Geochemical modeling and multivariate statistical approach for assessing the groundwater quality, and mechanism of arsenic mobilization in Bahraich region, Indo-Gangetic plains, India

2021 ◽  
Author(s):  
Mohd Usman Khan ◽  
Nachiketa Rai ◽  
Mukesh Kumar Sharma
Keyword(s):  
Heavy Metal ◽  
Drinking Water ◽  
Heavy Metal Contamination ◽  
Geochemical Modeling ◽  
Sulfide Oxidation ◽  
Dissolution Mechanism ◽  
Multivariate Statistical ◽  
Gangetic Plains ◽  
Groundwater Samples

<p>As contamination in groundwater has been reported from various regions of the Indian subcontinent but no data related to heavy metal contamination of groundwater has been reported for the Bahraich area in the Indo-Gangetic plains. We report the first dataset on arsenic contamination and groundwater hydrogeochemistry, in Bahraich. This includes concentrations of heavy metal such as As, Mn, and Fe, along with major cations (Na<sup>+</sup>, K<sup>+</sup>, Ca<sup>2+</sup>and Mg<sup>2+</sup>) and anions (F<sup>-</sup>, Cl<sup>-</sup>, NO<sub>3</sub><sup>-</sup>, SO<sub>4</sub><sup>2-</sup> and PO<sub>4</sub><sup>3-</sup>), and dissolved organic carbon (DOC), along with various physico-chemical parameters such as EC, pH, and Eh from samples collected during two extensive field campaigns conducted during pre-monsoon, and post-monsoon seasons respectively. The combined use of geochemical modeling and multivariate statistical approaches such as principal component analysis (PCA) and correlation analysis (CA) suggest several processes affecting the geochemistry of groundwater including the lithological characteristics of aquifers and anthropogenic activities.</p><p>The groundwater of the study area predominantly belongs to the Ca-Mg-HCO<sub>3</sub> type hydrochemical facies. HCO<sub>3</sub><sup>−</sup>/Na<sup>+</sup> and Ca<sup>2+</sup>/Na<sup>+</sup> signatures of groundwater indicate the influence of silicate weathering and carbonate dissolution processes with the insignificant role of evaporate dissolution mechanism. As concentration was found to range from 0.6 μg/L to ~100 μg/L with almost 40% of the collected samples exceeding the WHO defined limit of 10 μg/L for drinking water. 70 % of the groundwater samples were found to have very high Fe concentrations exceeding the WHO guideline of 0.3 mg/l in drinking water. Mn concentrations in the groundwater samples were relatively low with only ~10 % of the samples exceeding the WHO defined limit for Mn (400 μg/L). The majority of the groundwater samples were found to be anoxic in nature showing low NO<sub>3</sub><sup>−</sup> & SO<sub>4</sub><sup>2-</sup> concentrations, high Fe & Mn and DOC concentrations, and negative Eh values.</p><p>Results from this study show that the reductive dissolution mechanism of iron oxyhydroxide is the dominant mechanism responsible for arsenic release in groundwater of the region, ruling out any role of sulfide oxidation and alkali desorption.</p><p> </p><p> </p>

Evaluation of heavy metal contamination in groundwater samples from Kapas Island, Terengganu, Malaysia

2013 ◽  
Vol 7 (3) ◽  
pp. 1087-1100 ◽  
Author(s):  
Noorain Mohd Isa ◽  
Ahmad Zaharin Aris ◽  
Wan Ying Lim ◽  
Wan Nor Azmin Wan Sulaiman ◽  
Sarva Mangala Praveena
Keyword(s):  
Heavy Metal ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Groundwater Samples

scholarly journals Multivariate Analysis and Geochemical Signatures of Shallow Groundwater in the Main Urban Area of Chongqing, Southwestern China

Water ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2833
Author(s):  
Si Chen ◽  
Zhonghua Tang ◽  
Jian Wang ◽  
Jialing Wu ◽  
Chang Yang ◽  
...  
Keyword(s):  
Geochemical Modeling ◽  
Shallow Groundwater ◽  
Poor Quality ◽  
Easy Access ◽  
Multivariate Statistical ◽  
Drinking Purposes ◽  
Groundwater Samples ◽  
New Findings ◽  
Group 2 ◽  
Group 1

Hydrogeochemical processes and quality assessment for shallow groundwater are pivotal issues to be solved in many regions over the world due to the easy access of shallow groundwater. In this study, eighty-six water samples were collected from shallow aquifers of Chongqing, China, during July–September 2019. Multivariate statistical techniques, major ion ratios, and geochemical modeling were integrated to investigate hydrogeochemical characteristics and controlling factors. Afterwards, groundwater quality in spatial was classified by entropy-weighted water quality index and geographic information system (GIS) spatial analysis. Groundwater samples were alkaline and possessed high total dissolved solids (TDS) values. Two-group samples were distinguished as mix cations-HCO3-SO4 (group 1) and Ca-Mg-SO4 (group 2) facies. Hydrogeochemical compositions of group 1 samples were dominated by silicate dissolution and ion exchange, while sulfate and calcite dissolution were the main factors influencing the hydrogeochemical characteristics of group 2. The overall quality of groundwater samples varied greatly from excellent quality to extremely poor quality. Group 1 samples were found with excellent and good quality and suitable for drinking purposes. Group 2 samples were all unsuitable for direct drinking purposes as the quality varied from medium to extremely poor, but were spatially limited. Groundwaters with relatively poor quality were due to dissolution of sulfate that were locally enriched in the aquifers. The new findings of this study are expected to provide the reference for future management and sustainable exploitation of groundwater in Chongqing.

Risk estimation and multivariate statistical analysis of the heavy metal content of drinking water samples

2018 ◽  
Vol 34 (10) ◽  
pp. 714-725
Author(s):  
Rajan Jakhu ◽  
Rohit Mehra
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Drinking Water ◽  
Statistical Analysis ◽  
Water Samples ◽  
Multivariate Statistical Analysis ◽  
Inductively Coupled Plasma ◽  
Principal Component ◽  
Multivariate Statistical ◽  
Drinking Water Samples

Drinking water samples of Jaipur and Ajmer districts of Rajasthan, India, were collected and analyzed for the measurement of concentration of heavy metals. The purpose of this study was to determine the sources of the heavy metals in the drinking water. Inductively coupled plasma mass spectrometry was used for the determination of the heavy metal concentrations, and for the statistical analysis of the data, principal component analysis and cluster analysis were performed. It was observed from the results that with respect to WHO guidelines, the water samples of some locations exceeded the contamination levels for lead (Pb), selenium (Se), and mercury (Hg), and with reference to the EPA guidelines, the samples were determined unsuitable for drinking because of high concentrations of Pb and Hg. Using multivariate statistical analysis, we determined that copper, manganese, arsenic, Se, and Hg were of anthropogenic origin, while Pb, copper, and cadmium were of geogenic origin. The present study reports the dominance of the anthropogenic contributions over geogenics in the studied area. The sources of the anthropogenic contaminants need to be investigated in a future study.

scholarly journals The role of sulphate-reducing bacteria in mercury-contaminated estuarine sediments : a case study of Durban Bay

2003 ◽  
Author(s):  
◽  
Elizabeth Anne Simpson
Keyword(s):  
Heavy Metal ◽  
Methyl Mercury ◽  
Heavy Metal Contamination ◽  
Desulfovibrio Desulfuricans ◽  
Estuarine Sediments ◽  
Physical Parameters ◽  
Sulfate Reducing ◽  
Initial Survey ◽  
Reducing Bacteria

Stimulated by the findings of international researchers, that the sulfate-reducing microorganism Desulfovibrio desulfuricans could be incriminated in the process of mercury bio-methylation, it was decided to test this hypothesis on sediments from selected areas of Durban Bay where elevated levels of the bio-hazardous heavy metal had previously been detected. The Environmentek Division of the Council for Scientific and Industrial Research (Durban) is involved in an ongoing chemical assessment of heavy metal contamination (including levels of mercury) in the sediments of this estuary, but nothing is currently understood about the form in which mercury exists or the biological processes that could be determining its fate. The purpose of this project was to attempt to answer some of these questions. The study involved attempting to isolate, identify and quantify microorganisms of the species Desulfovibrio desulfuricans, Escherichia coli and Clostridium perfringens in one hundred and eighty sediment samples taken from three designated sites in the bay. Each sample was additionally analysed for total and methyl mercury and sulfate content, as well as a number of physical parameters. Based on the outcome of the initial survey, it was envisaged that further laboratory experimentation would be conducted to determine whether or not isolates were responsible for the production of the highly toxic organic mercury and whether this process was occurring in situ in the sediments. The findings of this project were contrary to what had been expected. Total mercury concentrations (apart from one instance) did not appear to be appreciably elevated in the areas under study. Similarly, the levels of methyl mercury were fourrd to be either diminished or absent. Numbers of D. desulfuricans were low and not uniformly distributed throughout the sediments. Cl. perfringens was more in evidence, but counts were not perceptibly increased. Sulfate levels were consistently high, indicating significantly impaired rates of sulfate reduction. Difficulty experienced in sub-culturing

On the contribution of background sources to the heavy metal content of municipal sewage sludge

2001 ◽  
Vol 43 (2) ◽  
pp. 67-74 ◽  
Author(s):  
M. Koch ◽  
W. Rotard
Keyword(s):  
Heavy Metal ◽  
Drinking Water ◽  
Sewage Sludge ◽  
Metal Content ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
Faecal Excretion ◽  
Soil Application ◽  
Metal Load

The role of human excretion, drinking water, and deposition as a source of heavy metals to municipal sewage was investigated and compared with common levels in sludge for soil application. These sources contributed more than half of the copper (Cu), zinc (Zn), and lead (Pb) content of municipal sewage sludge for soil application, while other sources dominated the fluxes of chromium (Cr) and cadmium (Cd). Drinking water was an important source for Cu and Zn. Deposition contributed about 40% to the Pb flux. Faecal excretion commonly caused less than 10% of the heavy metal load, while urinary excretion was here a negligible heavy metal source.

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