organic matter removal

2004 ◽  
Vol 4 (4) ◽  
pp. 113-119 ◽  
Author(s):  
C.A. Murray ◽  
S.A. Parsons
Keyword(s):  
Molecular Weight ◽  
Organic Matter ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Natural Organic Matter ◽  
Advanced Oxidation Processes ◽  
Advanced Oxidation ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Oxidation Processes

Advanced oxidation processes have been reported to have the potential to remove natural organic matter from source waters. Of these Fenton's reagent, photo-Fenton's reagent and titanium dioxide photocatalysis are the three most promising processes. Compared to conventional coagulation/flocculation processes they have higher removal efficiencies in terms of both dissolved organic carbon and UV254 absorbance. Under optimum reaction conditions all three remove over 80% dissolved organic carbon and 0% UV254 absorbance. In addition the enhanced removal of natural organic matter leads to a corresponding reduction in the formation of disinfection by-products following chlorination of the treated water. Advanced oxidation processes give enhanced removal of organic species ranging from low to high molecular weight while coagulation/flocculation is inefficient at removing low molecular weight species. One additional benefit is all three processes produce less residuals compared to conventional coagulation, which is advantageous as the disposal of such residuals normally contributes a large proportion of the costs at water treatment works.

scholarly journals Natural organic matter removal by ion exchange at different positions in the drinking water treatment lane

2013 ◽  
Vol 6 (1) ◽  
pp. 1-10 ◽  
Author(s):  
A. Grefte ◽  
M. Dignum ◽  
E. R. Cornelissen ◽  
L. C. Rietveld
Keyword(s):  
Water Quality ◽  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Organic Carbon ◽  
Natural Organic Matter ◽  
Drinking Water Treatment ◽  
Biological Stability ◽  
Sand Filtration ◽  
Slow Sand Filtration

Abstract. To guarantee a good water quality at the customers tap, natural organic matter (NOM) should be (partly) removed during drinking water treatment. The objective of this research was to improve the biological stability of the produced water by incorporating anion exchange (IEX) for NOM removal. Different placement positions of IEX in the treatment lane (IEX positioned before coagulation, before ozonation or after slow sand filtration) and two IEX configurations (MIEX® and fluidized IEX (FIX)) were compared on water quality as well as costs. For this purpose the pre-treatment plant at Loenderveen and production plant Weesperkarspel of Waternet were used as a case study. Both, MIEX® and FIX were able to remove NOM (mainly the HS fraction) to a high extent. NOM removal can be done efficiently before ozonation and after slow sand filtration. The biological stability, in terms of assimilable organic carbon, biofilm formation rate and dissolved organic carbon, was improved by incorporating IEX for NOM removal. The operational costs were assumed to be directly dependent of the NOM removal rate and determined the difference between the IEX positions. The total costs for IEX for the three positions were approximately equal (0.0631 € m−3), however the savings on following treatment processes caused a cost reduction for the IEX positions before coagulation and before ozonation compared to IEX positioned after slow sand filtration. IEX positioned before ozonation was most cost effective and improved the biological stability of the treated water.

scholarly journals Effects of ozonation and temperature on biodegradation of natural organic matter in biological granular activated carbon filters

2010 ◽  
Vol 3 (1) ◽  
pp. 107-132 ◽  
Author(s):  
L. T. J. van der Aa ◽  
L. C. Rietveld ◽  
J. C. van Dijk
Keyword(s):  
Carbon Dioxide ◽  
Organic Matter ◽  
Activated Carbon ◽  
Organic Carbon ◽  
Natural Organic Matter ◽  
Granular Activated Carbon ◽  
Carbon Dioxide Production ◽  
Oxygen Removal ◽  
Theoretical Maximum ◽  
Increasing Temperature

Abstract. Four pilot (biological) granular activated carbon ((B)GAC) filters were operated to quantify the effects of ozonation and water temperature on the biodegradation of natural organic matter (NOM) in (B)GAC filters. Removal of dissolved organic carbon (DOC), assimilable organic carbon (AOC) and oxygen and the production of carbon dioxide were taken as indicators for NOM biodegradation. Ozonation stimulated DOC and AOC removal in the BGAC filters, but had no significant effect on oxygen removal and carbon dioxide production. The temperature had no significant effect on DOC and AOC removal, while oxygen removal and carbon dioxide production increased with increasing temperature. Multivariate linear regression was used to quantify these relations. In summer the ratio between oxygen consumption and DOC removal exceeded the theoretical maximum of 2.5 g O2·g C−1 and the ratio between carbon dioxide production and DOC removal exceeded the theoretical maximum of 3.7 g CO2·g C−1. Bioregeneration of large NOM molecules could explain this excesses and the non-correlation between DOC and AOC removal and oxygen removal and carbon dioxide production. However bioregeneration of large NOM molecules was considered not likely to happen, due to sequestration.

Dynamics of Aeolian Sand Streamers and Airflow Turbulence over a Beach Surface

2021 ◽  
Author(s):  
Andreas Baas
Keyword(s):  
Boundary Layer ◽  
Turbulent Boundary Layer ◽  
Temporal Variability ◽  
Large Scale ◽  
Sonic Anemometer ◽  
Dynamic Structure ◽  
Sand Transport ◽  
Video Imagery ◽  
Spatio Temporal ◽  
The Impact

<p>Sand transport by wind over granular beds displays dynamic structure and organisation in the form of streamers (aka ‘sand snakes’) that appear, meander and intertwine, and then dissipate as they are advected downwind. These patterns of saltating grain populations are thought to be initiated and controlled by coherent flow structures in the turbulent boundary layer wind that scrape over the bed surface raking up sand into entrainment. Streamer behaviour is thus fundamental to understanding sand transport dynamics, in particular its strong spatio-temporal variability, and is equally relevant to granular transport in other geophysical flows (fluvial, submarine).</p><p>This paper presents findings on streamer dynamics and associated wind turbulence observed in a field experiment on a beach, with measurements from 30Hz video-imagery using Large-Scale Particle Image Velocimetry (LS-PIV), combined with 50Hz wind measurements from 3D sonic anemometry and co-located sand transport rate monitoring using an array of laser particle counters (‘Wenglors’), all taking place over an area of ~10 m<sup>2</sup> and over periods of several minutes. The video imagery was used to identify when and where streamers advected past the sonic anemometer and laser sensors so that relationships could be detected between the passage of turbulence structures in the airflow and the length- and time-scales, propagation speeds, and sand transport intensities of associated streamers. The findings form the basis for a phenomenological model of streamer dynamics under turbulent boundary layer flows that predicts the impact of spatio-temporal variability on local measurement of sand transport.</p>

scholarly journals Dissolved and Particulate Organic Carbon in Icelandic Proglacial Streams: A First Estimate

Water ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 748 ◽  
Author(s):  
Peter Chifflard ◽  
Christina Fasching ◽  
Martin Reiss ◽  
Lukas Ditzel ◽  
Kyle S. Boodoo
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Particulate Organic Carbon ◽  
Ice Cap ◽  
Glacier Terminus ◽  
Fluorescence Measurements ◽  
Sampling Locations ◽  
Carbon Release ◽  
Annual Carbon ◽  
Spatio Temporal

Here for the first time, we analyze the concentration of dissolved (DOC) and particulate organic carbon (POC), as well as its optical properties (absorbance and fluorescence) from several proglacial streams across Iceland, the location of Europe’s largest non-polar ice cap. We found high spatial variability of DOC concentrations and dissolved organic matter (DOM) composition during peak melt, sampling 13 proglacial streams draining the 5 main Icelandic glaciers. Although glacial-derived organic matter (OM) was dominated by proteinaceous florescence, organic matter composition was variable among glaciers, often exhibiting relatively higher aromatic content and increased humification (based on absorbance and fluorescence measurements) closer to the glacier terminus, modulated by the presence of glacial lakes. Additional sampling locations the in flow path of the river Hvitá revealed that while POC concentrations decreased downstream, DOC concentrations and the autochthonous fraction of OM increased, suggesting the reworking of the organic carbon by microbial communities, with likely implications for downstream ecosystems as glaciers continue to melt. Based on our measured DOC concentrations ranging from 0.11 mg·L−1 to 0.94 mg·L−1, we estimate a potential annual carbon release of 0.008 ± 0.002 Tg·C·yr−1 from Icelandic glaciers. This non-conservative first estimate serves to highlight the potentially significant contribution of Icelandic pro-glacial streams to the global carbon cycle and the need for the quantification and determination of the spatio-temporal variation of DOC and POC fluxes and their respective drivers, particularly in light of increased rates of melting due to recent trends in climatic warming.

Comparison of disinfection byproduct (DBP) formation from different UV technologies at bench scale

2002 ◽  
Vol 2 (5-6) ◽  
pp. 515-521 ◽  
Author(s):  
W. Liu ◽  
S.A. Andrews ◽  
J.R. Bolton ◽  
K.G. Linden ◽  
C. Sharpless ◽  
...  
Keyword(s):  
Organic Matter ◽  
Carboxylic Acids ◽  
Natural Organic Matter ◽  
Uv Irradiation ◽  
Direct Action ◽  
Disinfection Byproduct ◽  
Pressure Medium ◽  
The Impact ◽  
As Effects

The impact of UV irradiation on disinfection byproduct (DBP) formation was investigated for low pressure, medium pressure and pulsed UV technologies using a broad range of UV doses. Four classes of DBPs (THMs, HAAs, aldehydes and carboxylic acids) were examined. This enabled the determination of effects resulting from the direct action of UV irradiation on natural organic matter (aldehydes, carboxylic acids) as well as effects on the ultimate formation of chlorinated DBPs (THMs and HAAs) from secondary chlorination. For doses of less than 1,000 mJ/cm2, UV irradiation did not affect THM and HAA formation in subsequent chlorination processes, however higher UV doses resulted in lower ultimate concentrations of THMs and HAAs. UV irradiation also resulted in the formation of aldehydes and carboxylic acids at UV doses above 500 mJ/cm2, compounds that are known to adversely effect drinking water biostability.

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