scholarly journals The SPARC Data Initiative: comparisons of CFC-11, CFC-12, HF and SF<sub>6</sub> climatologies from international satellite limb sounders

2016 ◽  
Vol 8 (1) ◽  
pp. 61-78 ◽  
Author(s):  
S. Tegtmeier ◽  
M. I. Hegglin ◽  
J. Anderson ◽  
B. Funke ◽  
J. Gille ◽  
...  
Keyword(s):  
Time Series ◽  
Satellite Data ◽  
Lower Stratosphere ◽  
Atmospheric Transport ◽  
Temporal Structure ◽  
Data Sets ◽  
Upper Troposphere ◽  
Mean Fields ◽  
Mean State

Abstract. A quality assessment of the CFC-11 (CCl3F), CFC-12 (CCl2F2), HF, and SF6 products from limb-viewing satellite instruments is provided by means of a detailed intercomparison. The climatologies in the form of monthly zonal mean time series are obtained from HALOE, MIPAS, ACE-FTS, and HIRDLS within the time period 1991–2010. The intercomparisons focus on the mean biases of the monthly and annual zonal mean fields and aim to identify their vertical, latitudinal and temporal structure. The CFC evaluations (based on MIPAS, ACE-FTS and HIRDLS) reveal that the uncertainty in our knowledge of the atmospheric CFC-11 and CFC-12 mean state, as given by satellite data sets, is smallest in the tropics and mid-latitudes at altitudes below 50 and 20 hPa, respectively, with a 1σ multi-instrument spread of up to ±5 %. For HF, the situation is reversed. The two available data sets (HALOE and ACE-FTS) agree well above 100 hPa, with a spread in this region of ±5 to ±10 %, while at altitudes below 100 hPa the HF annual mean state is less well known, with a spread ±30 % and larger. The atmospheric SF6 annual mean states derived from two satellite data sets (MIPAS and ACE-FTS) show only very small differences with a spread of less than ±5 % and often below ±2.5 %. While the overall agreement among the climatological data sets is very good for large parts of the upper troposphere and lower stratosphere (CFCs, SF6) or middle stratosphere (HF), individual discrepancies have been identified. Pronounced deviations between the instrument climatologies exist for particular atmospheric regions which differ from gas to gas. Notable features are differently shaped isopleths in the subtropics, deviations in the vertical gradients in the lower stratosphere and in the meridional gradients in the upper troposphere, and inconsistencies in the seasonal cycle. Additionally, long-term drifts between the instruments have been identified for the CFC-11 and CFC-12 time series. The evaluations as a whole provide guidance on what data sets are the most reliable for applications such as studies of atmospheric transport and variability, model–measurement comparisons and detection of long-term trends. The data sets will be publicly available from the SPARC Data Centre and through PANGAEA (doi:10.1594/PANGAEA.849223).

scholarly journals The SPARC Data Initiative: comparisons of CFC-11, CFC-12, HF and SF<sub>6</sub> climatologies from international satellite limb sounders

2015 ◽  
Vol 8 (2) ◽  
pp. 759-808
Author(s):  
S. Tegtmeier ◽  
M. I. Hegglin ◽  
J. Anderson ◽  
B. Funke ◽  
J. Gille ◽  
...  
Keyword(s):  
Time Series ◽  
Satellite Data ◽  
Lower Stratosphere ◽  
Atmospheric Transport ◽  
Temporal Structure ◽  
Data Sets ◽  
Upper Troposphere ◽  
Mean Fields ◽  
Mean State

Abstract. A quality assessment of the CFC-11 (CCl3F), CFC-12 (CCl2F2), HF, and SF6 products from limb-viewing satellite instruments is provided by means of a detailed inter-comparison. The climatologies in the form of monthly zonal mean time series are obtained from HALOE, MIPAS, ACE-FTS, and HIRDLS within the time period 1991–2010. The inter-comparisons focus on the mean biases of the monthly and annual zonal mean fields and aim to identify their vertical, latitudinal and temporal structure. The CFC evaluations (based on MIPAS, ACE-FTS and HIRDLS) reveal that the uncertainty in our knowledge of the atmospheric CFC-11 and CFC-12 mean state, as given by satellite data sets, is smallest in the tropics and mid-latitudes at altitudes below 50 and 20 hPa, respectively, with a 1-sigma multi-instrument spread of up to ±5 %. For HF, the situation is reversed. The two available data sets (HALOE and ACE-FTS) agree well above 100 hPa with a spread in this region of ±5 to ±10 %, while at altitudes below 100 hPa the HF annual mean state is less well known with a spread ±30 % and larger. The atmospheric SF6 annual mean states derived from two satellite data sets (MIPAS and ACE-FTS) show only very small differences with a spread of less than ±5 % and often below ±2.5 %. While the overall agreement among the climatological data sets is very good for large parts of the upper troposphere and lower stratosphere (CFCs, SF6) or middle stratosphere (HF), individual discrepancies have been identified. Pronounced deviations between the instrument climatologies exist for particular atmospheric regions which differ from gas to gas. Notable features are differently shaped isopleths in the subtropics, deviations in the vertical gradients in the lower stratosphere and in the meridional gradients in the upper troposphere, and inconsistencies in the seasonal cycle. Additionally, long-term drifts between the instruments have been identified for the CFC-11 and CFC-12 time series. The evaluations as a whole provide guidance on what data sets are the most reliable for applications such as studies of atmospheric transport and variability, model-measurement comparisons and detection of long-term trends. The data sets will be publicly available from the SPARC Data center and through PANGAEA (doi:10.1594/PANGAEA.849223).

scholarly journals Global HCFC-22 measurements with MIPAS: retrieval, validation, global distribution and its evolution over 2005–2012

2016 ◽  
Vol 16 (5) ◽  
pp. 3345-3368 ◽  
Author(s):  
M. Chirkov ◽  
G. P. Stiller ◽  
A. Laeng ◽  
S. Kellmann ◽  
T. von Clarmann ◽  
...  
Keyword(s):  
Time Series ◽  
Satellite Data ◽  
Lower Stratosphere ◽  
Positive Trend ◽  
Altitude Range ◽  
Quasi Biennial Oscillation ◽  
Near Surface ◽  
Upper Troposphere ◽  
The Tropics ◽  
Balloon Measurements

Abstract. We report on HCFC-22 data acquired by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) in the reduced spectral resolution nominal observation mode. The data cover the period from January 2005 to April 2012 and the altitude range from the upper troposphere (above cloud top altitude) to about 50 km. The profile retrieval was performed by constrained nonlinear least squares fitting of modelled spectra to the measured limb spectral radiances. The spectral ν4-band at 816.5 ± 13 cm−1 was used for the retrieval. A Tikhonov-type smoothing constraint was applied to stabilise the retrieval. In the lower stratosphere, we find a global volume mixing ratio of HCFC-22 of about 185 pptv in January 2005. The rate of linear growth in the lower latitudes lower stratosphere was about 6 to 7 pptv year−1 in the period 2005–2012. The profiles obtained were compared with ACE-FTS satellite data v3.5, as well as with MkIV balloon profiles and cryosampler balloon measurements. Between 13 and 22 km, average agreement within −3 to +5 pptv (MIPAS – ACE) with ACE-FTS v3.5 profiles is demonstrated. Agreement with MkIV solar occultation balloon-borne measurements is within 10–20 pptv below 30 km and worse above, while in situ cryosampler balloon measurements are systematically lower over their full altitude range by 15–50 pptv below 24 km and less than 10 pptv above 28 km. MIPAS HCFC-22 time series below 10 km altitude are shown to agree mostly well to corresponding time series of near-surface abundances from the NOAA/ESRL and AGAGE networks, although a more pronounced seasonal cycle is obvious in the satellite data. This is attributed to tropopause altitude fluctuations and subsidence of polar winter stratospheric air into the troposphere. A parametric model consisting of constant, linear, quasi-biennial oscillation (QBO) and several sine and cosine terms with different periods has been fitted to the temporal variation of stratospheric HCFC-22 for all 10°-latitude/1-to-2-km-altitude bins. The relative linear variation was always positive, with relative increases of 40–70 % decade−1 in the tropics and global lower stratosphere, and up to 120 % decade−1 in the upper stratosphere of the northern polar region and the southern extratropical hemisphere. Asian HCFC-22 emissions have become the major source of global upper tropospheric HCFC-22. In the upper troposphere, monsoon air, rich in HCFC-22, is instantaneously mixed into the tropics. In the middle stratosphere, between 20 and 30 km, the observed trend is inconsistent with the trend at the surface (corrected for the age of stratospheric air), hinting at circulation changes. There exists a stronger positive trend in HCFC-22 in the Southern Hemisphere and a more muted positive trend in the Northern Hemisphere, implying a potential change in the stratospheric circulation over the observation period.

scholarly journals On a new assessment method for long-term chemistry-climate simulations in the UTLS based on IAGOS data: application to MOCAGE CCMI-REFC1SD simulation

2020 ◽  
Author(s):  
Yann Cohen ◽  
Virginie Marécal ◽  
Béatrice Josse ◽  
Valérie Thouret
Keyword(s):  
Climate Models ◽  
Lower Stratosphere ◽  
Global Scale ◽  
Assessment Method ◽  
Data Sets ◽  
Observation Data ◽  
Data Set ◽  
Upper Troposphere ◽  
Airborne Measurements

Abstract. A wide variety of observation data sets are used to assess long-term simulations provided by chemistry-climate models (CCMs) and chemistry-transport models (CTMs). However, the upper troposphere – lower stratosphere (UTLS) has hardly been assessed in the models yet. Observations performed in the framework of IAGOS (In-service Aircraft for a Global Observing System) combine the advantages of in situ airborne measurements in the UTLS with an almost global-scale sampling, a ~ 20-year monitoring period and a high frequency. If a few model assessments have been made using IAGOS database, none of them took advantage of the dense and high-resolution cruise data in their whole ensemble yet. The present study proposes a method to compare this large IAGOS data set to long-term simulations used for chemistry-climate studies. For this purpose, a new software (named Interpol-IAGOS) projects all IAGOS data on the 3D grid of the chosen model with a monthly resolution, since generally chemistry-climate models provide 3D outputs as monthly means. This provides a new IAGOS data set (IAGOS-DM) mapped at the model's grid and time resolution. As a first application, the REF-C1SD simulation generated by MOCAGE CTM in the framework of CCMI phase-I has been evaluated during the 1994–2013 period for ozone and the 2002–2013 period for carbon monoxide. This comparison is exclusively based on the grid cells sampled by IAGOS, thus the assessed model output (MOCAGE-M) is obtained by applying a corresponding mask onto the grid. First, climatologies are derived from the IAGOS-DM product. Good correlations are reported between IAGOS-DM and MOCAGE-M spatial distributions. As an attempt to analyse MOCAGE-M behaviour in the upper troposphere (UT) and the lower stratosphere (LS) separately, UT and LS data in IAGOS-DM were sorted according to potential vorticity. From this, we derived O3 and CO seasonal cycles in eight regions well sampled by IAGOS flights in the northern mid-latitudes. They are remarkably well-reproduced by the model for lower-stratospheric O3 and also good for upper-tropospheric CO. The data projection onto the model's grid is a necessary step for a more accurate assessment, as it allows to filter out biases only due to either spatial or temporal resolution. Beyond the MOCAGE REF-C1SD evaluation presented in this paper, the method could be used by CCMI models for individual assessments in the UTLS and for model intercomparisons with respect to IAGOS data set.

scholarly journals Analysis of HCl and ClO time series in the upper stratosphere using satellite data sets

2010 ◽  
Vol 10 (4) ◽  
pp. 8623-8655
Author(s):  
A. Jones ◽  
J. Urban ◽  
D. P. Murtagh ◽  
C. Sanchez ◽  
K. A. Walker ◽  
...  
Keyword(s):  
Time Series ◽  
Satellite Data ◽  
Atmospheric Chemistry ◽  
Montreal Protocol ◽  
Data Sets ◽  
Sigma Level ◽  
Chlorine Monoxide ◽  
The Tropics ◽  
Chemistry Experiment

Abstract. Previous analyses of satellite and ground-based measurements of hydrogen chloride (HCl) and chlorine monoxide (ClO) have suggested that total inorganic chlorine in the upper stratosphere is on the decline. We create HCl and ClO time series using satellite data sets with the intension of extending them to beyond November 2008 so that an update can be made on the long term evolution of these two species. We use the HALogen Occultation Experiment (HALOE) and the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) data for the HCl analysis, and the Odin Sub-Millimetre Radiometer (SMR) and the Aura Microwave Limb Sounder (Aura-MLS) measurements for the study of ClO. Altitudes between 35 and 45 km and three latitude bands between 60° S–60° N for HCl, and 20° S–20° N for ClO are studied. HCl shows values to be reducing from peak 1997 values by −4.4% in the tropics and between −6.4% to −6.7% per decade in the mid-latitudes. Trend values are significantly different from a zero trend at the 2 sigma level. ClO is decreasing in the tropics by −7.1% ± 7.8%/decade based on measurements made from December 2001. As both of these species contribute most to the chlorine budget at these altitudes then HCl and ClO should decrease at similar rates. The results found here confirm how effective the 1987 Montreal protocol objectives and its amendments have been in reducing the total amount of inorganic chlorine.

scholarly journals Construction of merged satellite total O<sub>3</sub> and NO<sub>2</sub> time series in the tropics for trend studies and evaluation by comparison to NDACC SAOZ measurements

2014 ◽  
Vol 7 (10) ◽  
pp. 3337-3354 ◽  
Author(s):  
M. Pastel ◽  
J.-P. Pommereau ◽  
F. Goutail ◽  
A. Richter ◽  
A. Pazmiño ◽  
...  
Keyword(s):  
Time Series ◽  
Lower Stratosphere ◽  
Atmospheric Composition ◽  
Data Sets ◽  
Composition Change ◽  
Long Time ◽  
Uv Visible ◽  
The Tropics ◽  
Lower Noise ◽  
Total Column

Abstract. Long time series of ozone and NO2 total column measurements in the southern tropics are available from two ground-based SAOZ (Système d'Analyse par Observation Zénithale) UV-visible spectrometers operated within the Network for the Detection of Atmospheric Composition Change (NDACC) in Bauru (22° S, 49° W) in S-E Brazil since 1995 and Reunion Island (21° S, 55° E) in the S-W Indian Ocean since 1993. Although the stations are located at the same latitude, significant differences are observed in the columns of both species, attributed to differences in tropospheric content and equivalent latitude in the lower stratosphere. These data are used to identify which satellites operating during the same period, are capturing the same features and are thus best suited for building reliable merged time series for trend studies. For ozone, the satellites series best matching SAOZ observations are EP-TOMS (1995–2004) and OMI-TOMS (2005–2011), whereas for NO2, best results are obtained by combining GOME version GDP5 (1996–2003) and SCIAMACHY – IUP (2003–2011), displaying lower noise and seasonality in reference to SAOZ. Both merged data sets are fully consistent with the larger columns of the two species above South America and the seasonality of the differences between the two stations, reported by SAOZ, providing reliable time series for further trend analyses and identification of sources of interannual variability in the future analysis.

scholarly journals Flexible approach for quantifying average long-term changes and seasonal cycles of tropospheric trace species

2019 ◽  
Author(s):  
David D. Parrish ◽  
Richard G. Derwent ◽  
Simon O'Doherty ◽  
Peter G. Simmonds
Keyword(s):  
Time Series ◽  
Seasonal Cycle ◽  
Linear Trend ◽  
Power Series Expansion ◽  
Mathematical Representation ◽  
Seasonal Cycles ◽  
Data Sets ◽  
Significant Information ◽  
Long Term Changes

Abstract. We present an approach to derive a systematic mathematical representation of the statistically significant features of the average long-term changes and seasonal cycle of concentrations of trace tropospheric species. The results for two illustrative data sets (time series of baseline concentrations of ozone and N2O at Mace Head, Ireland) indicate that a limited set of seven or eight parameter values provides this mathematical representation for both example species. This method utilizes a power series expansion to extract more information regarding the long-term changes than can be provided by oft-employed linear trend analyses. In contrast, the quantification of average seasonal cycles utilizes a Fourier series analysis that provides less detailed seasonal cycles than are sometimes represented as twelve monthly means; including that many parameters in the seasonal cycle representation is not usually statistically justified, and thereby adds unnecessary noise to the representation and prevents a clear analysis of the statistical uncertainty of the results. The approach presented here is intended to maximize the statistically significant information extracted from analyses of time series of concentrations of tropospheric species regarding their mean long-term changes and seasonal cycles, including non-linear aspects of the long-term trends. Additional implications, advantages and limitations of this approach are discussed.

Long-term temporal structure analysis of sediment fluxes in the Upper Changjiang (Yangtze River) using a wavelet transformation

2021 ◽  
Author(s):  
Noelia Garijo ◽  
Carmelo Juez ◽  
Marwan Hassan ◽  
Estela Nadal-Romero
Keyword(s):  
Time Series ◽  
Yangtze River ◽  
Wavelet Transformation ◽  
Temporal Structure ◽  
Land Use Changes ◽  
River Networks ◽  
Physical Processes ◽  
Full Spectrum ◽  
Sediment Fluxes

&lt;p&gt;Temporal fluctuations of suspended sediment fluxes are highly related with the flow and sediment regime of river networks. Flow dynamics are mainly triggered by climatic forces. Conversely, sediment regime is majorly controlled by land cover/land use changes and by human infrastructures (e.g. dams). Resulting sediment fluxes thus show a non-linear and non-stationary nature.&amp;#160; The wavelet transformation technique emerges as a skilful tool capable of dealing with this type of data. It allows to distinguish within the full spectrum of time-scales, those which are dominant and thus govern the overall trend of the time-series. Furthermore, the temporal multiresolution wavelet technique allows to accurately denoise the discharge and SSC time-series, filtering out the high frequency intermittent physical processes which are superimposed on the main signal. In this research, we analyse a long-term dataset of discharge and sediment fluxes time-series for the Upper Changjiang (Yangtze River, China).&lt;/p&gt;

scholarly journals Transport of short-lived halocarbons to the stratosphere over the Pacific Ocean

2020 ◽  
Vol 20 (2) ◽  
pp. 1163-1181
Author(s):  
Michal T. Filus ◽  
Elliot L. Atlas ◽  
Maria A. Navarro ◽  
Elena Meneguz ◽  
David Thomson ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Lower Stratosphere ◽  
Atmospheric Transport ◽  
Convective Transport ◽  
Transport Processes ◽  
Lagrangian Model ◽  
Convection Scheme ◽  
Model Calculations ◽  
Upper Troposphere ◽  
Tropical Troposphere

Abstract. The effectiveness of transport of short-lived halocarbons to the upper troposphere and lower stratosphere remains an important uncertainty in quantifying the supply of ozone-depleting substances to the stratosphere. In early 2014, a major field campaign in Guam in the western Pacific, involving UK and US research aircraft, sampled the tropical troposphere and lower stratosphere. The resulting measurements of CH3I, CHBr3 and CH2Br2 are compared here with calculations from a Lagrangian model. This methodology benefits from an updated convection scheme that improves simulation of the effect of deep convective motions on particle distribution within the tropical troposphere. We find that the observed CH3I, CHBr3 and CH2Br2 mixing ratios in the tropical tropopause layer (TTL) are consistent with those in the boundary layer when the new convection scheme is used to account for convective transport. More specifically, comparisons between modelled estimates and observations of short-lived CH3I indicate that the updated convection scheme is realistic up to the lower TTL but is less good at reproducing the small number of extreme convective events in the upper TTL. This study consolidates our understanding of the transport of short-lived halocarbons to the upper troposphere and lower stratosphere by using improved model calculations to confirm consistency between observations in the boundary layer, observations in the TTL and atmospheric transport processes. Our results support recent estimates of the contribution of short-lived bromocarbons to the stratospheric bromine budget.

scholarly journals Comparison of GPS tropospheric delays derived from two consecutive EPN reprocessing campaigns from the point of view of climate monitoring

2016 ◽  
Vol 9 (9) ◽  
pp. 4861-4877 ◽  
Author(s):  
Zofia Baldysz ◽  
Grzegorz Nykiel ◽  
Andrzej Araszkiewicz ◽  
Mariusz Figurski ◽  
Karolina Szafranek
Keyword(s):  
Time Series ◽  
Point Of View ◽  
Trend Test ◽  
Data Sets ◽  
Total Delay ◽  
University Of Technology ◽  
Time Period ◽  
Seasonal Signals ◽  
Linear Trends

Abstract. The main purpose of this research was to acquire information about consistency of ZTD (zenith total delay) linear trends and seasonal components between two consecutive GPS reprocessing campaigns. The analysis concerned two sets of the ZTD time series which were estimated during EUREF (Reference Frame Sub-Commission for Europe) EPN (Permanent Network) reprocessing campaigns according to 2008 and 2015 MUT AC (Military University of Technology Analysis Centre) scenarios. Firstly, Lomb–Scargle periodograms were generated for 57 EPN stations to obtain a characterisation of oscillations occurring in the ZTD time series. Then, the values of seasonal components and linear trends were estimated using the LSE (least squares estimation) approach. The Mann–Kendall trend test was also carried out to verify the presence of linear long-term ZTD changes. Finally, differences in seasonal signals and linear trends between these two data sets were investigated. All these analyses were conducted for the ZTD time series of two lengths: a shortened 16-year series and a full 18-year one. In the case of spectral analysis, amplitudes of the annual and semi-annual periods were almost exactly the same for both reprocessing campaigns. Exceptions were found for only a few stations and they did not exceed 1 mm. The estimated trends were also similar. However, for the reprocessing performed in 2008, the trends values were usually higher. In general, shortening of the analysed time period by 2 years resulted in a decrease of the linear trends values of about 0.07 mm yr−1. This was confirmed by analyses based on two data sets.

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